254-Smo
254-Smo
254-Smo
254 SMO
4565
EN
ASTM
1.4539
1.4547
1.4565
N08904
S31254
S34565
Characteristic properties
General characteristics
High performance austenitic stainless steels differ substantially from more conventional grades with regard to resistance
to corrosion and, in some cases, also mechanical and physical
properties. This is mainly due to the high contents of chromium, nickel, molybdenum and nitrogen. High performance
austentic stainless steels have good weldability and excellent
formability.
Outokumpu manufactures a number of steels of this type:
904L, 254 SMO and 4565. Grade 4529 can also be delivered if specified. The properties of 4529 are in general terms
very similar to those of 254 SMO.
Applications
Chemical composition
The typical chemical composition of Outokumpu grades are
shown in table 1. The chemical composition of a specific
steel grade may vary slightly between different national standards. The required standard will be fully met as specified on
the order.
Chemical composition
Duplex Austenitic
Outokumpu
steel name
Table 1
International
steel No
Chemical composition, %
typical values
EN
ASTM
Cr
Ni
Mo Others
BS
DIN
NF
SS
4404
4439
904L
254 SMO
4529
4565
1.4404
1.4439
1.4539
1.4547
1.4529
1.4565
316L
S31726
N08904
S31254
N08926
S34565
0.02
0.02
0.01
0.01
0.01
0.02
0.14
0.20
0.20
0.45
17
18
20
20
20
24
10
13
25
18
25
17
2.1
4.1
4.3
6.1
6.5
4.5
1.5 Cu
Cu
Cu
5.5 Mn
316S11
904S13
1.4404
1.4439
1.4539
1.4529
1.4565
Z3 CND 17-11-07
Z3 CND 18-14-05 Az
Z2 NCDU 25-20
2348
2562
2378
2205
SAF 2507
1.4462 S32205*
1.4410 S32750
0.02 0.17 22
0.02 0.27 25
5.7
7.0
3.1
4.0
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2377
2328
Microstructure
Mechanical properties
Table 2
Minimum values,
according to EN 10088
H
P (15mm)
MPa
MPa
MPa
%
220
260
520
35
220
260
530
35
240
270
530
35
260
300
600
50
155
Rp0.2
Rp1.0
Rm
A5
HB
MPa
MPa
MPa
%
300
340
650
40
300
340
650
35
320
350
650
35
340
380
680
50
160
Rp0.2
Rp1.0
Rm
A5
HB
MPa
MPa
MPa
%
420
460
800
30
420
460
800
30
420
460
800
30
440
480
825
55
200
904L
Proof strength
Proof strength
Tensile strength
Elongation
Hardness
Rp0.2
Rp1.0
Rm
A5
HB
254 SMO
Proof strength
Proof strength
Tensile strength
Elongation
Hardness
4565
Proof strength
Proof strength
Tensile strength
Elongation
Hardness
Typical values
P = hot rolled plate. H = hot rolled strip. C = cold rolled coil and strip.
Table 3
Rp0.2
904L
Rp1.0
Rm
254 SMO
Rp0.2
Rp1.0
Rm
Rp0.2
4565
Rp1.0
100C
200C
300C
400C
205
175
145
125
235
205
175
155
500
460
440
230
190
170
160
615
560
525
510
350
270
240
210
400
310
270
240
270
225
200
190
Rm
750
640
640
610
Physical Properties
In table 4 typical values of some physical properties are given for 904L, 254 SMO and the grade 4565.
