Cambridge International Examinations

Cambridge Ordinary Level

* 1 5 6 1 4 6 6 2 4 5 *

CHEMISTRY 5070/21
Paper 2 Theory May/June 2016
1 hour 30 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.

READ THESE INSTRUCTIONS FIRST

Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.

Section A
Answer all questions.
Write your answers in the spaces provided in the Question Paper.

Section B
Answer any three questions.
Write your answers in the spaces provided in the Question Paper.

Electronic calculators may be used.

You may lose marks if you do not show your working or if you do not use appropriate units.
A copy of the Periodic Table is printed on page 20.

At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.

This document consists of 19 printed pages and 1 blank page.

DC (NF/SG) 107489/3
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Section A

Answer all the questions in this section in the spaces provided.

The total mark for this section is 45.

A1 Choose from the following polymers to answer the questions.

Terylene

O O C C O O C C

O O O O

PTFE

F F F F F F F F

C C C C C C C C

F F F F F F F F

nylon

N N C C N N C C
H H O O H H O O

starch

O O O O O

poly(propene)

CH3 H CH3 H CH3 H CH3 H

C C C C C C C C

H H H H H H H H

PVC

Cl H Cl H Cl H Cl H

C C C C C C C C

H H H H H H H H
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protein

C N C N C N C N
O H O H O H O H

polyester

O C O C O C O C

O O O O

poly(ethene)

H H H H H H H H

C C C C C C C C

H H H H H H H H

Each polymer can be used once, more than once or not at all.

Which is a polymer that

(a) is made from propene,

.............................................................................................................................................. [1]

(b) will form hydrogen chloride when combusted,

.............................................................................................................................................. [1]

(c) can be hydrolysed to form amino acids,

.............................................................................................................................................. [1]

(d) can be hydrolysed to make simple sugars,

.............................................................................................................................................. [1]

(e) contains the same linkage as that present in a fat?

.............................................................................................................................................. [1]

[Total: 5]

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A2 Hydrogen sulfide, H2S, has a simple molecular structure. It is soluble in water.

(a) Suggest one other physical property of hydrogen sulfide.

.............................................................................................................................................. [1]

(b) Aqueous hydrogen sulfide is a weak acid.

(i) Write an equation to show the dissociation of hydrogen sulfide.

...................................................................................................................................... [1]

(ii) Why is aqueous hydrogen sulfide described as a weak acid?

...........................................................................................................................................

...................................................................................................................................... [1]

(c) Aqueous hydrogen sulfide reacts with aqueous potassium hydroxide.

H2S(aq) + 2KOH(aq) K2S(aq) + 2H2O(l)

What is the minimum volume, in cm3, of 0.150 mol / dm3 KOH required to completely react
with a solution containing 0.170 g of H2S?

volume of KOH(aq) = ................................................... cm3 [3]

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(d) Magnesium reacts with sulfur to make the ionic compound magnesium sulfide.

(i) Predict two physical properties of magnesium sulfide.

1. .......................................................................................................................................

2. .......................................................................................................................................
[2]

(ii) Explain, in terms of electrons, how a magnesium atom reacts with a sulfur atom to make
a magnesium ion and a sulfide ion.

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

...................................................................................................................................... [2]

[Total: 10]

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A3 Esters, such as propyl ethanoate, are often used as solvents.

(a) Give one other use for esters such as propyl ethanoate.

.............................................................................................................................................. [1]

(b) Draw the structure of propyl ethanoate, showing all of the atoms and all of the bonds.

[1]

(c) A bottle of propyl ethanoate is opened in a room. Some of the propyl ethanoate evaporates
and then diffuses into the room.

(i) What is meant by the term diffusion?

...........................................................................................................................................

...........................................................................................................................................

...................................................................................................................................... [1]

(ii) What happens to the rate of diffusion of propyl ethanoate as the temperature of the room
increases?

Explain your answer in terms of the kinetic particle theory.

...........................................................................................................................................

...........................................................................................................................................

...................................................................................................................................... [2]

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(iii) The table shows some information about different esters.

name structure relative molecular mass (Mr)

methyl methanoate HCO2CH3 60
ethyl methanoate HCO2C2H5 74
propyl methanoate HCO2C3H7 88
butyl methanoate HCO2C4H9 102
pentyl methanoate HCO2C5H11 116

Which ester has the greatest rate of diffusion at room temperature and pressure?

...........................................................................................................................................

Explain your answer.

...........................................................................................................................................

...........................................................................................................................................
[2]

[Total: 7]

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A4 Ammonia is manufactured by the reaction between hydrogen and nitrogen in the Haber process.

