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The document discusses various types of surfactants used in latex polymerization including alkyl sulfates, alkyl ether sulfates, phosphated esters, alcohol ethoxylates, nonionic substituted phenol derivatives, and anionic substituted phenol derivatives.

The different types of surfactants discussed include alkyl sulfates and sulphonates, alkyl ether sulfates, phosphated esters, alcohol ethoxylates, nonionic substituted phenol derivatives, and anionic substituted phenol derivatives.

Some properties of surfactants mentioned include hydrophobe, ethoxylate (EO) moles, ionic character, solid percentage, and hydrophile-lipophile balance (HLB).

SURFACTANTS

ALKYL SULPHATES AND SULPHONATES


Denomination Hydrophobe EO
moles
Ionic
character
Solid %
(approx)
Salt Remarks and
Applications
Type
of latex
Amepon UB/E-28 C12-C16 - A 28 Na Lower solid, lower pour point
grade.
Geropon ACR/4 Monoalkyl
(Fatty Alcohol)
3 A 30 Na Primary emulsifier to be used
in combination with non-ionic
FA
Geropon ACR/9 Monoalkyl (NP) 9 A 29 Na Primary emulsifier to be used
in combination with non-ionic
FA
Geropon CYA/60 Dialkyl (C8) - A 60 Na Highly effective sulfosuccinate
wetting agent (solvent: IBA)
FA
Geropon CYA/75 Dialkyl (C8) - A 75 Na Highly effective sulfosuccinate
wetting agent (solvent: EtOH)
Geropon DOS Dialkyl (C8) - A 68 Na Highly effective sulfosuccinate
wetting agent (solvent: IPA)
Geropon T/36 DF Olefin - A 25 Na Dispersant for suspension
polymerisation to use in
solvent stripping phase
(toluene/cyclohexane) when
shifting from solvent to
aqueous dispersion avoiding
agglomerations.
SBR
Geropon
BIS SODICO 2
Dialkyl (C13) - A 60 Na Highly effective in PVC
polymerization
PVC
Rhodacal A/246 L Alpha-olefin - A 40 Na Effective surfactant for pure
acrylic latexes.
FA
Rhodacal DS/10 E Branched
Dodecylbenzene
- A 98 Na Solid surfactant in powder form. VeoVa/VAc
VAc
PVA
Rhodacal DS/4 E-25 Linear
Dodecylbenzene
- A 25 Na High performing surfactant for
vinyl latexes.
Veova/VAc
VAc
PVA
Rhodacal DS/4 E-30 Linear
Dodecylbenzene
- A 30 Na High performing surfactant for
vinyl latexes.
VeoVa/VAc
VAc
PVA
ALKYL ETHER SULFATES
Denomination Hydrophobe EO
moles
Ionic
character
Solid %
(approx)
Salt Remarks and
Applications
Type
of latex
Abex 18 S C12-C16 50 A 35 Na Emulsifier especially effective in
polymerisation of vinyl or soft
pure acrylic latexes.
FA
VAc
PVA
Abex 26 S Proprietary - A 35 Na High surface tension = 40
dynes/cm
FA
SA
VAc
Abex EP 110 NP 9 A 30 NH4 Provide good chemical and
mechanical stability + good
electrolyte compatibility.
SA
PVA
Abex EP 120 NP 30 A 30 NH4 Provide good chemical and
mechanical stability + good
electrolyte compatibility.
SA
PVA
Abex JKB C12-C16 12 A 30 NH4 Highly versatile surfactant used
as sole emulsifier in latexes of
particle size 100 - 150 nm.
FA
SA
Abex LIV 30 NP 5 A 30 NH5 Provide good chemical and
mechanical stability + good
electrolyte compatibility.
FA
SA
PVA
Rhodapex AB/20 C12-C15 9 A 29 NH4 Highly versatile surfactant used
as sole emulsifier for particle
size 100 - 150 nm. Appropriate
for PSA formulations.
FA
SA
Rhodapex CO 436 E NP 4 A 28 NH4 Highly versatile surfactant used
as sole emulsifier for particle
size 100 - 150 nm. Appropriate
for PSA formulations.
FA
SA
Rhodapex LA 40 S C12-C16 4 A 31 Na Versatile emulsifier designed
for particle size control in the
range 100-150 nm. Usually
combined with nonionic
FA
SA
Rhodapex TR 2030 S iC13 20 A 30 Na Emulsifier effective as APE SA
Rhodapex TR 2030 S iC13 20 A 30 Na Emulsifier effective as APE
replacement in latexes of
particle size 150 - 200 nm.
Provides outstanding latex
stability.
SA
PHOSPHATED ESTERS
Denomination Hydrophobe EO
moles
Ionic
character
Solid %
(approx)
Salt Remarks and
Applications
Type
of latex
Rhodafac RA-600E C8-C10 4 A 100 Acid Emulsifier for polymerization of
most monomer systems.
Generally effective in PSA
formulations.
FA
SA
VAc
Rhodafac RE-610E NP 9 A 100 Acid Aromatic phosphate ester,
general purpose emulsifier.
FA
SA
VAc
Rhodafac RS-410 iC13 4 A 100 Acid Emulsifier for polymerization of
most monomer systems when
high calcium stability is
required.
FA
SA
VAc
Rhodafac RS-610E iC13 6 A 100 Acid Emulsifier for polymerization of
most monomer systems when
