Membrane Technology in Wastewater Reclamation / reuse TorOve leiknes, Gary Amy KAUST - King Abdullah University of Science and Technology WDRC - Water Desalination and Reuse Center (wdrc) Outline The evolution of wastewater treatment (WWT) Brief history of Membrane Technology applied to WWT Changing paradigms of advanced WWT Key aspects of Membrane Technology Pros and cons of MBR technology Key challenges in MBR technology.
Membrane Technology in Wastewater Reclamation / reuse TorOve leiknes, Gary Amy KAUST - King Abdullah University of Science and Technology WDRC - Water Desalination and Reuse Center (wdrc) Outline The evolution of wastewater treatment (WWT) Brief history of Membrane Technology applied to WWT Changing paradigms of advanced WWT Key aspects of Membrane Technology Pros and cons of MBR technology Key challenges in MBR technology.
Membrane Technology in Wastewater Reclamation / reuse TorOve leiknes, Gary Amy KAUST - King Abdullah University of Science and Technology WDRC - Water Desalination and Reuse Center (wdrc) Outline The evolution of wastewater treatment (WWT) Brief history of Membrane Technology applied to WWT Changing paradigms of advanced WWT Key aspects of Membrane Technology Pros and cons of MBR technology Key challenges in MBR technology.
Membrane Technology in Wastewater Reclamation / reuse TorOve leiknes, Gary Amy KAUST - King Abdullah University of Science and Technology WDRC - Water Desalination and Reuse Center (wdrc) Outline The evolution of wastewater treatment (WWT) Brief history of Membrane Technology applied to WWT Changing paradigms of advanced WWT Key aspects of Membrane Technology Pros and cons of MBR technology Key challenges in MBR technology.
Water Reuse Tuesday - February 25, 2014 2 Membrane Technology in Wastewater Reclamation / Reuse TorOve Leiknes, Gary Amy
KAUST King Abdullah University of Science and Technology WDRC Water Desalination and Reuse Center (torove.leiknes@kaust.edu.sa) Workshops Session 3.1 Water Reuse Tuesday - February 25, 2014 Outline The evolution of wastewater treatment (WWT) Brief history of membrane technology applied to WWT Changing paradigms of advanced WWT Key aspects of MBR technology Pros and cons of MBR technology Key challenges in MBR technology The potentials of membranes in advanced WWT Summary Conventional wastewater treatment: Primary Secondary Tertiary Membranes in WWT 50 years evolution:
GAC RO Sand filter AS Air stripping Sludge treatment Recarbonation GAC RO Sand filter AS Air stripping Air stripping Sludge treatment Recarbonation MF/UF RO AS Sludge treatment Pre-treatment MF/UF RO AS Sludge treatment MF/UF RO AS Sludge treatment Sludge treatment RO MBR Pre-treatment 1. For tertiary treatment 2. Process optimization 3. Replace conventional treatment 4. Membrane bioreactors 5. ? Membranes and wastewater: End of 1960s: - UF: for municipal wastewater, sludge separation in AS (1969)
1970s and 1980s: - MF/UF of industrial wastewater (f.ex. textile industry, oily wastewater, separation of metals, organic compounds) - In connection with separation in anaerobe digestion
1990s: - Membrane bioreactor concepts - Submerged MBR becomes state-of-the-art Application distinction: Municipal / industrial Membranes and wastewater: Why the interest in MBR developments? 1989: Proto type of current MBR solutions, Yamamoto et.al. Flux: ~3-9 LMH Sludge: 10-11 kg/m 3 TMP: P ~ 1.33 bar Energy: 0.007 kWh/m 3 Treatment efficiencies: - 93 - 95% COD - 94 - 99% TOC - no SS
(Gander et al., 2000) MBR is a proven technology: Yamamoto, 2009:
Evolution of development and implementation of membrane technology (MBRs) in WWT.
