Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.

ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 1 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

MATERIAL SAFETY DATA SHEET

SECTION 1 - IDENTIFICATION
Product identifier Product Code(s) Product Use Chemical Family Suppliers name and address: : : : :

ALKI-FOAM
AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124) Refrigeration coil cleaner. Mixture.
Manufacturers name and address:

Parker Hannifin Corporation - Sporlan Division

206 Lange Drive Washington,MO, U.S.A. 63090
Information Telephone # 24 Hr. Emergency Tel # : :

Refer to Supplier

(636) 239-1111 Chemtrec 1-800-424-9300 (Within Continental U.S.); Chemtrec 703-527-3887 (Outside U.S.).

SECTION 2 - HAZARDS IDENTIFICATION

Classification :

WHMIS information: This product is a WHMIS Controlled Product. It meets one or more of the criteria for a controlled product provided in Part IV of the Canadian Controlled Products Regulations (CPR). WHMIS classification: Class E (Corrosive Material). OSHA: This material is classified as hazardous under OSHA regulations (29CFR 1910.1200). Hazardous classification: Acute Health Hazard; Chronic Health Hazard. Purple liquid. Bland odour. DANGER! Contact with some reactive metals may produce flammable hydrogen gas. May be corrosive to metals. Corrosive material. Causes eye, skin and digestive tract burns. Severe respiratory irritant. Could result in pulmonary edema (fluid accumulation).

Emergency Overview

POTENTIAL HEALTH EFFECTS:

Signs and symptoms of short-term (acute) exposure

Inhalation : If mists are formed, may cause severe irritation to the nose, throat and respiratory tract. Symptoms
may include coughing, choking and wheezing. Could result in pulmonary edema (fluid accumulation). Symptoms of pulmonary edema (chest pain, shortness of breath) may be delayed.

Skin Eyes Ingestion

: Direct skin contact may cause corrosive skin burns, deep ulcerations and possibly permanent
scarring.

: Causes severe burns. Contact may lead to permanent injury and blindness. : May cause severe irritation and corrosive damage in the mouth, throat and stomach. Symptoms

may include abdominal pain, vomiting, burns, perforations, bleeding and eventually death. Effects of long-term (chronic) exposure : Chronic skin contact with low concentrations may cause dermatitis. Carcinogenic status : See TOXICOLOGICAL INFORMATION, Section 11.
Additional health hazards Potential environmental effects : :

See TOXICOLOGICAL INFORMATION, Section 11. See ECOLOGICAL INFORMATION, Section 12.

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 2 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients
sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

CAS #

Wt.%

1310-73-2 68515-73-1 527-07-1 6834-92-0

15.00 - 40.00 1.00 - 5.00 0.50 - 1.50 0.50 - 1.50

SECTION 4 - FIRST AID MEASURES

Inhalation :

Skin contact

Eye contact Ingestion

: :

Notes For Physician

Immediately remove person to fresh air. If breathing has stopped, give artificial respiration. Keep warm and in a quiet place. If breathing is difficult, give oxygen by qualified medical personnel only. Seek immediate medical attention/advice. Immediately remove contaminated clothing and shoes. Flush affected skin with gently flowing lukewarm water for at least 20 minutes. Seek immediate medical attention/advice. Wash contaminated clothing before re-use. Leather and shoes that have been contaminated with the solution may need to be destroyed. Immediately flush eyes with running water for at least 20 minutes. Protect unharmed eye. Seek immediate medical attention/advice. Do NOT induce vomiting. Have victim rinse mouth with water, then give one to two glasses of water to drink. Never give anything by mouth to an unconscious person. Seek immediate medical attention/advice. Immediate medical attention is required. Corrosive. Treat symptomatically.

SECTION 5 - FIRE FIGHTING MEASURES

Fire hazards/conditions of flammability :

Not flammable under normal conditions of handling. Closed containers are contained under pressure and may explode if exposed to excess heat for a prolonged period of time. Contact with metals may release small amounts of flammable hydrogen gas.

Flammability classification (OSHA 29 CFR 1910.1200) : Non-flammable. Oxidizing properties :

None known.

Explosion data: Sensitivity to mechanical impact / static discharge : Not expected to be sensitive to mechanical impact or static discharge.

Use media suitable to the surrounding fire such as water fog or fine spray, alcohol foams, carbon dioxide and dry chemical. Some chemical extinguishing agents may react with this material. Special fire-fighting procedures/equipment : Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. A full-body chemical resistant suit should be worn. Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame. Avoid spreading burning liquid with water spray used for cooling purposes. Hazardous combustion products : Carbon oxides; Hydrogen; Sodium oxides.
Suitable extinguishing media : NFPA Rating :

0 - Minimal Health: 3

1 - Slight 2 - Moderate 3 - Serious 4 - Severe Flammability: 0 Instability: 1 Special Hazards:

None.

