Material Safety Data Sheet

Alcohol 70%
Section 1: Chemical Product and Company Identification

Product Name: OneMed Alcohol 70% Contact Information:

CAS #: Mixtures PT. Jayamas Medica Industri

RTECS: Not Applicable By Pass Krian KM-28

TSCA: TSCA 8(b) inventory; Water; Ethyl Alcohol 95% Sidoarjo - Indonesia

CI#: N/A Telp: +62 31 8982349 ; 8985269

Synonim: - Fax: +62 31 8985268

Chemical Formula: N/A Email: jmi@onemedhealthcare.com

Website: www.onemed.co.id

Section 2: Composition and Information on Ingredients

Composition:
Name CAS # % by Weight
Water 7732-18-5 27
Ethyl alcohol 95% 64-17-5 73

Toxicological Data on Ingredients: Ethyl alcohol: ORAL (LD50): Acute: 7060 mg/kg [Rat]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), . Slightly hazardous in case of skin contact
(permeator), of ingestion. Non-corrosive for skin. Non-corrosive to the eyes. Non-corrosive for lungs.

Potential Chronic Health Effects:

Slightly hazardous in case of skin contact (sensitizer)
CARCINOGENIC EFFECTS: Classified PROVEN
Classified A4 (Not classifiable for human or animal.)
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Ethyl alcohol 95% ]. Mutagenic for
bacteria and/or yeast. [Ethyl alcohol 95% ].
TERATOGENIC EFFECTS: Classified PROVEN for human [Ethyl alcohol 95% )
ELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 95% ) . Classified
Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 95% ].

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 The substance is toxic to blood, the reproductive system, liver, upper respiratory tract, skin, central nervous

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
keeping eyelids open. Cold water may be used. Get medical attention.

Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention if symptoms appear.

Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.

Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: The lowest known value is 363C (685.4F) (Ethyl alcohol 95% ).

Flash Points: CLOSED CUP: 18.5C (65.3F).(estimated)

Flammable Limits: The greatest known range is LOWER: 3.3% UPPER: 19% (Ethyl alcohol 95% )

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:

Highly flammable in presence of open flames and sparks, of heat.
Slightly flammable to flammable in presence of oxidizing materials.
Non-flammable in presence of shocks, of reducing materials, of combustible materials, of organic materials, of
metals, of acids, of alkalis.

Explosion Hazards in Presence of Various Substances:

Slightly explosive in presence of open flames and sparks, of heat, of oxidizing materials, of acids.
Non-explosive in presence of shocks.

Fire Fighting Media and Instructions:

Flammable liquid, soluble or dispersed in water.
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog.

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 Special Remarks on Fire Hazards:
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel
considerable distance to source of ignition and flash back. May form explosive mixtures with air.
Contact with Bromine pentafluoride is likely to cause fire or explosion.
Ethanol ignites on contact with chromyl chloride.
Ethanol ignites on contact with iodine heptafluoride gas.
It ignites than explodes upon contact with nitrosyl perchlorate.
Additon of platinum black catalyst caused ignition.
(Ethyl alcohol 95% )

Remarks on Explosion Hazards:

Ethanol has an explosive reaction with the oxidized coating around potassium metal.
Ethanol ignites and then explodes on contact with acetic anhydride + sodium hydrosulfate (ignites and may
explode), disulfuric acid + nitric acid, phosphorous(III) oxide platinum, potassium-tert-butoxide+ acids.
Ethanol forms explosive products in reaction with the following
compound : ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane
iodide), magnesium perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver
fulminate) silver nitrate (forms ethyl nitrate) silver(I) oxide + ammonia or hydrazine (forms
silver nitride and silver fulminate), sodium (evolves hydrogen gas).
Sodium Hydrazide + alcohol can produce an explosion.
Alcohols should not be mixed with mercuric nitrate, as explosive mercuric fulminate may be formed.
May form explosive mixture with manganese perchlorate + 2,2-dimethoxypropane.
Addition of alcohols to highly concentrate hydrogen peroxide forms powerful explosives.
Explodes on contact with calcium hypochlorite
Vapor may explode if ignited in an enclosed area.
Containers may explode when heated or involved in a fire.
(Ethyl alcohol 95% )

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
container.

Large Spill:
Flammable liquid.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or
confined areas; dike if needed. Be careful that the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of
insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and
show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents, acids, alkalis, moisture.

Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly
closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above
23C (73.4F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

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 Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.

Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.

Exposure Limits:
Ethyl alcohol 200 Proof
TWA: 1900 (mg/m3) from OSHA (PEL) [United States]
TWA: 1000 (ppm) from OSHA (PEL) [United States]
TWA: 1900 (mg/m3) from NIOSH [United States]
TWA: 1000 (ppm) from NIOSH [United States]
TWA: 1000 (ppm) [United Kingdom (UK)]
TWA: 1920 (mg/m3) [United Kingdom (UK)]
TWA: 1000 STEL: 1250 (ppm) [Canada]
Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor:
Alcohol like. Mild to strong. Like wine or
whiskey; Ethereal, vinous. Pleasant.

Taste: Burning. Pungent.

Molecular Weight: Not applicable.

Color: Clear Colorless.

pH (1% soln/water): Neutral.

Boiling Point: The lowest known value is 78.5C (173.3F) (Ethyl alcohol 95% ). Weighted average: 79.58C (175.2F)

Melting Point: May start to solidify at -114.1C (-173.4F) based on data for: Ethyl alcohol 95% ) .