(a) State the conditions used in the Haber process.

temperature ..............................................................................................................................

pressure ....................................................................................................................................

catalyst ................................................................................................................................. [2]

(b) Describe and explain the effect of increasing the pressure on the rate of this reaction.

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

.............................................................................................................................................. [2]

(c) Explain how a catalyst speeds up the rate of a chemical reaction.

...................................................................................................................................................

.............................................................................................................................................. [1]

(d) Ammonia is used to make fertilisers.

The table gives some information about two fertilisers made from ammonia.

fertiliser formula relative formula mass (Mr)

ammonium nitrate NH4NO3 80
urea (NH2)2CO 60

Use the data in the table to show that urea contains a greater percentage by mass of nitrogen
than ammonium nitrate.

[2]

[Total: 7]

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A5 The statements give some of the chemical properties of metal X and its compounds.

X does not react with cold water.

X fizzes slowly with dilute hydrochloric acid.
X does not react with aqueous sodium chloride.
X reacts with aqueous lead(II) nitrate.
X reacts with aqueous silver nitrate.
XO reacts with magnesium to form X.

(a) Use the information to help arrange the following metals in order of reactivity.

lead, magnesium, silver, sodium and X

most reactive ...........................................................................

...........................................................................

...........................................................................

...........................................................................

least reactive ........................................................................... [2]

(b) Suggest a possible identity for X.

.............................................................................................................................................. [1]

(c) Construct the equation for the reaction between the oxide, XO, and magnesium.

.............................................................................................................................................. [1]

(d) Construct the ionic equation for the reaction between X and aqueous lead(II) nitrate,
Pb(NO3)2(aq).

.............................................................................................................................................. [1]

(e) Metal X is a good electrical conductor and has a high melting point.

Explain why X

conducts electricity, ....................................................................................................

....................................................................................................................................

....................................................................................................................................

has a high melting point. ............................................................................................

....................................................................................................................................

....................................................................................................................................
[3]

[Total: 8]

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A6 The atmosphere contains a large number of gases including oxygen, nitrogen, carbon dioxide,
sulfur dioxide, oxides of nitrogen, methane and chlorofluorocarbons (CFCs).

(a) Carbon dioxide, methane and CFCs are greenhouse gases.

(i) State one effect of an increase in the atmospheric concentration of carbon dioxide and
methane.

...........................................................................................................................................

...................................................................................................................................... [1]

(ii) State one source of methane gas.

...................................................................................................................................... [1]

(iii) State one other environmental effect of the presence of CFCs in the atmosphere.

...................................................................................................................................... [1]

(b) The formula of one chlorofluorocarbon is CFCl 3.

Draw the dot-and-cross diagram to show the bonding in a molecule of CFCl 3. Only draw the
outer-shell electrons.

[1]

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(c) Oxides of nitrogen are produced during the combustion of petrol (gasoline) in a car engine.

(i) Describe the chemical reaction that takes place within a car engine to form
nitric oxide, NO.

...........................................................................................................................................

...................................................................................................................................... [1]

(ii) Most of the nitric oxide and other pollutants present in the exhaust gases of a car are
removed in a catalytic converter.

Describe the redox reactions that happen within a catalytic converter.

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

...................................................................................................................................... [2]

(d) Nitrogen dioxide is one of the causes of acid rain.

Two moles of nitrogen dioxide react with one mole of water to make an aqueous solution of
two acids only.

One of these acids is nitric acid.

Deduce the formula of the other acid.

.............................................................................................................................................. [1]

[Total: 8]

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BLANK PAGE

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Section B

Answer three questions from this section in the spaces provided.

The total mark for this section is 30.

B7 Silver nitrate has the formula AgNO3.

(a) Describe how a pure sample of silver nitrate crystals can be prepared from solid silver oxide,
which is insoluble in water.

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

.............................................................................................................................................. [4]

(b) Aqueous zinc chloride is added to a sample of acidified aqueous silver nitrate.

(i) Describe what you would observe.

...................................................................................................................................... [1]

(ii) Construct the ionic equation, with state symbols, for the reaction that occurs.

...................................................................................................................................... [2]

(c) Aqueous silver nitrate is electrolysed using graphite electrodes.

(i) Identify the product formed at the cathode (negative electrode).

...................................................................................................................................... [1]

(ii) Oxygen and water are formed at the anode (positive electrode).

Construct the equation for the reaction at the anode.

...................................................................................................................................... [1]

(d) Silver nitrate decomposes on heating to form Ag2O, NO2 and O2.

Construct the equation for this reaction.

.............................................................................................................................................. [1]

[Total: 10]

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B8 Cyclohexane, C6H12, is a cycloalkane.