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 3 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Personal precautions :

Environmental precautions Spill response/cleanup

: :

Prohibited materials Special spill response procedures

: :

Restrict access to area until completion of clean-up. Keep all other personnel upwind and away from the spill/release. Individuals involved in the cleanup must wear appropriate personal protective equipment. Refer to protective measures listed in sections 7 and 8. Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. Ventilate area of release. Stop the spill at source if it is safe to do so. Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent material into a container for later disposal (see Section 13). Recovered solutions can be carefully diluted with water and then neutralized with acids, such as acetic acid (vinegar) or hydrochloric acid. Flush any residue in the spill area with water. Do not flush into surface water or sanitary sewer system. Notify the appropriate authorities as required. None known or reported by the manufacturer. If a spill/release in excess of the EPA reportable quantity is made into the environment, immediately notify the national response center in the United States (phone: 1-800-424-8802). US CERCLA Reportable quantity (RQ): sodium hydroxide (1000 lbs / 454 kg)

SECTION 7 - HANDLING AND STORAGE

Safe Handling procedures :

Storage requirements

Incompatible materials Special packaging materials

: :

Wear chemically resistant protective equipment during handling. Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with eyes, skin and clothing. Keep away from extreme heat and flame. Keep away from acids and other incompatibles. Always replace cap after use. Wash thoroughly after handling. Keep out of the reach of children. Store in a cool, dry, well ventilated area. Store away from incompatibles and out of direct sunlight. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. No smoking in the area. Inspect periodically for damage or leaks. Store in corrosion-resistant containers. Avoid contact with aluminum. Acids; Metals (e.g. tin, aluminum, zinc and alloys containing these metals). Always keep in containers made of the same materials as the supply container.

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limits
ACGIH TLV Ingredients
sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

OSHA PEL STEL

N/Av N/Av N/Av N/Av

TWA
2 mg/m (Ceiling) N/Av N/Av N/Av

PEL
2 mg/m N/Av N/Av N/Av

STEL
N/Av N/Av N/Av N/Av

Ventilation and engineering measures :

Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits.

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 4 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

Respiratory protection :

In case of insufficient ventilation wear suitable respiratory equipment. Use NIOSH/MSHA approved full-face respirator with an organic vapour cartridge if the recommended exposure limit is exceeded. Respirators should be selected based on the form and concentration of contaminants in air, and in accordance with OSHA (29 CFR 1910.134) or CSA Z94.4-02. Advice should be sought from respiratory protection specialists. Wear impervious gloves, such as butyl rubber. Advice should be sought from glove suppliers. Chemical splash goggles must be worn when handling this material. Do not wear contact lenses. A full face shield may also be necessary. An eyewash station and safety shower should be made available in the immediate working area. Where extensive exposure to product is possible, use resistant coveralls, apron and boots to prevent contact. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Do not eat, drink, smoke or use cosmetics while working with this product. Upon completion of work, wash hands before eating, drinking, smoking or use of toilet facilities. Remove soiled clothing and wash it thoroughly before reuse.

Skin protection Eye / face protection Other protective equipment

: : :

General hygiene considerations :

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical state Odour pH Boiling point Melting/Freezing point : : : : :

Liquid. Bland odour. 13.5 - 14 100C (212F) N/Av

Appearance Odour threshold Specific gravity

: Purple liquid. : N/Av : 1.2

Coefficient of water/oil distribution : N/Av Solubility in water : miscible

Vapour pressure (mmHg @ 20 C / 68 F) : same as water Vapour density (Air = 1) :

>1

Evaporation rate (n-Butyl acetate = 1) :<1 Volatiles (% by weight) : 80.2%

Volatile organic Compounds (VOC's) : N/Av Flash point Flash point Method Lower flammable limit (% by vol.) : Flame Projection Length Viscosity Absolute pressure of container : N/Ap : :

: None.
:

N/Av N/Ap N/Ap < 10 cPs

Auto-ignition temperature

: N/Av : N/Ap

Upper flammable limit (% by vol.) Flashback observed : N/Ap

SECTION 10: STABILITY AND REACTIVITIY

Stability and reactivity :

Hazardous polymerization Conditions to avoid

: :

Stable at ambient temperatures and pressures. Closed containers may build up pressure when exposed to heat and flame. Contact with metals may release small amounts of flammable hydrogen gas. May be corrosive to Aluminum. Hazardous polymerization does not occur.

Keep out of direct sunlight. Avoid contact with incompatible materials. Do not use in areas without adequate ventilation. Materials To Avoid And Incompatibility : See Section 7 (Handling and Storage) for further details.
Hazardous decomposition products : None known, refer to hazardous combustion products in Section 5.

