EXPERIMENT 5 : ANODES AND CATHODES IN CORROSION

REACTIONS

OBJECTIVE :

To perform corrosion testing on several metals and understand hoe corrosion

occur.
To show the existance and location of anodes and cathodes in corrosion
processes.
To demonstrate methods of effective corrosion protection.

INTRODUCTION :

In analyzing corrosion, the first thing that must be determined is whether a

metal reacts with its environment. It is generally accepted that corrosion processes
are caused by the formation of electrochemical cells. The electrochemical reactions
in these cells can be divided into two reactions:- anodic reactions and cathodic
reactions where each reaction is called a half-cell reaction. In the anodic reaction,
metal goes into solution as an ion. In the cathodic reaction, electrons provided by the
anode, flow through the metal until they reach the cathode where they can be
combined with positively charged ions. Both the anodic and cathodic reactions must
occur simultaneously for a corrosion process to proceed.

The electrode potential in the electrochemical cell is when an ideal metal is

placed in an electrolyte, an electrode potential develops that is related to the
tendency of the material to give up electrons. To measure this tendency, we measure
the potential difference between the metal and a standard electrode using a half-cell.
The relative corrosion resistance of a material can be evaluated using the following
criteria: Relative Corrosion Resistance mpy outstanding 200 Consider a car engine
block with and without the addition of antifreeze, as an example of a corrosion rate
problem. Engine blocks are generally made from low carbon steel that corrodes
when exposed to tap water. This is the brown rust that is often seen in cooling
systems containing water only. The corrosion reactions for low carbon steel are:
 Fe --> Fe2+ + 2e-
Fe2+ --> Fe3+ + e-
O2 + 2H2O + e- --> 4OH-
2Fe + 2H2O + O2 --> 2Fe2+ + 2OH- --> 2Fe(OH)2
2Fe(OH)2 + H2O + 1/2 O2 --> 2Fe(OH)3 (rust)

PROCEDURE :

1. 200 mL of 0.1 M sodium nitrate was heated to boil in a 500 mL beaker. While
stirring with a glass rod, 3 g of powdered agar was added. The mixture was
heated and stirred until agar forms a suspension.
2. 10 drops of 0.1 M potassium ferricyanide and 10 drops of phenolphthalain
was added to the agar suspension.
3. Three iron nail was cleaned with sand paper.
4. One iron nail was placed in the bottom of the first petri dish.
5. The 10 cm of copper wire and 10 cm of zinc wire was polished with sand
paper.
6. The 10 cm copper wire was wrapped around the second iron nail.
7. The 10 cm zinc wire was wrapped around the third iron nail.
8. The second and third wrapped iron was placed in the bottom of the second
petri dish. The two wrapped nail is not touch each other.
9. Enough warm agar was pour in both petri dishes to cover all of the iron strips
to a depth of about 1 mm.
10. Both dishes was covered and let stand about 48 hours.
11. On day 1, the subsequent color developments was observed over a period of
several hours.
12. On the day 3,the petri dishes was observed against both white and black
backgrounds and the results was recorded.
13. On the day 4,the petri dishes was observed against both white and black
backgrounds and the results was recorded.

RESULT AND OBSERVATIONS :

Time Item Experimental Conditions Observations Sketch

 Dish 1 (iron nail) Iron in agar + Blue and brown
phenolphthalein + colours formed at
potassium ferricyanide different places
on the nail.

Dish 2 (zinc) Iron wrapped with zinc + Blue coloration

phenolphthalein + appears.
potassium ferricyanide
Day 1

Dish 3 (copper) Iron wrapped with copper The brown and

+ phenolphthalein blue colour
+ potassium ferricyanide develops along
the copper
surface and the
blue color
develops on the
bare.
 Dish 1 (iron nail) Iron in agar + The iron nail
phenolphthalein + corrode
potassium ferricyanide

Day 2

Dish 2 (zinc) Iron wrapped with zinc + The surface of

phenolphthalein + iron nail that does
potassium ferricyanide not covered with
zinc start to
corrode

Iron wrapped with copper The iron nail

Dish 3 (copper) + phenolphthalein corrode
+ potassium ferricyanide

Time Item Experimental Conditions Observations Sketch

 Dish 1 (iron nail) Iron in agar +
phenolphthalein +
potassium ferricyanide
Brown colours
formed along the
nail.

