Recycling, Packaging
Recycling, Packaging
Recycling, Packaging
1. Introduction
Recycling is steadily increasing in both the developed and under-developed countries. World population is both growing and becoming more concentrated in
urban areas. Increased urbanization will increase the concentration of packaging
wastes, thus improving collection efforts (1).
The United States Environmental Protection Agencys official statement on
packaging states that in most parts of the developed world, packaging constitutes as much as one-third of the non-industrial solid waste stream. As the developing world races to raise living standards, more countries are seeing significant
growth in their packaging waste. At least 28 countries have laws designed to
encourage reduced packaging and greater recycling of package discards. Many
countries are requiring manufacturers to take back packaging discards or pay
for their recycling (2).
There are no federal packaging mandates of similar nature in the United
States. However, state and local government concern about packaging waste continues to grow, while new containers emerge that complicate recycling. More
recently, government reductions in recycling subsidies and a growing demand
for secondary materials from abroad have placed increased pressure on domestic
recyclers, especially plastic recyclers, who are competing for limited feedstock.
New ways to increase the recovery of secondary materials, including packaging
and plastics, are needed.
Packaging can be made more sustainable by applying the principles of product stewardship. This means: eliminating toxic constituents; using less material; making packaging more reusable; using more recycled content; and
making it more readily recyclable (2).
Kirk-Othmer Encyclopedia of Chemical Technology. Copyright John Wiley & Sons, Inc. All rights reserved.
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has remained constant. The number of landfills in the U.S. in 2007 was 1,754
down from 1,967 in 2006. In 1988 there were 7,924 landfills.
Concerns about landfill disposal costs are becoming less of a factor in promoting North American recycling. The EPA reports that discards sent to landfills
after recycling and combustion with energy recovery declined to 2.5 lb/person/
day.
The European Union is planning to increase recycling to keep waste out of
landfills. By 2012 the Legislature of European Parliament Environmental Committee supported reforms that would stabilize the waste levels to 2009. Recycling
varies from country to country. The Netherlands and Denmark send 10% of
waste to landfills, Eastern Europe and the island nations send 90% of their
trash to landfills. Targets is to reduce 279303 106 t of greenhouse gases. A
ban on discarding biodegradable waste into landfills would be in place (4).
4. Glass
The United States generated 13.6 106 tons of glass in MSW in 2007. About 24%
was recovered for recycling. Soft drinks, beer, food, wine, and liquor containers
represent the largest source of glass generated and recovered for recycling.
Ninety percent of recycled glass is used to make new containers. Since glass
has an unlimited life, it can be recycled repeatedly (5). Glass Packaging Institute
members have set a goal to use 50% higher recycled content by 2013.
4.1. Collection and Sorting. Glass is collected at curb-side or drop-off
locations. Glass is usually co-mingled with different colors and types of glass.
This glass must be sorted by color or other characteristics at a materials recovery
facility. Often glass collected at a drop-off center is separated by color. Local recycling agencies instruct residents on how to recycle glass curbside. Although glass
is made of silica and soda, the type and quantity vary slightly with different
types of glass. These differences can cause manufacturing problems due to different melting points and chemical incompatibility. Neither amber nor brown glass
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is used to make clear glass. Glass separated by color yields cullet (crushed glass)
of higher economic value. Sorting also reduces contamination.
Waste Management Recycle America constructed an automated optical
glass sorting line at its California Facility that removes ceramic and metal contaminants from color-separated clear, brown, green glass. The new sorting technology also has the ability to convert three-color mixed glass into clean usable
cullet.
4.2. Processing. When processing MSW, glass is generally removed by
hand sorting after separation paper and metals. The mineral jig may be used to
separate glass particles from other particles. Particles should be less than 5 cm in
their longest dimension. Glass occurs in the middle layer of the slurry formed by
the mineral jig. Froth flotation is most efficient for particles less than 850 mm in
size. A cationic fatty acid amine surfactant has been used to improve the efficiency of froth flotation of glass.
Today most glass manufacturers rely on a steady supply of recycled cullet to
supplement raw materials. To make glass, manufacturers mix sand, soda ash
limestone and cullet, heat the mixture to a temperature of 2,600 to 2,8008F,
and then mold into the desired shape. Sand is the only material used in greater
volume than cullet in glass manufacturing.
