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Non-Hydrocarbon - Esters: RCOOR Where R and R Represented The Same or Different Alkyl Groups

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SPM Form 5 Terminology and Concepts: Carbon Compounds (Part 7)

Non-Hydrocarbon Esters
1. General formula: CnH2n+1COOCmH2m+1
Where n = 0, 1, 2, 3 and m = 1, 2, 3 (n and m = number of carbon)
RCOOR where R and R represented the same or different alkyl groups.
2. Esters are non-hydrocarbons which contain carbon, hydrogen and oxygen atoms.
3. The functional group in ester is carboxylate group, COO -.
CnH2n+1COOH + CmH2m+1OH > CnH2n+1COOCmH2m+1 + H2O

First part: taken from the alcohol (alkyl group)


Second part: taken from the carboxylic acid (-oic to -oate)

Name of ester
Ethyl methanoate
Methyl ethanoate
Propyl ethanoate
Ethyl propanoate

Molecular formula of
ester
HCOOC2H5
CH3COOCH3
CH3COOC3H7
C2H5COOC2H5

Prepared from
Ethanol + Methanoic acid
Methanol + Ethanoic acid
Propanol + Ethanoic acid
Ethanol + Propanoic acid

4. Physical properties of ester


Name
Odour
3-metylbutyl acetate Banana
Ethyl butanoate
Pineapple
Octyl ethanoate
Orange
Isoamyl isovalerate
Apple
Simple esters are colourless liquid and are found in fruits and flowers.
Esters have sweet pleasant smell.

Esters are covalent compounds.

Esters are insoluble in water but soluble in organic solvent.

Esters are less dense than water.

Esters are neutral and cannot conduct electricity.

The higher and more complex esters have higher boiling points and less volatile.

Natural sources:

Vegetable oils (palm oil) and liquids esters can be found in plants derived from
glycerol and fatty acids.
Fats are solid esters (milk fat) derived from glycerol and fatty acids.

Waxes (beewax) are solid ester derived from long-chain fatty acids and long-chain
alcohols.

5. Uses of Esters

Preparation of cosmetics and perfumes (esters are volatile and have sweet smell).
Synthetic esters used as food additives (artificial flavour).

Natural esters serves as storage reserve of energy in living things.

In plant, wax (esters) helps to prevent dehydration and attack of microorganisms.

Esters used as solvents for glue and varnishes.

Esters used to make plastics softer.

Esters used to produce polyester (threads and synthetics fabrics)

Esters used to produce soap and detergents.

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