Section-I (Single Correct Choice) : HC CH 1.1eq Nanh Nanh Nanh X X
Section-I (Single Correct Choice) : HC CH 1.1eq Nanh Nanh Nanh X X
Section-I (Single Correct Choice) : HC CH 1.1eq Nanh Nanh Nanh X X
ctive
ALCOHOLS, ETHERS AND PHENOLS E M RAO
81. Select the correct statement.
A) D is a racemic mixture. B) A is 4-octene
C) A is 3-octene D) E is 5-octanol
SECTION-IV (Matching)
82.
COLUMN-I COLUMN-II (Distinguishing reagents)
(A) OH
NO
2
NO
2
O
2
N
OH
&
(P) Na
(B) OH
C
2
H
5
OH
&
(Q) NaHCO3
(C) C2H5OH & CH3OCH3 (R) FeCl3
(D) CH2=CHCH2OH & CH3CH2CH2OH (S) MnO2
(T) Br/H2O
83. Match column-I (containing pairs of compounds) with column-II (containing distinguishing reagents)
COLUMN-I COLUMN-II
(A) CH3CH=CH2 and (CH3)3COH
(P)
| |
3 2
Ag(NH )
+
(B) CH3CH=CH2 and CH3CHOHCH3 (Q) Br2/H2O
(C) CH3CH=CH2 and CH3C CH (R) KMnO4
(D) CH3CH2CH2OH and CH3OCH3 (S) Na
84.
COLUMN-I COLUMN-II (Products with HIO4)
(A)
HO
OH
O
OH
(P) CH3CH2COOH and OHCCH2CHO
(B)
HO
OH
O
O
(Q) HCOOH, CO2 and OHCCH2CHO
(C)
O
O
OH
(R) 2 HCOOH and OHCCH2CHO
(D)
HO
OH
OH
OH
(S) CO2, HCOOH, and OHCCH2COOH
ALCOHOLS, ETHERS AND PHENOLS E M RAO
85.
COLUMN-I COLUMN-II
(A)
H
3
O
+
(P)
OH
(B)
1.Hg(OAc)
2
/H
2
O
2. NaBH
4
(Q) OH
(C)
*
1.B
2
H
6
/THF
2. H
2
O
2
;NaOH
(R) OCH
3
(D)
1.Hg(OAc)
2
/CH
3
OH
2. NaBH
4
(S)
OH
ANSWERS
1.B 2.D 3.D 4.D 5.D 6.C 7.A 8.C 9.B 10.A
11.B 12.C 13.A 14.B 15.B 16.D 17.B 18.B 19.A 20.D
21.B 22.A 23.A 24.D 25.B 26.B 27.B 28.B 29.A 30.B
31.B 32.B 33.D 34.A 35.C 36.C 37.B 38.B 39.B 40.C
41.B 42.A 43.A 44.A 45.C 46.B 47.A 48.B 49.B 50.C
51.C 52.A 53.B 54.A 55.C 56.CD 57.ABCD 58.BCD 59.BC 60.AC
61.BD 62.AB 63.AD 64.ACD 65.CD 66.ABCD 67.BC 68.A 69.AB 70.AB
71.B 72.B 73.A 74.D 75.C 76.B 77.B 78.D 79.A 80.C
81.B
82. A-QT B-RT C-P D-ST
83. A-QRS B-QS C-PS D-RS
84. A-Q B-S C-P D-R
85. A-P B-Q C-S D-R