GC Catalogue
GC Catalogue
GC Catalogue
GC AND GC/MS
GC AND GC/MS
• Inert Flow Path components – Ultra Inert GC columns, Ultra Inert liners,
Ultra Inert gold seals, UltiMetal Plus Capillary Flow Technology devices with
Flexible Metal ferrules – have Agilent proprietary deactivation chemistries
to ensure sample integrity.
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Table of Contents
Agilent Solutions, Services and Support .......................4 Detector Systems.................................................................92
Featured Products .............................................................8 Flame Ionization Detector (FID)......................................92
Agilent Parts and Supplies ..............................................14 Electron Capture Detector (ECD) ...................................100
GC and GC/MS Maintenance Schedule ..........................14 Thermal Conductivity Detector (TCD) ...........................103
Bulk GC Supplies..................................................................16 Flame Photometric Detector (FPD)................................108
Inlet Septa .............................................................................17 Nitrogen Phosphorus Detector (NPD) ..........................116
Inlet Liners.............................................................................24 Nitrogen and Sulfur
Chemiluminescence Detectors ......................................122
Agilent Ultra Inert Liners ....................................................26
GC Standards ........................................................................124
Capillary Column Ferrules and Nuts .................................34
7820A GC System.................................................................125
GC Column Connection Supplies ......................................40
GC/MS Parts and Supplies ................................................141
Capillary Flow Technology Supplies..................................42
MSD Contamination .........................................................142
Press-fit Capillary Column Connectors ............................44
Ion Source ..........................................................................149
Graphpak Capillary Connectors .........................................45
MSD Filaments..................................................................162
Large Valve Oven..................................................................46
Vent Valve Supplies ..........................................................163
Valves and Loops .................................................................47
Gas Clean Filters ...............................................................164
Sample Introduction Systems............................................50
Quadrupole Mass Filter....................................................164
Agilent Vials and Closures for GC, GC/MS and GC/HS ....56
MSD Electron Multipliers
Headspace Vials and Closures .......................................56
and Replacement Horn ....................................................165
High Performance Septa..................................................57
Vacuum Systems and Pumps .........................................166
CombiPAL Headspace Vials and Closures ...................59
Diffusion Pump..................................................................168
Crimping and Decapping Tools .......................................60
Quiet Cover ........................................................................169
Teledyne Tekmar Purge and Trap Supplies ......................62
Foreline Pump....................................................................170
Markes Thermal Desorption ..............................................65
7000 Triple Quadrupole GC/MS .....................................171
Inlet Systems ........................................................................67
7200 Q-TOF for GC/MS ....................................................175
Split/Splitless Inlets.........................................................69
240-MS Ion Trap Parts and Supplies .............................178
Multimode Inlet.................................................................76
220-MS Parts and Supplies.............................................180
Cool On-Column Inlets .....................................................78
GC/MS Standards................................................................181
Programmable Temperature Vaporizer (PTV) Inlets ...81
Agilent Syringes ...................................................................183
Purged Packed Inlets .......................................................88
2
Agilent CrossLab GC Parts and Supplies .......................192 Applications .......................................................................500
Product Introductions..........................................................193 Environmental ......................................................................501
Supplies for Bruker, Varian GC Systems..........................206 Hydrocarbons.....................................................................501
Supplies for PerkinElmer GC Systems..............................221 Pesticides and Herbicides...............................................506
Supplies for Shimadzu GC Systems..................................227 Semivolatiles......................................................................532
Supplies for Thermo Scientific GC Systems....................234 Volatiles ..............................................................................544
Supplies for CTC GC Autosamplers ..................................239 Air Analysis........................................................................549
Agilent J&W GC Columns ................................................240 Food, Flavor and Fragrance ...............................................554
Column Selection .................................................................247 Energy and Fuels..................................................................576
Column Selection Principles ..............................................247 Industrial Chemical ..............................................................602
GC Column Application and Method Guides ..................262 Forensic Toxicology and Pharma.......................................635
Agilent J&W Ultra Inert GC Columns...............................286 Indices ................................................................................652
Agilent J&W High Efficiency GC Capillary Columns .....293 Ordering Information ........................................................684
Low-bleed GC/MS Columns ..............................................294
Premium Polysiloxane Columns........................................318
Polyethylene Glycol (PEG) Columns .................................351
Specialty Columns ...............................................................362
PLOT Columns ......................................................................420
Columns with Non-Bonded Stationary Phases ..............441
Guard Columns .....................................................................445
LTM Column Modules .........................................................447
Fused Silica Tubing ..............................................................464
Stainless Steel Tubing.........................................................469
Packed GC Columns ............................................................470
Custom GC Column Ordering .............................................481
GC Column Test Standards.................................................482
Column Installation and Troubleshooting........................484
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Agilent Solutions
PUT MORE THAN 40 YEARS OF RELENTLESS INNOVATION
BEHIND YOUR EVERY RESULT
By continually raising the standards for technologies that support your routine analyses, Agilent's R&D efforts have led to breakthroughs such as:
• New GC columns that help you achieve higher levels of inertness and column-to-column reproducibility
• LC column choices that deliver the sensitivity and reliability you need for demanding applications
• Cutting-edge sample preparation products that promote reliable extraction and concentration
• Fresh atomic and molecular spectroscopy ideas for identifying and confirming targets and unknowns
Longtime Agilent customers have experienced our commitment firsthand. And now, we look forward to demonstrating
how Agilent's approach to relentless innovation can work to your advantage, too.
C H E M I C A L A N A LY S I S S O L U T I O N S
Food Forensics
From high-volume pesticide screening in food products to rapid Whether testing for poisons in a forensics investigation, screening athletes
identification of pathogens, Agilent understands the analytical needs for performance enhancing drugs, analyzing samples for recreational
of food producers, shippers, and regulators. Utilizing our easy-to-use drugs, or checking a crime scene for explosive residue – lives and
analyzers and updated screening libraries, customers can quickly develop professions may be dependent on the accuracy of your equipment.
robust and reliable methods. Agilent's leading gas chromatography and Agilent Technologies leads the industry with a comprehensive portfolio
mass spectrometry systems are widely regarded as valuable food testing of workflow solutions that provide the ability to identify, confirm
techniques for an array of different analyses. and quantify thousands of substances.
