Professional Documents
Culture Documents
EPPT-Physical and Chemical Properties of Coal and Its Products
EPPT-Physical and Chemical Properties of Coal and Its Products
Copyright-MS-2013
Proximate analysis
The objective of coal proximate analysis is to determine the
amount of fixed carbon (FC), volatile matters (VM), moisture,
and ash within the coal sample.
The variables are measured in weight percent (wt. %) and are
calculated in several different bases. AR (as-received) basis is the
most widely used basis in industrial applications. AR basis puts all
variables into consideration and uses the total weight as the basis of
measurement.
AD (air-dried) basis neglect the presence of moistures other than
inherent moisture while DB (dry-basis) leaves out all moistures,
including surface moisture, inherent moisture, and other moistures.
DAF (dry, ash free) basis neglect all moisture and ash constituent in
coal while DMMF (dry, mineral-matter-free) basis leaves out the
presence of moisture and mineral matters in coal, for example:
quartz, pyrite, calcite, etc. Mineral matter is not directly measured
but may be obtained by one of a number of empirical formula based
on the ultimate and proximate analysis.
Copyright-MS-2013
Moisture
Source: http://en.wikipedia.org/wiki/Coal_assay#Chemical_properties_of_coal
Volatile matter
Volatile matter in coal refers to the components of coal,
except for moisture, which are liberated at high
temperature in the absence of air. This is usually a
mixture of short and long chain hydrocarbons, aromatic
hydrocarbons and some sulfur. The volatile matter of
coal is determined under rigidly controlled standards. In
Australian and British laboratories this involves heating
the coal sample to 900 5 C (1650 10 F) for 7
minutes in a cylindrical silica crucible in a muffle furnace.
American Standard procedures involve heating to 950
25 C (1740 45 F) in a vertical platinum crucible.
Copyright-MS-2013
Ash
Ash content of coal is the non-combustible
residue left after coal is burnt. It represents
the bulk mineral matter after carbon,
oxygen, sulfur and water (including from
clays) has been driven off during
combustion. Analysis is fairly
straightforward, with the coal thoroughly
burnt and the ash material expressed as a
percentage of the original weight.
Copyright-MS-2013
Fixed carbon
Proximate Analysis
unit
(ar)
(ad)
(db)
(daf)
Moisture
(wt. %)
3.3
2.7
Ash
(wt. %)
22.1
22.2
22.8
Volatile Matter
(wt. %)
27.3
27.5
28.3
36.6
Fixed Carbon
(wt. %)
47.3
47.6
48.9
63.4
(ar) as received
(ad) air dried
(db) dry basis
(daf) dry ash free
Copyright-MS-2013
Ultimate analysis
Ultimate analysis is the determination of
the percentage composition in terms of
carbon, hydrogen, sulfur, nitrogen, and
ash, and the calculation of the oxygen
content the difference.
Copyright-MS-2013
10
Ultimate Analysis
unit
Carbon (C)
Hydrogen (H)
Nitrogen (N)
(wt. %)
0.4
0.39 0.39
Oxygen (O)
(wt. %)
8.8
8.8
Copyright-MS-2013
9.1
11
Conversion table
Desired
Basis >
As Received
Given Basis
Air Dried
100-Mad
100-Mar
As Received
100-Mar
Air Dried
100-Mad
Dry
Dry, ash
free
100-Mar
100
100-Mad
100
100(Mar+Aar)
100
100(Mad+Aad)
100
Dry
Dry, ash
free
Dry, mineral
matter free
100
100Mar
100
100(Mar+Aar)
100
100Mad
100
100
100100(Mad+Aad) (Mad+MMad)
100
100-Ad
100Ad
100
Dry,
100100100mineral (Mar+MMar) (Mad+MMad) MMd 100-MMd
100-Ad
matter free 100
100
100
Copyright-MS-2013
100
100(Mar+MMar)
100
100-MMd
100-Ad
100-MMd
Definition of Variables
M = moisture (%)
A = ash (%)
MM = mineral matter (%)
Definition of Subscripts
ar = as received basis
ad = air dried basis
d = dry basis
12
Copyright-MS-2013
13
Number of atoms
7
6
No.
Type of fuel
1
2
3
4
5
6
7
Peat
Lignite
Flame coal, type 31
Gas coal, type 33
Ortho-coking coal, type 35
Semi-coking coal, type 37
Anthracite
Hydrogen
Oxygen
Carbon
5
4
3
2
1
0
1
4
Type of fuel
Copyright-MS-2013
14
C/H*10
H/O
60
Stosunki atomowe
50
40
30
20
10
0
1
Typ paliwa
Copyright-MS-2013
15
16
Number of atoms
7
6
No.
Type of fuel
1
2
3
4
5
6
7
Peat
Lignite
Flame coal, type 31
Gas coal, type 33
Ortho-coking coal, type 35
Semi-coking coal, type 37
Anthracite
Hydrogen
Oxygen
Carbon
5
4
3
2
1
0
1
4
Type of fuel
Copyright-MS-2013
17
C/H*10
H/O
60
Stosunki atomowe
50
40
30
20
10
0
1
Typ paliwa
Copyright-MS-2013
18
19
35000
30000
25000
20000
15000
10000
5000
0
60
65
70
75
80
85
90
95
100
105
Copyright-MS-2013
20
21
Content, % mas.
Moisture
Ash
Volatile
Carbon
Hydrogen
Nitrogen
Sulphur
Oxygen
Wa
Aa
Va
Ca
Ha
Na
Sc a
Oda
2,5
16,8
30,2
69,57
3,93
1,17
0,17
5,86
0,6
0,4
Biuminous coal
- Wieczorek -
0,3
0,2
0,5
0,4
0,3
0,2
0,1
0,1
0
500
700
900
Temperature, K
H2
CH4
C2H6
V
CO
CO2
H2O
Tar
1100
1300
0
500
700
900
1100
1300
Temperature, K
Enthalpy
of formation
H o, kJ/kg
Q daf, MJ/kg
f
s
34,7
-463,2
Copyright-MS-2013
Heating value
Activation
energy
E, kJ/kmol
11181,2
Frequency
index
ln (k8 )
-5,97 22
Coke
Coke is the solid carbonaceous material
derived from destructive distillation of lowash, low-sulfur bituminous coal. Cokes
from coal are grey, hard, and porous.
Coke is used as a fuel and as a reducing
agent in smelting iron ore in a blast
furnace. It is there to reduce the iron oxide
(haematite) in order to collect iron.
Copyright-MS-2013
23
Coal tar
Coal tar is a brown or black liquid of extremely
high viscosity, which smells of naphthalene and
aromatic hydrocarbons.
Coal tar is among the by-products when coal is
carbonized to make coke or gasified to make
coal gas.
Coal tars are complex and variable mixtures of
phenols, polycyclic aromatic hydrocarbons
(PAHs), and heterocyclic compounds, about 200
substances in all.
Copyright-MS-2013
24
Coke gas
Coal gas (also town gas and illumination gas) is a
flammable gaseous fuel made by the destructive
distillation of coal containing a variety of calorific gases
including hydrogen, carbon monoxide, methane and
volatile hydrocarbons together with small quantities of
non-calorific gases such as carbon dioxide and nitrogen.
It was the primary source of gaseous fuel both the
United States and Great Britain until the widespread
adoption of natural gas during the 1940s and 1950s. It
was used for lighting, cooking and heating and was often
supplied to households via a municipally-owned piped
distribution system.
Copyright-MS-2013
25