Spec Epoxyprene Enr Tds

Epoxyprene - a specialty polymer
EPOXYPRENES are cis 1,4 polyisoprenes with epoxide

groups randomly dispersed along the polymer backbone . Two
grades are available commercially from the manufactures
Muang Mai Guthrie Public Company Limited of Thailand,
Epoxyprene 25 and Epoxyprene 50. indicating 25% and 50%
epoxidation.
Epoxidation results in a systematic increase in the polarity
and glass transition temperature ; these increase are reflected
in the vulcanizate properrties. Property changes with
increasing level of epoxidation include :
Table 1 : Typical properties of Epoxyprenes.

Property
Epoxide level, %
Glass transition temp C
3
Density,Mg/m
-3 0.5
Solubitity parameter,(jm )
Lovibond colour
Mooney viscosity
ML(1+4),100 C
Protein level,amg/g rubber
Latex allcrgen activity,
normalized unit
an increase in damping ;
a reduction in swelling in hydrocarbon oils ;
a.
a decrease in gas permeability ;

increase
in
silica
reinforcement
0.97
1.02
17.4
4.5
70-90
80-100
0.0008
18.2
3.5
70-90
80-100
0.0008
2- 4
2- 4
Lowry method used to measure protein levels.

Protein levels of SMR CV and AMR 10
an increase in absorption of microwave energy ;

an
Epoxyprene25 Epoxyprene 50
25 2
50 2
-47
-24
;improved
measured at <0.02 mg/g rubber.

b.
compatibility with polar polymers like polyvinyl

chloride ;
reduced rolling resistance and increased wet grip.
The epoxidation process also reduces the level
Of protein inherent of the starting natural rubber.
Strength and fatigue properties of Epoxyprenes are still
RAST method used. Control samples : untreated

gloves, 362: raw natural latex,100.
The high adhesion characteristics of Epoxyprenes can

result in their compounds sticking to the rolls of mills
under certain processing conditions. Such problems can
be overcome by careful control of the mill temperature or
by the simple addition of a process aid such as Struktol
high because being stercoregular polymers.
A60.
Epoxyprenes are able to undergo strain crystallization.
Compounding
Epoxyprenes may be vulcanized in the usual manner
The general properties of Epoxyprenes are shown in Table
applicable for unsaturated polymers. However, for best
1. Epoxyprenes exhibit a unique set of properties and should
ageing resistance, the use of sulphur is recommended at
be considered where there are problems with current polymer
1.5 parts phr or lower. Hence, a semi EV or EV systems,
usage of new specifications need to be met.
sulphur donor or sulphurless formulations are normally
Processing
used
for
Epoxyprenes.1
As
with
other
rubbers,
prevulcanization inhibitors can be used to extend

Generally processing characteristics are similar to those of a
natural rubber and standard mix cycles may be employed.
processing safety.
The principles of protection of unsaturated rubbers
However, Epoxyprenes do mot need to be
against oxidative ageing and ozone are applicablu to
premasticated even though their Mooney viscosities are high,
Epoxyprene. In addition the sulphur acids produced by
as the breakdown on a mill or in an internal mixer is rapid.
oxidation of the sulphur crosslinks may open the epoxides
The rapid initial breakdown of Eprxyprene 25 leads
resulting in stiffening of vulcanizates. These acids are
to easy dispersion of fillers and power savings. The slower
also produced in other sulphur crosslinked polymers but
subsequent breakdown rate enables mixes to be reworked
are not detrimental to properties. The addition of abase to
without substantial changes in viscosity. The breakdown rate
Epoxyprene formulations neutralizes these sulphur acids
of Epoxyprene 50 is higher than that of Epoxyprene 25.
and inhibits the stiffening of vulcanizates.

