Chemical Bonding - Multiple Choice Questions 1. The ion that isoelectronic with CO is a. CNb. O2+ c. O2d.

N2+ (JEE 1982) ans: (a) isoelectronic means same number of electrons 2. carbon tetrachloride has no net dipole moment because of a. its planar structure b. its regular tetrahedral structure c. similar sizes of carbon and chlorine atoms d. similar electron affinities of carbon and chlorine (JEE 1983) ans (b) 3. which one among the following does not have the hydrogen bond? a. phenol b. liquid NH3 c. water d. liquid HCl (JEE 1983) Ans: (d) 4. the types of bonds present in CuSO4.5H2O are only a. b. c. d. electrovalent and covalent electrovalent and coordinate covalent electrovalent, covalent and coordinate covalent covalent and coordinate covalent

5. On hybridization of one s and one p orbitals we get: a.two mutually perpendicular orbitals b. two orbital at 180 c. four orbitals directed tetrahedrally d. three orbital in a plane (JEE 1984) Answer: (b) 6. the molecule having one unpaired electron is: a. NO b. CO c. CNd. O2 (JEE 1985)

Ans: (a) 7. The bond between two identical non-metal atoms has a pair of electrons: a. unequally shared between the two. b.transferred fully from one atom to another c. with identical spins d. equally shared between them (JEE 1986) Ans: (d) 8. the hydrogen bond is strongest in: a. O-H S b. S-H O c. F-H S d. F-H...O (JEE 1986) Answer: ( c ) 9. The hybridization of sulphur dioxide is: a. sp b. sp c. dsp d. sp (JEE 1986) answer (b) 10. The bonds present in N2O5 are ______ a. only ionic b. covalent and coordinate c. only covalent d. covalent and ionic (JEE 1986) ans: (b) Posted by KVSSNrao at 10:30 AM No comments: Labels: Chemical bonding, Multiple choice questions SATURDAY, JULY 5, 2008 Chemical Bonding - True or False Type 1. Linear overlap of two atomic p-orbitals leads to a sigma bond. (JEE 1983) True 2. The H-N-H bond angle in NH3 is greater than the H-As-H bond angle in AsH3. True Reason: Repulsion is more in NH3 which makes the bond angle greater than in AsH3 . 3. All molecules with polar bonds have dipole moment. (JEE 1985)

False. Reason; If symmetrical arrangement of atoms is there, there is no dipole moment. Example CCl4. 4. SnCl2 is nonlinear molecule. (JEE 1985) True There is a lone pair in the bond. Due to repulsion between Lone pair and bonding pair, the bond angle less than 180. 5. sp hybrid orbitals have equal s and p character. False sp hybrid use one s orbital and 2 p orbital for hydridisation. Hence sp hybrid orb itals have 1/3 s character and 2/3 p character. 6. All the Al-Cl bonds in Al2Cl6 are equivalent. (JEE 1989) False The terminal Al-Cl bonds are different from the bridge Al-Cl bonds. 7. Nitric oxide, though an odd electron molecule, is diamagnetic in liquid state . (JEE 1991) False In liquid state, some dimerization takes place, but it is only partial. So it is still paramagnetic only. 8. Dipole moment of CH3F is greater than CH3Cl. (JEE 1993) False Bond distance is more in CH3Cl and hence more dipole moment. Dipole moment = charge * distance Posted by KVSSNrao at 9:35 AM No comments: Labels: Chemical bonding, True or false type TUESDAY, JULY 1, 2008 Chemical Bonding - 11 - Fill in the Blanks Type Questions Fill in the blanks 1. There are ____________________ ? (pi) bonds in a nitrogen molecule. (JEE 1982 ) Anwer : 2 2. __________ hybrid orbitals of nitrogen are involved in the formation of ammon ium ion. (JEE 1982) Answer sp 3. The terminal carbon atom in butane is _____________ hybridized. (JEE 1985) Answer sp

The shape of [CH3] + is ------------------------. (JEE 1990)

