Canadian Bleve Text
Canadian Bleve Text
Response
and
Prevention
technical
documentation
Prepared for
Transport Canada
Canadian Association of Fire Chiefs
Propane Gas Association of Canada Inc.
by
Dr. A. M. Birk
Department of Mechanical Engineering
Queens University
Kingston, Ontario, CANADA
September 1995
Contents
Introduction .................................................................................... 1
Pressure Liquefied Gases .............................................................. 2
BLEVE ........................................................................................... 5
Safety Devices ............................................................................... 8
Hazards from BLEVEs ................................................................. 12
Response Tactics ......................................................................... 14
Summary ..................................................................................... 21
Contacts ...................................................................................... 23
Sample Problem .......................................................................... 28
Bibliography ................................................................................. 29
Introduction
This document is intended to go with the video of the same title, and will provide the
viewer with additional technical information to support the content of the video. It is
recommended that the video be viewed first, then this document should be read and
discussed.
This video and technical document have been prepared for emergency responders
who may be called to a scene where a tank holding a pressure liquefied gas has been
severely damaged by impact or by fire exposure. In this case a severe explosion is
possible and the hazards can be far reaching.
This document is not suggesting that all tanks in fires or other accidents will BLEVE.
Tanks designed to carry pressure liquefied gases are very strong and safe. In recent
experiments conducted to study the BLEVE it was very difficult to make the tanks
BLEVE even though strong torch fires were applied to the tank vapour space wall area.
However, if a fire is severe enough and long lasting enough, or if a tank has been
weakened by impact or corrosion then a BLEVE can happen. The objective of this
video is to provide some guidance as to the hazards involved if a BLEVE takes place.
Suggestions are made regarding tactics so that responders are not exposing themselves to unnecessary danger.
This document in the format of questions and answers, and is organized in the following order:
i) general information about pressure liquefied gases
ii) what, why and hows of BLEVEs
iii) brief description of common safety devices
iv) hazards from BLEVEs
v) response tactics
vi) sample problems
This document and the video will concentrate on propane or LPG because they are the
most common, flammable pressure liquefied gases.
What are the properties of a PLG?
The physical and chemical properties of PLGs vary widely and cannot be given here in
any detail. The reader should seek other references to find out more about the specific
properties of PLGs (for example, Handbook of Compressed Gases , from the Compressed Gas Association Inc. Arlington Virginia, ISBN 0-442-21881-8). Some important properties to look for are:
- pressure vs temperature
- toxicity
- expansion ratio
- specific gravity of gas at 1 atmosphere
pressure (14.7 psia, or 0.101 MPa)
- flammability limits
- boiling point
Let us consider propane as an example of a very commonly used PLG.
Figure 1 shows how the pressure required to hold propane as a liquid increases with
the temperature of the propane. At -42 degrees C, propane can be held as a liquid in an
open container. At 25 C the pressure needed to hold propane as a liquid is 0.95 MPa
(138 psia).
If 1 litre of propane liquid at 25 degrees C is released it will expand to 270 l of propane
vapour. This is called the expansion ratio and is an important factor to remember if
liquid propane is accidentally released.
Figure 1: Pressure vs Temperature for Propane
4.0
Pressure (MPa gage)
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
-60
-40
-20
20
40
Temperature (degrees C)
60
80
100
400
litres
4 000
litres
40 000
litres
PLG tanks are not filled full with liquid so that there is space for the liquid to expand if
there is a temperature increase. The space not filled with liquid forms a vapour space in
the top of the tank as shown in Figure 3.
Figure 3: Liquid and Vapour Space in PLG Tank
Vapour
Liquid
Tank L/D
You should learn to recognize standard cylinder sizes for propane. The most common
are 1, 4, 11, 20, 30, 40, 60, 100, 200, 300 and 420 lb. Sizes larger than this can be
estimated from the above figure.
What happens if the tank is punctured?
If the containment vessel is punctured in the vapour space the vapour will leak out and
the liquid will boil off to replace the lost vapour. Depending on the properties of the
liquefied gas and the size of the hole in the vapour space, the boiling can be slow or it
can be explosive. If a pin hole forms in a tank then the vapour will leak out slowly and
the boiling will be very gradual. If the tank is suddenly completely broken open, the
release will be explosive i.e. a BLEVE.
4
If the tank is punctured in the liquid space then liquid will leak out and it will boil off
rapidly outside of the tank. Once again, the violence of the process will depend on the
size of the puncture and on the properties of the released substance.
Will the tank empty itself if there is a puncture or leak?