high calcium stability is
required.
FA
SA
VAc
Rhodafac RS-710E iC13 10 A 100 Acid Emulsifier for polymerization of
most monomer systems when
high calcium stability is
required.
FA
SA
VAc
Rhodafac RS-710E-30 iC13 10 A 30 Acid Diluted version of Rhodafac
RS-710E.
FA
SA
VAc
ALCOHOL ETHOXYLATED
Denomination Hydrophobe HLB Ionic
character
Solid %
(approx)
Remarks and
Applications
Type
of latex
Abex 2545 Proprietary 18.3 N 50 Proprietary emulsifier with high HLB
to achieve high chemical stability.
Commonly post added.
Gen
Alkamuls S/20 Sorbitan
Monolaurate
8.6 N 100 Non ethoxylated emulsifier for
inverse emulsion systems
Alkamuls S/80 Sorbitan
Monoleate
4.3 N 100 Non ethoxylated emulsifier for
inverse emulsion systems
Alkamuls T/20 Sorbitan
Monolaurate
16.7 N 100 Ethoxylated version of S/20
Alkamuls T/80 Sorbitan
Monoleato
15.0 N 100 Ethoxylated version of S/80
Antarox FM/33 Fatty Alcohol
EO/PO
- N 100 Block copolymer used as wetting
agent due to its fast migration to
interfaces
Antarox MPL/46A Fatty Alcohol
EO/PO
- N 46 Block copolymer absorbed on Silica;
in powder form. Wetting agent
Rhodasurf 3065 Proprietary 16.5 N 65 Versatile emulsifier with best
performances when used in
combination with low EO sulfated
surfactants.
FA
SA
Rhodasurf 870/H-20 iC13 14.0 N 80 Cost-effective surfactant used as a
nonionic co-emulsifier in
polymerization or post added to
increase stability
Gen
Rhodasurf CET 20 C16-C18 16.2 N 100 Linear, eco-friendly and
multipurpose surfactant for
emulsion polymerisation. In flakes
form
Gen
Rhodasurf LA 30 C12-C16 8.0 N 100 Oil soluble co-emulsifier, visco-
depressant for PVC paste with low
impact on thermal stability
PVC
Rhodasurf LA 40 C12-C16 9.7 N 100 Oil soluble co-emulsifier, visco-
depressant for PVC paste with low
impact on thermal stability
PVC
Rhodasurf ON/870-E C16-C18 15.4 N 100 Linear, eco-friendly and
multipurpose surfactant for
emulsion polymerisation.
Gen
Rhodasurf ROX iC13 12.7 N 85 Cost-effective surfactant used as a
nonionic co-emulsifier in
polymerization or post added to
increase stability
Gen
Rhodasurf S 30 Proprietary 16.5 N 65 Versatile emulsifier with best
performances when used in
combination with low EO sulfated
surfactants.
FA
SA
Rhodasurf TR 3,2 iC13 9.5 N 100 Cost-effective surfactant used as a
nonionic co-emulsifier in
polymerization or post added to
increase stability
Gen
Rhodasurf TR 35/70 iC13 17.7 N 70 Multipurpose surfactant for emulsion Gen
Rhodasurf TR 35/70 iC13 17.7 N 70 Multipurpose surfactant for emulsion
polymerisation. Commonly post
added to get high chemical stability.
Gen
Rhodasurf TR 6 iC13 11.4 N 100 Cost-effective surfactant used as a
nonionic co-emulsifier in
polymerization or post added to
increase stability
Gen
Rhodasurf UN 721 Proprietary 16.8 N 70 Multipurpose surfactant commonly
post added to get high stability.
Gen
NONIONIC SUBSTITUTED PHENOL DERIVATIVES
Denomination Character HLB Ionic
character
Solid %
(approx)
Remarks and
Applications
Type
of latex
Soprophor 796 P EO/PO block
copolymer
- N 100 Emulsifier and dispersant for
increased stability and compatibility
with pigments
FA
SA
Soprophor BSU Ethoxylate 12.6 N 100 Emulsifier and dispersant co-
surfactant for increased compatibility
with pigments
FA
SA
Soprophor S/25 Ethoxylate 14.5 N 100 Emulsifier and dispersant co-
surfactant for increased compatibility
with pigments
FA
SA
ANIONIC SUBSTITUTED PHENOL DERIVATIVES
Denomination Character EO
Moles
Ionic
character
Solid %
(approx)
Salt Remarks and
Applications
Type
of latex
Soprophor 3D33 Phosphated 16 A 100 Acid Unusual hydrophobe. Excellent
compatibility with pigments.
Acid form.
FA
SA
Soprophor 4D384 Sulfated 16 A 100 NH4 Sulfate derivative, high anionic
active level. Partially
neutralised.
FA
SA
Soprophor FL Phosphated 16 A 100 TEA Neutralized version of
Soprophor 3D33
FA
SA
LEGENDA
IONIC CHARACTER
A : A nionic
N: Nonionic
TYPE OF LATEX
FA : Full A crylic(A A , MA A , BA , MMA , EEA , HMA )
V eoV a/V A c: V inil / V eova / A A
V A c: V inil / A crylic
PV A : V inil A cetate
PV C: Poly V inyl Chloride
SBR: Styrene Butadiene Rubber
SA : Styrene A crylic
Gen: General/Multipurpose use
Information herein is believed to be reliable, we do not guarantee its accurancy.

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