Global trends / markets:
In < 15 yrs from 1 to ~ 500 mill USD Advanced WWT: The driving factor for the growth of this market is waster stress Non-conventional water sources (impaired water quality) Need to recycle and reuse wastewater The concept of fit for purpose Stricter environmental regulations worldwide Need for new advanced WWT technologies Sustainable wastewater management practice Why the interest of membranes in advanced WWT? Changing paradigms The status of the global water resources is changing There is an increasing demand for water Water scarcity is becoming a daily reality for millions Many factors are affecting both quality and availability In some regions non-conventional / impaired quality water sources are becoming the norm There is a need for new and efficient treatment technologies The concept of fit for purpose treatment options? Sustainable water management solutions are required for the future The result, changing paradigms in WWT Changing paradigms Advanced wastewater treatment Changing paradigm a shift from CAS to MBR Wastewater is a resource! WWT can be a resource factory The water itself! wastewater reclamation / reuse Constituents in the water (i.e. phosphorus, nutrients etc.) Energy (i.e. heat, bio-gas etc.) Product formation (i.e. bio-polymers etc.) Basic principles of MBRs: Replacing sedimentation in CAS with membrane filtration for the separation of biomass from the aqueous phase. Principle of an AS-MBR process: http://www.thembrsite.com/feature_reducing_energy_demand.php MBR technology Biological process Membrane process Aeration Feed characteristics Hydraulics Membrane module Biomass characteristics: - Floc structure - EPS (free/bound) Bulk characteristics: - viscosity Membrane fouling: - reversible / irreversible Clogging: - membrane channels - aeration system Aerobic phase Mass transfer Air scouring Cleaning Retention times: - Hydraulic (HRT) - Solids (SRT) Flux / TMP Fouling Cleaning Membrane characteristics - pore size / surface properties Module configuration - Geometry / dimensions Composition of feed Treatment requirements - Nutrient removal - End use of treated water O p e r a t i n g
p a r a m e t e r s O p e r a t i n g
p a r a m e t e r s Interactions, Fouling Process parameters biological membrane hydrodynamics
Interaction between the biological and membrane processes
Membrane fouling is a major problem - biofouling
Fundamentals and key aspects of MBR technology: 1 9 8 0 1 9 8 5 1 9 9 0 1 9 9 5 2 0 0 0 2 0 0 5 2 0 1 0 0 1000 2000 3000 c u m u l a t i v e
n u m b e r
o f
p a p e r s
publication year scientific publications 1983-2010 55% published in 2006-2009 biofouling is a major problem
but what is biofouling? What is biofouling? Is it the biofilm itself or constituents of the biofilm? How significant is the floc structure? How significant is the EPS? Bound vs. free? What is the composition of the EPS? Which is more important, polysaccharides proteins? How should it be measured / reported or quantified? Does composition / structure change? How dynamic is biofouling? Can it be removed? Biofilm fingerprinting? Is quorum sensing a key phenomenon? How sensitive is the biofilm interaction to stress? Behavior Response Impact Why the concern on biofouling? Advanced water treatment = energy water - energy nexus Example USA: 3% of total electricity generated is consumed for water and wastewater treatment by 2016, water treatment is expected to consume >100 million kWh / day increase of 30% from 1996 levels 60-75% of the energy required is consumed in the aeration processes more stringent requirements = more energy demands MBRs are considered energy intensive MBRs aeration demands: 38 % - membrane air scouring 35 % - aerobic biological process Source www.gewater.com Biofouling mitigation and control Key MBR issues: The key issues of MBRs:
High aeration demands (e.g. energy) Membrane fouling, biofouling in particular Design of membrane filtration units Changes in biological treatment processes Membrane cleaning
What are the MBR advantages / disadvantages? MBR cons Commonly expressed concerns about MBRs:
MBRs are too energy demanding Plants are expensive, high investment costs Complicated operations, membrane maintenance / cleaning Need more skilled personnel Membrane life-time and replacements Does not eliminate the need for advanced post-treatment (e.g. RO)
MBR energy Biofouling mitigation and control by:
- choice of operating modes (e.g. aeration) - improved module and reactor designs (e.g. CFD) Aeration in MBRs: Membrane module operation air scouring Bioprocess operation oxygen for aerobic degradation Coarse bubbles - membrane operation Fine bubbles - bioprocess operation Can represents 70-80% of the energy demands! Anoxic Aerobic Pre-treated wastewater Sludge recirculation Permeate Air MBR aeration Biological needs: Objective: Oxygen transfer for aerobic degradation Practice: Fine bubble diffusers Challenge: Change in fluid viscosity Poorer masstransfer efficiencies, more energy High operating costs Change in biomass characteristics?