Yes, but it may take quite a while, depending on if there is a fire, how large the hole is,
where the hole is and the tank size and its fill level. As mentioned above if the hole
forms in the liquid space the tank can empty quickly. If the hole is in the vapour space
then the liquid must boil off to leave the tank as a vapour.
The liquid needs heat energy to convert from liquid to vapour (i.e. boil). If a fire is
present the heat energy will come from the fire and in this case the punctured tank can
empty fairly quickly.
If there is no fire, or if the fire has been put out, then the heat energy for boiling must
come from the liquid itself, and in this case the boiling will cool the liquid. As it cools, its
vapour pressure will decrease until eventually the liquid will reach its atmospheric boiling point temperature (this is autorefrigeration). At this temperature the boiling will almost stop. This means that if a tank is punctured and there is no fire, then the tank will
not boil empty immediately. You may see this if a tank has a puncture in the vapour
space the bottom of the tank may ice over telling you that the tank is still partly full of
very cold liquid. This liquid will now boil off very slowly as heat from the surrounding air
enters the tank and liquid. The pressure in the tank is now gone but there is still a
hazard. If something or someone causes this liquid to be spilled on the ground, then a
very hazardous situation can result. The cold spilled liquid will contact the warm ground
and it will boil rapidly, and cause a vapour cloud.
For propane starting at 20 degrees C, up to 60% of the original liquid can remain in the
tank after a puncture in the vapour space.
B L EV E
Exactly what is a BLEVE and what are the hazards?
A boiling liquid expanding vapour explosion or BLEVE happens if a container holding a
pressure liquefied gas fails catastrophically. Catastrophic failure of the vessel is followed by the explosive release of boiling liquid and expanding vapour.
The BLEVE is a physical explosion where the hazards are blast and projectiles. It
should be noted that a commodity does not have to be flammable to suffer a BLEVE.
If the commodity happens to be flammable, then a fireball may happen after the BLEVE
if the released cloud is immediately ignited. This is usually the case if the tank failure is
caused by fire impingement. If a flammable cloud is not ignited immediately then delayed ignition could lead to other fires, explosions, etc. If the cloud is toxic then this too
becomes a possible threat.
What could cause a tank to fail catastrophically?
Containers holding pressure liquefied gases are pressure vessels. Internal pressure
puts the container wall under stress. If the container is weakened the internal pressure
may exceed the tank strength resulting in tank failure. Tanks can be weakened by:
- severe corrosion
- severe mechanical damage from impacts, scraping, etc.
- very high temperatures as from fires
5
A
A
Another possible mechanism for tank failure is when the top half of the tank is heated to
high temperature by fire exposure. This causes the top half of the tank to expand.
However, the bottom of the tank is cool since it is cooled by liquid. This cool half of the
tank does not expand and resists the expansion of the tank top. This adds to the tension in the tank caused by the internal pressure. This differential expansion also makes
the tank bend (i.e. the top is longer than the bottom) and this too adds to the stress in
the tank wall. Eventually the aggravated stress condition may initiate a failure that
propagates along the length of the tank.
In any event, tank mechanical damage from accidental impacts may cause additional
weakening and as a result less fire heating may be needed for tank failure. Other
mechanical damage such as corrosion can also weaken a tank making it even more
susceptible to fire induced failure.
At what temperature does steel weaken?
Normal steels start to weaken significantly above 300 degrees C. If the fire exposure is
severe, it only takes a few minutes to reach these temperatures in the vapour space
region of the tank. Figure 6 shows how steel strength drops with increasing temperature.
Relative Strength
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
100
200
300
400
500
600
700
Temperature (deg C)
The problem is that you rarely know when the fire start time was, and how much liquid
is in the tank. Tank mechanical damage reduces the time to failure this is another
very important unknown.
In other words, dont try to guess when a BLEVE will happen. If a tank is exposed to
severe fire then assume the worst and stay back.
What tanks are easier to BLEVE large or small?
Small tanks empty faster through the PRV (i.e. wall is quickly exposed to vapour
poor cooling effect, etc.). Small tanks have thinner walls and these can heat up faster
and fail more quickly than larger tanks with thick walls (with severe torch fire impingement tanks with 3 mm wall thickness can fail in less than 2 minutes, tanks with 6 mm
wall can fail in about 4-5 minutes, larger tanks with wall thickness 12 - 18 mm may take
8 - 10 min or less to fail).
Obviously large tanks give more powerful explosions, larger fireballs and tank fragments can go further. However, dont be fooled by small tanks, small tanks are also
very dangerous because they can make very good rockets.