All Epoxyprene formulations should be compounded
with a base, the preferred material being calcium stearate
at a loading of 3 to 5 parts phr. This level of base lcads to
substantial improvements in ageing resistance.
Table 2 : Physical properties of black and silica

Epoxyprenes
Filler (50 Parts phr ) Polymer
Hardness,IRHD
Modulus at 300%,MPa
Tensile strength, MPa
Elongation at break, %
Compression set,25%,24b/70C,%
Akron abrasion,mm3 / 500 rev
Goodrich HBU,C
Dunlop resilience,% , 23 C
NR
65
11.9
29.5
495
18
21
7
66
N330 Black
E-25
69
12.4
25.5
435
17
14
7
49
E-50
73
13.5
24.5
500
21
11
23
31
NR
65
5.8
23.5
720
32
63
47
68
Silica
E-25
67
12.8
21.0
405
18
15
7
51
E-50
68
12.6
27.5
435
22
14
19
38
Figure 1 : Microwave energy absorption by Epoxyprenes

Figure 2 : Air permeability rating at 23 C
Epoxyprenes respond to the addition of fillers in a

similar manner to other rubbers with the exception of
silicas. Here a high degree of reinforcement is observed in
the absence of a coupling agent due to a specific
interaction between the rubber and filler. Comparable
vulcanizate properties are observed for black and silica
Figure 3 : Oil resistance of some selected polymers.
filled vulcanizates (Table 2) without the addition of a

silica coupling agent.
Epoxyprenes may be compression moulded, extruded
and injection moulded employing standard formulations,
particularly those associated with natural rubber.
Due to its polar nature, Epoxyprenes can be heated
using microwave energy and have been used as additives
to increase the microwave heating rate of non-polar
polymers (Figure 1)
Properties/Applications
The properties of Epoxyprenes and hence, applications.
are dominated by its ability to strain crystallize, its glass
transition
temperature
and
Vulcanizates thus exhibit low
solubility
parameter.
gas permeability ( Figure 2 ) and high oil resistance

(Figure3). Epoxyprenes are beneficial where these
properties are required in combination with high
tensile, fatigue or tear strengths, particularly when the use

of reinforcing fillers is not practical.
Figure 5 :
Figure 4 : Relilience of natural rubber and Epoxyprens.
Wet traction/rolling resistance properties of polymers

containing 50 parts phu of filler. The higher the value the
better
property
performance.(a)
NR/black.(b)
OESBR/black (c) Epoxyprene 25 /
black.
(d)
Epoxyprene 25/silica.
Typical properties of black-and silica-filled (no

coupling agent) Epoxyprene vulcanizates are recorded
in Table2.
The good Akron abrasion resistance is indicative of the
Figure 6 : Cured adhesion of Epoxyprene
excellent wear resistance of Epoxyprene-covered conveyor

belts operating under severe conditions.
The glass transition temperature increases with epoxide
content hence damping increases and resilience decreases.
Typical resilience/hardness correlations for natural rubber,
Epoxyprene 25 and Epoxyprene 50 are shown in Figure 4.
Thus Epoxyprenes are used in antivibration mountings,
surrounds for audio speakers, machinery, road vehicles and
railway coaches. High damping is also advantageous in shock
absorption, eg footwear components such as heel inserts or
mid sole components. Acoustic devices such as constrained
layer damping components have been constructed to reduce
The high hysteresis of Epoxyprenes is also
noise emission from vibrating pannels in machinery or
translated in high wet friction properties. Epoxyprene
automotive vehicles. 2
25 is an excellent tyre tread rubber as its
A compatible blend with PVC can be used to further
hysteresis/temperature profile results in high wet
increase the damping of Epoxyprene 50 ,with the additional
traction and low rolling resistance, properties which
advantage of enhancing ozone resistance.
are illustrated in Figure 5.
As the damping is related to the glass transition
The
solubility
parameters
and
ability
of
temperature, the former is temperature dependent. However, a
Epoxyprene to exhibit specific interactions with
recently developed blend system based on
chlorinated
Epoxyprene
polymers,
eg
polychloroprene
and
exhibits high damping characteristics over a wide temperature
polyvinyl chloride,results in excellent adhesive
range.3 This system has extensive applications.
properties. Epoxyprenes are employed as primers, tie

coats, sealants and bonding agents. The adhesion of
Epoxyprenes to a number of other polymers is shown in

Figure 6.
Analysis of
Epoxyprene
samples by the Rubber
Research Institute of Malaysia4 showed negligible levels

of water solution proteins present in the rubber (Table 1)
Clinical test on allergenicity by the University of Finland.
where the allergen activity lot all the samples was
normalize talking the control ( Natural rubber latex) as
100. indicated very lows allergernicity for the two
Epoxyprene sample.
Epoxyprenes
unique
combination
of
desnable
properties make it the preferred .special purpose polymer

for a range of new applications of as an improvement
over other polymers to enhance existing products.
References
1. Gelling I.R. and Metherell., C.,Vulcanization systems
for ENR 50,Rubber Developments, 199346,49-61
2. Metherell,
C.M.
Epoxidized
natural
rubber
for
controlled damping applications. Progress in rubber