Critical Temperature: The lowest known value is 243C (469.4F) (Ethyl alcohol 95% ).

Specific Gravity: Weighted average: 0.8 (Water = 1)

Vapor Pressure: The highest known value is 5.7 kPa (@ 20C) (Ethyl alcohol 95% ). Weighted average: 5.53 kPa (@
20C)

Vapor Density: The highest known value is 1.59 (Air = 1) (Ethyl alcohol 95% ). Weighted average: 1.54 (Air = 1)

Volatility: Not available.

Odor Threshold: 100 ppm

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

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Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.

Solubility:
Easily soluble in cold water, hot water, methanol, diethyl ether.
Soluble in acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Incompatible materials, heat, sources of ignition.

Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:

Ethanol rapidly absorbs moisture from the air.
Can react vigorously with oxiders.
The following oxidants have been demonstrated to undergo vigorous/explosive reaction with ethanol: barium
perchlorate, bromine pentafluoride, calcium hypochlorite, chloryl perchlorate, chromium trioxide, chromyl chloride,
dioxygen difluoride, disulfuryl difluoride, fluorine nitrate, hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl
perchlorate, perchloric acid permanganic acid, peroxodisulfuric acid, potassium dioxide, potassium perchlorate,
potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver peroxide, uranium hexafluoride, uranyl
perchlorate.
Ethanol reacts violently/expodes with the following compounds: acetyl bromide (evolves hydrogen bromide)
acetyl chloride, aluminum, sesquibromide ethylate, ammonium hydroxide & silver oxide, chlorate, chromic
anhydride, cyanuric acid + water, dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen peroxide +
sulfuric acid, iodine + methanol + mercuric oxide, manganese perchlorate + 2,2-dimethoxy propane,
perchlorates, permanganates + sulfuric acid, potassium superoxide, potassium tert-butoxide, silver & nitric acid,
silver perchlorate, sodium hydrazide, sulfuric acid + sodium dichromate, tetrachlorisilane + water.
Ethanol is also incompatible with platinium, and sodium.
No really safe conditions exist under which ethyl alcohol and chlorine oxides can be handled.
Reacts vigorously with acetyl chloride (Ethyl alcohol 95% )

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 3632 mg/kg (Mouse) (Calculated value for the mixture).

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: Classified PROVEN
Classified A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 95% ].
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Ethyl alcohol 95% ]. Mutagenic for
bacteria and/or yeast. [Ethyl alcohol 95% ].
TERATOGENIC EFFECTS: Classified PROVEN for human [Ethyl alcohol 95% ].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 95% ]. Classified
Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 95% ].

Other Toxic Effects on Humans:

Hazardous in case of skin contact (irritant), of inhalation.
Slightly hazardous in case of skin contact (permeator), of ingestion.

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Special Remarks on Toxicity to Animals:
Lowest Published Dose/Conc:
LDL[Human] - Route: Oral; Dose: 1400 mg/kg
LDL[Human child] - Route: Oral; Dose: 2000 mg/kg
LDL[Rabbit] - Route: Skin; Dose: 20000 mg/kg (Ethyl alcohol 95% )

Special Remarks on Chronic Effects on Humans:

May affect genetic material (mutagenic)
Causes adverse reproductive effects and birth defects (teratogenic) , based on moderate to heavy consumption.
May cause cancer based on animal data.
Human: passes through the placenta, excreted in maternal milk. (Ethyl alcohol 95% )

Special Remarks on other Toxic Effects on Humans:

Acute potential health effects:
Skin: causes skin irritation
Eyes: causes eye irritation
Ingestion: May cause gastrointestinal tract irritation with nausea, vomiting, diarrhea, and alterations in gastric
secretions. May affect behavior/central nervous system (central nervous system depression - amnesia,
headache, muscular incoordination, excitation, mild euphoria, slurred speech, drowsiness, staggaring gait, fatigue,
changes in mood/personality, excessive talking, dizziness, ataxia, somnolence, coma/narcosis, hallucinations,
distorted perceptions, general anesthetic), peripherial nervous system (spastic paralysis)vision (diplopia).
Moderately toxic and narcotic in high concentrations. May also affect metabolism, blood, liver, respiration
(dyspnea), and endocrine system.
May affect respiratory tract, cardiovascular(cardiac arrhythmias, hypotension), and urinary systems.
Inhalation: May cause irritation of the respiratory tract and affect behavior/central nervous system with symptoms
similar to ingestion.
Chronic Potential Health Effects:
Skin: Prolonged or repeated skin contact may casue dermatitis, an allergic reaction.
Ingestion: Prolonged or repeated ingestion will have similiar effects as acute ingestion. It may also affect the
brain. (Ethyl alcohol 95% )

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.

Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental
control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.

Identification: : Ethanol (Ethyl alcohol 95% ) UNNA: 1170 PG: II

Special Provisions for Transport: Not available.

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 Section 15: Other Regulatory Information
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8C (100F).
CLASS D-2B: Material causing other toxic effects (TOXIC).

DSCL (EEC):
R11- Highly flammable.
S7- Keep container tightly closed.
S16- Keep away from sources of ignition - No
smoking.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 3

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 3

Reactivity: 0

Specific hazard:

Protective Equipment:
Gloves.
Lab coat.
Vapor respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 05:28 PM

Last Updated: 11/06/2008 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we
assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes.

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