Does there have to be a fire for a BLEVE to occur?
NO. There have been reported BLEVEs where no fire was involved. These are usually
due to some structural problem with the tank (i.e. corrosion, fatigue, impact damage,
etc.).
Anything that leads to a sudden catastrophic failure (i.e. tank splits open completely)
will result in a BLEVE.
With no fire present the resulting cloud will drift downwind and into low lying areas
(sewers, ditches, etc.). For large releases toxic concentrations or flammable mixtures
may last for considerable distances from the source.
When is the danger of a BLEVE over?
For a severely weakened tank, the danger of a BLEVE is gone only when the pressure
in the tank is gone.
You can only be sure the pressure is gone if there is a reliable pressure reading from
the tank or if there is a hole in the tank and nothing is coming out. Even if the pressure
is gone you can still have vapours and liquid in the tank (if there is liquid and no pressure the liquid has refrigerated itself for example, propane at -42 degrees C has a
pressure of 1 atmosphere).
If the fire is out, stay away from the tank. Call in experts to evaluate the tank condition.
It is very dangerous to approach a tank after it has been weakened by fire exposure.
Safety Devices
What are examples of safety devices?
The following are examples of safety devices that may be found on tanks to protect
them from accidental fire impingement:
- pressure relief valves
- thermal barriers (i.e. thermal insulation)
- water spray systems
8
All pressure tanks in North America have pressure relief valves (PRV) that open if the
tank pressure exceeds some predetermined level. PRVs are designed to close again
when the pressure in the tank is reduced slightly below the PRV opening pressure. This
is an important point to remember PRVs do not reduce the pressure in the tank all
the way down to zero! For propane tanks PRVs are normally set at pressures between
1.7 and 2.6 MPa (250 - 380 psi).
Most tanks are not equipped with thermal barriers or water spray. Some transportation
tanks such as rail tank-cars have thermal barriers. Some large stationary facilities have
thermal barriers or water spray systems. Both of these systems act to limit the heating
effects of fire on the tanks and this tends to make more time available to get the situation under control.
Thermal barriers and water spray systems are not perfect and tanks can still BLEVE if
for some reason the water spray or thermal barrier has been damaged. However, they
are much less likely to BLEVE if they are equipped with these systems.
Is the situation under control if the pressure relief valve (PRV) is working?
A pressure relief valve or PRV by itself cannot stop a BLEVE. PRVs are only designed
to keep the pressure in the tank below some set pressure tanks can and do fail even
though the PRV is working properly.
Recent fire tests of tanks have shown that you cant always rely on a PRV to open at
the set pressure (test results show first opening pressures may be well above the
normal set pressure).
Keep in mind that PRVs dont do anything to keep the tank strong. As the tank weakens
due to high wall temperature even perfect operation of the PRV may not be enough to
save a tank. If the PRV is open take this as a warning that something may happen. In
very rare cases the PRV may not open at all, due to a malfunction.
Is the tank more likely to BLEVE when the PRV is open or closed ?
Tanks can BLEVE with the PRV open or closed if the tank has been severely weakened by mechanical damage or fire exposure. An open or cycling PRV should be taken
as a warning that something is heating the tank and therefore the situation is serious.
Does the operation of the relief valve tell us anything?
As stated above PRV operation should be taken as a warning. When the PRV first
opens it will usually cycle a few times (open, close, open, close, etc.) and then it may
remain open continuously. This valve behavior depends on the severity and location of
the fire contact. If valve is cycling open and closed for an extended period this suggests that there is not enough heat being added to the tank contents by the fire to
maintain the pressure to hold the PRV open this could mean the fire impingement is
minor or it could mean the fire is impinging on the vapour space and this is very bad.
A PRV that is open continuously suggests a very bad situation stay clear. A long
duration with the PRV open suggests that the tank is emptying and more of the tank
wall is not cooled by the internal liquid if fire is impinging the vapour space wall then
a BLEVE may be imminent.
Look for signs such as increased PRV noise, or increased length of PRV flare these
suggest the pressure is rising and this could be very bad. But beware that it may be
very difficult to notice these effects in an accident. Dont expect to get some clear
9
warning that something is about to happen. Table 1 gives a brief summary of signs to
look for.
Table 1: Summary of PRV Signs
Fire Condition
PRV Condition
Comments
no fire
PRV closed
no fire
PRV open
fire
no PRV action
fire
cycling PRV
fire
fire out
PRV closes
If the fire is out and the PRV is closed then stay back and let the tank cool down. Call in
the experts to assess the condition of the tank and its contents.