4
LIFE SCIENCE SOLUTIONS
Biopharmaceutical Genomics
Biotherapeutics have enormous potential to improve human health, with Agilent is a global leader in microarrays, scanners, and NGS reagents
growing numbers of protein and antibody therapeutics to address unmet used in a wide variety of genomic-based disease research experiments.
medical needs. At every development stage, from disease research to Our SureSelect and HaloPlex Target Enrichment Systems dominate the
QA/QC and manufacturing, Agilent can help you make the right choices category, streamlining next generation sequencing studies. Agilent offers
for moving therapeutics to market. We understand the biopharmaceutical a wide range of catalog CGH and gene expresssion microarrays and a
workflow so our product families work together seamlessly, as engines of highly-developed capability to produce custom arrays using our free online
research, discovery, and development. Agilent columns deliver complete design tool, SureDesign. All Agilent microarrays feature highly sensitive,
characterization of biomolecules using reversed-phase, size exclusion, ion selective 60-mer probes, and, with as many as eight arrays printed on
exchange, and affinity chromatography. Our bio-inert supplies ensure that a slide, the cost per sample is cost-efficient.
every part of your workflow delivers the performance you need to optimize
your bio-separation.
Life Science Informatics
Pharmaceutical Mirroring its extensive instrument portfolio, Agilent offers the industry’s
most extensive suite of bioinformatics software, helping users derive
You need the most efficient processes to evaluate drug candidates, knowledge from complex genomic, proteomic, metabolomic and other
determine efficacy, and ensure safety and compliance during development biological data. SureCall and CytoGenomics software analyzes NGS and
and manufacture. Agilent has worked with pharma companies for many aCGH data and the GeneSpring suite provides multi-omic analysis and
years to ensure reliability and reproducibility for regulatory compliance, visualization capabilities to help compare complex datasets to explore
from lab-to-lab and around the world. Our pharma solutions provide biological questions from multiple perspectives. The GeneSpring suite
high-throughput capability at every stage of the product lifecycle, with includes the GX module for microarray-based gene expression and
automated sample prep, industry-leading U/HPLC systems, the largest genotyping data, the PA module for Pathway Analysis and multi-omic
family of Fast LC columns, open access LC/MS, spectroscopy, and analysis and the MPP software, which analyzes mass spec data from
automated dissolution. A complete family of LC supplies and lamps help proteomics and metabolomics experiments.
optimize every analysis and take day-to-day lab efficiency one step further.
Lab Automation
Proteomics
To meet the skyrocketing demand for more throughput and automation,
Research into how large sets of proteins affect the health of an organism Agilent has substantially expanded its lab automation offerings. The
requires special sets of analytical tools. Agilent has built a formidable Agilent line of liquid handlers and microplate processors are designed
arsenal of liquid chromatograph/mass spectrometers, bioinformatics to streamline high-volume life science workflows. Agilent is also
systems, multiple affinity protein removal columns, and OFFGEL continually upgrading its advanced autosamplers for LC, GC, LC/MS
electrophoresis for protein identification and protein biomarker discovery. and GC/MS, adding functionality and speed to reflect the performance
Accurate-Mass mass spectrometry and the microfluidic HPLC-Chip/MS of its advanced instruments.
are two Agilent innovations speeding the work of proteomics researchers
around the globe.
Vacuum Technology
Metabolomics Agilent works with customers to solve vacuum challenges from
experiments in high-energy physics to developing systems for
Collections of small molecules are increasingly being seen as rich sources nanotechnology. Agilent manufactures vacuum systems used in its
of biomarkers, but studying metabolites presents many challenges. The own mass spectrometry instruments as well as those of other
need for speed, accuracy, and powerful interpretation capabilities in looking manufacturers. Agilent's vacuum technology has been proven by
at chemical profile snapshots is underscored because molecules are the most powerful physics experiment ever built, CERN’s Big Bang
constantly entering, leaving or changing within the metabolome. Agilent’s machine, which was used in the discovery of the Higgs boson.
GC, LC, and MS portfolios, along with our excellent bioinformatics offerings,
user-customizable METLIN metabolite database for LC/MS, and the
industry’s first commercial GC/MS retention time locked metabolite library
align well with the needs of metabolomics researchers.
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AGILENT SERVICE AND SUPPORT
Laboratory decision makers and users • Improve qualification efficiency by harmonizing protocols across platforms to ensure greater efficiency
ranked Agilent as their first choice and minimize regulatory risk
for general laboratory
compliance services.
• Standardize your entire compliance operation with robust test designs that work with all your instruments
• Add, remove or reconfigure tests based upon your unique user requirements
• Reduce staff review time significantly with consistently formatted, computer generated,
tamper-proof reports
6
AGILENT SERVICE AND SUPPORT
• Classroom, online, and on-site training in instrument operation, troubleshooting and maintenance
• Customized consulting services to meet your lab’s unique needs
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AGilent J&W GC Columns
240
AGilent J&W GC Columns
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AGilent J&W GC Columns
• The capacity to run up to four column modules simultaneously – with four different temperature
LTM II standard format with 5 in column toroid
programs – to maximize your productivity
• Rapid temperature programming rates for higher analysis speeds
• Faster cooling times – as low as one minute or less – to decrease idling and downtime
• Excellent retention time repeatability and performance – comparable to conventional GC
All LTM II column modules are packaged with:
• Two 1 m guard columns (one each for the inlet and detector) fused silica
the same id as the analytical column
• Flexible Metal ferrules that fit the dimensions of the analytical and guard columns
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AGilent J&W GC Columns
Agilent offers LTM technology for our popular 7890 and 6890 Series GC systems, and the 5975T GC/MS.
WWW.AGilent.Com/Chem/GC 243
AGilent J&W GC Columns
GC Capillary Columns
more than just essential products…
reliable results!
With the highest inertness, lowest bleed levels, and the tightest column-to-column reproducibility,
Agilent J&W GC Capillary columns perform better than any columns on the market.
ultra inert Columns – allow you to perform trace level analysis – including the analysis of acids, bases,
or other active compounds – with the utmost confidence. They also help ensure an inert GC flow path
that is essential for sensitivity, performance, and the integrity of your analytical results.
high efficiency Columns – are ideal for applications that require reduced analysis time, such as
high-throughput screening, fast process monitoring, fast QC analyses, and fast method development.
low-bleed GC/ms Columns – are specifically designed to chromatograph a broad range of trace-level
samples, and offer low bleed and high inertness even at higher temperatures.
Premium Polysiloxane Columns – are stable, robust, and versatile and are available in a wide variety
of stationary phases.
Polyethylene Glycol (PeG) Columns – offer a variety of unique phase characteristics to meet the
varying needs of your laboratory, thanks to Agilent’s strict quality control of the cross-linking
and deactivation processes.
specialty Columns – meet Agilent’s uncompromising standards for high-temperature, life science,
pesticide, petroleum, semivolatile, and volatile applications.
Plot Columns – deliver superior separation for compounds that are gases at room temperature.
They are also ideal for analyzing fixed gases, low molecular weight hydrocarbon isomers, volatile
polymer compounds, and reactive analytes such as gases, amines, and hydrides.
On the following pages you will find details on our complete line of innovative Agilent J&W GC columns.
For more information, contact your local Agilent representative or Agilent Authorized Distributor.
Or you can order online at www.agilent.com/chem/store.