Membrane needs: Objective: Generate crossflow hydrodynamic conditions Generate high shear stress on surface Remove deposition on membrane surface Practice: Continuous aeration for air scouring Intermittent aeration (on/off cycles) Relaxation techniques (no production during aeration) Challenge: High specific aeration demands High operating costs
MBR aeration - Same fundamental Monod kinetics apply - Process must be designed for oxygen necessary to degrade both organic matter and to convert NH 4 to NO 2 /NO 3 as required - Determines oxygen transfer rate (OTR) Challenge: - Parameters in OTR equation affected by high SS concentrations - Particularly viscosity and the -factor - Correlations have been proposed where is viscosity (kg/(m s)) x is the correlation exponential MBR: MLSS of 12 g/L -value of 0.6 CAS: MLSS of 3-5 g/L -value of 0.8 Consequence higher aeration demand MBR aeration Impact of aeration on aerobic process (modeling): Deterministic including biofouling products into the ASM models for activated sludge Aspects included: - affect of aeration on the behavior of SMP and EPS - biomass associated products (BAP), best observed in endogenous respiration conditions - uptake associated products (UAP), which are released during the consumption of a substrate MBR aeration EPS / SMP behavior as a function of SRT Modeling Y obs as a function of SRT 20-40 days optimal SRT for minimizing foulant species MBR aeration P. Cote et al. Desalination 288 (2012) 145151 Before After Significance of aeration: - reduced sludging - reduced fouling - more efficient systems Tremendous efforts in R&D have reduced aeration demands, increased efficiencies, yet aeration is still one of the key energy issues in MBRs.
Example GE Zenon - Influence of aeration mode MBR module designs: - Influence of module design - Impact on module design (open vs, closed) - Air loads - Choice of aeration cycling - Impact on hydraulics Example: modeling a full-scale plant, FS modules (EUROMBRA project) MBR module designs: Resulting biofouling behavior? Photographs of fouled flat-sheets Computed shear-stress distribution (0-4 N/m 2 ) - insights into the air distribution within a module - shear stress distribution on the surface of the flat-sheet membranes (EUROMBRA project) Example: CFD modeling of aeration, FS modules MBR module designs: Improved module design and performance Less fouling Less energy consumption MBR developments: In summary;
Great steps and achievements have been accomplished in making MBR a viable advanced wastewater treatment option. Stipulated average annual growth rates Large regional difference China and Middle East key future markets Region Annual growth (% / year) N. America 15 % Middle East 25 % Europe 10 % Asia Pacific 10 % China 20 % J apan 10 % Total 20 % Market prediction growth rates: MBR pros Commonly expressed benefits of MBRs:
Consistently high effluent water quality Competitive to advanced tertiary WW treatment Small foot-print, compact treatments plants Modular, can be scaled to any treatment plant size Well-suited for retrofitting / upgrading Produces high quality water well-suited for reclamation / reuse
MBR pros Effluent water quality:
What can be achieved by MBR processes? Effluent BOD <5 mg/L Effluent TSS <5 mg/L Total Phosphorus <1 mg/L Total Nitrogen <8 mg/L (lower if DN) Ammonia <1 mg/L Turbidity <0.4 NTU Bacteria up to 6 Log Removal Viruses up to 3 Log Removal COD, TSS, N, P Example of removal efficiencies: Example of hygienic capacity compared with CAS: Organism Size (um) Enteric Virus 0.025 0.075 Coliform Bacteria 1 3 Cryptospoidium occyst 3 8 Giardia cyst 7 - 14 1,00E+00 1,00E+01 1,00E+02 1,00E+03 1,00E+04 1,00E+05 1,00E+06 1,00E+07 1,00E+08 1,00E+09 1,00E+10 Coliforme Esch.-Coli C F U
p e r
1 0 0
m l Influent Effluent CAS Effluent MBR Guide value Hygienic parameters MF / UF (Brepols. 2010) No need for additional disinfection MBR pros Compound MBR Rejection (%) CAS Rejection (%) Estrone 94 99 88 98 17--Estradoil 96 100 91 98 17--Ethinylestradiol 82 94 60 100 Bisphenol A 93 100 83 Nonylphenol 81 - (Hegemann et al., 2002; Zuhlke et al., 2003; Clara et al., 2004) Comparing MBRs capacity to remove emerging compounds of concern compared with CAS e.g. EDCs: MBR pros MBR pros Costs / energy consumption: Example GE Zenon; drop in relative membrane costs, increased capacity P. Cote et al. Desalination 288 (2012) 145151 The costs of MBRs have dropped drastically through commercialization Extensive R&D efforts have increased unit capacities Energy to operate systems keeps dropping. Costs Capacity Investment cost, new and retrofitted WWTPs 1989 - 2006 0 200 400 600 800 1000 1200 1400 1600 1800 2000 0 10 20 30 40 50 60 70 80 90 100 Treatment Capacity, MLD S p e c i f i c