How long should it take for a tank to empty through the pressure relief valve?
This depends on the size and fill of the tank, and the heat input rate. The worse the fire
exposure the faster the tank will empty. If the PRV is cycling then the time will be longer
(i.e. if the PRV is open 1/10th of the time then the time to empty increases by a factor of
10).
Remember as the tank empties more of the tank wall is exposed to vapour contact and
if fire is present, tank weakening can be taking place. In some cases it has taken hours
of fire contact before a BLEVE these may be examples where PRV action or leaks
have lowered the liquid level to the point where fire began to contact the vapour space
wall.
Figure 7 shows some estimates of times to empty tanks. As can be seen the larger
tanks need more time to empty. Also, if the tank is only partially exposed to fire it will
empty more slowly.
Time (minutes)
responders more time to act but it also means the tank remains partially full of liquid for
a longer period of time more liquid means stronger BLEVE if one happens.
R fireball = 3m1 /3
where,
Rfireball
= mass of propane in kg
However, keep in mind that fireballs are not always spherical. In some cases, when the
tank fails a large ground fire can result that has a radius larger than that predicted
above. So dont assume if you are just beyond the predicted fireball radius, that you will
be outside of the fire envelope.
If you dont know how full a tank is, then assume the tank is 80% full with liquid when
you calculate the fireball size for a given tank size. Also remember that liquid propane at
25 degrees C is about 50% as dense as water i.e. 1 litre propane = 0.5 kg. This
means then that the lading mass in kg is 0.4 x tank capacity in litres.
The duration of the fireball can be estimated from its size by the following equation:
12
Propane Mass
Fireball Radius
Fireball Duration
400 l
160 kg
16 m
2.4 seconds
4000 l
1600
35
5.3
40000 l
16000
75
11.3
2.6% yield
5.4% yield
Overpressure (bar)
0.12
personnel
knocked down
0.10
0.08
0.06
window glass
shattered
0.04
0.02
0.00
10
12
You can also have a blast wave from the combustion of a flammable cloud. This could
happen if a release of a flammable material is allowed to mix with air and become
confined in a structure or sewer. If this is ignited it could result in a powerful explosion
with severe blast. This is a very difficult threat to quantify and it can be far reaching. If a
flammable liquefied gas is released and it does not ignite to form a fireball then get back
late ignition could cause severe explosions.
13
Tank Axis
Projectile effects are very unpredictable. There is only one thing for sure that can be
said about projectiles the further away you are from the BLEVE the safer you are.
Response Tactics
Should we go in immediately to put out the fire?
NO - time is very important, but accurate size-up is critical before personnel go in.
When first responders arrive they should stay well back use binoculars or viewing
14
scopes to view the tank. If there is, or has been severe fire impingement on the tank
then the tank should not be approached.
Important questions are:
- how long did it take to get to the site ?
- how long was the fire going before responders arrived ?
- how severe is/was the fire contact?
- are there high risk exposures?
- can other facilities become involved to escalate the situation?
- do you have enough water flow capacity?
- can you apply water for the necessary time?
Remember it takes 5, 10 ... 15 minutes for a severe fire to cause a thermal rupture
are you arriving just in time to witness (or be part of ) a BLEVE?
If there has been no fire impingement of the tank and you are absolutely sure of this
then you should make sure the tank does not get impinged by fire keep it cool with
water, get the fire out by shutting the fuel off at the source.
How do we assess the severity of the fire contact?
The severity of the fire contact can vary significantly and it may be very difficult to
assess this accurately. We should always try to err on the safe side. Do not assume
that you have 10-15 minutes to act.
Assess the fire severity from a safe distance, using aids such as binoculars. The questions to answer are:
i)
15
16
As a crude approximation, projectile ranges can also be related to the fireball radius.
The following is suggested as a guide.
80-90 % projectiles fall within 4 R from the tank side
severe rockets can go 15 R
in very severe, very rare cases it may be possible to see rockets
travel 22-30 R
Based on the above, civilians should be evacuated to beyond 15 R 30 R if possible.
As can be seen firefighters positioned at 4 R are still exposed to significant projectile
hazards. It must be stressed that the above are based on limited data and should be
considered as approximate.
Table 3 shows a summary of this calculation for various tank sizes with Propane as the
commodity.