SECTION 11 - TOXICOLOGICAL INFORMATION

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 5 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

Target organs Routes of exposure Toxicological data : : :

Eyes, skin, respiratory system and digestive system.

Inhalation: YES

Skin Absorption:

NO

Skin & Eyes:

YES

Ingestion:

YES

There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data.
LC50(4hr) LD50

Ingredients
sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

inh, rat
N/Av N/Av N/Av N/Av

(Oral, rat)
N/Av N/Av N/Av 600 mg/kg

(Rabbit, dermal)
N/Av N/Av N/Av >4640 mg/kg

Carcinogenic status Reproductive effects Teratogenicity Mutagenicity Epidemiology Sensitization to material Synergistic materials Irritancy other important hazards

: : : : : : : : :

No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Not expected to cause reproductive effects. Not expected to be a teratogen. Not expected to be mutagenic in humans. Not available. Not expected to be a skin or respiratory sensitizer. N/Av Corrosive None known or reported by the manufacturer.

Conditions aggravated by overexposure : Pre-existing skin, eye and respiratory disorders.

SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicity :

See the following tables for individual ingredient ecotoxicity data.

Ecotoxicity data:

Toxicity to Fish
Ingredients CAS No
1310-73-2 68515-73-1 527-07-1 6834-92-0

LC50 / 96h
125 mg/L (Mosquito fish) 2.95 mg/L (Zebra fish) > 100 mg/L (Japanese ricefish) 210 mg/L (Zebra fish)

NOEC / 21 day
N/Av N/Av N/Av N/Av

M Factor
None. None. None. None.

sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

Ingredients

CAS No EC50 / 48h

Toxicity to Daphnia
NOEC / 21 day
N/Av 1 - 4 mg/L (Water flea) N/Av N/Av

M Factor
None. None. None. None.

sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

1310-73-2 68515-73-1 527-07-1 6834-92-0

40 mg/L (Water flea) 7 - 14 mg/L (Water flea) N/Av N/Av

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 6 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

Ingredients

CAS No EC50 / 96h or 72h

Toxicity to Algae
NOEC / 96h or 72h
N/Av N/Av N/Av N/Av

M Factor
None. None. None. None.

sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

1310-73-2 68515-73-1 527-07-1 6834-92-0

N/Av 5 - 12.5 mg/L/72hr (Green algae) > 1000 mg/L/72hr (Green algae) N/Av

Mobility Persistence Bioaccumulation potential

: : : :

No data is available on the product itself. No data is available on the product itself. No data is available on the product itself. No data is available on the product itself.

Other Adverse Environmental effects

SECTION 13 - DISPOSAL CONSIDERATIONS

Handling for Disposal Methods of Disposal RCRA : : :

Handle waste according to recommendations in Section 7. Empty containers retain residue (liquid and/or vapour) and can be dangerous. Improper disposal can cause damage to the environment. Dispose in accordance with all applicable federal, state, provincial and local regulations. If this product, as supplied, becomes a waste in the United States, it may meet the criteria of a hazardous waste as defined under RCRA, Title 40 CFR 261. It is the responsibility of the waste generator to determine the proper waste identification and disposal method. For disposal of unused or waste material, check with local, state and federal environmental agencies.

SECTION 14: TRANPORT INFORMATION

Regulatory Information
TDG

UN Number
UN1760

Shipping Name
CORROSIVE LIQUID, N.O.S. (sodium hydroxide )

Class
8

Packing Group
II

Label

TDG Additional information

May be shipped as LIMITED QUANTITY when transported in containers no larger than 1.0 Litre, in packages not exceeding 30 kg gross mass. Under the TDGR, refer to Section 1.17 for additional exemption information, if shipping under this exemption. NA1760 Compound, Cleaning Liquid (sodium hydroxide ) 8 II

49CFR/DOT

49CFR/DOT Additional information

May be shipped as LIMITED QUANTITY when transported in containers no larger than 1.0 Litre, in packages not exceeding 30 kg gross mass. Refer to 49 CFR Section 173.154. UN1760 Corrosive liquid, n.o.s. (sodium hydroxide ) 8 II

ICAO/IATA

ICAO/IATA Additional information

Refer to the appropriate Packing Instruction, prior to shipping this material. Review all State and Operator Variations, prior to shipping this material. UN1760 CORROSIVE LIQUID, N.O.S. (sodium hydroxide) 8 II

IMDG

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 7 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

IMDG Additional information

May be shipped as Limited Quantity when transported in containers no larger than 1.0 Litre, in packages not exceeding 30 kg gross mass. May be shipped as a Limited Quantity according to the IMDG Code Chapter 3.4.