c o s t ,
E U R
p e r
P E CAS CAS with tertiary treatment MBR Cost function (all WWTPs) Comparison of CAS MBR Erftverband, Germany (Brepols, 2009) Investment costs Energy consumption, (~ 0,9 kWh/m 3 ) MBR pros Example Nordkanal, Germany: MBR pros MBR footprint compared to CAS: energy consumption < 0,7 kWh/m 3 can be achieved Case study - Heenvliet WWTP, The Netherlands (EUROMBRA project) MBR pros Retrofit / upgrade: MBR MBR status MBRs, a proven technology! Competitive for tertiary treatment requirements BAT for wastewater reuse / recycling MBR Large scale installations Retrofitting / upgrading Package plants MBR vs. CAS-TF? Principle: MBR CAS-TF Bioreactor with MF/UF Clarifier Bioreactor clarifier MF/UF Case study: (P. Cote et al. Desalination 167 (2004) 1-11) Process performance: - Suspended Solids: both below detection limit - Physical barrier on microorganisms: both - MBR has higher MLSS conc., better control of SRT, more diversified biomass giving overall improved removal of COD/SOCs - MBR has enhanced TN removal - Phosphorous removal similar in both - MBR better than CAS-TF MBR vs. CAS-TF Comparison of plant size, capital costs, O&M costs, Total life-cycle costs: Size defined by HRT and plant surface area: MBR CAS-TF MBR CAS-TF HRT MBR 75% (small plants) to 50% (large plants) < CAS-TF
Land space MBR is about 50% of CAS-TF MBR vs. CAS-TF Costs 1. capital. 2. O&M, 3. life-costs 1. 2. 3. 1. capital: MBR < CAS < CAS-TF - eliminating secondary clarifiers - reduced size of aeration tanks - reduced footprint - all offset added costs for the membrane system and fine screens 2. O&M: CAS < CAS-TF < MBR - CAS-TF/MBR similar, 20-30% >CAS - MBR >CAS-TF mainly from membranes air scouring 3. life-costs: CAS < MBR < CAS-TF - (20 years, 6% interest rate, 2.5% inflation rate) - membrane filtrated wastewater compared to CAS, adds 5-20% on total life-cost depending on plant size MBR post-treatment Post-treatment What if the water quality after MBR / CAS-TF is not enough? pretreatment to NF/RO AOP advanced oxidation processes mineralization and water stability ensuring water hygiene Post-treatment options: MBR post-treatment Potentials of MBR / CAS-TF with post-treatment: Removal of unregulated compounds: Emerging disinfection by-products (DBPs) (e.g., NDMA) Endocrine disrupting compounds (EDCs): Steroidal hormones (e.g., estrone) Bisphenol A Pharmaceutical active compounds (PhACs) and other emerging organic contaminants analgesics, antiepileptics, lipid regulators, antibiotics flame retardants, 1,4-dioxane
MBR post-treatment DOC removal during Pilot-Scale MF/RO and MF/NF (Drewes, 2003) 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Tertiary effluent mean NF-90 NF TFC-S RO TFC HR RO TFC HR full-scale D O C
( m g / L ) 0.43 0.34 0.24 0.16 Composition? TOC < 1.0 mg/L but 1 mg/L = 1,000 g/L = 10 6 ng/L! MBR post-treatment Rejection of Pharmaceuticals / EDCs with MF/RO (Drewes, 2003) 445 15 65 40 35 115 100 n.d. n.d. n.d. n.d. n.d. n.d. <10 0 50 100 150 200 250 300 350 400 450 500 c a r b a m a z e p i n e d i c l o f e n a c g e m f i b r o z i l i b u p r o f e n k e t o p r o f e n n a p r o x e n p r i m i d o n e n g / L Scottsdale tertiary effluent Scottsdale tertiary effluent after MF/RO 1 8.9 186 0.17 0.06 0 20 40 60 80 100 120 140 160 180 200 NP/OP Total APEO Total APEC m i c r o g r a m
p e r
l i t e r RO-Feed RO (TFC-XLE) permeate WR-199A Pharmaceuticals: full-scale MF/RO EDCs: pilot-scale MF/RO MBR post-treatment Comparing NF vs. RO as a post-treatment option: Rejection of hydrophilic non-ionic organics Rejection of hydrophilic ionic organics 0 0.2 0.4 0.6 0.8 1 100 150 200 250 Molecular weight (Da) R e j e c t i o n ESNA RO-XLE NF ESNA RO - XLE 0 10 20 30 40 50 60 70 80 90 100 N a p r o x e n d ic l o f e n a c i b u p r o f e n m e c o p r o p k e t o p r o f e n g e m f ib r o z il P r i m id o n e R e j e c t i o n