Table 3: Fireball sizes and durations for a range of tank sizes
R fireball
Firefighter
Evacuation
400 l
(100 US gal)
160 kg
16 m
90 m
245 - 490 m
4000 l
(1000 US gal)
1600 kg
35 m
140 m
525 - 1050 m
40000 l
(10000 US gal)
16000 kg
75 m
300 m
1125 - 2250 m
Distance (m)
The above distances do not consider vapour cloud dispersion, vapour cloud explosions, or related effects. For this reason if the commodity is toxic, or if delayed ignition
of a release is a concern then danger distances should be increased, especially downwind if wind is an issue.
17
When a tank is going to BLEVE does it give some kind of warning just before
it happens?
Dont expect to hear or see a warning that gives you time to get out. Common practice
tells you to look for bulging, or discoloration, or deep gouges, or listen for pinging
noises but these signs may not always be visible or audible. In some cases the tank
splits and hesitates before the BLEVE but this hesitation may only last a few seconds,
sometimes only 1/10 th of a second. In most cases the tank is intact one instant and the
next moment the tank is flat on the ground, engulfed in a rising fireball.
What effect does wind have on these kinds of cases?
You should approach the tank with the wind at your back to stay out of any escaped
vapours. If there is a fire on a tank the wind will tend to blow the fire to the leeward side
of the tank. This means the fire will probably be hottest on the side of the tank facing
away from the approaching responders. This may make it hard for the responders to
see the full effects of the fire.
If the tank fails, it will probably fail on the hottest side, and if this is the leeward side the
contents may be directed up and away from the approaching responders. However,
the resulting thrust may propel the tank towards the responders.
This is an example of how a procedure may be safer in one respect, but less safe in
another respect keep this in mind.
What is the most effective way for firefighters to protect a tank from fire
impingement?
Water spray has been shown to be effective at cooling fire exposed surfaces if
water is applied immediately. Remember it only takes minutes of severe fire
contact to weaken a tank and cause a BLEVE.
Experiments have shown that to cool metal heated by fire contact it takes approximately 14 litres/min per square metre of exposed surface (0.35 gal/min per square foot
of exposed surface) this is not true for severe torch impingement. This flow rate
applies if the water is turned on immediately when the fire starts.
You may be arriving 5, 10, 15 or more minutes after the fire has started and by this time
the tank may be severely weakened. If you arrive after the fire has already caused
damage to the tank, then you are taking a big risk if you go close enough to setup
monitors for water cooling.
If the tank is not impinged by fire, but is being heated by radiation from a nearby fire
then water application is very important to protect the tank from possible damage. A
rule of thumb suggested by some is 5 x square root of the tank capacity (gal) for the
required gal/min. Table 4 shows how this flow increases with tank size.
18
Tank Capacity
400 l
(100 gal)
0.61 m diameter
1.5 m long
50 gpm
4000 l
(1000 gal)
1.1 m diameter
5 m long
160 gpm
40000 l
(10000 gal)
2.1 m diameter
12 m long
500 gpm
NFPA states that 250 -500 gal/min streams are needed to carry an effective cooling
stream 50 -100 ft personnel should never be located this close if a BLEVE is a
possibility!
A metal surface at high temperature will cause violent flashing (steam) of the cooling
water when it contacts the wall take this as a sign that the tank has been severely
heated. The instant the water hits the hot metal may be the most dangerous. So make
sure you are out of danger before the water is turned on. Make sure you have enough
water to keep the water flow going for the necessary time.
When is it NOT a good idea to apply water for cooling?
When there is no fire, and there is a damaged tank, and the tank temperature is below
the cooling water temperature (i.e. winter time, etc.) applying water may actually
heat the tank and slowly increase the pressure and thereby increase the stresses in
the tank wall. If a tank has already been severely weakened by fire or impact, then the
increased stresses could initiate a failure and BLEVE.
What should we do if we dont have enough water?
If you dont have enough water then there is very little you can do. If the tank is exposed
to fire and the fire cannot be eliminated then stay back out of range of projectiles and
fire.
Should we cool a damaged tank if it is being heated by the sun?
If a tank has been damaged by fire or impact it may be undesirable to have the pressure increase in the tank. If the tank is being heated by the sun the pressure is probably
rising in the tank. To control this it is normally a good idea to cool the tank with water. For
sun heating it is only necessary to have enough water flow to keep the tank surface
wet.
If the fire is put out, how long should we wait before we approach the tank?
This depends on the size of the tank and its fill level. If cooling water has been applied,
continue with water cooling of the tank. However, in severe cases personnel should
stay back and let the tank and remaining lading cool naturally until the pressure in the
tank has dropped back down to normal values this could take several hours for a
large tank!
