General Characteristics
General Characteristics
General Characteristics
CARBOHYDRATES
Living things use carbohydrates as a
key source of
ENERGY
!
Plants use carbohydrates for structure
(
CELLULOSE
)
include sugars and complex carbohydrates
(starches)
contain the elements carbon, hydrogen,
General characteristics
Most carbohydrates are found naturally in
bound form rather than as simple sugars
Polysaccharides (starch, cellulose, inulin, gums)
Glycoproteins and proteoglycans (hormones, blood group
substances, antibodies)
Glycolipids (cerebrosides, gangliosides)
Glycosides
Mucopolysaccharides (hyaluronic acid)
Nucleic acids
Functions
sources of energy
intermediates in the biosynthesis of other
basic biochemical entities (fats and proteins)
associated with other entities in vitamins and
antibiotics
form structural tissues in plants and in
microorganisms (cellulose)
participate in biological transport, cell-cell
recognition, activation of growth factors, modul
the immune system
Classification of
carbohydrates
Monosaccharides (monoses or glycoses)
Trioses, tetroses, pentoses, hexoses
Oligosaccharides
Polysaccharides
Complex carbohydrates
Carbohydrates
Monosaccharides
- simple sugars with multiple OH groups. Based
on number of carbons (3, 4, 5, 6), a
monosaccharide is a
triose
,
tetrose
,
pentose
or
Monosaccharides
also known as simple sugars
classified by the number of carbons
most (99%) are straight chain compounds
sugars have the ending
ose
(glucose, galactose, ribose, lactose, etc)
Monosaccharides
Aldoses
(e.g., glucose) have an
aldehyde
group at one end.
Ketoses
(e.g., fructose) have a
keto
group, usually at C2.
Pentoses and
hexoses can
cyclize
as the ketone
or aldehyde
reacts with a distal
OH.
Glycosidic Bonds
Disaccharides
:
Maltose
, a cleavage product of starch (e.g.,
amylose), is a disaccharide with an
(1
4)
glycosidic
link between C1 - C4 OH of 2 glucoses.
It is the
Other
disaccharides
include:
Sucrose
, common table sugar, has a glycosidic bond
linking
glucose
&
fructose
.
Lactose
, milk sugar, is composed of
galactose
&
glucose
Polysaccharides
Formed of three or more simple sugar
units
Glycogen - animal starch stored in liver
& muscles
Cellulose - indigestible in humans forms cell walls
Starches - used as energy storage
Polysaccharides
:
Plants
store glucose as
amylose
or
starch
Amylose
is a glucose polymer with
(1
Cellulose
, a major constituent of
plant cell walls
, consists of long linear chains of glucose with
(1
4)
linkages.
Dehydration Synthesis
Combining simple molecules to form a
more complex one with the
removal of water
ex. monosaccharide + monosaccharide
----> disaccharide + water
(C
6
H
12
O
6
Hydrolysis
Addition of
WATER
to a compound to
SPLIT
it into smaller subunits
(also called chemical digestion)
ex. disaccharide + H
2
O ---> monosaccharide +
monosaccharide