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Lesson 36: de Broglie Wavelengths

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Lesson 36: de Broglie Wavelengths

In 1923 Prince Louis de Broglie proposed a new idea


Could things believed to be particles (like electrons and baseballs so!eti!es
act like waves"
#ll the stu$$ discovered so $ar has shown that what appeared to be waves
(%&' so!eti!es acted like a particle( so de Broglie )ust wanted to know i$
particles could act like waves*
+obod, reall, took de Broglie seriousl, until %instein read his paper and
agreed with his ideas*
de Broglie suggested co!bining a couple o$ $or!ulas( one o$ the! a particle t,pe( the
other a wave t,pe*
p=mv p=
h


mv=
h

=
h
mv
- . wavelength (!
h . Planck/s Constant (alwa,s 0*03e132
! . !ass (kg
v . velocit, (!3s
4his $or!ula allows us to calculate the de Broglie 5avelength o$ a
!oving particle*
6or an ob)ect to have a wavelength( it !ust be !oving*
7a, to da, ob)ects that are around us have wavelengths so s!all
that we can never hope to !easure the!*
Example 18 Determine the de Broglie wavelength o$ a 9*29kg ball
!oving at 1:!3s*
=
h
mv
=
0*03e132
9*291:
=2*2e132m
+ow the hard part $inding e;peri!ental data to support the theor,*
4he proble! was that no one had ever seen a particle di$$ract or inter$ere with another particle(
which would be proo$ that the particle was acting like a wave*
5ith wavelengths as s!all as the one we $ound in %;a!ple 1( it/s i!possible to see the wave
properties*
<3223299< = stud,ph,sics*ca Page 1 o$ 2 3 >ection 12*2
Illustration 1:
Louis de
Broglie
Warning!
Many people make the
mistake of calculating the
energy of the moving particle
using kinetic energy, then
using E = hc / to find the
wavelength. You can NO do
this, as it assumes the mass
stops, changing all its energy
into a pulse of EM!.
'e!e!ber $ro! ?oung@s 7ouble >lit e;peri!ent that to be able to see the e$$ects o$
di$$raction and !easure wavelength( ,ou need slits or ob)ects which are not !uch larger
than the wavelengths being studied*
It is i!possible to build a di$$raction grating as s!all as 19
132
!* 4hat/s s!aller than the
orbits o$ electrons around a nucleusA
But notice where !ass is in the $or!ula with a reall, s!all !ass (like an electron( the
wavelength gets biggerA
4hese !ight be !easurable*
Example 28 Determine the wavelength o$ an electron accelerated b, a 199B potential di$$erence*
6irst calculate the velocit, o$ the electron using $or!ulas ,ou used in the electricit, unit
E
k
=
1
2
mv
2
E=qV
qV=
1
2
mv
2
v=

2CB
m
v=

21*09e119199
9*11e131
v=:*93e0m/ s
+ow use that velocit, to calculate the wavelength
=
h
mv
=
0*03e132
9*11e131:*93e0
=1*23e119 m
#lthough this wavelength is ver, s!all( the spaces between the ato!s o$ a
cr,stal are about this siDe*
7avisson and Eer!er shot electrons at a cr,stal sa!ple o$ nickel in a
vacuu! tube and observed a di$$raction pattern*
4he spaces between the ato!s o$ nickel are about the sa!e siDe
as the wavelength o$ the !oving electrons( so the, acted like the
openings in a di$$raction grating*
Fn the other side o$ the nickel the electrons (acting as waves
inter$ering with each other hit the phosphorescent coating on the
tube and $or!ed the glowing pattern as shown in Illustration 2*
Gust like !easuring values in ?oung/s 7ouble >lit e;peri!ent( we
can !ake si!ilar !easure!ents here to $ind the wavelength*
4he value de Broglie predicted and 7avisson1Eer!er/s values were
e;actl, the sa!e*
4he conclusion8 particles have wave propertiesA

<3223299< = stud,ph,sics*ca Page 2 o$ 2 3 >ection 12*2
Illustration 2:
Interference pattern seen
for electron diffraction.

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