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Bragg Diffraction Experiment

1. The document describes an experiment using Bragg diffraction to determine the molecular structure of a foam crystal sample. Microwaves are directed at the crystal from different angles and the reflected intensities are measured. 2. In part A, peaks in reflection are detected and used to calculate the spacing of molecules in the original and side orientations of the crystal. A 3D model of the crystal structure is drawn. 3. In part B, the crystal's orientation is hidden and reflection peaks again give spacing data, allowing prediction of which face is being measured for verification.

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Vednivead
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© Attribution Non-Commercial (BY-NC)
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Download as PDF, TXT or read online on Scribd
379 views

Bragg Diffraction Experiment

1. The document describes an experiment using Bragg diffraction to determine the molecular structure of a foam crystal sample. Microwaves are directed at the crystal from different angles and the reflected intensities are measured. 2. In part A, peaks in reflection are detected and used to calculate the spacing of molecules in the original and side orientations of the crystal. A 3D model of the crystal structure is drawn. 3. In part B, the crystal's orientation is hidden and reflection peaks again give spacing data, allowing prediction of which face is being measured for verification.

Uploaded by

Vednivead
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
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Year 12

Physics

Synchrotron

Bragg Diffraction Experiment


BACKGROUND THEORY Braggs Law derived in 1913 by the English physicists Sir W.H. Bragg and his son Sir W.L. Bragg to explain why crystals appear to reflect X-ray beams at certain angles of incidence. Bragg's Law: n = 2d sin

Where d is the distance between atomic layers in a crystal, is the wavelength in metres of the incident beam, is the angle of incidence; and n is an integer representing the number of wavelengths required for constructive interference to occur. At the smallest angle of incidence () for a maxima n = 1, at the next smallest angle n = 2, etc. Braggs Law is an example of X-ray wave interference or X-ray diffraction (XRD), and is used to determine the atomic structure of crystals. The Braggs were awarded the Nobel Prize in physics in 1915 for their work in determining crystal structures (NaCl, ZnS and diamond).

dsin d

dsin

Extra distance travelled by photon that enters the second layer is twice dsin = 2dsin. If this equals a whole number of wavelengths of the incident beam then constructive interference occurs. The reflected beam will be detected at a higher intensity.

Although Bragg's law was used to explain the interference pattern of X-rays scattered by crystals, diffraction has been developed to study the structure of all kinds of matter with a beam, as long as the wavelength used is comparable to the spacing of the molecules (or atoms) within the object under investigation. In this experiment microwaves will be used with a frequency roughly 1/50,000th lower than the X-rays the Braggs used. This will allow the measurement of crystal spacings 50,000 times greater than those found in compounds such as diamond or sodium chloride (NaCl).

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Year 12 APPARATUS Microwave transmitter and receiver Foam Crystal Large Protractor 2 1 metre ruler Aluminium barrier METHOD PART A

Physics

Synchrotron

1. Align one straight edge of the foam crystal along the base of the large protractor as shown in figure 1. 2. Place the aluminium sheet barrier on the 90o line of the protractor. 3. Place the microwave transmitter and receiver on the small blocks provided to raise them off the desk surface. 4. Point the microwave transmitter toward the face of the foam crystal at an initial angle of ~30o. Similarly align the receiver at 30o to the face of the foam crystal to detect the reflected beam. See figure 1. (Hint: using 1 metre rulers to align the receiver and transmitter can save considerable time in setting up) 5. Set the transmitter to the CW (continuous wave) and switch on. CAUTION: Never allow the transmitter to be directed towards a persons eyes at any time. Damage to the retinas is possible!
FOAM CRYSTAL

Figure 1

Transmitter

Aluminium sheild

Receiver

6. Switch the receiver on and use the gain control (1 4) to adjust the sensitivity of the meter. 7. Gradually move both the transmitter and receiver closer to the foam crystal face by reducing the angle. Ensure both devices are at the same angle at the same time. 8. Record any angles () when a marked increase is detected by the receiver. 9. Reset the apparatus as in steps 13 and repeat but gradually increase the value of this time. Each new peak will represent a value for n 10. Use Braggs Law to determine the spacing of the molecules in the foam crystal in this plane. 11. Repeat steps 19 with the foam crystal now placed on its side. See Figure 2. 12. Draw a 3-D model of the molecular structure of the foam crystal

Figure 2.

Original orientation of foam crystal

Alternate orientation of foam crystal on its side

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Year 12

Physics

Synchrotron

RESULTS Record the angle () at which maximum readings were recorded for each orientation of the foam crystal. Stop if = 90o. You do not need to fill in every line. Original Orientation n 1 2 3 4 5

Alternate (side) Orientation n 1 2 3 4 5

Calculations using Braggs Law to determine the spacing (d) of the molecules: d = n/2sin (microwave wavelength, = 2.8 cm) Original Orientation Alternate (side) Orientation

3-D Model of Foam Crystal

d1 d2

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Year 12 PART B Powder Diffraction

Physics

Synchrotron

1. Place the foam crystal in a cardboard or opaque plastic container, so that the orientation of the face cannot be seen. This container hides the direction of the face. 2. Place the container on the protractor randomly. Ensure that the foam crystal overlaps the straight edge. 3. Place the transmitter on the 0o line and put the aluminium barrier against the box edge on the 90o line again. 4. Move the receiver slowly from 0o towards 90o recording any angles of high intensity. 5. This time the angle recorded will equal 2. 6. Calculate the molecular spacing. 7. Predict which face of the foam crystal the transmitter is directed at. Use your answers from PART A to assist you. 8. Open the container and check your prediction.

CONCLUSION Which of the methods (Part A or B) was easiest to actually perform? Explain your choice.

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Year 12

Physics

Synchrotron

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