19
Time will also result in the tank recovering some of its strength as the wall temperature
drops back down to normal values. But remember, the tank may have been severely
weakened by the fire and it may have suffered permanent deformation and thinning.
In any case, keep away from the tank. Call in experts from industry who have the
equipment to evaluate the tank condition. You dont have the tools necessary to make
a proper evaluation of the tank structural integrity.
Under what circumstances is it appropriate to send personnel deep into the danger
zone?
There is no simple answer to this question. This document has made some suggestions about working distances. Some will find these distances very large and may choose
to ignore them. However, it should be made very clear if you go closer, and if the tank
BLEVEs, your chances of injury or death increase rapidly.
Dont go closer.
How can we prepare for such an event?
This problem is so technical that it is very difficult to account for all the factors at the
scene of an accident. This means that planning ahead is very important. Fire Departments should do the following:
- go out and survey facilities
- become aware of the safety devices and how they work
- locate critical valves, etc.
- know the capacity of various tank types, and prepare for an accident by
calculating fireball dimensions, safety distances, etc.
- know how much water is available at the site
- know how long it takes to get to the site how long will it take you to
setup at the site
- plan ahead for all possible situations from minor leaks to major fires
If you dont think your team can handle the situation then let your Fire
Marshal know so that something can be done.
20
Summary
The following table gives a summary of tank properties, critical times, critical distances
and cooling water flow rates for various tank sizes. This table is provided to give responders some guidance but it should be used with caution.
The tank dimensions are approximate and can vary depending on the tank design and
application.
The minimum time to failure is based on severe torch fire impingement on the vapour space of a tank in good condition, and is approximate. Tanks may fail earlier if they
are damaged or corroded. Tanks may fail minutes or hours later than these minimum
times depending on the conditions. It has been assumed here that the tanks are not
equipped with thermal barriers or water spray cooling.
The minimum time to empty is based on an engulfing fire with a properly sized PRV. If
the tank is only partially engulfed then time to empty will increase (i.e., if tank is 50%
engulfed then the tanks will take twice as long to empty). Once again, it has been
assumed that the tank is not equipped with a thermal barrier or water spray.
If tanks are equipped with thermal barriers or water spray cooling then the times to
failure and the times to empty both increase significantly. A thermal barrier can reduce
the heat input to a tank by a factor of ten or more. This means it could take ten times as
long to empty the tank through the PRV.
The fireball radius and emergency response distance are based on the equations given
earlier and are approximate. They assume spherical fireballs and this is not always the
case.
Two safety distances are given for public evacuation. The minimum distance is based
on tanks that are launched with a small elevation angle (i.e., a few degrees above
horizontal). This is most common for horizontal cylinders. The preferred evacuation
distance has more margin of safety since it assumes the tanks are launched at a 45
degree angle to the horizontal. This might be more appropriate if a vertical cylinder is
involved.
It is understood that these distances are very large and may not be practical in a highly
populated area. However it should be understood that the risks increase rapidly the
closer you are to a BLEVE. Keep in mind that the furthest reaching projectiles tend to
come off in the zones 45 degrees on each side of the tank ends.
The water flow is based on the rule of thumb 5
capacity(USgal )
= usgal/
21
kg
mass
propane
minutes
torch
severe
failure for
time to
minimum
minutes
fire
engulfing
empty for
time to
approximate
radius
fireball
distance
response
emergency
154
distance
evacuation
minimum
307
distance