( % ) J o/k=1.3 DI J o/k=1.3 EfOM TFC-HR 0 10 20 30 40 50 60 70 80 90 100 N a p r o x e n d ic l o f e n a c i b u p r o f e n m e c o p r o p k e t o p r o f e n g e m f ib r o z il P r i m id o n e R e j e c t i o n
( % ) J o/k=2.4 DI J o/k=2.4 EfOM TFC-SR2 N/A DI EFOM DI EFOM MWCO = 100 Da vs. 400 Da Summary In a changing world with water scarcity reclamation / reuse of wastewater is becoming a necessity Changing paradigms of advanced wastewater treatment MBRs are a realistic, viable solution to advanced treatment for high quality effluents treating water of impaired quality CAS cannot meet current standards for wastewater reuse MBR has been shown to be a better solution than CAS-TF MBRs with post-treatment can provide very high effluent qualities well suited for multiple reuse purposes Treatment scheme can remove unregulated emerging contaminants of concern The technology is available, advancement in regulations and policies are needed 46 Part II 47 Looking towards future MBR solutions in wastewater reclamation / reuse TorOve Leiknes, Gary Amy
KAUST King Abdullah University of Science and Technology WDRC Water Desalination and Reuse Center (torove.leiknes@kaust.edu.sa) Workshops Session 3.1 Water Reuse Tuesday - February 25, 2014 Outline Rethinking MBR systems Looking for new MBR solutions for wastewater reuse New trends and directions Coupling alternative biological processes with membrane separation technologies Overview of novel MBR systems being developed Where is MBR development headed? Summary Statement: MBRs, is a proven technology! Competitive for tertiary treatment requirements Competitive for for wastewater reuse / recycling MBR developments Rethinking MBRs 1. MBR reactor designs 2. Biological processes 3. Novel / hybrid solutions Overall reactor designs and hydraulics CFD Membrane module designs Improved air-scouring systems (e.g. less energy) Alternative filtration unit design / operation Improved hydrodynamics Biofouling mitigation - new membrane materials - anti fouling surfaces - quorum sensing Using alternative biological process Biofilms vs. suspended Aerobic vs. anaerobic Nutrient removal Removal efficiency of emerging contaminants Biological product formation (e.g. biogas, biopolymers) Implementing microalgae systems Coupling MBRs with other unit processes: coagulation, adsorption, AOP etc. Alternative membrane separation systems: NF, FO/PRO, MD, MABR etc. Potentials of algae MBR solutions Integrated systems 1. MBR reactor designs: Large-scale CFD vs. modules: (Example Nordkanal plant, EUROMBRA project) Impact of inlet design / construction Impact of additional mixers 1. MBR reactor designs: Enhanced membrane filtration reactor design: I. Ivanovic & T.O. Leiknes, The biofilm membrane bioreactor (BF-MBR) - a review, Desalination and Water Treatment, 2012, 37 (1-3), 288-295 ? Completely mixed reactor (CM-MR) CM with sludge hopper (SH-MR) modified SH-MR (MSH-MR) BF-MBR - one step system - membrane unit for enhanced particle removal - alternative fouling control strategies 1. MBR reactor designs: Performance of alternative membrane reactors: General: Separation factor (Ks) increased; CM- MR SH-MR MSH-MR
Why? 1. MBR reactor designs: Impact of colloidal fraction on membrane filtration: Inlet Example of PSD analysis:
Zones in MSH-MR unit Reduction in colloidal fraction correlates with improved performance! Summary: 1. External membrane reactor should be designed as an enhanced particle separation unit (with focus on colloidal material) 2. Reactor design will affect composition of water around the membrane and thus fouling rates and overall performance 3. Potential to reduce air scouring for sustainable operation, i.e. energy 1. MBR reactor designs: AS - fouling BF - fouling Understanding membrane fouling: AS: BF: 24 hours 168 hours 312 hours Applying CLSM techniques Estimates biofouling porosity / hydraulic resistance Understanding biofouling in MBR systems will be an ongoing activity in all future developments as a function of operating conditions and system design! 