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AGilent J&W GC Columns
Table of Contents
Column selection Principles .......247 Premium Polysiloxane Columns...318 specialty Columns ........................362
GC Column Application DB-1.....................................................318 High Temperature Columns ................. 362
and method Guides.......................262 HP-1 .....................................................322 DB-1ht .................................................362
ultra inert GC Columns ................286 CP-Sil 5 CB..........................................324 DB-5ht .................................................363
DB-1ms Ultra Inert ............................289 Ultra 1 ..................................................327 DB-17ht ...............................................364
HP-1ms Ultra Inert.............................289 Ultra 2 ..................................................328 VF-5ht and VF-5ht UltiMetal............365
DB-5ms Ultra Inert ............................290 DB-5.....................................................329 Petroleum Columns............................... 366
HP-5ms Ultra Inert.............................290 HP-5 .....................................................332 Lowox ..................................................366
DB-35ms Ultra Inert ..........................291 CP-Sil 8 CB..........................................334 GS-OxyPLOT .......................................366
DB-624 Ultra Inert .............................291 CP-Sil 13 CB .......................................336 CP-Sil 5 CB for Formaldehyde .........367
DB-Select 624 UI for <467> ............292 DB-35...................................................337 HP-PONA ............................................367
DB-UI 8270D Ultra Inert ...................292 HP-35 ...................................................338 CP-Sil PONA CB.................................368
Agilent J&W high efficiency DB-17...................................................339 CP-Sil PONA for ASTM D5134 ........368
GC Capillary Columns...................293
HP-50+.................................................340 DB-Petro .............................................369
low-bleed GC/ms Columns........294
CP-Sil 24 CB .......................................341 HP-1 Aluminum Clad.........................369
DB-1ms................................................295
DB-23...................................................342 DB-2887...............................................370
HP-1ms................................................296
DB-200.................................................343 DB-HT SimDis ....................................370
VF-1ms ................................................297
DB-210.................................................344 CP-SimDist..........................................371
DB-5ms................................................299
DB-225.................................................345 CP-SimDist UltiMetal ........................372
HP-5ms................................................301
CP-Sil 43 CB .......................................346 CP-Sil 2 CB..........................................373
VF-5ms ................................................302
DB-1301...............................................347 CP-TCEP for Alcohols in Gasoline ...373
DB-XLB................................................304
CP-1301 ...............................................348 DB-Sulfur SCD....................................374
VF-Xms ................................................305
DB-1701...............................................349 Select Low Sulfur ..............................375
DB-35ms .............................................306
CP-Sil 19 CB .......................................350 CP-Sil 5 CB for Sulfur........................375
VF-35ms ..............................................307
Polyethylene Glycol (PeG) Select for Permanent Gases –
DB-17ms .............................................308 Columns..........................................351 Dual Column.......................................376
VF-17ms ..............................................309 DB-WAX and DB-WaxFF ..................351 Select Al2O3 MAPD...........................376
VF-23ms ..............................................310 DB-WAXetr .........................................354 Biodiesel Capillary GC Columns .....377
VF-200ms ............................................311 HP-INNOWax .....................................355 Select Biodiesel.................................379
DB-225ms ...........................................312 CP-Wax 52 CB ....................................356 Select Silanes ....................................380
VF-WAXms..........................................313 DB-FFAP..............................................358 CP-Volamine .......................................381
VF-624ms and VF-1301ms ...............315 HP-FFAP ..............................................359 CP-Sil 8 CB for Amines.....................382
VF-1701ms ..........................................317 CP-Wax 58 FFAP CB..........................360 CP-Wax for Volatile
Amines and Diamines ......................382
Carbowax 20M and HP-20M ...........361
PoraPLOT Amines .............................383
(Continued)
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AGilent J&W GC Columns
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AGilent J&W GC Columns
• Understand how column diameter influences factors like efficiency, solute retention,
head pressure, and carrier gas flow rates.
• Determine which column length will affect solute retention, column head pressure,
column bleed – and cost.
• Appreciate the difference between thin-film and thick-film columns with regard to capacity,
inertness, bleed, and upper temperature limit.
While there are no foolproof techniques, shortcuts, tricks or secrets to column selection, there are some
guidelines and concepts that simplify the process. There are four major column parameters to consider:
stationary phase, diameter, length, and film thickness.
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AGilent J&W GC Columns
The concepts of stationary phase selectivity and polarity are very useful when selecting stationary phases.
For best performance, start with the general purpose Agilent J&W Ultra Inert 1ms and 5ms columns to get
the lowest column bleed and column activity for a wide range of analytes, including active compounds and
trace level samples.
Synonymous use of the terms polarity and selectivity is not accurate, but it is very common. Selectivity is
determined by the physicochemical interactions of the solute molecules with the stationary phase. Polarity
is determined by the structure of the stationary phase. Polarity does have an effect on separation; however,
it is only one of the many stationary phase properties that influence peak separation (see the next section
on polarity).
Selectivity can be thought of as the ability of the stationary phase to differentiate between two solute
molecules by differences in their chemical or physical properties. Separation is obtained if the interactions
between the stationary phase and solutes are different. For liquid or gum stationary phase (polysiloxanes
and polyethylene glycols), there are three major interactions: dispersion, dipole, and hydrogen bonding.
The following is a simplified and condensed explanation of the interactions for polysiloxane and
polyethylene glycol stationary phases.
Dispersion is the dominant interaction for all polysiloxane and polyethylene glycol stationary phases.
Dispersion can be simplified into the concept of volatility. Simply stated, the more volatile a solute, the faster
it elutes from the column (i.e., shorter retention time). However, this order can be altered by the effect of
solute and stationary phase polarities, and the other interactions. Solute boiling points are sometimes used
as a measure of compound volatility. That is, compounds elute in the order of their increasing boiling points.
Unfortunately, boiling points cannot be universally applied to the dispersion interactions. Boiling points are
fairly valid when dealing with compounds with similar structures, functional groups or homologous series
(Figure 1). When dealing with compounds with mixed functional groups, the boiling points simplification
often fails (Figure 2). If compound boiling points differ by more than 30 °C, they usually can be separated
by most stationary phases (there are exceptions). If compound boiling points differ by less than 10 °C, the
boiling point simplification becomes less certain and more likely to be in error (except for compounds in a
homologous series).
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AGilent J&W GC Columns
Homologous series of hydrocarbons. The solutes elute in order of their increasing boiling points; however, the peaks are not spaced in proportion to their
respective boiling points.
Solutes outside of the homologous series do not elute in the boiling point order.