Technology. 1993.9.237
3. Ahmadi, H.R.,Puller , K.N.G., Legorbum. N.and
Metherell, C.M., Epoxidized natural rubbers and their
blends; dynamic storage modulus and damping
behaviour. Paper presented at the North American
Conference on Smart Structures and Materials, Florida,
1994. MRPRA Reprint 1494.
4.Wong, S.T., Internal Laboratory Report, Guthrie

Research Chemara, August 1994
5. Wong, S.T., Internal Laboratory Report Guthrie
Research Chemara, September 1994.
6. Gelling. L.R., Epoxidized natural rubber, Progress in.
Rubber. Technology.1991,7,271
There are many potential applications for Epoxyprene,but this paper only presents the basic properties of these
polymers and a limited number of applications More detailed information and technical advice and assistance in the
use of Epoxyprenes in particular applications can be obtained from:
MUANG MAI GUTHRIE PUBLIC COMPANY LIMITED.
CONTACT : NANTCHANOK(CAROL)/RUBBER DEPT

COMPANY : SAN-THAP INTERNATIONAL CO.,LTD
EMAIL
: NANTCHANOK@SAN-THAP.CO.TH
MOBILE PHONE : +66-95-639-1565

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Epoxyprene - a specialty polymer

EPOXYPRENES are cis 1,4 polyisoprenes with epoxide

Table 1 : Typical properties of Epoxyprenes.

a decrease in gas permeability ;

Lowry method used to measure protein levels.

an increase in absorption of microwave energy ;

measured at <0.02 mg/g rubber.

compatibility with polar polymers like polyvinyl

RAST method used. Control samples : untreated

The high adhesion characteristics of Epoxyprenes can

high because being stercoregular polymers.

Epoxyprenes are able to undergo strain crystallization.

The general properties of Epoxyprenes are shown in Table

applicable for unsaturated polymers. However, for best

1. Epoxyprenes exhibit a unique set of properties and should

ageing resistance, the use of sulphur is recommended at

be considered where there are problems with current polymer

1.5 parts phr or lower. Hence, a semi EV or EV systems,

usage of new specifications need to be met.

sulphur donor or sulphurless formulations are normally

prevulcanization inhibitors can be used to extend

However, Epoxyprenes do mot need to be

against oxidative ageing and ozone are applicablu to

premasticated even though their Mooney viscosities are high,

Epoxyprene. In addition the sulphur acids produced by

as the breakdown on a mill or in an internal mixer is rapid.

oxidation of the sulphur crosslinks may open the epoxides

The rapid initial breakdown of Eprxyprene 25 leads

resulting in stiffening of vulcanizates. These acids are

to easy dispersion of fillers and power savings. The slower

also produced in other sulphur crosslinked polymers but

subsequent breakdown rate enables mixes to be reworked

are not detrimental to properties. The addition of abase to

without substantial changes in viscosity. The breakdown rate

Epoxyprene formulations neutralizes these sulphur acids

of Epoxyprene 50 is higher than that of Epoxyprene 25.

and inhibits the stiffening of vulcanizates.

Table 2 : Physical properties of black and silica

Figure 1 : Microwave energy absorption by Epoxyprenes

Epoxyprenes respond to the addition of fillers in a

Figure 3 : Oil resistance of some selected polymers.

filled vulcanizates (Table 2) without the addition of a

Vulcanizates thus exhibit low

gas permeability ( Figure 2 ) and high oil resistance

tensile, fatigue or tear strengths, particularly when the use

Wet traction/rolling resistance properties of polymers

OESBR/black (c) Epoxyprene 25 /

Typical properties of black-and silica-filled (no

Figure 6 : Cured adhesion of Epoxyprene

excellent wear resistance of Epoxyprene-covered conveyor

The high hysteresis of Epoxyprenes is also

noise emission from vibrating pannels in machinery or

translated in high wet friction properties. Epoxyprene

25 is an excellent tyre tread rubber as its

A compatible blend with PVC can be used to further

hysteresis/temperature profile results in high wet

increase the damping of Epoxyprene 50 ,with the additional

traction and low rolling resistance, properties which

advantage of enhancing ozone resistance.