Dish 2 (zinc) Iron wrapped with zinc + Blue coloration

phenolphthalein + appears along the
potassium ferricyanide nail.
Day 4

Dish 3 (copper) Iron wrapped with copper The brown colour

+ develops along
phenolphthalein + the copper
potassium ferricyanide surface and the
blue color
develops on the
unwrapped side.

DISCUSSION :

In this experiments, the observation for dish 1(where the experiment

conditions with iron in agar, phenolphtalein and potassium ferricyanide) at day 1 is
the outer layer of nails is brown and slightly blue while at day 3 and 4 the outer layer
of nail is clearly brown in color. The piece of iron appears uniform on the large scale,
but at the atomic level it is quite irregular. Regions of the iron which have been
subjected to intense stress, like the stamped head and point of the nail, or the
sheared ends of the wire, contain atoms that have a higher energy than there
unstressed neighbors. These regions lose electrons or undergo oxidation slightly
more readily than the unstressed regions. The reaction is shown below.

Fe (s) Fe2+(aq) + 2 e-

These electrons are readily taken up during the reduction of water, according to the
reaction below.

2 H2O (l) + 2 e- 2 OH-(aq) + H2 (g)

Alternatively

2 H2O (l) + O2 (g) + 4 e- 4 OH-(aq)

If we can keep water and oxygen away from our iron surfaces, we can minimize the
amount of corrosion that can occur, since oxidation cannot occur without reduction.
The colors are created from two additional reactions as shown below.
Phenolphthalein is a weak acid and will be denoted as HPh.

HPh(aq) + OH-(aq) Ph-(aq) + H2O(l)

colorless pink

Wherever there are significant quantities of OH - the region will turn pink.

H2O (l) + K+(aq) + Fe2+(aq) + Fe(CN)63-(aq) KFe[Fe(CN)6] H2O(s)

pale yellow blue

This last compound is call variously Turnbulls blue or Prussian blue. It is somewhat
unusual in that it is a mixed valence compound containing iron in both the +2 and +3
oxidation states. The agar solution will turn blue in any region with a supply of Fe 2+.

When iron is corroded, rust is formed in the reaction :

4Fe(s) + 3O2(g) + H2O(l) = 2Fe2O3H2O(s)

The amount of rust that forms depends on the amount of water available for the iron
to react with. The two electrochemical half-reactions are:

Fe(s) = Fe2+(aq) + 2e- . This is the anode.

O2(g) + 2H2O(l) + 4e- = 4OH-(aq). This is the cathode.

 The anode and cathode are both on the same piece of iron but different
regions of it. For this reaction to work, the electrons need a wire of some sort or
some way of conducting the electron flow. In this case, the iron itself acts as the wire.

Besides, the observation for dish 2 (where the experiment conditions with iron
wrapped with zinc in agar, phenolphtalein and potassium ferricyanide) at day 1 white
haze appeared at the port with zinc wire and the wrapped port then turn slightly pink.
While, at day 3 and 4 the unwrapped port become more pinky while more white haze
form at wrapped port. In this results, blue coloration appears because zinc is more
active than iron and performs as the anode in the zinc-iron galvanic couple. Zinc ions
form at the anode but they do not form a colored compound with the indicators used.
Hence, no color develops on the zinc area but white haze was appeared.