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AGilent J&W GC Columns
If the stationary phase is capable of dipole interaction, it enhances its power to separate solutes whose dipole
moments are different. Only some stationary phases are able to exploit this interaction. Polyethylene glycols,
and cyanopropyl and trifluoropropyl substituted polysiloxanes readily undergo the dipole interactions; methyl
or phenyl substituted groups do not undergo a dipole interaction (table 1). The amount of peak separation
for solutes with different dipoles often changes if a stationary phase with a different interaction is used
(Figure 3). If the dipole difference between compounds is small, a greater amount of the appropriate group
is needed (e.g., a 50% cyanopropylphenyl-methyl polysiloxane instead of a 14% cyanopropylphenyl-methyl
polysiloxane). It is difficult to accurately predict the magnitude of the separation change for all of the peaks.
Empirical results have shown that dipole interaction stationary phases are well suited for samples containing
compounds that have base or central structures to which different groups are attached in various positions.
Examples include substituted aromatics, halocarbons, pesticides and drugs.
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AGilent J&W GC Columns
The hydrogen bonding interaction occurs if there is hydrogen bonding between the solute molecules and the stationary phase. table 2 lists the types of
compounds that can form hydrogen bonds along with their relative bonding strengths. It is the difference in the strength of the hydrogen bonding that is
critical. The same stationary phases that undergo dipole interactions also undergo hydrogen bonding interactions. The amount of peak separation for solutes
whose hydrogen bonding potentials differ often changes if a stationary phase with a different amount of hydrogen bonding interaction is used (Figure 4).
If the hydrogen bonding difference between compounds is small, a great amount of the appropriate group is needed (e.g., a polyethylene glycol instead
of a 14% cyanopropylphenyl-methyl polysiloxane). It is difficult to accurately predict the magnitude of the separation change for all of the peaks.
Sometimes the desired separation is obtained, but another set of peaks now co-elute with the new stationary phase.
1. Toluene
4
1 1 2 2. Hexanol
6 3
2 4 6 3. Phenol
5
DB-WAX 3 4. Decane (C10)
5 DB-1
5. Naphthalene
6. Dodecane (C12)
0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16
DB-1 does not undergo hydrogen bonding interactions. The change in the elution order of hexanol and phenol with DB-WAX is a combination of the
dipole and hydrogen bonding interaction.
1. Toluene
1
2 4 2. Hexanol
3 6 5 1 3
2 4 6 3. Phenol
50% Phenyl 5 4. Decane (C10)
DB-17 DB-1 5. Naphthalene
6. Dodecane (C12)
0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16
The aromatics increase in retention relative to the hydrocarbons for the DB-17 columns. DB-17 contains 50% phenyl substitution. DB-1
contains no phenyl substitution.
Another stationary phase characteristic that may effect retention in a predictable manner is the phenyl content. In general, the higher the phenyl content of
the stationary phase, the higher the retention of aromatic solutes relative to aliphatic solutes. This does not mean that aromatic solutes are more retained
(e.g., higher k) by high phenyl content stationary phases, but that aromatic solutes are more retained relative to aliphatic solutes. Figure 5 shows an
example of this retention behavior.
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AGilent J&W GC Columns
Polarity
Stationary phase polarity is determined by the polarity of the substituted groups and their relative amounts. table 3 lists a variety of stationary phases in
order of their increasing polarity. Polarity is often erroneously used to select columns or to determine separation characteristics. Stationary phase polarity is
only one of many factors that affect retention and separation.
While polarity is not directly related to selectivity, it has a pronounced affect on compound retention, thus separation. For compounds of similar volatility,
greater retention is obtained for solutes with polarities similar to the stationary phase. In other words, polar compounds are more strongly retained by a polar
stationary phase than a less polar stationary phase, and vice versa. This effect can be seen in Figure 6. The changes in retention and elution order can be
largely attributed to the changes in stationary phase polarity. Changes in the amount of phenyl substitution, and dipole and hydrogen bonding interactions
also contribute to the changes; however, it is difficult to assess the magnitude of their individual contributions.
Separation and efficiency have to be considered together and not as separate column attributes, as each contributes to peak resolution. When the stationary
phase provides adequate resolution between peaks, higher efficiency is not needed. Shorter or larger diameter columns and less than optimal GC conditions
can be used in these situations. When resolution is not adequate, there is a need for higher column efficiency.
0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16
The alcohols (polar) increase in retention relative to hydrocarbon (non-polar) for the DB-225 column. DB-225 is more polar than DB-1.
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AGilent J&W GC Columns
In addition to retention, stationary phase polarity influences other column characteristics. There is a general trend between stationary phase polarity
and column lifetime, temperature limits, bleed and efficiency. Column life, temperature limits and efficiency tend to be higher for more non-polar stationary
phases. These are general trends and not absolute certainties. Low bleed stationary phases sometimes go against this trend.
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AGilent J&W GC Columns
Gas-solid or PLOT column stationary phases are physically different than polysiloxanes and polyethylene glycols. Gas-solid stationary phase are small, porous
particles. The particles are stuck to the inner wall of the capillary tubing using a binder or similar means. Solutes are separated based on differences in their
adsorption properties. Since the particles are porous, size and shape differentiation also occurs.
Alumina PLOT columns are well suited for the separation of C1-C10 hydrocarbons and small aromatics. The KCl version of the Alumina PLOT column changes
the retention order for some of the hydrocarbons. The PLOT Q column provides slightly better separation for C1-C3 hydrocarbons, but C4 and higher
hydrocarbons are better separated with an Alumina PLOT column. PLOT Q exhibits extremely long retention times and very broad peaks for C6 and higher
hydrocarbons and aromatics. PLOT Q separates sulfur gases from each other and from most light hydrocarbons. Molesieve PLOT columns are used to
separate many noble and permanent gases. GS-GasPro columns combine many of the features of the various other PLOT columns. Light hydrocarbons,
inorganic gases and solvents are some of the samples suitable for GS-GasPro.
Dispersive
shape/size ionic surface
Molecular Sieves Porous Polymers Bonded Silica
Bonded Graphitized Carbon
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AGilent J&W GC Columns
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AGilent J&W GC Columns
table 4:
Column Diameter
Column efficiency vs. Diameter
Column diameter has an influence over five parameters of primary concern. They are efficiency, retention,
Column iD theoretical Plates/
Diameter (mm) meter pressure, carrier gas flow rate, and capacity.
0.10 12,500
0.18 6,600 Column efficiency (N/m) is inversely proportional to column diameter. The efficiencies listed in table 4
show that smaller diameter columns have higher theoretical plates per meter. Resolution is a square root
0.20 5,940
function of the theoretical plate number. Therefore, doubling column efficiency theoretically increases
0.25 4,750 resolution only by 1.41 times (the square root of 2), but closer to 1.2-1.3 times in real practice. Smaller
0.32 3,710 diameter columns are used when peak separation is small and high column efficiency (i.e., narrow peaks)
0.45 2,640 is needed. Figure 7 shows the difference in resolution for two different diameter columns.