Cullet saves money and helps the environment. It costs less than raw materials and prolongs furnace life since it melts at a lower temperature. Cullet
demands less energy such as electricity, natural gas, and coal. Less energy
means reduced emissions.
4.3. Source Reduction. Source reduction is the process of reducing the
amount of toxicity of waste that is generated. Lightweighting reduces the
amount of material used to make a specific product. Money and resources
saved help make glass a more effective packaging product. The glass container
industry continues to reduce the weight of non-returnable glass. Manufacturers
reduced the weight of non-returnable glass containers by about 44% from 1972 to
1987.
Glass container maker Ardagh, as well as Coca-Cola. Coors, and other beverage companies are using facsimile bottles with built-in active RFID tags and
sensors to identify sites on assembly lines that subject glass to damaging pressure or collisions. In manufacturing, bottling, and transportation processes
were designed to handle heavier and studier bottles. These processes are not
always appropriate for the new more sustainable designs. With lighter glass
weight, the risk of breakage and waste in bottle and filling factories as well as
in transporting these bottles has increased. These new RFID tags were developed to address this problem (6).
4.4. Markets for Recovered Glass. About 80 percent of recycled glass
is used to make new containers. The demand for high quality cullet is larger than
the supply. Factors such as contamination can lead to low quality cullet. High
quality cullet is free of contaminants that can jeopardize the integrity of an
entire batch of glass. The Glass Packaging Institute (GPI) lists a number of secondary uses for high quality cullet: abrasives, aggregate substitute, bead manufacturing (used for reflective paint for highways), decorative applications,
fiberglass, frictionators, and fluxes in metal foundry work. Low quality cullet
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is used in secondary applications such as the manufacture of fiberglass insulation, roadbed aggregate, driving safety reflective beads, and decorative tile (7)
5. Paper
In 2007, a record 54.5% of the paper consumed for packaging in the United States
(45.24 106 t) was recovered for recycling. The amount of paper and paperboard
products in MSW was 80 106 t (3). The American Forest and Paper Association
has set a goal of recovery at 60% by 2012 (8).The paperboard and packaging category covers containerboard used to make corrugated shipping containers and
paperboard used in a wide variety of packaging applications such as folding cartons, blister cards, beverage carriers, mailing tubes, and video cassette boxes.
Containerboard (corrugated board) is actually a composite paperboard
made by sandwiching fluted corrugated medium in between layers of linerboard.
Linerboard, made primarily from both virgin and recovered fiber from old corrugated containers (OCC) is used to make the inner and outer walls of a box. The
inside fluted medium layer in the middle is made almost exclusively from postconsumer recovered fiber from OCC and old newspapers and office papers.
Paperboard containing recovered fiber is a multiply material, formed in
layers of recovered fiber. Often gray in appearance, a white top layer made
from recovered office paper is often used to provide a clean printing surface.
Paperboard mills use more recovered fiber than any other segment of the
paper industry to manufacture a wide variety of product packaging (9).
5.1. Processing. The primary process steps in recycling old corrugated
containers and other paper packing materials are pulping, high-density cleaning,
coarse and fine screening, centrifugal (reverse cleaning), fiber fractionation, and
refining. Pulping disintegrates the containers into individual fibers dispersed in
water. High-density cleaning removes large dense particles such as nails and
large staples. Coarse screening removes large low-density contaminants such
as un-pulped tapes and large adhesives particles. Screening is used to separate
contaminant particles such as plastic, wax, and adhesive particles.
Despite the use of screening and reverse cleaning to remove adhesive
stickies their removal is inefficient. Stickies in pulp cause paper-mill operating
problems by reducing pulp drainage rates on paper machines. They do this by
forming deposits on various areas of the machinery.
Fabrication separates fine particles and short, weak cellulose fibers from
longer, stronger fibers. Refining is used to develop the desired pulp drainage
properties on the paper machine and to control paper bulk and density, strength,
surface smoothness, and porosity. Caustic soaking improves OCC fiber properties. Extensive bleaching can produce high-brightness pulp. Many corrugated
containers are coated with wax. Waxes and adhesives can form a thin film
when making linerboard. Removal of the wax is difficult. Flotation can be
used, but high paper losses make this process uneconomical. A fiber can be
used five to seven times before it becomes too short (from too much pulping).
Recovered paper such as office paper has long cellulose fibers and has the greatest flexibility. It is more valuable and can be used for short fiber (newspaper) and
long fiber (office paper) products.