Lastly, the observation for dish 3(where the experiment conditions with iron
wrapped with copper in agar, phenolphtalein and potassium ferricyanide) at day 1
the unwrapped port turn slightly blue and wrapped port turn slightly pink. At the day 3
and 4, dark blue formed at the unwrapped port and more pinky color formed at
wrapped part. The slightly pink colour develops along the copper surface because it
is performing as a cathode and the blue color develops on the bare iron surface that
is the anode in the copper-iron galvanic couple. The slightly pink colour results from
the accumulation of alkali on cathode areas and the blue color reveals the presence
of ferrous ions at the iron anode surface.

CONCLUSION :

Corrosion is when metal is gradually destroyed through chemical reactions.

Because it is a chemical reaction, we can prevent it with chemical reactions, namely
redox reactions. For dish 1, Fe act as anode, while for dish 2, Zinc ions form at the
anode and for dish 3, the copper surface performing as a cathode. Therefore, if any
of this component which is an anode, a cathode, a conducting environment for ionic
movement (electrolyte), an electrical connection between the anode and cathode for
the flow of electron current is missing or disabled, the electrochemical corrosion
process will be stopped. Clearly, these elements are thus fundamentally important
for corrosion control.

QUESTIONS :

1. Locate the anode and cathode in the three different conditions.

For dish 1 : The anode and cathode are both on the same piece of iron but
different regions of it.
Fe(s) = Fe2+(aq) + 2e- . This is the anode.
O2(g) + 2H2O(l) + 4e- = 4OH-(aq). This is the cathode.

For dish 2 : Zinc ions form at the anode and zinc as a cathode.

For dish 3 : Iron as an anode and Copper surface performing as a cathode.

2. Why does the iron behave differently in the three cases in this experiments?
Because it is depend on the reactivity of iron and the other metal (wrapped
metal: zinc znd copper)

3. Which atom have corroded?

Iron, Fe

4. Write the possible electrochemical reactions for the rusting of iron nails until it
become stable oxide compound (or rust).
1) Fe (s) Fe2+(aq) + 2 e-
2) 2 H2O (l) + O2 (g) + 4 e- 4 OH-(aq)

Phenolphthalein is a weak acid and will be denoted as HPh.

HPh (aq) + OH-(aq) Ph-(aq) + H 2O (l)

colorless pink

3) H2O (l) + K+(aq) + Fe2+(aq) + Fe(CN)63-(aq) KFe[Fe(CN)6] H2O(s)

pale yellow blue
4) 4Fe(s) + 3O2(g) + H2O(l) = 2Fe2O3H2O(s)

5. Rank the metals used in this experiment based on their reactivity.

 Cu Fe Zn

More reactive

6. Explain how cathodic protection works.

Corrosion is the principal cause of leaks in underground storage tanks and

pipelines. External corrosion of underground steel is an electrochemical
process. The soil is an electrolyte, or conductor of corrosion currents.
Corrosion current flow through the soil between different points on the buried
metallic structure. When corrosion current enters or leaves the metal surface,
a chemical reaction takes place. The results of the process is corrosion of the
metal surface where current leaves the metal and enter the soil. Cathodic
protection halts the corrosion process on the underground or submerged
structure by changing the electrical condition and transferring the damaging
chemical reaction away from the structure to an independent anode. Once the
anode is installed on the soil, it will continue to provide a protective barrier to
the structure for the design life of the system.

REFERENCES :

Cathode and Anode Half-Cell Reactions (n. d.). Education portal. Retrieved November 8,
2014 from http://education-portal.com.

Joseph Franek (2001). Iron corossion. The Regents of the University of Minnesota. Retrieved
November 8, 2014 from https://www.chem.umn.edu

K.R. Trethewey and J. Chamberlain: "Corrosion for Science and Engineering 2 nd Edn.",
Longman (UK), 1995. Retrieved November 8, 2014 from http://www.corrosion
club.com.
Laque, May, and Uhlig. (n. d.). A Classic Corrosion Experiment : Anodes and Cathodes in
Corrosion Reactions. Corrosion in Action. Retrieved November 8, 2014 from
http://www.corrosion-doctors.org