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Ceramic: From Wikipedia, The Free Encyclopedia

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Ceramic
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Fixed Partial Denture, or "Bridge"

18th century (Qing dynasty) Chinese porcelain vase

A ceramic is an inorganic, non-metallic solid prepared by the action of heat and


subsequent cooling.[1] Ceramic materials may have a crystalline or partly crystalline
structure, or may be amorphous (e.g., a glass). Because most common ceramics are
crystalline, the definition of ceramic is often restricted to inorganic crystalline materials,
as opposed to the non-crystalline glasses.

The earliest ceramics were pottery objects made from clay, either by itself or mixed with
other materials. Ceramics now includes domestic, industrial and building products and art
objects. In the 20th century new ceramic materials were developed for use in advanced
ceramic engineering, for example, in semiconductors.
The word ceramic comes from the Greek word κεραμικός (keramikos) meaning pottery,
which is said to derive from the Indo-European word ker, meaning heat.[2][3] Ceramic may
be used as an adjective describing a material, product or process; or as a singular noun,
or, more commonly, as a plural noun, ceramics.[4]

Contents
[hide]

• 1 Types of ceramic products


o 1.1 Examples of whiteware ceramics
o 1.2 Classification of technical ceramics
• 2 Other applications of ceramics
• 3 Types of ceramic materials
o 3.1 Crystalline ceramics
o 3.2 Non-crystalline ceramics
• 4 See also
• 5 References

• 6 External links

[edit] Types of ceramic products


For convenience ceramic products are usually divided into four sectors, and these are
shown below with some examples:

• Structural, including bricks, pipes, floor and roof tiles


• Refractories, such as kiln linings, gas fire radiants, steel and glass making
crucibles
• Whitewares, including tableware, wall tiles, pottery products, and sanitary ware
• Technical, is also known as Engineering, Advanced, Special, and in Japan, Fine
Ceramics. Such items include tiles used in the Space Shuttle program, gas burner
nozzles, ballistic protection, nuclear fuel uranium oxide pellets, bio-medical
implants, jet engine turbine blades, and missile nose cones. Frequently the raw
materials do not include clays.[5]

[edit] Examples of whiteware ceramics

• Earthenware, which is often made from clay, quartz and feldspar.


• Stoneware
• Porcelain, which are often made from kaolin
• Bone china

[edit] Classification of technical ceramics


Technical ceramics can also be classified into three distinct material categories:

• Oxides: Alumina, zirconia


• Non-oxides: Carbides, borides, nitrides, silicides
• Composites: Particulate reinforced, combinations of oxides and non-oxides.

Each one of these classes can develop unique material properties.

[edit] Other applications of ceramics


• Ceramics are used in the manufacture of knives. The blade of a ceramic knife will
stay sharp for much longer than that of a steel knife, although it is more brittle and
can be snapped by dropping it on a hard surface.

• Ceramics such as alumina and boron carbide have been used in ballistic armored
vests to repel large-calibre rifle fire. Such plates are known commonly as small-
arms protective inserts (SAPI). Similar material is used to protect cockpits of
some military airplanes, because of the low weight of the material.

• Ceramic balls can be used to replace steel in ball bearings. Their higher hardness
means that they are much less susceptible to wear and can offer more than triple
lifetimes. They also deform less under load meaning they have less contact with
the bearing retainer walls and can roll faster. In very high speed applications, heat
from friction during rolling can cause problems for metal bearings; problems
which are reduced by the use of ceramics. Ceramics are also more chemically
resistant and can be used in wet environments where steel bearings would rust.
The two major drawbacks to using ceramics is a significantly higher cost, and
susceptibility to damage under shock loads. In many cases their electrically
insulating properties may also be valuable in bearings.

