LAMPIRAN

1. PENGENCERAN
A. NaCl
1
3M = 1,5 M
2

1,5 M.50 mL = 3M.

=
1,5 .50
3

25 mL =
1
3M = 0,75 M
4

0,75 M.50 mL= 3M.

=
0,75 .50
3

12,5 mL =
1
3M = 0,375 M
8

0,375 M.50 mL= 3M.

=
0,375 .50
3

6,25 mL =
1
3M = 0,1875 M
16

0,375 M.50 mL= 3M.

=
0,1875 .50
3

3,125 mL =

B. PENGENCERAN NH4Cl
1
1M = 0,5 M
2

0,5 M.50 mL = 1 M.

=
0,5 .50
1

25 mL =
1
1M = 0,25 M
4

0,25 M.50 mL= 1M.

 =
0,25 .50
1

12,5 mL =
1
1M = 0,125 M
8

0,375 M.50 mL= 3M.

=
0,375 .50
3

6,25 mL =
1
1M = 0,0625 M
16

0,375 M.50 mL= 1M.

=
0,1875 .50
1

3,125 mL =

2. MASSA JENIS
A. NaCl
Konsentrasi 1,5 M
0 ( )
d= (0 )

0,911 ( 41,271 31,202 )

= ( 40,3146 31,202)

= 1,00

Konsentrasi 0,75 M
0 ( )
d= (0 )

0,911 ( 41,151 31,202)

=
( 40,3146 31,202 )

= 0,994

Konsentrasi 0,375 M
0 ( )
d= (0 )

0,911 ( 40,8133 31,202)

= ( 40,3146 31,202 )

= 0,960
 Konsentrasi 0,1875 M
0 ( )
d= (0 )

0,911 ( 40,4813 31,202)

= ( 40,3146 31,202 )

= 0,927

B. NH4Cl
Konsentrasi 1,5 M
0 ( )
d= (0 )

0,911 ( 41,192 31,202)

= ( 40,3146 31,202 )

= 0,998

Konsentrasi 0,75 M
0 ( )
d= (0 )

0,911 ( 40,947 31,202)

= ( 40,3146 31,202 )

= 0,974

Konsentrasi 0,375 M
0 ( )
d= (0 )

0,911 ( 40,6873 31,202)

= ( 40,3146 31,202 )

= 0,948

Konsentrasi 0,1875 M
0 ( )
d= (0 )

0,911 ( 40,055 31,202)

= ( 40,3146 31,202 )

= 0,885

3. MOLALITAS
A. NaCl
Konsentrasi 1,5 M
 1
m= 2

1000
1
= 1,00
58,5


1,5 1000

= 1,64 molal
Konsentrasi 0,75 M
1
m=
2
1000
1
= 0,994
58,5


0,75 1000

= 0,793 molal
Konsentrasi 0,375 M
1
m=
2
1000
1
= 0,960
58,5


0,375 1000

= 0,40 molal
Konsentrasi 0,1875 M
1
m=
2
1000
1
= 0,927
58,5


0,1875 1000

= 0,204 molal
B. NH4Cl
Konsentrasi 1,5 M
1
m=
2
1000
1
= 0,998
53,45


0,5 1000
 =0,515 molal
Konsentrasi 0,75 M
1
m=
2
1000
1
= 0,974
53,45


0,25 1000

= 0,260 molal
Konsentrasi 0,375 M
1
m=
2
1000
1
= 0,948 53,45


0,125 1000

=0,132 molal
Konsentrasi 0,1875 M
1
m=
2
1000
1
= 0,885
53,45


0,0625 1000

=0,0709 mol

4. VOLUME MOLAL SEMU ZAT TERLARUT

A. NaCl
Konsentrasi 1,5 M
1000 0
2 (2 )( )
0
=
1000 ( 41,271 40,3146 )
58,5 (58,5 ) ( ( 40,3146 31,202 ) )
1,64
=
1,00

= 116,35 mL/mol
Konsentrasi 0,75 M
1000 0
2 (2 )( )
0
=
 1000 ( 41,151 40,3146)
58,5 (58,5 ) ( ( 40,3146 31,202 ) )
0,793
=
0,994

