Design Assignment
Design Assignment
Design Assignment
1. MANUAL CALCULATIONS
N10 Cl2 N10 Cl2 N11 H2O
N8 C6H6 + Cl2 > C6H5Cl + HCl C6H6 + 2Cl2 > C6H5Cl2 + 2HCl N2 Cl2 N1 C 6H 6 N3 N4 N5 N6 Cl2 C6H6 C6H5Cl C6H4Cl2 HCl N7 Cl2 C6H6 C6H5Cl C6H4Cl2 HCl N12 C6H6 C6H5Cl C6H4Cl2 Cl2 HCl
N13 C6H6
+ 40.7
14.5
29.1
14.5
29.1
( )
( (
) )
( (
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Comment
2. SPREAD SHEET
Assumptions are the same as those of manual calculation stated above. Values shown in the table below are of the streams entering and leaving the reactor. The products of chlorine and benzene are only MCB and DCB. Basis of 1 hour reactor chlorine benzene MCB DCB HCI in 90 100 0 0 0 out 90 100 40.7008 14.5439 69.7886
Table below shows the stream that is entering the condenser and is separated in the vapor and liquid stream. Chlorine and HCl leave as vapour at the top stream and benzene, MCB and DBC leave as the liquid stream at the bottom of the column. condenser/ flush drum chlorine benzene MCB DCB HCL
Table below shows the stream coming in with HCl and chlorine. Chlorine leaving at the top stream is recycled while the one in solution is removed as the bottom stream with HCl absorber chlorine HCl in 20 70 tops 19.80717 bottoms 0.404228 69.7886
kmol kmol
kmol
kmol kmol
Table below shows the light and heavy key components. 95% of benzene is recovered as the light key component and recycled back. The MCB, DBC and the unrecovered benzene is removed as the heavy components at the bottom (reboiler) distillation column benzene MCB DCB
tops 42.465
Results obtained after scaling down reactor in chlorine 0.818985 benzene 0.909983 MCB 0 DCB 0 HCI 0 out 0.18392 0.406762 0.37037 0.132347 0.635064
COMMENT Results obtained are the same as those of the manual calculations. Only advantage is that with the spreadsheet we can vary our input streams and get the solution of the output streams immediately. While for the manual calculations, changing the values of the input streams would mean doing the calculations again. Assumptions made were used to simplify the calculation process
50 1 50 1 50 2 1 B1 3 B2 4
-3 1 50 1 1 50 1 B3 6 168 2
be nzene chlorine re action Strea m ID Temperature P ressure Vapor Frac Mole Flow Ma ss Flow Volum e Flow Enthalpy Ma ss Flow BENZENE CHLORINE WATER HCL C6H5C-01 C6H4C-01 Mole Flow BENZENE CHLORINE WATER HCL C6H5C-01 C6H4C-01 0.680 0.396 0.142 0.667 0.026 0.002 0.013 0.371 0.140 0.013 < 0.001 trac e 0.370 0.140 k mol/hr 0.974 0.877 0.436 0.197 0.137 0.182 0.299 0.015 0.298 0.015 < 0.001 trac e 24.781 44.620 20.819 24.324 2.913 0.278 0.457 41.707 20.540 0.457 0.042 trac e 41.666 20.540 k mol/hr k g/hr cum/hr Gca l/hr k g/hr 76.083 62.156 34.055 13.964 10.724 12.922 23.331 1.042 23.307 1.042 0.023 trac e C ba r 1 50.0 1.000 0.000 0.974 76.083 0.090 0.012 2 50.0 1.000 1.000 0.877 62.156 23.338 < 0.001 3 50.0 1.000 0.548 1.851 138.238 27.120 -0.007 4 50.0 1.000 1.000 1.014 51.161 27.036 -0.011 5 50.0 1.000 0.000 0.836 87.077 0.084 0.004 6 -3.4 1.000 0.000 0.326 24.848 0.027 0.003 7 167.6 2.000 0.000 0.510 62.229 0.063 0.003
COMMENT
RAD12
RADGB2K
RADB4
RADG7K
be nzen e chlor ine r e action Str ea m I D T em p er atur e P r essur e V ap or Fr ac Mo le Flo w Ma ss Flo w E nthalpy Ma ss Flo w BE N ZE N E CH L O RI N E W A T ER H CL C6H 5 C- 0 1 C6H 4 C- 0 1 Mo le Flo w BE N ZE N E CH L O RI N E W A T ER H CL C6H 5 C- 0 1 C6H 4 C- 0 1 0 .4 57 0 .0 22 < 0 .0 01 0 .4 67 0 .3 92 0 .0 37 0 .0 10 0 .3 70 0 .0 37 0 .0 10 < 0 .0 01 tr ac e tr ac e 0 .3 70 0 .0 37 km o l/hr 0 .0 26 0 .5 20 0 .4 67 0 .0 90 tr ac e 0 .0 64 0 .0 54 0 .0 11 16.65 8 2 .5 07 0 .0 63 17.02 7 44.15 8 5 .4 90 0 .3 69 41.65 1 5 .4 27 0 .3 69 0 .0 02 tr ac e tr ac e 41.64 9 5 .4 27 km o l/hr kg/hr G ca l/hr kg/hr 2 .0 11 40.61 1 33.11 3 7 .0 49 tr ac e 5 .0 38 4 .2 00 0 .8 38 C ba r RA D 12 50 .0 1 .0 00 1 .0 00 0 .5 05 21.23 8 13.49 6 - 0.009 RA D G 1K 50 .0 1 .0 00 0 .0 00 0 .5 20 40.61 1 0 .0 48 0 .0 07 RA D G 2K 50 .0 1 .0 00 1 .0 00 0 .4 67 33.11 3 12.43 3 < 0 .0 01 RA D G 3K 50 .0 1 .0 00 1 .0 00 0 .9 87 73.72 4 25.96 9 - 0.003 RA D G 5K 50 .0 1 .0 00 0 .0 00 0 .4 82 52.48 6 0 .0 49 0 .0 02 RA D G 6K - 4 6.9 1 .0 00 0 .0 00 0 .0 64 4 .5 72 0 .0 05 < 0 .0 01 RA D G 7K 1 31.0 1 .0 00 0 .0 00 0 .4 18 47.91 4 0 .0 48 0 .0 03
5. Hazop form
Unit: flash unit
V-1
P-5
V-3
P-4
E-1
P-3
V-2