SECTION 15 - REGULATORY INFORMATION

US Federal Information:

Components listed below are present on the following U.S. Federal chemical lists:
SARA TITLE III: Sec. 302, Extremely Hazardous Substance, 40 CFR 355:

Ingredients

CAS #

TSCA Inventory

CERCLA Reportable Quantity(RQ) (40 CFR 117.302):

SARA TITLE III: Sec. 313, 40 CFR 372, Specific Toxic Chemical
Toxic Chemical de minimus Concentration

sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

1310-73-2 68515-73-1 527-07-1 6834-92-0

Yes Yes Yes Yes

1000 lb/ 454 kg N/Ap N/Ap N/Ap

N/Av N/Ap N/Ap N/Ap

No No No No

No No No No

SARA TITLE III: Sec. 311 and 312, MSDS Requirements, 40 CFR 370 Hazard Classes: Acute Health Hazard. Chronic Health Hazard. Under SARA Sections 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
US State Right to Know Laws:

The following chemicals are specifically listed by individual States:

California Proposition 65 Ingredients CAS # Listed Type of Toxicity CA MA MN NJ PA RI State "Right to Know" Lists

sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

1310-73-2 68515-73-1 527-07-1 6834-92-0

No No No No

N/Ap N/Ap N/Ap N/Ap

Yes No No No

Yes No No No

Yes No No No

Yes No No No

Yes No No No

Yes No No No

Canadian Information:

WHMIS information: Refer to Section 2 for a WHMIS Classification for this product. Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS contains all the information required by the CPR. International Information:

Components listed below are present on the following International Inventory list:

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 8 of 9
Australia AICS Philippines PICCS Japan ENCS Korea KECI/KECL China IECSC NewZealand IOC

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

Ingredients CAS #
European EINECs

sodium hydroxide Polyglycidyl Decyl Ether Sodium Gluconate Sodium metasilicate, anhydrous

1310-73-2 68515-73-1 527-07-1 6834-92-0

215-185-5 N/Av 208-407-7 229-912-9

Present Present Present Present

Present Present Present Present

(2)-1972; (1)-410 (5)-287 (2)-1410 (1)-508

KE-31487 KE-10718 KE-17676 KE-12354

Present Present Present Present

HSR001547 Not listed Present HSR003511

SECTION 16 - OTHER INFORMATION

HMIS Rating :

- Chronic hazard Health: *3

0 - Minimal 1 - Slight Flammability:

2 - Moderate 0

3 - Serious Reactivity:

4 - Severe 1

Legend

ACGIH: American Conference of Governmental Industrial Hygienists AICS: Australian Inventory of Chemical Substances CAS: Chemical Abstract Services CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of 1980 CFR: Code of Federal Regulations DOT: Department of Transportation EINECS: European Inventory of Existing Commercial chemical Substances ENCS: Existing and New Chemical Substances HMIS: Hazardous Materials Identification System HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation IOC: Inventory of Chemicals KECI: Korean Existing Chemicals Inventory KECL: Korean Existing Chemicals List LC: Lethal Concentration LD: Lethal Dose MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NFPA: National Fire Protection Association NIOSH: National Institute of Occupational Safety and Health NOEC: No observable effect concentration NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit PICCS: Philippine Inventory of Chemicals and Chemical Substances RCRA: Resource Conservation and Recovery Act RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System

Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington, MO 63090 U.S.A.
ALKI-FOAM

AKF1 (P/N 475117); AKF5 (P/N 475121); AKF55 (P/N 475124)

Page 9 of 9

MSDS Revision Date (mm/dd/yyyy): 11/14/2013

References :

1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2013. 2. International Agency for Research on Cancer Monographs, searched 2013. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2013 (Chempendium, HSDB and RTECs). 4. Material Safety Data Sheets from manufacturer. 5. US EPA Title III List of Lists - October 2012 version. 6. California Proposition 65 List - September 27, 2013 version.

Prepared for:
Parker Hannifin Corporation - Sporlan Division 206 Lange Drive; Washington, MO 63090 U.S.A. Telephone: (636) 239-1111 www.sporlan.com Direct all enquiries to: Parker Hannifin Corp. - Sporlan Division.

Prepared by:
ICC The Compliance Center Inc.

http://www.thecompliancecenter.com

DISCLAIMER OF LIABILITY
This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by / obtained from Parker Hannifin Corp and CCOHS Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and Parker Hannifin Corp expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Parker Hannifin Corp.
Preparation Date (mm/dd/yyyy) : MSDS Revision Date (mm/dd/yyyy) : Revision No. Revision Information : :

09/06/2012

11/14/2013 2 (M)SDS sections updated: 3. COMPOSITION/INFORMATION ON INGREDIENTS 12. ECOLOGICAL INFORMATION 15. REGULATORY INFORMATION

END OF DOCUMENT