• In the early 1980s, Toyota researched production of an adiabatic ceramic engine


which can run at a temperature of over 6000°F (3300°C). Ceramic engines do not
require a cooling system and hence allow a major weight reduction and therefore
greater fuel efficiency. Fuel efficiency of the engine is also higher at high
temperature, as shown by Carnot's theorem. In a conventional metallic engine,
much of the energy released from the fuel must be dissipated as waste heat in
order to prevent a meltdown of the metallic parts. Despite all of these desirable
properties, such engines are not in production because the manufacturing of
ceramic parts in the requisite precision and durability is difficult. Imperfection in
the ceramic leads to cracks, which can lead to potentially dangerous equipment
failure. Such engines are possible in laboratory settings, but mass-production is
not feasible with current technology.[citation needed]

• Work is being done in developing ceramic parts for gas turbine engines.
Currently, even blades made of advanced metal alloys used in the engines' hot
section require cooling and careful limiting of operating temperatures. Turbine
engines made with ceramics could operate more efficiently, giving aircraft greater
range and payload for a set amount of fuel.

• Recently, there have been advances in ceramics which include bio-ceramics, such
as dental implants and synthetic bones. Hydroxyapatite, the natural mineral
component of bone, has been made synthetically from a number of biological and
chemical sources and can be formed into ceramic materials. Orthopedic implants
made from these materials bond readily to bone and other tissues in the body
without rejection or inflammatory reactions. Because of this, they are of great
interest for gene delivery and tissue engineering scaffolds. Most hydroxyapatite
ceramics are very porous and lack mechanical strength and are used to coat metal
orthopedic devices to aid in forming a bond to bone or as bone fillers. They are
also used as fillers for orthopedic plastic screws to aid in reducing the
inflammation and increase absorption of these plastic materials. Work is being
done to make strong, fully dense nano crystalline hydroxyapatite ceramic
materials for orthopedic weight bearing devices, replacing foreign metal and
plastic orthopedic materials with a synthetic, but naturally occurring, bone
mineral. Ultimately these ceramic materials may be used as bone replacements or
with the incorporation of protein collagens, synthetic bones.

• High-tech ceramic is used in watchmaking for producing watch cases. The


material is valued by watchmakers for its light weight, scratch-resistance,
durability and smooth touch. IWC is one of the brands that initiated the use of
ceramic in watchmaking. The case of the IWC 2007 Top Gun edition of the Pilot's
Watch Double chronograph is crafted in high-tech black ceramic.[6]

[edit] Types of ceramic materials


A ceramic material is often understood as restricted to inorganic crystalline oxide
material. It is solid and inert. Ceramic materials are brittle, hard, strong in compression,
weak in shearing and tension. They withstand chemical erosion that occurs in other
materials subjected to acidic or caustic environment. Ceramics generally can withstand
very high temperatures such as temperatures that range from 1,000°C to 1,600°C
(1,800°F to 3,000°F). Exceptions include inorganic materials that do not include oxygen
such as silicon carbide or silicon nitride. A glass is often not understood as a ceramic
because of its amorphous (non-crystalline) character. However, glass making involves
several steps of the ceramic process and its mechanical properties are similar to ceramic
materials.

Traditional ceramic raw materials include clay minerals such as kaolinite, whereas more
recent materials include aluminium oxide, more commonly known as alumina. The
modern ceramic materials, which are classified as advanced ceramics, include silicon
carbide and tungsten carbide. Both are valued for their abrasion resistance, and hence
find use in applications such as the wear plates of crushing equipment in mining
operations. Advanced ceramics are also used in the medicine, electrical and electronics
industries.
[edit] Crystalline ceramics

Crystalline ceramic materials are not amenable to a great range of processing. Methods
for dealing with them tend to fall into one of two categories - either make the ceramic in
the desired shape, by reaction in situ, or by "forming" powders into the desired shape, and
then sintering to form a solid body. Ceramic forming techniques include shaping by hand
(sometimes including a rotation process called "throwing"), slip casting, tape casting
(used for making very thin ceramic capacitors, etc.), injection moulding, dry pressing,
and other variations. (See also Ceramic forming techniques. Details of these processes are
described in the two books listed below.) A few methods use a hybrid between the two
approaches.

[edit] Non-crystalline ceramics

Non-crystalline ceramics, being glasses, tend to be formed from melts. The glass is
shaped when either fully molten, by casting, or when in a state of toffee-like viscosity, by
methods such as blowing to a mold. If later heat-treatments cause this glass to become
partly crystalline, the resulting material is known as a glass-ceramic.

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