Typical values according to EN 10088
Table 4
Density
Modulus of elasticity
Linear expansion at (20 100)C
Thermal conductivity
Thermal capacity
Electric resistivity
g/cm
GPa
x10-6/C
W/mC
J/kgC
m
3
904L
254 SMO
4565
8.0
195
15.8
12
450
1.0
8.0
195
16.5
14
500
0.85
8.0
190
14.5
12
450
0.92
904L
40
4404
20
0
10
20 Steel
High Performance
Austenitic
Stainless
30
Corrosion resistance
Uniform corrosion
Temperature, C
100
80
60
254 SMO
904L
40
4404
20
0
5
HCI %
4565
60
60
80
4404
80
904L
4404
40
60
4565
40
60
254 SMO
20
400
10
20
30
40
50
60
70
80
90
904L
100
H2SO4 %
4404
20
40
0
254 SMO
10
20
30
40
50
4404
254 SMO 2
4
HF %
904L
20
0
254 SMO
4404
4404
60
70
80
90
100
20
0
4
HF %
H2SO4 %
Temperature, C
100
Temperature, C
100
Temperature, C
80
100
80
Temperature, C
100
254 SMO
4565
60
60
80
80
40
60
904L
254 SMO
4404
20
0
40
904L
10
4565
40
60
4404
20
4404
30
10
20
30
20
40
0
5
4404
254 SMO
904L
10
15
20
25
30
35
254 SMO
H2SiF6 %
904L
20 Fig. 5. Isocorrosion curves, 0.1 mm/year, in pure
0
fluosilicic
5
10 acid. 15
20
25
30
35
H2SiF6 %
Steel grade
Steel grade
4404
904L
254 SMO
>5
1.2
0.05
Table 6
>5
0.51
0.31
Table 8
Table 5
4404
4439
2205
904L
SAF 2507
254 SMO
4565
25
33
35
35
43
43
46
The PRE value can be used for rough comparisons of different materials. A much more reliable means, however, is to
rank the steel according to the critical pitting temperature of
the material (CPT).
There are several different methods available to measure
the CPT. Figure 6 shows the CPT, as measured in the Avesta
Cell (ASTM G 150), in a 1M NaCl solution (35,000 ppm
or mg/l chloride ions). The actual value of mill finish surface
may differ between product forms.
CPT, C
100
80
60
40
Table 7
PRE
0.88
0.29
0.06
0.01
20
0
4404
4439
2205
904L
SAF
2507
254
SMO
4565
Grade 4565 has such a good resistance to pitting that common test methods are not sufficiently aggressive to initiate
any corrosion. A better measure of resistance is given by evaluating the results of various crevice corrosion tests.
CCT, C
60
50
40
30
20
254 SMO c
60
904L p
10
50
40
0
4404
4439
904L
2205
SM
25
SA
0
25
6
45
Fig. 7. Typical critical crevice corrosion temperature (CCT) according to ASTM G48
Method F. Test surfaces dry ground to
120 mesh. CCT varies with product form
and surface finish.
254 SMO p
4404 c
30
4404 p
2205 c
2205 p
20
100
1000
Cl- ppm
10000
100000
p=pitting, full line c=crevice corrosion, broken line phe=plate heat exchanger
Seawater
Conventional stainless steels such as 4307 and 4404 are sensitive to stress corrosion cracking (SCC) under certain conditions, i.e. a special environment in combination with tensile
stress in the material and often also an elevated temperature.
Resistance to SCC increases with the increased content of
above all nickel and molybdenum. This implies that the high
performance austenitic steels 904L, 254 SMO and 4565
have very good resistance to SCC.
Different methods are used to rank stainless steel grades
with regard to their resistance to SCC. The results can vary
depending on the method and testing environment. The
resistance to stress corrosion cracking in a chloride solution
under evaporative conditions can be determined according to
the drop evaporation method. This means that a salt solution
is allowed to slowly drip onto a heated specimen, while it is
being subjected to tensile stress.
By this method the threshold value is determined for the
maximum relative stress not resulting in rupture after 500
hours testing. The threshold value is usually expressed as a
percentage of the proof strength of the steel at 200C. Fig. 9
shows the results of such a test.
High performance austenitic steels and duplex steels offer
considerably better resistance than 4404 to SCC, fig. 9.
100
80
60
40
20
<10
0
4404
2205
904L
Intercrystalline corrosion
Erosion corrosion
Galvanic corrosion
if they come into contact with most stainless steels (or with
titanium). The intensity of corrosion is closely related to the
surface area ratio between the stainless steel and the copper
alloy, fig 10. The tests presented have been carried out with
254 SMO but the relation is the same for other high performance steels.
The galvanic effect is reduced somewhat if the seawater is
chlorinated.
0.6
CuNi
70/30
0.4
Monel
Al-bronze
0.2
0.0
4
5
10
Area ratio 254 SMO/Metal
Fabrication
Hot forming
annealing of the material may sometimes be necessary, especially if the workpiece is welded.