Answer: Triangular planar The valence atomic orbitals of carbon in silver acetylide is _________________. (JEE 1990) Answer: sp IN P4O10, the number of oxygen atoms bonded to each phosphorus atom is _________ ___ . (JEE 1992) Answer: 4 When N2 goes to N2+ The N N bond distance _________ and when O2 goes to )2+, the O O bond distance _____ _________. (JEE 1996) Answer: increases, decreases Posted by KVSSNrao at 8:22 AM No comments: Labels: Chemical bonding, Fill-in-the blanks Chemical Bonding - 12 - True or False type Questions State whether the following statements are True or False. 1. Linear overlap of two atomic p-orbitals leads to a sigma bond. (JEE 1983) True 2. The H-N-H bond angle in NH3 is greater than the H-As-H bond angle in AsH3. (J EE 1984) True. Repulsion among bonds is more in NH3 and it makes bond angle greater. 3. All molecules with polar bonds have dipole moment. (JEE 1985) False. Symmetrical molecules will have zero dipole moment. 4. SnCl2 is nonlinear molecule (JEE 1985) True 5. sp2 hybrid orbitals have equal s- and p- character (JEE 1987) False. One third s and two thirds p. The presence of polar bonds in a polyatomic molecules suggests that molecule has non-zero dipole moment (JEE 1990) False. Some polyatomic molecules having polar bonds have zero dipole moment. H2O molecule is linear. (JEE 1993) False. It is V-shaped. The dipole moment of CH3F is greater than that of CH3Cl. (JEE 1993) False. Dipole moment in CH3F is less than CH3Cl as bond length is shorter in CH3 F. Remember the definition of dipole moment from physics.

=============================================================== http://www.geekmcq.com/chemistry/chemical-bonding/ Entry Test MCQ :: Chemical Bonding 1. The relative attraction of the nucleus for the electrons in a chemical b ond is called A. Ionization energy B. Electron affinity C. Electro negativity D. None of the above Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 2. The ionization energy A. Generally increases from left to right in a period B. Does not change in a period C. Increase from top to bottom in a group D. Does not change in a gro up Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 3. Which of the following will have highest value of electron affinity A. F B. Cl C. Br D. I Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 4. Which type of bond is formed by overlap of p orbitals A. Pi (?) B. Sigma(?) C. Both D. Neither Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 5. The octet rule does not always hold for which of the following elements A. C B. O C. F D. P Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 6. Which of the solid does not contain covalent bond A. Copper B. Ice C. Diamond D. Graphite Answer & Explanation

Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 7. Which of the following is the best explanation that CO2 is non polar mol ecule A. Linear geometry B. Dipole moment is zero C. Sp hybridization D. None Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 8. Shielding effect across the period A. Increases B. Decreases C. Constant D. None Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 9. Which one is not the absolute term of the element? A. Ionization energy B. Electron affinity C. Electro negativity D. Atomic size Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 10. Which one has maximum number of unpaired electrons? A. 6X B. 7Y C. 9Z D. 13W Answer & Explanation Answer: Option B Explanation: 11. The molecule having ?-bond A. H2O B. C2H6 C. O2 D. NH3 Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 12. When 2 lone pair and 2 bond pair are around the central atom reduction i n the bond angle is up to. A. 109.5? B. 104.5? C. 107.5? D. 102? Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum

13. In O2 each oxygen atom is hybridized A. sp3 B. sp2 C. sp D. All Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 14. Molecular orbitals are filled according to A. Auf bau principle B. Hunds rule C. Paulis Exclusion principle D. All these Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 15. Measurement of the degree of polarity is A. Electron affinity B. Ionic character C. Ionization energy D. Dipole moment Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 16. Which one shows high %age of the ionic character? A. H2O B. HF C. HCI D. HBr Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 17. A specie with maximum number of unpaired electrons. A. F B. H2O C. HF D. NH-2 Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 18. Which of the following have their outer most shell complete in atomic fo rm? A. Noble gases B. Alkali metals C. Coinage metals D. Gun metals Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 19. Force responsible to hold atoms together in a compound is called A. Bond B. Attractive force C. Interaction D. All of above represent same entity Answer & Explanation Answer: Option A

