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    24: 12.07.05 Flory-Huggins Theory: Today

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    This document summarizes a lecture on the Flory-Huggins theory of polymer solutions. It discusses concepts like the entropy of mixing based on counting polymer chain configurations, the energy of mixing using the Bragg-Williams approximation, and predictions of the Flory-Huggins model. It provides reading from a textbook on polymer solutions and announces a final quiz on concepts from lectures 17-24, including thermodynamics and statistical mechanics.

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    24: 12.07.05 Flory-Huggins Theory: Today

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    This document summarizes a lecture on the Flory-Huggins theory of polymer solutions. It discusses concepts like the entropy of mixing based on counting polymer chain configurations, the energy of mixing using the Bragg-Williams approximation, and predictions of the Flory-Huggins model. It provides reading from a textbook on polymer solutions and announces a final quiz on concepts from lectures 17-24, including thermodynamics and statistical mechanics.

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    This document summarizes a lecture on the Flory-Huggins theory of polymer solutions. It discusses concepts like the entropy of mixing based on counting polymer chain configurations, the energy of mixing using the Bragg-Williams approximation, and predictions of the Flory-Huggins model. It provides reading from a textbook on polymer solutions and announces a final quiz on concepts from lectures 17-24, including thermodynamics and statistical mechanics.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    59 views4 pages

    24: 12.07.05 Flory-Huggins Theory: Today

    Uploaded by

    dwiputriliana
    This document summarizes a lecture on the Flory-Huggins theory of polymer solutions. It discusses concepts like the entropy of mixing based on counting polymer chain configurations, the energy of mixing using the Bragg-Williams approximation, and predictions of the Flory-Huggins model. It provides reading from a textbook on polymer solutions and announces a final quiz on concepts from lectures 17-24, including thermodynamics and statistical mechanics.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 4

    3.

    012 Fundamentals of Materials Science Fall 2005

    Lecture 24: 12.07.05 Flory-Huggins Theory

    Today:

    LAST TIME ........................................................................................................................................................................................ 2


    Lattice Models of Solutions ..........................................................................................................................
    .............................. 2
    ENTROPY OF MIXING IN THE FLORY-HUGGINS MODEL .................................................................................................................. 3
    CONFIGURATIONS OF A SINGLE CHAIN.........................................................................................................
    ................... 3
    COUNTING CONFIGURATIONS FOR A COLLECTION OF CHAINS .................................................................
    .............. 4
    THE ENERGY OF MIXING IN THE FLORY-HUGGINS MODEL............................................................................................................. 7
    The Bragg-Williams approximation
    .......................................................................................................................................... 9
    PREDICTIONS FROM THE FLORY-HUGGINS MODEL ...................................................................................................................... 11
    REFERENCES .................................................................................................................................................................................. 14

    Reading: Dill and Bromberg Ch. 31 Polymer Solutions, pp. 593-605.

    Supplementary Reading:

    Announcements:

    Final quiz: Tuesday, Dec. 20 1:30pm-4:30pm DuPont


    Same format and length as first 2 quizzes; you will have 3 hrs but quiz should
    only take 2 hrs
    Equation sheet is allowed, as in prior quizzes

    Review sessions (tentatively): Thermo/Stat Mech review: Friday, Dec. 16, 5-7pm (normal recitation room)
    Structure review: Sunday, Dec. 18, time TBD (normal recitation room)

    Thermo coverage on Quiz 3: lectures 17-24


    Lecture 25 Flory-Huggins theory continued 1 of 14
    12/7/05

    3.012 Fundamentals of Materials Science Fall 2005

    Last time

    Lattice Models of Solutions

    Lattice models are a form of COARSE GRAINING, where only the most important molecular details of a
    system are retained in a statistical mechanical model. This is a powerful approach to create stat mech
    models where meaningful predictions can be made for complex materials. We began a derivation of the
    free energy of mixing for a polymer solution based on Flory-Huggins theory:

    np = number polymer chains M = total lattice sites = ns + Nnp


    N = number of segments per chain
    ns = number of solvent molecules

    Figure by MIT OCW.


    Lecture 25 Flory-Huggins theory continued 2 of 14
    12/7/05

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