= 169,98 mL/mol
Konsentrasi 0,375 M
1000 0
2 (2 )( )
0
=
1000 ( 40,8133 40,3146)
58,5 (58,5 ) ( ( 40,3146 31,202 ) )
0,40
=
0,960

= 200 mL/mol
Konsentrasi 0,1875 M
1000 0
2 (2 )( )
0
=
1000 ( 40,4813 40,3146)
58,5 (58,5 ) ( ( 40,3146 31,202 ) )
0,204
=
0,927

= 158,68 mL/mol
B. NH4Cl
Konsentrasi 1,5 M
1000 0
2 (2 )( )
0
=
1000 ( 41,192 40,3146)
53,45 (53,45 ) ( ( 40,3146 31,202 ) )
0,515
=
0,998

= 235,73 mL/mol
Konsentrasi 0,75 M
1000 0
2 (2 )( )
0
=
1000 ( 40,947 40,3146)
53,45 (53,45 ) (( 40,3146 31,202 ))
0,260
=
0,974

= 325,11 mL/mol
Konsentrasi 0,375 M
1000 0
2 (2 )( )
0
=
 1000 ( 40,687 40,3146)
53,45 (53,45 ) ( ( 40,3146 31,202 ) )
0,132
=
0,948

= 380,65 mL/mol
Konsentrasi 0,1875 M
1000 0
2 (2 )( )
0
=
1000 ( 40,055 40,3146)
53,45 (53,45 ) ( ( 40,3146 31,202 ) )
0,0709
=
0,885

= 391,90 mL/mol

5. VOLUM MOLAL PARSIAL PELARUT (V1)

NaCl
Konsentrasi m

1,5 1,28 116,35

0,75 0,890 169,98

0,375 0,63 200

0,1875 0,45 158,68

Grafik m vs NaCl
1.2

0.8

0.6

Series1
0.4
Linear (Series1)
0.2

0
0 50 100 150 200 250
m

y = mx + C
y = -67,958x + 216,47

= ( ) +

Dari persamaan diatas didapatkan ( ) = 67,958 ; = 216,47

a. Konsentrasi 1,5 M

V1= + ( 2
) ( )
1,64 molal
V1 = 116,35 mL/mol + ( 2
1,28) (-67,958)
V1 = 116,35 + (-71,328)
V1 = 45,021 mL

b. Konsentrasi 0,75 M

V1= + ( 2
) ( )
0,793 molal
V1 = 169,98 mL/mol + ( 2
0,890) (-67,958)
V1 = 169,98 mL +(-23,981)
V1 = 146 mL
c. Konsentrasi 0,375 M

V1= + ( 2
) ( )
0,40 molal
V1 = 200 mL/mol + ( 2
0,63) (-67,958)
V1 = 200 mL + (-8,56)
V1 = 191,43 mL

d. Konsentrasi 0,1875 M

V1= + ( 2
) ( )
0,204molal
V1 = 158,68 mL/mol + ( 2
0,45) (-67,958)
V1 = 158,68 mL +(-3,11)
V1 = 155,56 mL

NH4Cl
Konsentrasi m

1,5 0,717 235,73

0,75 0,509 325,11

 0,375 0,363 380,65

0,1875 0,266 391,90

Grafik m vs NH4Cl
1.2

0.8

0.6

Series1
0.4
Linear (Series1)
0.2

0
0 0.5 1 1.5
m

y = mx + C

y = -358,97x + 499,82

= ( ) +

Dari persamaan diatas didapatkan ( ) = 358,97 ; = 499,82

a. Konsentrasi 1,5 M

V1= + ( 2
) ( )
0,515 molal
V1 = 235,73 mL/mol + ( 2
0,717) (358,97)
V1 = 235,73 mL + (- 66,27)
V1 = 169,46 mL

b. Konsentrasi 0,75 M

V1= + ( 2
) ( )
0,260 molal
V1 = 325,11 mL/mol + ( 2
0,509) (358,97)
V1 = 325,11 mL + (-23,75 )
V1 = 301,35 mL

c. Konsentrasi 0,375 M

V1= + ( 2
) ( )9
0,132 molal
V1 = 380,65 mL/mol + ( 2
0,363) (358,97)
V1 = 380,65 mL + (-8,60)
V1 = 372,05 mL

d. Konsentrasi 0,1875 M

V1= + ( 2
) ( )
0,0709 molal
V1 = 391,90 mL/mol + ( 2
x0,266) (358,97)
V1 = 391,90 mL + (-3,38)
V1 = 388,52 mL