0.53 2,240
Maximum efficiency for a solute with k=5 solute retention is inversely proportional to column diameter, for isothermal temperature conditions.
For temperature program conditions, the change is 1/3-1/2 of the isothermal value. Column diameters
are rarely selected based on retention. Figure 7 shows the difference in retention for two different
diameter columns.
Column head pressure is approximately an inverse squared function of the column radius. For example,
a 0.25 mm id column requires about 1.7 times the head pressure of a 0.32 mm id column of the same length
(also, carrier gas and temperature). Column head pressures increase or decrease dramatically with changes
in column diameter. Column diameters of 0.18 mm id or larger are used for standard GC analysis due to the
very high pressures needed for smaller diameter columns. Wider diameter columns, especially shorter ones
(e.g., 15 m x 0.32 mm id), are impractical for use in GC/MS systems. The vacuum at the exit of the column
greatly reduces the required head pressure, and it is difficult to maintain or control very low head pressures.
Rs = 0.87 Rs = 1.01
1
2 1
2
1. 1,3-Dichlorobenzene
N = 58,700 N = 107,250 2. 1,4-Dichlorobenzene
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AGilent J&W GC Columns
At constant pressure, carrier gas flow rates increase as column diameters increase. For applications or
hardware requiring high flow rates, larger diameter columns are normally used. Headspace and purge &
trap systems require higher carrier gas flow rates for proper operation. 0.45 or 0.53 mm id columns are
used with these systems so that the higher flow rates can be used. Special considerations must be taken
if small diameter columns are used in these types of systems. This includes the use of cryogenic interfaces
or ovens, or interfacing through split injectors. Added complexity and/or cost, or sample loss, are involved
with these techniques. For applications or hardware requiring low carrier gas flow rates, smaller diameter
columns are normally used. GC/MS is the typical system requiring low carrier gas flow rates, and therefore,
0.25 mm id and smaller id columns are used in these applications.
Column capacity increases as the column diameter increases. The actual column capacity also depends
on the stationary phase, solute and film thickness. table 5 lists typical capacity ranges for a variety of
column diameters.
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AGilent J&W GC Columns
Column Length
Column length influences three parameters of major concern. They are efficiency, retention (analysis time)
and carrier gas pressure.
Column efficiency (n) is proportional to column length. Resolution is a square root function of the
theoretical plate number. For example, doubling column length (thus efficiency) theoretically increases
resolution by only 1.41 times (closer to 1.2-1.3 times in practice). Longer columns are used when peak
separation is small and high column efficiency (i.e., narrow peaks) is needed. Figure 8 shows the
difference in resolution for three different lengths.
1 1 1
2
2
2 1. 1,3-Dichlorobenzene
2. 1,4-Dichlorobenzene
solute retention is proportional to column length for isothermal temperature conditions. For temperature
program conditions, the change is 1/3-1/2 of the isothermal value. When efficiency is increased by
lengthening the column, there is a significant increase in analysis time. Figure 8 shows the difference in
retention for three different lengths.
258
AGilent J&W GC Columns
Column head pressure is nearly proportional to column length. Pressure is usually not an issue unless
the column has a very small or large diameter. Long, small diameter columns require extremely high head
pressures, and short, wide diameter columns require very low head pressures. Neither situation is very
practical and may be a limiting factor. Choice of carrier gas will also have an impact on column pressure.
Column bleed increases as column length increases. Longer columns have more stationary phase, thus
more degradation products are produced. The increase in bleed with longer columns is not large and should
not be a deterrent to using a longer column when one is necessary.
Column cost is directly related to column length. Doubling column length nearly doubles the price of the
column. When efficiency is increased by lengthening the column, there is a significant increase in column
cost. When considered in conjunction with the increase in analysis time, lengthening the column should
be the last reasonable option for increasing efficiency.
Shorter columns cost more per meter than longer columns. Cutting longer columns into shorter lengths
seems like a good method to save money, but it is not recommended. The quality of the smaller pieces
cannot be guaranteed and may not be the same as the original, intact column. Theoretically, each piece
should provide satisfactory and consistent results. In practice, this does not always occur. The probability of
individual piece variation is higher when shorter pieces are cut from the original column. Greater variability
between individual pieces is observed as column length, film thickness and stationary phase polarity
increases, and column diameter decreases. Finally, there is the increased chance of tubing breakage when
rewinding the shorter columns on other cages. Technically, cutting a column into shorter pieces voids the
performance warranty.
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AGilent J&W GC Columns
For isothermal conditions, solution retention is directly proportional to film thickness. For temperature
program conditions, the change is 1/3-1/2 of the isothermal value. Thicker film columns are used to
obtain higher retention for very volatile solutes. Volatile solutes normally requiring cryogenic (subambient)
cooling with standard film thickness columns can be sufficiently retained at temperatures above 30 °C.
Changing to a thicker film column has a net effect of providing equal or greater retention at a higher column
temperature. Thicker film columns are typically used for volatile compounds like solvents and select gases.
Thinner film columns are used to reduce the retention of highly retained solutes. Highly retained solutes can
be eluted faster or at a lower temperature. Changing to a thinner film column has the net effect of providing
equal or less retention at a lower column temperature. Thinner film columns are typically used for high
boiling or molecular weight compounds. Figure 9 shows the difference in retention for two different
film thicknesses.
Solutes with k values less than 2 are very difficult to resolve due to insufficient retention by the column.
Changing to a thicker film column results in better resolution since solute retention is increased. The
resolution improvement depends on the solute k value for the original column. For solutes with k values
of about 5 or less, increasing their retention results in improved resolution. For solute peaks with values
of 5-10, increasing their retention provides a small to moderate increase in resolution. For peaks with k
values above 10, increasing their retention often results in no resolution improvement and sometimes
a loss of resolution. Increasing film thickness to improve the resolution of early eluting peaks may result
in a resolution loss for later eluting peaks.
7.00
2
3
0.25 µm
0 2 4 6 8 1. n-Decane
Time (min) 2. n-Undecane
1 3. n-Dodecane
24.59
2
3 1.00 µm
0 5 10 15 20 25
Time (min)
260
AGilent J&W GC Columns
For a given stationary phase, column bleed increases as film thickness increases. Since thicker film
columns are more retentive, later eluting peaks may shift into a region of much higher column bleed when
increasing film thickness. The upper temperature limits of thick film columns may be lower due to their
higher bleed levels.
Thicker film columns are more inert. There is more stationary phase to shield the solutes from the tubing
surface. Peak tailing for active compounds can often be reduced or eliminated with a thicker film column.
Thicker film columns have higher solute capacities. When one solute is present in significantly higher
amounts, the resulting broad peak may interfere or co-elute with an adjacent peak. Changing to a thicker
film column may reduce peak broadening, thus co-eluting. table 5 lists typical capacity ranges for a variety
of film thickness.