Cycloalkanes react in a similar way to alkanes.

H H
H H
C
H C C H

H C C H
C
H H
H H

cyclohexane

(a) Cyclohexane is a saturated hydrocarbon.

(i) What is the meaning of the term saturated?

...........................................................................................................................................

...................................................................................................................................... [1]

(ii) What is the meaning of the term hydrocarbon?

...........................................................................................................................................

...................................................................................................................................... [1]

(b) Construct the equation for the complete combustion of cyclohexane.

.............................................................................................................................................. [1]

(c) Cyclohexane reacts with chlorine in the presence of ultraviolet light.

This is a substitution reaction.

Write the molecular formulae of two products of this reaction.

.............................................................................................................................................. [2]

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(d) Cyclohexane can be manufactured from hexane as shown in the equation.

C6H14 C6H12 + H2

Calculate the mass of cyclohexane that can be made from 258 g of hexane.
[Mr of cyclohexane = 84]

mass of cyclohexane = ...................................................... g [2]

(e) Another cycloalkane has the following percentage composition by mass.

C, 85.7%; H, 14.3%

(i) Use the percentage composition by mass to show that the empirical formula of the
cycloalkane is CH2.

[2]

(ii) Draw the structure of the cycloalkane with an Mr of 56, showing all of the atoms and all of
the bonds.

[1]

[Total:10]

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B9 Carbon reacts with steam in a reversible reaction.

C(s) + H2O(g) H2(g) + CO(g) H = +131 kJ / mol

The reaction reaches an equilibrium if carried out in a closed container.

(a) Explain, in terms of bond breaking and bond forming, why this reaction is endothermic.

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

.............................................................................................................................................. [2]

(b) When one mole of hydrogen, H2, is formed, 131 kJ of energy is absorbed.

Calculate the amount of energy absorbed when 240 dm3 of hydrogen, measured at room
temperature and pressure, is formed.

energy absorbed = ...................................................... kJ [2]

(c) Predict, with a reason, how the position of equilibrium of this reaction changes as the

(i) pressure is increased at constant temperature,

...........................................................................................................................................

...........................................................................................................................................

...................................................................................................................................... [2]

(ii) temperature is increased at constant pressure.

...........................................................................................................................................

...........................................................................................................................................

...................................................................................................................................... [2]

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(d) The reaction between carbon and steam is a possible source of hydrogen.

(i) Suggest one disadvantage of using this reaction as a source of hydrogen.

...........................................................................................................................................

...................................................................................................................................... [1]

(ii) Another source of hydrogen is the cracking of hydrocarbons from crude oil.

Give one advantage of manufacturing hydrogen from the reaction of carbon with steam
rather than from crude oil.

...........................................................................................................................................

...................................................................................................................................... [1]

[Total: 10]

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B10 Both zinc and iron react with dilute sulfuric acid.

Zn(s) + H2SO4(aq) ZnSO4(aq) + H2(g)

Fe(s) + H2SO4(aq) FeSO4(aq) + H2(g)

(a) A 0.65 g sample of zinc is reacted with excess sulfuric acid.

(i) Calculate the volume of hydrogen, measured at room temperature and pressure, formed
in this reaction.

volume of hydrogen = .................................................. dm3 [2]

(ii) Explain why a different volume of hydrogen, measured at room temperature and
pressure, is formed when 0.65 g of iron is reacted with excess sulfuric acid.

...........................................................................................................................................

...................................................................................................................................... [1]

(b) A mixture of iron powder and zinc powder is added to excess sulfuric acid.

When the reaction stops, aqueous sodium hydroxide is added drop by drop to the reaction
mixture until it is in excess.

Describe what you would observe during the addition of aqueous sodium hydroxide and
explain the reactions taking place.

observations

...................................................................................................................................................

...................................................................................................................................................

explanations

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................
[4]

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(c) The products of heating iron(II) sulfate are iron(III) oxide, sulfur dioxide and sulfur trioxide.

(i) Explain how you can tell that the reaction involves an oxidation.

...........................................................................................................................................

...................................................................................................................................... [1]

(ii) Describe the chemical test for sulfur dioxide.

test ....................................................................................................................................

...........................................................................................................................................

observation ........................................................................................................................

...........................................................................................................................................
[2]

[Total: 10]

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UCLES 2016 5070/21/M/J/16

 The Periodic Table of Elements
Group

UCLES 2016
I II III IV V VI VII VIII
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18

Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
20

85 88 89 91 93 96 101 103 106 108 112 115 119 122 128 127 131
55 56 5771 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

5070/21/M/J/16
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209
87 88 89103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
232 231 238

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.)