evacuation
preferred
25
USgal/min
flow rate
water
cooling
length
90
diameter
10
capacity
litres
112
834
158
40
417
1050
224
1.5
111
525
1323
371
0.3
28
140
661
1852
512
100
18
35
176
926
2200
716
50
5
20
44
247
1149
2200
935
488
800
22
62
306
1435
2200
244
3
1600
28
77
383
1715
90
0.96
4.9
3200
32
96
457
16
2000
1
6.5
8800
40
114
12
4000
1.25
6.7
16800
45
8000
2.1
11.8
32800
160
22000
2.1
13.7
56000
1.5
42000
2.75
17.2
0.61
82000
3.3
400
140000
22
Region
Transport Canada Regional Office
ATLANTIC
Transport Dangerous Goods Office
45 Alderney Drive - Suite 1415, Queen Square Building
DARTMOUTH, Nova Scotia B2Y 2N6
Telephone: (902) 426-9351/Fax: (902) 426-6921
QUBEC
Bureau du transport des marchandises dangereuses
685, rue Cathcart - Suite 701
MONTRAL (Qubec) H3B 1M7
Telephone: (514) 283-0303/Fax: (514) 283-8234
ONTARIO
Transport Dangerous Goods Office
20 Toronto Street - Suite 600
TORONTO, Ontario M5C 2B8
Telephone: (416) 973-2989/Fax: (416) 973-5905
CENTRAL
Transport Dangerous Goods Office
101 - 22nd Street East, Federal Building - Room 305
SASKATOON, Saskatchewan S7K 0E1
Telephone: (306) 975-5059/Fax: (306) 975-4555
PACIFIC
Transport Dangerous Goods Office
625 Agnes Street - Suite 225
NEW WESTMINISTER, British Columbia V3M 5Y4
Telephone: (604) 666-6740/Fax: (604) 666-7747
Highway Tanks
Jurisdiction Provincial/Territorial Department
ALBERTA
Director, Dangerous Goods Control
Motor Transport Services
Alberta Transportation and Utilities
Twin Atria Building - 1st Floor, 4999 - 98th Street,
Edmonton, ALBERTA T6B 2X3
Telephone: (403) 427-8901 Ext 233/Fax: (403) 427-1044
23
BRITISH COLUMBIA
Manager, Dangerous Goods Office
Commercial Transport and Inspection Department
Ministry of Transportation and Highways
2631 Douglas Street,
Victoria, BRITISH COLUMBIA V8T 5A3
Telephone: (604) 387-5585/Fax: (604) 356-8986
MANITOBA
Environment Officer
Dangerous Goods/Hazardous Wastes
Department of Environment
139 Tuxedo Avenue, Building 2,
Winnipeg, MANITOBA R3N 0H6
Telephone: (204) 945-7025/Fax: (204) 948-2420
NEW BRUNSWICK
Registrar of Motor Vehicles
Department of Transportation
P.O. Box 6000
Room 570, York Tower - Kings Place,
Fredericton, NEW BRUNSWICK E3B 5H1
Telephone: (506) 453-2407/Fax: (506)453-3076
NEWFOUNDLAND
Manager, Transportation Regulation Enforcement
Motor Registration Division
Department of Works, Services and Transportation
Motor Vehicle Registration Building
P.O. Box 8710,
St. Johns, NEWFOUNDLAND A1B 4J5
Telephone: (709) 729-3454/Fax: (709) 729-0120
NORTHWEST TERRITORIES
Director, Motor Vehicle Division
Department of Transportation
P.O. Box 1320
4510 - 50th Avenue, Highways Building, 1st Floor,
Yellowknife, NORTHWEST TERRITORIES X1A 2L9
Telephone: (403) 873-7406/Fax: (403) 873-0120
ONTARIO
Compliance Branch
Ministry of Transportation
1201 Wilson Avenue, Room 212, West Building,
Downsview, ONTARIO M3M 1J8
Telephone: (416) 235-3580/Fax: (416) 235-4549
24
Jurisdiction
Department Responsable and Contact for
Non-Transport Tanks
ALBERTA
Alberta Boilers Safety Association
Administrator (Chief Inspector), Pressure Equipment Safety
Province of Alberta
10808 - 99th Avenue,
Edmonton, Alberta T5K 0G5
Telephone: (403) 427-6855/Fax: (403) 422-3562
BRITISH COLUMBIA
Ministry of Municipal Affairs
Office of the Fire Commissioner
800 Johnson Street,
Victoria, British Columbia V8V 1X4
Telephone: (604) 356-9000/Fax: (604) 356-9019
25
MANITOBA
Department of Labour, Mechanical Engineering
Boiler and Pressure Vessels,
Room 500, Norquay Building, 401 York Avenue,
Winnipeg, Manitoba R3C 0P8
Telephone: (204)945-3374
Department of Environment
139 Tuxedo Avenue, Building 2,
Winnipeg, Manitoba, R3N 0H6
Telephone: (204) 945-7110
Office of the Fire Commissioner, Department of Labour,
Room 508, Norquay Building,401 York Avenue,
Winnipeg, Manitoba R3C 0P8
Telephone: (204) 945-3374
NEW BRUNSWICK
Department of Environment
Operations Branch, Industrial Programs Section
P.O. Box 6000,
Fredericton, New Brunswick E3B 5H1
Telephone: (506) 457-4848/Fax: (506) 453-2265
NEWFOUNDLAND
Director of Operations
Government Service Centre
Department of Municipal and Provincial Affairs
5 Mews Place, P.O. Box 8700,
St. Johns, Newfoundland A1B 4J6
Telephone: (909) 729-3086 or 3084
NORTHWEST TERRITORIES
General Operations Manager
Products Division
Department of Public Works and Services
