Corrosion

CORROSION < Electrical Circuit Anode, cathode, electrolyte Electro-chemical means Hydrogen gas Hydroxyl iron oxides <
< Chemical Reactions Temperature, hygroscopic salt, SRB and MEM, acid and alkalis, bi-metallic corrosion Galvanic list or electro motive forces or electro-chemical series. < Millscale FeO, Fe3O4, Fe2O3 or Wustite, Magnetite, Haematite 25 to 100 m SURFACE PREPARATIONS METHODS AND STANDARDS < Dry abrasive blast cleaning Compressor, blast pot, vapour traps, carbon impregnated hose, nozzle, dead mans valve 100 psi at 450 mph for venturi and 100 psi at 200 mph for straight bore SI 1657 less 1% free silica, COSHH REGS Rogue peak, hackle, lamination Molecular interference and attraction Surface profile, anchor pattern, key, peak to trough height and amplitude Replica tape / testex / cornplaster method paper, mylar tough transparent polyester plastic, testes paste Coarse grade 20 to 50 m and Extra Coarse grade 37 to 115 m BS 7079 Pt C or ISO 8503.1 assessing using comparator by naked eye, visual aid and tactite BS 7079 Pt A or ISO 8501 or SIS 055900 Rust Grade A, B, C, D Wheelabrator 220 mph nozzle 103 cfm 100 psi and 1/2 413 100 psi Phosphor bronze material for wire brush < Water Blasting < High pressure water blasting up to 30000 psi < High pressure water plus abrasive injection < Low pressure plus abrasive injection < Steam cleaning < Air Blasting with water injection < Hand and power tool cleaning < Flame cleaning Expansion, dehydration, heat penetration < Pickling Footners Duplex System solvent, sulphuric acid (5 to 10% at 65C for 5 to 25 min), rinse, phosphate ( 2 % at 80C for 2 min), rinse, ph 4.5 to 7.0 < Vapour degreasing < Weathering SURFACE CONTAMINANTS AND TEST FOR DETECTION Qualitative and Quantitative Soluble Iron Salts Potassium Ferrycyanide Test, Merkoquant and Bresle Chlorides Silver nitrate test
Millscle Copper sulphate Test
PAINT CONSTITUENTS AND BASIC TECHNOLOGY Barrier, Passivation and Cathodic Protection Enviromental Protection Act 1990 MCL multi component liquids Binder ease of application , adhesion to substrate, resistance to abrasion and chemical, cohesive strength, low permeability, change applied liquid to solid Acylic synthetic resins, can be used w/ HC solvents and H2O. Good colour retention, good film properties, can be modified w/ other binder. Alkyd from alcohol-acid reaction Ashphaltic bitumens thermoplastic matl, water proof, poor resistance to UV and solvents Cellulose resins synthetic matl, not used for industrial coating, reversible matl. Chlorinated rubber organic resins from reaction of rubber with chlorine, resistant to alkalies and Acids and poor resistance to HC solvent. Advantages (6), disadvantages (3) Emulsions Epoxies synthetic organic resin, resistance to chemical, solvent and water.durable. Ethyl and methyl silicates inorganic matl, excellent weathering, solvent and heat resistance. Binder is a silicate w/ contains high % of zinc dust Natural oils slow drying, modified w/ other binders, produced from seeds of plant (vegetable) Drying oil drying by ambient temp Semi-drying oil drying by heat addition or catalyst Non drying oil will not oxidize and cannot be used as binder.can be used as plasticizers. Oil and resins ratio to give binder: Long oil - > 60% oil to resin, elastic, slow drying Medium oil 45% to 60% Short oil - < 45% oil to resin, Natural resins brittle and fast drying, not soluble in water Oleoresinous mixture of oil and resin, faster drying Phenolic resins from phenol, excellent adhesion and resistance to heat and chemicals. were used In temp where chlorinated rubber cannot be used > 65 C. Commonly called hot drying oils. Polyurethanes moisture curing, 2 pack, chemically curing and single pack. Synthetic w/ Outstanding abrasion resistance and chemical, good color exterior gloss with min. chalking Silicones high temp matl above 150C, aluminium pigmented and used to seal zinc silicates Styrene Vinyl similar matl as chlorinated rubber but use a different solvent not like chlorinated rubber Only one solvent Polymers Hydrogen, Carbon, Nitrogen, Oxygen, Chlorine Linear, Branched and Cross linked Methane saturated, Ethane saturated, Ethylene or Ethyne unsaturated Pigments opacity, glossiness, resistance to UV, additives to paint properties Dye being dissolve Rust inhibitive or anti-corrosive read lead, calcium plumbate, coal tar, zinc chromate, zinc phosphate, barium metaborate, zinc phosphosilicate Metallic pigments zinc and aluminium Opaque pigments Extender pigments Laminar pigments CPVC BS 2015

Corrosion

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CORROSION < Electrical Circuit Anode, cathode, electrolyte Electro-chemical means Hydrogen gas Hydroxyl iron oxides <

Millscle Copper sulphate Test

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