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7.2. Processing
Aluminum. Cans go to a material recovery facility (MRF) where they are
separated from other food and beverage containers. Since most UBCs are made
into cans, only high quality scrap must be produced. The scrap must be free of
steel, lead, caps, etc. Scrap is baled, which brokers can buy and can manufacturers can purchase. Can sheet manufacturers typically have arrangements
with food processors to refine metal and melt metal into ingots. The can-sheet
manufacturers then melt ingots into can sheets. They produce lids separately
and sell them to the beverage industry. The average can contains 40% of
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8. Regulations
Environmental regulations involving recycling and waste management affect the
packaging industry most.
All of the 50 U.S. states plus 12 of the Canadian provinces have environmental agencies and regulation that cover state, local, and municipal laws. Basically they follow the principles of product stewardship. New York States Solid
Waste Management Act of 1988 sets out the principles of reduce, recycle, and
reuse. The California Beverage Container Recycling and Litter Reduction Act
effective as of September 1986 and amended in January 2008 sets out the law
for efficient and large scale bottle and container recycling. Sections 14500
14501 declare that it is Californias intent to join in large-scale redemption
and recycling of beverage containers. The recycling goal was set out as 80%;
and when any one type of container falls below 65%, a refund value is increased.
The Legislature also urged cities and counties to make redemption and recycling
centers available to the public. The responsibility to provide redemption opportunities rests jointly with manufacturers, distributors, dealers, recyclers, processors, and the Department of Conservation. It established this act to significantly
reduce beverage container litter in the state.
Regulations outside the United States differ greatly, but impact U. S. products. In many countries, the polluter pays principle and the Extended Produce
Responsibility (EPR) is at the core of legislation. EPR has grown in popularity in
Central and Eastern Europe. Asia is involved in regulatory activities and has
achieved complex packaging design requirements.
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8.1. Bottle Bills. The term bottle bill refers to a container deposit law,
that is, a refundable deposit is paid on a beer, soft drink, or other beverage container at the time of purchase.
History. It was not until after World War I that cans replaced refillable
bottles in the beer industry. By 1960, approximately 47% of beer sold in the
United States was packaged in cans and no-return bottles. Soft drinks were
still sold in refillable glass bottles. With the centralization of the beverage industry, soft drinks shifted to no-deposit no-return one-way bottles and cans. This
trend resulted in an explosion of beverage container litter. The first bottle bill
was passed in Vermont in 1953. It did not require a deposit but banned the
sale of beer in non-refillable bottles. This law eventually expired due to the
strong beer lobby.
By 1970 cans and one-way bottles increased to 60% of the market share.
British Colombia enacted the first beverage container recovery system in
North America in 1970.
In 1971, Oregon passed the first bottle bill (deposit law). By 1986, ten states
enacted some from of bottle bill. Some of these states covered water, juice, and
other beverage not included in the Oregon bill. However, in 2009, Oregon
made its first change to its original bill by covering bottle water and flavored bottle water containers (18).
Current Bills. In 2009, eleven states and twelve Canadian provinces have
a deposit law. Several states and provinces have expanded their laws to cover
beverages such as juice and sports drinks, tea, and bottled water. Most of
these beverages did not exist when the original bill was passed. No state deposit
law has been repealed. The eleven U.S. states are California, Connecticut, Delaware, Hawaii, Iowa, Maine, Michigan, Massachusetts, New York, Oregon, and
Vermont (19).
These bills were intended to reduce beverage container litter. Now the protection of natural resources through recycling and reduction of solid waste going
to landfills. Seven states reported a reduction in beverage container litter ranging from 73 to 83% (19).
Senator Ed Markey of Massachusetts has introduced an amendment to the
Solid Wastes Disposal Act to require a refund value for certain beverage containers (of metal, glass, or plastic or in combination). Deposits would be $0.05, adjustable for inflation. The resources would go to the state for pollution prevention
and recycling. This Bottle Recycling Climate Protection Act (introduced November 2007) would apply to all of the United States. States with high recycling rates
would be exempt (19).
Opponents of bottle bills include beverage container manufacturers, soft
drink bottlers, beer, wine, and liquor distributors, and retail grocers. They consider the bottle bills inefficient and costly. Bottlers of new age bottled drinks, ie,
juice, sports drinks, water have joined the opposition. A new group of bottle bill
opponents are haulers and owners of materials recovery facilities who want revenue from the valuable aluminum cans recovered by bottle bills (19).