6. VOLUM MOLAL PARSIAL TERLARUT (V2)

NaCl
a. Konsentrasi 1,5 M
3
V2 = + ( ) ( )
2
3 1,28
V2 = 116,35 + ( ) (-67,958)
2

V2 = 116,35 + (1,92) (-67,958)

V2 = 116,35 + (-130,48)
V2 = -14,13 mL

b. Konsentrasi 0,75 M
3
V2 = + ( ) ( )
2
3 0,890
V2 = 169,98 + ( ) (-67,958)
2

V2 = 169,98 + (1,335) (-67,958)

V2 = 169,98 + (-90,724)
V2 = 79,25 mL
c. Konsentrasi 0,375 M
3
V2 = + ( ) ( )
2
3 0,63
V2 = 200 + ( ) (-67,958)
2

V2 = 200+ (0,945) (-67,958)

V2 = 200 + (-64,22)
V2 = 135,78 mL
d. Konsentrasi 0,1875 M
3
V2 = + ( ) ( )
2
3 0,45
V2 = 158,68 + ( ) (-67,958)
2

V2 = 158,68 + (0,675) (-67,958)

V2 = 158,68 + (-45,87)
V2 = 112,80 mL

NH4Cl
e. Konsentrasi 0,5 M
3
V2 = + ( ) ( )
2
3 0,717
V2 = 235,73+ ( ) (358,97)
2

V2 = 235,73+ (1,0755) (358,97)

V2 = 235,73+ (-386,07)
V2 = -150,34 mL
f. Konsentrasi 0,75 M
3
V2 = + ( ) ( )
2
3 0,509
V2 = 325,11 + ( ) (358,97)
2

V2 = 325,11 + (0,7635) (358,97)

V2 = 325,11 + (-274,07)
V2 = 51,03 mL
g. Konsentrasi 0,375 M
3
V2 = + ( ) ( )
2
3 0,363
V2 = 380,65 + ( ) (358,97)
2

V2 = 380,65 + (0,544) (358,97)

V2 = 380,65 + (-195,46)
V2 = 185,2 mL
h. Konsentrasi 0,1875 M
3
V2 = + ( ) ( )
2
 3 0,266
V2 = 391,90 + ( ) (358,97)
2

V2 = 391,90 + (0,400) (358,97)

V2 = 391,90 + (-143,3)
V2 = 248,6 mL
 Lampiran Grafik
Grafik vs m NaCl

Grafik vs m NaCl
250

200

150 y = -67.958x + 216.47

R = 0.4993

100 Series1
Linear (Series1)
50

0
0 0.5 1 1.5
m

Grafik vs m NaCl

Grafik vs m NH4Cl
450
400
350
300 y = -358.97x + 499.82
250 R = 0.9746

200
Series1
150
100 Linear (Series1)
50
0
0 0.2 0.4 0.6 0.8

m
Grafik Gabungan vs m NaCl dan NH4Cl

Grafik m Vs
450
400
y = -358.97x + 499.82
350 R = 0.9746
300
250

200 NaCl
150 NH4Cl
100 y = -67.958x + 216.47
50 R = 0.4993
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4
m

Grafik Gabungan m Vs V1 NaCl dan NH4Cl

Grafik Molalitas vs V1
450
400
y = -505.68x + 431.47
350
R = 0.9964
300
250
v1

200 NaCl
150 NH4Cl
100
y = -91.059x + 203.64
50 R = 0.8515
0
0 0.5 1 1.5 2
molalitas

Grafik Gabungan m Vs V2 NaCl dan NH4Cl

 Grafik Molalitas vs V2
300
250
200
150
y = -99.802x + 154.2
100 R = 0.9276
NaCl
v2

50
0 NH4Cl
-50 0 0.5 1 1.5 2

-100
y = -893.77x + 302.13
-150
R = 0.9945
-200
molalitas