The effect of work hardening, during and after coldforming, is illustrated in fig. 11 and 12.
Typical proof strength
Steel grade
Table 10
2 mm
Rp0.2,MPa
904L
254 SMO
4565
5 mm
Rp0.2,MPa
310 30
390 30
440 30
10 mm
Rp0.2,MPa
290 30
380 30
440 30
290 20
440 20
MPa/HB
A5
%
800
700
Rm
75
600
Rp0.2
Cold forming
500
50
400
300
A5
HB
25
200
100
10
15
20
25
Cold deformation, %
Characteristic temperatures, C
Hot forming
Solution
annealing
Pressure vessel
approval
Table 9
904L
254 SMO
4565
1200 - 950
1200 - 1000
1200 - 1000
1080 - 1160
1150 - 1200*
1120 - 1170
MPa
1400
A5
%
1200
Rm
(-60) - 400
(-60) - 400
(-196) - 400
Rp1.0
1000
Rp0.2
800
60
600
40
400
A5
20
200
0
20
40
0
60
Cold deformation, %
Fig. 12. 254 SMO influence of cold deformation on the mechanical properties.
Machining
All these steels are well suited for welding and the methods
used for welding conventional austenitic steels can also be
used on 904L, 254 SMO and 4565. However, due to their
stable austenitic structure, they are somewhat more sensitive
to hot cracking in connection with welding and generally
welding should be performed using a low heat input.
On delivery, sheet, plate and other processed products
have a homogeneous austenitic structure with an even distribution of alloying elements in the material. Solidification
after partial remelting, e.g. by welding, causes redistribution
of certain elements such as molybdenum, chromium and
nickel. These variations, segregation, remain in the cast
structure of the weld and can impair the materials corrosion
resistance in certain environments.
Segregation tendency is less evident in 904L and this steel
is normally welded using a filler of the same composition as
the base material and it can even be welded without filler.
For 254 SMO and 4565, however, the variation for molyb-
Welding consumables
Product form
Table 11
Designation
Typical composition, %
Si
Mn
Cr
Ni
Mo
Others
Welding of 904L
Welding wire
Covered electrode
ISO 20 25 5 Cu L
ISO 20 25 5 Cu N L
0.01
0.03
0.35
0.8
1.7
1.2
20
20.5
25.5
25
4.5
4.5
1.5 Cu
1.5 Cu
EN ISO NiCr22Mo9Nb
EN ISO NiCr21MoFeNb
0.01
0.02
0.1
0.4
0.1
0.4
22
21.5
65
66
9
9.5
3.6 Nb
2.2 Nb
ISO NiCr25Mo16
EN ISO NiCr23Mo16
0.01
0.02
0.1
0.2
0.2
0.3
25
25
60
59
15
15
0.02
0.2
5.1
26
22
5.5
0.35 N
* For use in certain oxidising environments, e.g. chlorine dioxide stage in pulp bleaching plants, when welding
254 SMO or 4565.
** For submerged arc welding it is preferable to use a Nb-free version, EN ISO NiCr22Mo9 or NiCr25Mo16.
Products
Outokumpu products
Table 12
Product
904L
254 SMO
4565
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Pipe fittings
Dimension according
to Outokumpu product
program
Dimension according
to Outokumpu product
program
Fagersta Stainless
Fagersta Stainless
Castings
Foundries
Licensed foundries
Material standards
Table 13
EN 10028-7
EN 10088-2
Stainless steels Corrosion resisting sheet/plate/strip for general and construction purposes
EN 10088-3
EN 10272
EN 10283
Forged or rolled alloy-steel pipe flanges, forged fittings etc for high temperature service
Alloy and stainless steel bolts and nuts for high pressure and high temperature service
Welded austenitic steel boiler, superheater, heat exchanger and condenser tubes
ASTM A269
Seamless and welded austenitic stainless steel tubing for general service
ASTM A276
Electric fusion-welded austenitic Cr-Ni alloy steel pipe for high temperature
ASME SA-403
ASTM A473
ASTM A743
ASTM A744
NACE MR0175
Norsok M-CR-630
VdTV WB 473
VdTV WB 537
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