Other countries that have bottle bills are Australia, Austria, Belgium, Denmark, Finland, Germany, Israel, Keribati Federated Micronesia, the Netherlands, Norway, Sweden, and Switzerland.
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10
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packaging as much as possible. And then identify the critical area which prevents
further reduction in weight or volume of the packaging component. (2) Recovery
standards. Packaging components must be recoverable by at least three recovery
routes (energy, organic, or material recovery). (3) Reuse. Optional but must meet
the requiremnts of the reuse standard if it is claimed as reusable. (4). Heavy
metal content. Sets a concentration limit for lead, cadmium, mercury, and hexavalent chromium. (5) Hazardous substances reduction. Noxious substances must
be minimized if they could be released in emissions, ash or leachate when the
packaging is landfilled or burned.
All packaging placed on the EU market must be in compliance with ERP or may
be removed from the market. U.S. companies must incorporate the ERs into their
packaging design and document how each standard of the Directive considered.
One of the problems with the Directive.is that each country can set up its
own economic instruments (ie, taxes, deposits, industry collection fees, or a
combination), and each country can stress different types of packaging from different sources. However, the European Parliament has adopted binding targets
for the recycing of waste for its 27 member countries. Plan should be formed by
2014 for full use by 2020. Countries that fail to comply will be faced with full legal
action (22).
8.6. International Material Restriction. South Korea currently bans
packaging press packed, coated or shrink-wrapped in PVC. Several countries
are expected to charge more for PVC packaging. Expanded polystyrene is forbidden in South Korea for packaging toys and composite matrials. Phase outs apply
to packaging of electrical, office, and audio-visual products. An increasing number have restrictions on the use of phthalates (Denmark, Sweden, Norway, and
Japan) used in food packaging and toys. Many retailers, especially in Asia and
Europe refuse to accept packaging made of PVC. France and Denamrk provide
a fee reduction of certain materials that contain more than 50% recycled material. China has banned free plastic bags (23).
8.7. International Packaging Reduction. Several countries have
implemented restrictions of empty space and the permissible number of layers
in a packaging product. South Korea has a limit of no more that 1035% empty
space or 25-40% for a set product (a gift containing several packaged products).
Australia has limits that range from 2540%. There is a 40% limit in Japan for
cosmetic products. New Zealand has regulations that forbids deceptive packaging. Many countries, such as, Australia, Belgium, the Netherlands, Greece,
Slovakia, Spain, and South Korea require companies to submit a detailed packaging reduction plan. The EU may make packaging reduction part of its reporting
requirement. Reduction plans vary. Belgium, Greece, and the Netherlands
require a company to develop a plan only if the goods are manufactured in that
country. Spain and Slovakia require a plan if the quantity of packaging placed in
the market exceeds a cetain tonnnage (21).
BIBLIOGRAPHY
1. J. Borchardt, Recycling in K. Yam, ed., The Wiley Encyclopedia of Packaging, 3rd
ed., Wiley, Hoboken, N.J., 2009.
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11
MICHALINA BICKFORD
Staff
12
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Weight %
paper
plastics
metals
glass
rubber, leather, textiles
yard trimmings
food scraps
32.7
12.1
8.2
5.3
7.6
12.8
12.5
Ref. 3.
Total generation,
103 t
Recovery,
103 t (%)
Discards,
103 t
2,960
4,150
410
3,000
2,040
300
770
13,630
680(23.0)
570 (13.7%)
2,280
3,580
410
2,690
2,030
280
770
12,040
3,760
5,650
1,660
6,400
4,570
2,620
6,070
30,730
Ref. 12.
PET = poly(ethylene terephthalate)
HDPE = high density polyethylene
PVC = poly(vinyl chloride)
LDPE = low density polyethylene
LLDPE = linear low density polyethylene
PP = polypropylene
PS = polystyrene
b
310 (10.3%)
10(0.5%)
20 (6.7)
1,590 (11.7)
680 (18.1)
570(10.1)
310 (4.8%)
10(0.2%)
20(0.8%)
500(8.2%)
2,090(6.8%)
3,080
5,080
1,660
6,090
4,560
2,600
5,570
28,640