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2.

Introduction to quantum mechanics


2.1 Linear algebra
Dirac notation
Complex conjugate
Vector/ket
Dual vector/bra
Inner product/bracket
Tensor product
Complex conj. matrix
Transpose of matrix
Hermitian conj/
adjoint of matrix
Inner product

Basis, vector representation


For a set of vectors

The set

spanning

constitutes a basis for

Linear operators
A linear operator

Notation

means

Matrix representation
For

spanning

a matrix representation of

Numbers

spanning
means

form matrix

Linear operator (basis given)


matrix representation
(to be used interchangeably...)
Pauli matrices

Inner vector product


A inner product on

is

We use notation

Hilbert space = inner product space


The vectors

are orthogonal if

The norm of a vector is

An orthonormal set of vectors

obey

Vector representation
With respect to an orthonormal basis

for

the inner product is

We thus have

(an orthonormal basis will be used unless otherwise stated)

Outer vector product


The outer product
is a linear operator

Cauchy-Schwartz inequality
For two vectors

Completeness relation
For vectors

forming an orthonormal basis

for

Eigenvectors and eigenvalues


The eigenvector

with

to

obeys

the eigenvalue.

The diagonal representation of

in terms of eigenvalues

is (for diagonalizable

and orthonormal eigenvectors

Hermitian operators
The Hermitian conjugate/adjoint of
We have
An Hermitian operator obeys

and

is
,

of

Projection operator
The operator

is a projection operator
Properties

Orthogonal complement
Normal operator
An operator

is normal if

An operator is normal if and only if it is diagonalizable.


An Hermitian operator is normal.

Unitary matrix
A matrix/operator

is unitary if

Positive operator
An operator

is positive if

and real for any vector

Any positive operator is Hermitian


Any positive operator has real, positive eigenvalues
and a spectral decomposition

in terms of eigenvalues

and orthonormal eigenvectors

of

Tensor product
A tensor product between vectors

in

is a vector in
Example:

A tensor product between operators/matrices

Operation

is denoted

Properties

Matrix representation
Example:
For matrices

we have the tensor product

Operator functions
For a normal operator

, written in the spectral decomposition

we define the/operator matrix function

Trace
The trace of a matrix

is

Cyclic property

Outer product formulation

Commutators
The commutator between two operators/matrices

is

The anti-commutator between two operators/matrices

is

Matrix decompositions
Polar decomposition: For a linear operator
unitary operator and positive operators

there exists a
so that

Singular value decomposition: For a square matrix


exists unitary matrices
and a diagonal matrix
non-negative elements (singular values), such that

there
with

2.2 Postulates of quantum mechanics


State space
Postulate 1:
Associated to any isolated physical system is a
Hilbert space, known as the state space of the
system. The system is completely described by its
state vector, a unit vector in the state space
Definitions/names
A two-level, qubit state

can generally be written as

This is a superposition of the two basis states


with amplitudes and
The normalization condition gives

and

Evolution
Postulate 2:
The evolution of a quantum system is described by a
unitary transformation. That is, the state
of the
system at time is related to the state
of the
system at time by a unitary operator
as

Postulate 2:
The evolution of state
of a quantum system is described
by the Schrdinger equation

where
is Plancks constant and
Hermitian operator.

the Hamiltonian, a

Closed system
For a closed system the Hamiltonian
and the system state
is

is independent on time

where we define the unitary time evolution operator

The Hamiltonian has the spectral decomposition

where

are the energy eigenstates and

the energy.

Effective Hamiltonian for open systems


For many open systems we have an effective time
dependent Hamiltonian acting on the system
The solution to the Schrdinger equation is non-trivial

Measurement
Projection measurement postulate
A projective measurement is described by an observable,
, an
Hermitian operator on the state space of the system. The observable
has the spectral decomposition
The possible outcomes correspond to the eigenvalues
Upon measuring the state
is given by

of

, the probability of getting the result

Given that
has occured, the state immediatelly after the
measurement is (wavefunction collapse)

Measurement problem?

General measurement
Postulate 3:
Quantum measurements are described by a collection
of
measurement operators, acting on the state space of the system. The
index
refers to the possible measurement outcomes. Upon measuring
the state
, the probability of getting the result
is given by
and the state after the measurement is

The measurement operators satisfy the completeness relation

Probabilities sum to one

Projective vs general measurement


For a projective measurement

The average measured value (over an ensemble of states

The magnitude of the quantum fluctuations are

Derivation: Heisenbergs uncertainty principle is

Composite systems
Postulate 4:
The state space of a composite system is the tensor product
of the state spaces of the component systems.
If we have systems numbered through , and system
prepared in state
, the state of the total system is

General measurement and projection II


Derivation: Given projection measurements and an ancilla
system, derive the general measurement principles.

is

POVM measurement
Common formulation of general measurement postulate.
A measurement is described by measurement operators
The probability to get the outcome
is given by

We define the positive operator


which has the properties

We call

the POVM-elements and the set

a POVM.

Distinghuishing quantum states


Given a single copy of one of two non-orthogonal states
not possible to determine which state by any measurement.
Derivation: The example with

, it is

Entanglement of two qubits


A composite state
of two qubits that can not be written as a
tensor product of the states
of the two qubits is entangled,
that is

Derivation: Show that the Bell state

is entangled

Entanglement is the energy for quantum information processing

2.3 Superdense coding


Suppose that Alice wants to send two bits of classical information to
Bob by only sending one qubit. Can she do it?
2 classical bits
1 qubit
Alice
Derivation: Superdense coding

Bob

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