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AGilent J&W GC Columns
(Continued)
262
AGilent J&W GC Columns
(Continued)
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AGilent J&W GC Columns
264
AGilent J&W GC Columns
ePA method
Drinking Water
ePA method Application Recommended Column Part no.
501, 501.3 Measurement of trihalomethanes in drinking water DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
by GC/MS and selected ion monitoring DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
VF-624ms, 30 m x 0.25 mm, 1.40 µm CP9102
DB-624 Ultra Inert, 30 m x 0.25 mm, 1.40 µm 122-1334UI
502.2 Volatile organic compounds in water by purge and trap DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
capillary column GC with photoionization and electrolytic DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
conductivity detectors in series
VF-624ms, 60 m x 0.25 mm, 1.40 µm CP9103
DB-624 Ultra Inert, 60 m x 0.25 mm, 1.40 µm 122-1364UI
VF-624ms, 30 m x 0.25 mm, 1.40 µm CP9102
503.1 Volatile aromatic and unsaturated organic compounds DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
in water by purge and trap gas chromatography DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
504.1 1,2-Dibromoethane (EDB) and DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
1,2-dibromo-3-chloropropane (DB CP), DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
GC, microextraction
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
DB-624 Ultra Inert, 30 m x 0.25 mm, 1.40 µm 122-1334UI
VF-1ms, 30 m x 0.32 mm, 1.00 µm CP8926
VF-1701ms, 30 m x 0.32 mm, 1.00 µm CP9163
505 Analysis of organohalide pesticides and commercial DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
polychlorinated biphenyl (PCB) products in water DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
by microextraction and GC
DB-XLB, 30 m x 0.25 mm, 0.50 µm 122-1236
VF-1ms, 30 m x 0.32 mm, 1.00 µm CP8926
VF-17ms, 30 m x 0.32 mm, 0.50 µm CP8991
506 Determination of phthalate and adipate esters in drinking DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
water by liquid-liquid extraction or liquid-solid extraction VF-5ms, 30 m x 0.32 mm, 0.25 µm CP8955
and GC with photoionization detection
VF-1ms, 30 m x 0.32 mm, 0.25 µm CP8924
507 Determination of nitrogen and phosphorus-containing DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
pesticides in water by GC with a nitrogen phosphorus DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
detector
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
VF-1701 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9070
(Continued)
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AGilent J&W GC Columns
Drinking Water
ePA method Application Recommended Column Part no.
508 Determination of chlorinated pesticides in water by GC DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
with an electron capture detector DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
DB-608, 30 m x 0.32 mm, 0.50 µm 123-1730
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
VF-1701 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9070
508.1 Determination of chlorinated pesticides, herbicides, DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
and organohalides by liquid-solid extraction DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
and electron capture GC
DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
515 Determination of chlorinated herbicides in drinking water DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
HP-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 19091S-433UI
DB-1701, 30 m x 0.25 mm, 0.25 µm 122-0732
515.3 Determination of chlorinated acids in drinking water by DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
liquid-liquid extraction, derivatization and GC with electron HP-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 19091S-433UI
capture detection
DB-1701, 30 m x 0.25 mm, 0.25 µm 122-0732
VF-1701ms, 30 m x 0.25 mm, 0.25 µm CP9151
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
515.4 Determination of chlorinated acids in drinking water by DB-5ms Ultra Inert, 20 m x 0.18 mm, 0.18 µm 121-5522UI
liquid-liquid microextraction, derivatization, and fast GC HP-5ms Ultra Inert, 20 m x 0.18 mm, 0.18 µm 19091S-577UI
with electron capture detection
DB-1701, 20 m x 0.18 mm, 0.18 µm 121-0722
VF-1701ms, 30 m x 0.25 mm, 0.25 µm CP9151
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
521 Determination of nitrosamines in drinking water by solid DB-5ms Ultra Inert, 30 m x 0.25 mm, 1.00 µm 122-5533UI
phase extraction and capillary column gas chromatography HP-5ms Ultra Inert, 30 m x 0.25 mm, 1.00 µm 19091S-233UI
with large volume injection and chemical ionization tandem
mass spectrometry (MS/MS) VF-5ms, 30 m x 0.25 mm, 1.00 µm CP8946
(Continued)
266
AGilent J&W GC Columns
Drinking Water
ePA method Application Recommended Column Part no.
524.2 Measurement of purgeable organic compounds in water DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
by capillary GC/MS DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
DB-624 Ultra Inert, 60 m x 0.25 mm, 1.40 µm 122-1364UI
HP-VOC, 60 m x 0.20 mm, 1.10 µm 19091R-306
DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
DB-624 Ultra Inert, 60 m x 0.25 mm, 1.40 µm 122-1364UI
VF-624ms, 30 m x 0.25 mm, 1.40 µm CP9102
VF-624ms, 60 m x 0.25 mm, 1.40 µm CP9103
VF-5ms, 30 m x 0.32 mm, 1.00 µm CP8957
525, 525.2 Determination of organic compounds in drinking water HP-5ms, 30 m x 0.25 mm, 0.50 µm 19091S-133
by liquid-solid extraction and capillary column GC/MS VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
526 Determination of selected semivolatile organic compounds DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
in drinking water by solid phase extraction and capillary HP-5ms, 30 m x 0.25 mm, 0.25 µm 19091S-433
column GC/MS
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
527 Determination of selected pesticides and flame retardants DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
in drinking water by solid phase extraction and capillary HP-5ms, 30 m x 0.25 mm, 0.25 µm 19091S-433
column GC/MS
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
528 Determination of phenols in drinking water by solid phase DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
extraction and capillary column GC/MS DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
529 Determination of explosives and related compounds DB-5ms Ultra Inert, 15 m x 0.25 mm, 0.25 µm 122-5512UI
in drinking water by solid phase extraction and capillary HP-5ms Ultra Inert, 15 m x 0.25 mm, 0.25 µm 19091S-431UI
column GC/MS
VF-5ms, 15 m x 0.25 mm, 0.25 µm CP8939
551 Determination of chlorination disinfection byproducts DB-5ms, 30 m x 0.25 mm, 1.00 µm 122-5533
and chlorinated solvents in drinking water by DB-1, 30 m x 0.25 mm, 1.00 µm 122-1033
liquid-liquid extraction and gas chromatography
with electron capture detection DB-210, 30 m x 0.25 mm, 0.50 µm 122-0233
VF-1301ms, 30 m x 0.25 mm, 1.00 µm CP9054
551.1 Determination of chlorination disinfection byproducts, DB-5ms, 30 m x 0.25 mm, 1.00 µm 122-5533
chlorinated solvents, and halogenated pesticides/herbicides DB-1, 30 m x 0.25 mm, 1.00 µm 122-1033
in drinking water by liquid-liquid extraction and GC with
electron capture detection DB-1301, 30 m x 0.25 mm, 1.00 µm 122-1333
VF-1ms, 30 m x 0.25 mm, 1.00 µm CP8913
VF-1301ms, 30 m x 0.25 mm, 1.00 µm CP9054
(Continued)
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AGilent J&W GC Columns
Drinking Water
ePA method Application Recommended Column Part no.
