Aqueous Hydrogen Peroxide: Ó UCLES 2004 5070/01/M/J/04
Aqueous Hydrogen Peroxide: Ó UCLES 2004 5070/01/M/J/04
Aqueous hydrogen peroxide undergoes catalytic decomposition as shown in the equation below.
2H2O2(aq) 2H2O(l) + O2(g)
The diagram shows part of the apparatus used to measure the rate of decomposition.
X
aqueous
hydrogen
peroxide
catalyst
burette
gas syringe
measuring cylinder
pipette
chromatography paper
beaker
spot of mixture
liquid
be placed so that the spot is just below the level of the liquid.
UCLES 2004
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3
3
In a sample of air at 25 oC, the molecules of oxygen, nitrogen and carbon dioxide all move with
different average speeds.
Which of the following lists the molecules in order of decreasing average speed?
fastest
slowest
carbon dioxide
oxygen
nitrogen
nitrogen
oxygen
carbon dioxide
oxygen
carbon dioxide
nitrogen
oxygen
nitrogen
carbon dioxide
Which of the following is the best method of obtaining pure water from ink?
A
chromatography
distillation
filtration
freezing
18 x 100
160
UCLES 2004
5 x 18 x 100
160 + 1 8
18 x 100
160 + 18
5070/01/M/J/04
5 x 18 x 100
160 + (5 x 18)
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4
6
fertiliser
solution
dirty green
precipitate
forms
warm the
mixture
UCLES 2004
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5
8
Li+
Mg2+
B
key
Silicon atom
Oxygen atom
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6
11 In the circuit below, the lamp lights up.
lamp
electrodes
substance X
liquid ethanol
12 The formula of china clay (aluminium silicate) was shown in an old book as Al2O3.2SiO2.2H2O.
This formula is shown in a modern book as Al2(OH)x Si2Oy.
What are the values of x and y in the modern formula?
x
13 What is the concentration of iodine, I2, molecules in a solution containing 2.54 g of iodine in
250 cm3 of solution?
A
U4Cl
UCl2
UCLES 2004
UCl4
U2Cl
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7
15 The equation for the burning of hydrogen in oxygen is shown below.
2H2(g) + O2(g) 2H2O(g)
Which information does this equation give about the reaction?
A
16 A current was passed through concentrated aqueous potassium chloride, KCl, as shown.
+
concentrated aqueous
potassium chloride
K+ only
Cl and OH
K+ only
Cl only
K+ and H+
Cl only
K+ and H+
Cl and OH
UCLES 2004
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17 When the experiment shown was set up, the bulb lit, but there were no decomposition products at
the electrodes.
lamp
+ve
_ve
electrodes
X
What is X?
A
bromine
mercury
H2O(l) H2O(s)
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9
19 The diagram shows apparatus for measuring the volume of hydrogen given off when an excess of
dilute hydrochloric acid is added to powdered metal. The volume of gas is measured at room
temperature and pressure.
dilute
hydrochloric
acid
tap
graduated
tube
water
metallic
powder
The experiment is carried out three times, using the same mass of powder each time but with
different powders:
pure magnesium
pure zinc
Which powder gives the greatest volume of hydrogen and which the least volume?
greatest volume of H2
least volume of H2
magnesium
zinc
magnesium
the mixture
zinc
magnesium
zinc
the mixture
20 Which change will increase the speed of the reaction between 1 mol of each of the gases, X and
Y?
A
a decrease in temperature
UCLES 2004
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10
21 Dilute hydrochloric acid was reacted with magnesium ribbon and the volume of hydrogen gas
evolved was measured for the first 80 s.
40
30
total
volume of
20
hydrogen
produced / cm3
10
0
10
20
30
40
60
50
70
80
0.4 cm3 / s
2.5 cm3 / s
4 cm3 / s
40 cm3 / s
22 Small portions of aqueous potassium iodide and of acidified, aqueous potassium manganate(VII)
were added to four solutions. The colour changes seen are shown in the table.
solution number
potassium iodide
potassium manganate(VII)
colourless to red
purple to colourless
colourless to red
no change
no change
purple to colourless
no change
no change
1 only
UCLES 2004
1 and 2 only
1 and 3 only
5070/01/M/J/04
2 and 4 only
11
23 The table gives information about three indicators.
colour change
indicator
low pH
methyl orange
bromothymol blue
phenolphthalein
pH at which colour
change takes place
high pH
red
yellow
4.0
yellow
blue
6.5
colourless
pink
9.0
If equal volumes of these three indicators were mixed, which colour would be observed at pH 5?
A
blue
green
orange
yellow
temperature / oC
10
20
30
40
50
HCl / cm3
50
40
30
20
10
NaOH / cm3
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12
25 Which method of preparation of a pure salt solution requires the use of a pipette and burette?
A
BaCl 2(aq) +
H2SO4(aq)
BaSO4(s)
2HCl (aq)
CuO(s)
2HCl (aq)
CuCl 2(aq)
H2O(l)
KOH(aq)
HCl (aq)
KCl (aq)
H2O(l)
MgCO3(s) +
H2SO4(aq)
MgSO4(aq) +
H2O(l) + CO2(g)
26 Which statement about the manufacture of ammonia by the Haber Process is correct?
A
element 2
element 3
1 and 2
1 and 3
2 and 4
3 and 4
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element 4
13
29 Sodium, aluminium and sulphur are in the same period of the Periodic Table.
What trend in types of oxide occurs across this period?
left
right
acidic
amphoteric
basic
amphoteric
basic
acidic
basic
acidic
amphoteric
basic
amphoteric
acidic
30 Use the Periodic Table to decide which element has all four of the properties shown.
caesium, Cs
cobalt, Co
iodine, I
strontium, Sr
painting it
The activation energy for the reaction of aluminium with other elements is too high.
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33 Which oxide can be reduced to the metal by hydrogen?
A
calcium oxide
copper(II) oxide
magnesium oxide
sodium oxide
34 The data gives the concentration, in parts of pollutant per billion parts of air, of polluting gases in
four different industrialised cities.
In which city are limestone buildings under greatest threat from pollution?
city
sulphur
dioxide
nitrogen
dioxide
ozone
17
46
23
32
33
30
38
40
11
45
14
21
mineral salts
nitrates
oxygen
phosphates
sewage
simple sugar
condensation.
hydrogenation.
hydrolysis.
polymerisation.
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15
37 Methane, CH4, the first member of the alkane homologous series, has a boiling point of 161 oC.
Which molecular formula and boiling point could be correct for another alkane?
molecular formula
boiling point / oC
C2H4
88
C2H6
185
C3H6
69
C3H8
42
results
stays red
aqueous bromine
stays brown
lighted splint
gas burns
ammonia
ethene
methane
oxygen
39 An organic compound, Y, reacts with sodium hydroxide to give a compound with formula
C3H5O2Na.
What is compound Y?
A
ethanol
propane
propanoic acid
propanol
C2H4
UCLES 2004
C2H6
C2H5OH
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CH3CO2H