Rankin Inlet, Northwest Territories XOC 0G0
Telephone: (819) 645-5172
NOVA SCOTIA
Department of Environment
5151 Terminal Road,
Halifax, Nova Scotia B3J 1A1
Telephone: (902) 424-5300
26
ONTARIO
Chief Engineering
Engineering and Standards Branch
Fuel Safety and Pressure Vessels Safety Engineering
Ministry of Consumer and Commercial Relations
3300 Bloor Street, West - 3rd Floor West Tower,
Etobicoke (Ontario) M3X 2X4
Telephone : (416) 234-6024
PRINCE EDWARD ISLAND
Department of Environmental Resources
P.O. Box 2000,
Charlottetown, Prince Edward Island C1A 7N8
Telephone: (902) 368-5057
QUBEC
Rgie du Btiment du Qubec
145, Crmazie, 7e tage
Montral (Qubec) H2M 2V2
Telephone: (514) 873-6538
Fax: (514) 873-9936
SASKATCHEWAN
Department of Municipal Government
Boiler & Pressure Vessel Branch
1855 Victoria Avenue, 3rd floor,
Regina, Saskatchewan S4P 3V8
Telephone: (306) 787-4509
YUKON
Department of Community and Transportation Services
Public Safety Branch
P.O. Box 2703, 308 Steele Street - Lynn Building,
Whitehorse, Yukon Y1A 2C6
Telephone: (403) 667-5825
27
Sample Problem
You have arrived at a scene and a tank is severely exposed by fire. You stop at a
distance of about 200 m and you look at the tank with binoculars. One end of the tank
is completely engulfed in a fire. There is a loud noise coming from the tank and a jet of
fire is coming out of the tank top (probably the PRV). It took you 7 minutes to get to the
site and therefore this tank may be ready to blow. It is too late to cool the tank with water
the most important thing now is to get any residents out of harms way.
You look at what is near the tank, some lumber, a small shed and you evaluate the
potential for fragments being thrown if the tank ruptures. You also note the wind direction and the orientation of the tank.
You start evacuating the immediate area, keeping in mind that downwind residents
and residents located off the tank ends may be at more risk. You now need to estimate
how large an area needs to be evacuated.
You estimate that the tank diameter is about 1 m (based on a comparison of nearby
objects) and the tank is about 6 times as long as its diameter. Now you need to estimate
the mass of propane in the tank.
The tank volume is approximated from Figure 4. With D = 1 m and L/D = 6 the volume
is approximately 5000 l (1250 USgal).
Propane has a mass about half that of water (1 litre water = 1 kg, or 1 litre propane = 0.5
kg). If we assume the tank is filled to 80% capacity with propane then the propane
mass is:
m = 5000 x 0.8 x 0.5 = 2000 kg
The fireball radius is:
R = 3m1/3 = 3 (2000)1/3 = 38 m
this fireball will last about 0.15 R seconds or in this case about 0.15 x 38 = 5.7 seconds.
A reasonable distance for emergency responders to observe the tank from is 4R or
90m which ever is larger. In this case 4R is 151 m. You move in to about 150 m, with the
wind at your back and away from the tank ends.
At this distance you would be safe from the fireball if you are wearing protective clothing. The blast expected at 4R is about 30 mbar (0.44 psi) and could break window glass
and it could knock personnel off their feet so be careful. The real danger at this location
is tank fragments.
This size of tank can send large pieces of the tank up to 15 R in this case 567 m. In
very rare cases it could send a fragment up to 30 R or 1130 m. Therefore, evacuate the
public out to a distance of 15 R or 567 m in this case, and if it is practical evacuate out
to 30 R or 1130 m in this case.
The evacuation is in progress and you are evaluating the situation further.
- where is the fire fuel coming from can it be eliminated safely?
- are there other tanks that could be exposed to fire heating or fragment
penetration if the first tank BLEVEs ?
If there is no risk to life let the fire burn until the fire burns itself out, the tank empties
through the PRV or it blows up.
28
Bibliography
Guidelines for Evaluating the Characteristics of Vapour Cloud Explosions, Flash Fires
and BLEVEs, Center for Chemical Process Safety, AIChE, 1994.
Explosion Hazards and Evaluation, Baker, W.E., Cox, P.A. , Westine, P.S., Kulesz,
J.J., Strehlow, R.A., Elsevier Scientific Publishing Company, New York, 1983.
Liquefied Petroleum Gases Handbook, 3rd Edition, T. C. Lemoff Editor, NFPA, 1992,
Quincy Mass. USA.
29