552 Determination of haloacetic acids in drinking water DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
by liquid-liquid extraction, derivatization, and gas DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
chromatography with electron capture detection
DB-1701, 30 m x 0.25 mm, 0.25 µm 122-0732
DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
HP-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 19091S-433UI
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
552.1 Determination of haloacetic acids and dalapon in drinking DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
water by ion-exchange liquid-solid extraction and gas DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
chromatography with an electron capture detector
DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
552.2 Determination of haloacetic acids and dalapon in drinking DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
water by liquid-liquid extraction, derivatization GC with DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
electron capture detection
DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
VF-1701ms, 30 m x 0.25 mm, 0.25 µm CP9151
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
552.3 Determination of haloacetic acids and dalapon in drinking DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
water by liquid-liquid microextraction, derivatization, and DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
GC with electron capture detection
DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
DB-1701, 30 m x 0.25 mm, 0.25 µm 122-0732
VF-1701ms, 30 m x 0.25 mm, 0.25 µm CP9151
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
556 Determination of carbonyl compounds in drinking water by DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
pentafluorobenzylhydroxylamine derivatization and capillary DB-1701, 30 m x 0.25 mm, 0.25 µm 122-0732
GC with electron capture detection
VF-1701ms, 30 m x 0.25 mm, 0.25 µm CP9151
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
268
AGilent J&W GC Columns
Waste Water
ePA method Application Column Part no.
601 Purgeable halocarbons DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
DB-624, 75 m x 0.45 mm, 2.55 µm 124-1374
DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
VF-624ms, 75 m x 0.53 mm, 3.00 µm CP9108
VF-624ms, 60 m x 0.32 mm, 1.80 µm CP9105
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
602 Purgeable aromatics DB-624, 75 m x 0.53 mm, 3.00 µm 125-1374
DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
VF-624ms, 75 m x 0.53 mm, 3.00 µm CP9108
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
VF-624ms, 30 m x 0.25 mm, 1.40 µm CP9102
603 Acrolein and acrylonitrile DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
VF-WAXms, 30 m x 0.25 mm, 1.00 µm CP9206
VF-624ms, 30 m x 0.25 mm, 1.40 µm CP9102
604 Phenols DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
VF-5ms, 60 m x 0.32 mm, 1.80 µm CP9105
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
605 Benzidines DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
DB-608, 30 m x 0.25 mm, 0.25 µm 122-6832
606 Phthalate esters DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
DB-608, 30 m x 0.25 mm, 0.25 µm 122-6832
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
607 Nitrosamines DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
CP-Sil 8 CB for Amines, 30 m x 0.32 mm, 1.00 µm CP7596
(Continued)
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AGilent J&W GC Columns
Waste Water
ePA method Application Column Part no.
608 Organochlorine pesticides and PCBs DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
DB-17ms, 30 m x 0.32 mm, 0.25 µm 123-4732
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
VF-1701 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9070
VF-17ms, 30 m x 0.25 mm, 0.25 µm CP8982
609 Nitroaromatics and isophorone HP-5ms, 30 m x 0.25 mm, 0.50 µm 19091S-133
DB-5ms, 30 m x 0.25 mm, 0.50 µm 122-5536
DB-608, 30 m x 0.25 mm, 0.25 µm 122-6832
VF-5ms, 30 m x 0.53 mm, 1.50 µm CP8976
VF-5ms, 30 m x 0.25 mm, 0.50 µm CP8945
610 Polynuclear aromatic hydrocarbons DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
DB-5ms, 30 m x 0.32 mm, 0.25 µm 123-5532
DB-17ms, 30 m x 0.25 mm, 0.25 µm 122-4732
VF-17ms, 30 m x 0.25 mm, 0.25 µm CP8982
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
611 Haloethers VF-5ms, 30 m x 0.53 mm, 1.50 µm CP8976
VF-5ms, 30 m x 0.25 mm, 0.50 µm CP8945
612 Chlorinated hydrocarbons DB-5ms, 30 m x 0.32 mm, 0.50 µm 123-5536
HP-5ms, 30 m x 0.32 mm, 0.50 µm 19091S-113
DB-1, 30 m x 0.32 mm, 0.50 µm 123-103E
VF-5ms, 30 m x 0.25 mm, 0.10 µm CP8943
VF-35ms, 30 m x 0.25 mm, 0.25 µm CP8877
VF-200ms, 30 m x 0.25 mm, 1.00 µm CP8860
613 2,3,7,8-Tetrachlorodibenzo-p-dioxin DB-5ms Ultra Inert, 60 m x 0.25 mm, 0.25 µm 122-5562UI
CP-Sil 88 for Dioxins, 50 m x 0.25 mm, 0.20 µm CP7588
VF-5ms, 60 m x 0.25 mm, 0.10 µm CP8948
614 The determination of organophosphorus pesticides DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
in municipal and industrial wastewater DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
615 Chlorinated herbicides DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
VF-1701 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9070
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
(Continued)
270
AGilent J&W GC Columns
Waste Water
ePA method Application Column Part no.
619 Triazine pesticides DB-35ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-3832UI
DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
VF-17ms, 30 m x 0.25 mm, 0.50 µm CP8983
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
622 The determination of organophosphorus pesticides DB-35ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-3832UI
in municipal and industrial wastewater DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
624 Purgeables DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
HP-VOC, 60 m x 0.20 mm, 1.10 µm 19091R-306
DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
VF-624ms, 75 m x 0.53 mm, 3.00 µm CP9108
VF-624ms, 60 m x 0.32 mm, 1.80 µm CP9105
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
625 Base/neutrals and acids HP-5ms Ultra Inert, 30 m x 0.25 mm, 0.50 µm 19091S-133UI
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
VF-1701 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9070
VF-200ms, 30 m x 0.25 mm, 0.25 µm CP8858
1613 Tetra- through octa-chlorinated dioxins and furans DB-5ms Ultra Inert, 60 m x 0.25 mm, 0.25 µm 122-5562UI
by isotope dilution HRGC/HRMS CP-Sil 88 for Dioxins, 50 m x 0.25 mm, 0.20 µm CP7588
VF-5ms, 60 m x 0.25 mm, 0.25 µm CP8960
1624 Volatile organic compounds by isotope dilution GC/MS DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
1625 Semivolatile organic compounds by isotope dilution GC/MS DB-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-5532UI
HP-5ms Ultra Inert, 30 m x 0.25 mm, 0.25 µm 19091S-433UI
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
8021 Volatile halogenated & aromatic organic compounds DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
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AGilent J&W GC Columns
solid Waste
ePA method Application Column Part no.