Explanation: View Answer Workspace Report Discuss in Forum 20. Energy of atom in compound is A. Higher than individual B. Lesser than individual C. No change D. Impossible to predict Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 21. In a period the atomic radii A. Increases B. Decreases C. Remain same D. First decreases then increases Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 22. An atom loses or gains electrons to A. Gain stability B. Form a bond C. Complete its outermost shell D. Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 23. In a group ionic radii A. Increases B. Decreases C. No change D. Variable trend Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 24. Energy required to remove electron from an atom A. Ionization potential B. Electronegativity C. Electron affinity D. Activation energy Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 25. Ionization energy in a period generally A. Increases B. Decreases C. No change D. Variable trend Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 26. Greater shielding effect corresponds to ionization energy value

all are accurate justifications

A. Greater B. C. Remain same Answer & Explanation Answer: Option B Explanation:

Lesser D. No effect

View Answer Workspace Report Discuss in Forum 27. Elements having high I.P values are A. Metals B. Non metals C. Liquids D. Solids Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 28. Energy released or absorbed when electrons are added in atom is A. Ionization potential B. Electronegativity C. Electron affinity D. Activation energy Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 29. In a period electronegativity from left to right A. Increases B. Decreases C. Remain constant D. Variable trend Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 30. Ionic bond is produced after complete transfer of A. Nucleus B. Neutrons C. Electrons D. Protons Answer & Explanation Answer: Option C Explanation: Elements of group IA IIA are A. Electronegative B. Electropositive C. Neutral D. IA is electropositive while IIA is electronegative Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 32. Bond will beionic when E.N difference of bonded atom is A. Equal to 1.7 B. Greater than 1.7 C. Less than 1.7 D. No specificity exists Answer & Explanation Answer: Option B Explanation:

View Answer Workspace Report Discuss in Forum 33. Mostly ionic compound are produced in between elements of A. IA and VIA B. IA IIA and VIIA C. IB and VIIB D. IA and IB Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 34. Which one of the following has polar covalent bond? A. HF B. CH4 C. H2 D. N2 Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 35. The Lewis acids are A. Electron deficient B. Electron rich C. Octet is complete D. No such acids exist View Answer Workspace Report Discuss in Forum 36. Sharing of 1 electron pair by one specie forms A. Single covalent bond B. Hydrogen bond C. Double covalent bond D. Coordinate covalent bond Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 37. Angle in water molecule is A. 104.9? B. 104.5? C. 109.5? D. 120? Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 38. The geometry of ammonia is A. Tetrahedral B. Square planner C. Trigonal bipyramidal D. Trigonal Pyramidal Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 39. Orbitals of same energy produced after mixing of orbitals of different e nergy are called A. Degenerate orbitals B. Generate orbitals C. Hybrid orbitals D. Zeeman orbitals Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum

40. By combining n atmic orbitals no. of hybrid orbitals will be A. 2n B. n C. 3n D. impossible to predict Answer & Explanation Answer: Option B Explanation: 41. on sp3 hybridization A. All p-orbitals are involved ved C. one p-orbital is involved Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 42. Geometry of simple molecule having sp3 hybrid orbital is A. Triangular B. Tetrahedral C. Square planner D. Linear Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 43. Geometry of molecule will be pyramidal if the outer post shell of the ce ntral atom has A. 3 bond pair one lone pair B. 2 bond pair 2 lone pair C. 1 bond pair 3 lone pair D. 3 lone pair 1 bond pair Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 44. Pi bonds are produced by overlapping of A. Un-hybrid orbitals B. Hybrid orbitals C. Hybrid and un hybrid orbitals D. atomic orbital and hybrid orbita l Answer & Explanation Answer: Option A Explanation: View Answer Workspace Report Discuss in Forum 45. According to VESPR Model the geometry of molecule having 5 bond pair in outer most shell will be A. Triangular B. Square planner C. Trigonal bipyramidal D. Octahedral Answer & Explanation Answer: Option C Explanation: View Answer Workspace Report Discuss in Forum 46. Molecular orbital which have higher energy than atomic orbitals is calle d A. Bonding molecular orbital B. Antibonding molecular orbital B. D. One s and 3 p-orbitals are invol four p-orbitals are involved

C. Hybrid orbital D. Answer & Explanation Answer: Option B Explanation:

Super atomic orbital

View Answer Workspace Report Discuss in Forum 47. Unpaired electron in a molecule gives _________ character. A. Ferromagnetic B. Paramagnetic C. Diamagnetism D. Both a & b Answer & Explanation Answer: Option B Explanation: View Answer Workspace Report Discuss in Forum 48. Bond order for N2 molecule is A. 2 B. 1 C. 3 D. 4 View Answer Workspace Report Discuss in Forum 49. Product of charge and distance is called A. Pressure B. Bond length C. Work D. Dipole moment Answer & Explanation Answer: Option D Explanation: View Answer Workspace Report Discuss in Forum 50. Unit of dipole moment is A. Debye B. Poise C. Pascal D. Newton Answer & Explanation Answer: Option A Explanation: