Chemistry 2 Answer Key

Name:_____________________________________________________
CHEMISTRY 1212
EXAM #1 VERSION 1
This exam is 8 pages long. Please read through all of the questions first and ask about
anything you do not understand. You will have one hour and 15 minutes to complete this
exam. Exams will be picked up at the end of the class period. No late exams will be
accepted!
You are allowed to use a calculator. If you do not have a calculator, setting up the
problem correctly will gain you some points but you will not receive full credit for any
question you do not answer completely.
Included in this exam is a periodic table, which should be stapled to the back of the exam.
CHEATING IS NOT ALLOWED. ANYONE CAUGHT CHEATING WILL RECEIVE A
ZERO ON THIS EXAM.
The exam is worth a total of 100 points. Each question is labeled with its exact point
value. Be sure to answer all of the questions on the exam.
Good Luck!
2
Multiple Choice: Circle all correct answers! (3 points each)
1.)Which response includes all of the following substances in which dispersion forces are
the most significant factors in determining boiling points, and no other substances?
I) Cl2
II) HF
III) Ne
IV) KNO2
V) CCl4
a.) I, III, and V

b.) I, II, and III
c.) II and IV
d.) II and V
e.) III, IV, and V
2.) Which response includes all of the following substances that exhibit hydrogen
bonding and no others?
I) H2
II) CH4
III) NH3
IV) SiH4
V) HF
a.) II and V
b.) I, II and III
c.) III, IV and V
d.) III and V
e.) I, III and IV
3.) Which of the following boils at the highest temperature?

a.) C2H8
b.) C3H8
c.) C4H10
d.) C5H12
e.) C6H14
4.) Which one of the following statements is NOT applicable to molecular solids?
a.) the units that occupy the lattice points are molecules
b.) the binding forces in molecular solids are dispersion forces
c.) molecular solids have relatively low melting points
d.) molecular solids are usually excellent conductors of electricity
e.) molecular solids re soft compared to covalent solids
5.) Which one of the following statements are NOT applicable to metallic solids?
a.) the units that occupy the lattice points are cations
b.) the binding forces in metallic solids are shared electron pairs
c.) the melting points of metallic solids vary over a large range
d.) the hardness of metallic solids range from quiet soft to quite hard
e.) metallic solids conduct electric current well
6.) Which of the following statements is not applicable to covalent solids?

a.) The units that occupy the lattice points are atoms
b.) The binding forces in covalent solids are shared electrons
c.) Covalent solids have low melting points
d.) Covalent solids are very hard
e.) Covalent solids do not conduct electric current well
7.) Which one of the following statements is not applicable to ionic solids?
a.) The units that occupy the lattice points are ions
b.) The binding forces in ionic solids are electrostatic attractions
c.) Most ionic solids are hard and brittle
d.) Ionic solids are usually excellent conductors of electric current
e.) Ionic solids have fairly high melting points
8.) The dissociation process is exothermic if the amount of energy released in bringing
about ______solvent solute___________ interactions exceeds the sum of the amounts of
energy absorbed in overcoming __solute solute_____________ and
solvent solvent___________ interactions.
4
9.) All of the following statements are false EXCEPT
a.) the solubility of a gas in water increases with temperature
b.) dissolving a solid in water is usually endothermic
c.) when an equilibrium is established between molecules in a solid and a
solution, the solution is said to be saturated
d.) if a precipitate forms when a solution is cooled, the solution is supersaturated
e.) network covalent solids are usually soluble in water
Answer B was also accepted
10.) The Henrys Law constant for the solubility of carbon dioxide in water is 0.0769
M/atm at 0.00C. if the pressure of CO2 is 0.550 atm, what concentration of carbon
dioxide can be dissolved in water at 0.00C?
C = kPgas
C = (0.0769 M/atm)(0.550 atm)
0.0423 M = C
5
(20 points)
11.) If 8.32 grams of methanol CH3OH are dissolved in 10.3 grams of water, what is the
molality, mole fraction, % by mass of methanol and molarity of the solution? You can
assume that the solution has the same density as that of pure water.
8.32 grams methanol / 32 g/mole = 0.26 moles methanol
10.3 grams water / 18 g/mole = 0.572 moles water
m=moles solute / Kg solvent
m=0.26 moles / 0.0103 Kg = 25.24 m
X = moles / total moles
X = 0.26 / (0.26+0.572) = 0.312
% by mass = (grams solute / total grams) * 100
% by mass = 8.32 g / (10.3g + 8.32 g) * 100 = 44.68%
M= moles solute / liters solution
Liter of solution = (18.62 grams) / (1.0 g/ml) / (1L/1000mL) = 0.01862 L
M = 0.26 moles / 0.01862 = 13.96 M
6
(10 points)
12.) Calculate the vapor pressure of water at 50.0C. The molar heat of vaporization of
water is 40.7 kJ/mole.
P2
40700 J / mole 1
1
1atm 8.314 J / moleK 373 323
ln
P2 = 0.1311 atm or 100 torr
(10 points)
13.) You are given the following information for ethanol
Normal Melting point
Normal Boiling Point
Critical temperature
Critical pressure
-117 C
78.0 C
243C
63.0 atm
Assume that the triple point is slightly lower in temperature than the melting point and
that the vapor pressure at the triple point is about 10-5 torr.
a.) Sketch the phase diagram for ethanol
b.) Ethanol at 1 atm and 140 C is compressed to 70 atm. Are two phases present at
any time during this process?
(10 points)
14.) Sucrose is a nonvolatile, non-ionizing solute in water. Determine the vapor pressure
lowering, at 27C of a solution of 75.0 grams of sucrose C12 H22O11, dissolved in 180.0
grams of water. The vapor pressure of pure water at 27C is 26.7 torr. Assume the
solution is ideal.
75 g / 342 g/mole = 0.219 moles sucrose

180 g water / 18 g/mole = 10 moles water
X = 0.219 / (10 + 0.219) = 0.0214 mole fraction
P = XP0
P = (0.0214 * 26.7 torr)
P = 0.57 torr
(10 points)
15.) The freezing point of a solution of 1.048 grams of an unknown non-electrolyte
dissolved in 36.21 grams of benzene is 1.39C. Pure benzene freezes at 5.48C and its Kf
value is 5.12 C/m. What is the molecular weight of the compound?
T = 5.48 1.39 = 4.09
4.09 = 5.12C/m * m
0.799 = m
0.799 m = x / 0.03621 Kg
x=0.0289 moles
1.048 grams / 0.0289 moles = 36.2 g/mole
(10 points)
16.) As solution is prepared by dissolving 5.00 grams of an unknown molecular solid in
water to make 1.00L of solution. The osmotic pressure of the solution is 1.61 atm at
25C. What is the molar mass of the solute?
1.61 atm = M (0.0821 Latm/moleK) (298K)

0.0658 = M
0.0658 = moles / L
In one liter of solution you have 0.0658 moles
5.00 grams / 0.0658 moles = 75.98 g/mole

Chemistry 2 Answer Key

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What types of substances have dispersion forces as the dominant intermolecular force?

What types of substances exhibit hydrogen bonding?

Name:_____________________________________________________

a.) I, III, and V

3.) Which of the following boils at the highest temperature?

6.) Which of the following statements is not applicable to covalent solids?

1atm 8.314 J / moleK 373 323

P2 = 0.1311 atm or 100 torr

75 g / 342 g/mole = 0.219 moles sucrose

1.61 atm = M (0.0821 Latm/moleK) (298K)

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