2. Biological processes: Can the biology be done differently? Comparing aerobic and anaerobic processes: Pros and cons: anaerobic low sludge production anaerobic potentially net energy balance aerobic higher kinetics, nutrient removal plus, plus (Veolia) 2. Biological processes: Matching the biological treatment to the reuse purpose Agricultural reuse Crops for human consumption Crops for animal feed Urban landscaping (e.g. parks) Recreational (e.g. golf courses) Water needs: - plant nutrients / fertilizers - emerging compounds of concern - water hygiene / risk - environmental impacts Industrial reuse Cooling water Process water Water needs: - low TDS - ultra-pure water - water stability - tailored properties Potable reuse Direct reuse Indirect reuse (e.g. aquifer recharge, reservoirs) Water needs: - meet drinking water standards - emerging compounds of concern - water hygiene / risk - disinfection by products - nutrient removal Anaerobic / Aerobic Anaerobic Anaerobic - MBR 2. Biological processes: H. Ozgun et al. / Separation and Purification Technology 118 (2013) 89104 Alternative An-MBR flow schemes: An-MBR 2. Biological processes: Adapted from: H. Lin et al. / Desalination 314 (2013) 169188
Comparing: Well suited for high strength wastewater Energy aspects; low requirement net production (e.g. biogas) Still relatively low fluxes, biofouling more of a challenge than in MBR Full commercial large-scale systems still not available Pros and cons: Effluent Influent Excess sludge Gas collection Air (recycle) Aerobic BF Anaerobic BF/AS Anaerobic / Aerobic - MBR 2. Biological processes: Systems integration: One-stage (upflow) Multiple biological processes Multiple use of aeration Integrated solids management Energy recovery Maximizing biological processes with membrane separation 3. Novel / hybrid solutions: Membrane distillation MBR (MD-MBR) Examples of novel processes being developed: http://www.desalination.biz/news/magazine _article.asp?id=5145&title= Principle:
Water vapor is extracted from the wastewater and condensed on the permeate side. System developments: Relatively high temperature in biological reactor thermophilic bacteria Application to wastewater treatment has been limited Mainly laboratory scale results found in literature R&D phase at small scale Potential of concept is acknowledged
3. Novel / hybrid solutions: MD-MBR case study: Phattaranawik et.al. Desalination, doi:10.1016/j.desal.2007.02.075 System status: No wastewater treatment to date R&D phase at small scale Overall summary: Very high quality effluent achieved Low fluxes Need waste-heat for economic operation Membrane integrity an issue 3. Novel / hybrid solutions: Forward osmosis MBRs (FO-MBR) Concept principle: A. Achilli et al. / Desalination 239 (2009) 1021
J.-J. Qin et al. / Water Science & TechnologyWST 62.6 (2010) 1353-1360
Study comparing MBR with FO-MBR: 3. Novel / hybrid solutions: Forward osmosis MBRs (FO-MBR) System status: No full-scale commercialization to date R&D phase at small scale Challenges in FO-MBR development: Choice of draw solution and applicability to wastewater reclamation Competitive fluxes compared to other membrane processes Although on average less, membrane fouling is still an issue Waste management FO-MBR potentials: Very high effluent qualities, f.ex. 99% TOC and 98% NH 4 + -N removal efficiencies Less membrane fouling, easier cleaning by backwashing 3. Novel / hybrid solutions: Membrane aerated bioreactors (MABR) Treatment concept: Principle: Gas permeable membrane supplies oxygen directly to the biofilm no bubbles, optimal mass transfer, less energy Biofilm stratification provides both aerobic and anaerobic zones allowing flexible bioreactor designs Efficient simultaneous nitrification / denitrification Potential biological conversions of recalcitrant emerging contaminants (e.g. pharmaceuticals) Combined aerobic and anaerobic reactor Gas transfer membranes (e.g. oxygen) Minimization of energy for aeration Selection of specialized biomass for desired conversions DO COD Air Water flow Biofilm Gas permeable membrane Air Water flow Biofilm DO COD System status: No commercialization to date R&D phase at small scale Summary A better understanding of fouling mechanisms interactions (biology/membranes) Improved membrane module designs novel solutions enhanced by CFD analysis Integrated systems AS-MBR, biofilm-MBR, anaerobic-MBR, etc. hybrid solutions More energy efficient Improved robustness and life-time Steps towards standardization Where is MBR development headed ? 67