8010 Volatile halogenated organic compounds list DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
by EPA method 8021 DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
8011 1,2-Dibromoethane and DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
1,2-dibromo-3-chloropropane DB-624 Ultra Inert, 30 m x 0.25 mm, 1.40 µm 122-1334UI
by microextraction and GC
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
VF-1ms, 30 m x 0.32 mm, 0.25 µm CP8924
8015 Nonhalogenated organics by GC DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
DB-624 Ultra Inert, 30 m x 0.25 mm, 1.40 µm 122-1334UI
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
8015c Nonhalogenated organics by GC DB-WAX, 30 m x 0.25 mm, 0.50 µm 122-7033
DB-5, 30 m x 0.25 mm, 1.00 µm 122-5033
HP-5, 30 m x 0.25 mm, 1.00 µm 19091J-233
VF-WAXms, 30 m x 0.53 mm, 1.00 µm CP9215
CP-Sil 8 CB, 30 m x 0.53 mm, 1.50 µm CP8736
8020 Volatile aromatic organic compounds list DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
by EPA method 8021 DB-624 Ultra Inert, 30 m x 0.25 mm, 1.40 µm 122-1334UI
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
8021, CLP Volamines Volatile halogenated & aromatic DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
organic compounds DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
8021b Aromatic and halogenated volatiles by GC VF-624ms, 60 m x 0.53 mm, 3.00 µm CP9107
VF-624ms, 60 m x 0.25 mm, 1.40 µm CP9103
8031 Acrylonitrile by GC DB-624, 30 m x 0.25 mm, 1.40 µm 122-1334
DB-624 Ultra Inert, 30 m x 0.25 mm, 1.40 µm 122-1334UI
DB-VRX, 30 m x 0.25 mm, 1.40 µm 122-1534
PoraBOND Q, 25 m x 0.53 mm, 10.00 µm CP7354
8032 Acrylamide by GC CP-Wax 58 FFAP CB, 25 m x 0.53 mm, 2.00 µm CP7654
8033 Acetonitrile by GC with nitrogen DB-WAX, 15 m x 0.25 mm, 0.50 µm 122-7013
phosphorus detection HP-INNOWax, 15 m x 0.25 mm, 0.50 µm 19091N-231
VF-WAXms, 15 m x 0.53 mm, 1.00 µm CP9226
8040, 8041, 8041a Phenols by gas chromatography DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
VF-5ms, 30 m x 0.53 mm, 1.50 µm CP8976
VF-1701ms, 30 m x 0.53 mm, 1.00 µm CP9171
VF-17ms, 30 m x 0.53 mm, 1.00 µm CP9001
(Continued)
272
AGilent J&W GC Columns
solid Waste
ePA method Application Column Part no.
8060 Phthalate esters DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
8061 Phthalate esters by GC with electron capture DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
detection (GC/ECD) DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
VF-1701ms, 30 m x 0.53 mm, 1.00 µm CP9171
8070, 8070a Nitrosamines by gas chromatography DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
CP-Sil 8 CB for Amines, 30 m x 0.53 mm, 1.00 µm CP7597
VF-17ms, 30 m x 0.53 mm, 1.50 µm CP9002
8081, 8081a Organochlorine pesticides by gas chromatography DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
DB-35ms, 30 m x 0.32 mm, 0.25 µm 123-3832
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
VF-5ms, 30 m x 0.25 mm, 1.00 µm CP8946
VF-35ms, 30 m x 0.25 mm, 1.00 µm CP8879
8082, CLP Pesticides, 8082a Polychlorinated biphenyls (PCBs) DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
by gas chromatography DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
DB-35ms, 30 m x 0.32 mm, 0.25 µm 123-3832
DB-XLB, 30 m x 0.32 mm, 0.50 µm 123-1236
VF-5ms, 30 m x 0.25 mm, 1.00 µm CP8946
VF-35ms, 30 m x 0.25 mm, 1.00 µm CP8879
8090 Nitroaromatics and isophorone DB-5ms, 30 m x 0.25 mm, 1.00 µm 122-5533
DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
HP-5ms, 30 m x 0.25 mm, 0.50 µm 19091S-133
8091 Nitroaromatics and cyclic ketones by GC VF-5ms, 30 m x 0.53 mm, 1.50 µm CP8976
VF-1701ms, 30 m x 0.53 mm, 1.00 µm CP9171
8095 Explosives by GC DB-225, 15 m x 0.53 mm, 1.00 µm 125-2212
HP-5, 15 m x 0.53 mm, 1.50 µm 19095J-321
DB-5, 15 m x 0.53 mm, 1.50 µm 125-5012
VF-1ms, 15 m x 0.53 mm, 1.50 µm CP8967
8100 Polynuclear aromatic hydrocarbons DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
DB-5ms, 30 m x 0.32 mm, 0.25 µm 123-5532
DB-1ms, 30 m x 0.25 mm, 0.25 µm 122-0132
DB-17ms, 30 m x 0.25 mm, 0.25 µm 122-4732
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
(Continued)
WWW.AGilent.Com/Chem/GC 273
AGilent J&W GC Columns
solid Waste
ePA method Application Column Part no.
8111 Haloethers by GC DB-5ms, 30 m x 0.25 mm, 1.00 µm 122-5533
HP-5ms, 30 m x 0.25 mm, 0.50 µm 19091S-133
DB-1701, 30 m x 0.25 mm, 1.00 µm 122-0733
VF-1701ms, 30 m x 0.53 mm, 1.00 µm CP9171
8120 Chlorinated hydrocarbons by gas chromatography DB-5ms, 30 m x 0.32 mm, 0.50 µm 123-5536
HP-5ms, 30 m x 0.32 mm, 0.50 µm 19091S-113
DB-1, 30 m x 0.32 mm, 0.50 µm 123-103E
8121 Chlorinated hydrocarbons by GC: DB-5ms, 30 m x 0.32 mm, 0.50 µm 123-5536
capillary column technique HP-5ms, 30 m x 0.32 mm, 0.50 µm 19091S-113
DB-1, 30 m x 0.32 mm, 0.50 µm 123-103E
VF-200ms, 30 m x 0.53 mm, 1.00 µm CP8868
VF-WAXms, 30 m x 0.53 mm, 1.00 µm CP9215
VF-5ms, 30 m x 0.53 mm, 1.50 µm CP8976
VF-1701ms, 30 m x 0.53 mm, 1.00 µm CP9171
8131 Aniline and selected derivatives by GC DB-5ms Ultra Inert, 30 m x 0.25 mm, 1.00 µm 122-5533UI
HP-5ms Ultra Inert, 30 m x 0.25 mm, 0.50 µm 19091S-133UI
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
CP-Sil 8 CB for Amines, 30 m x 0.25 mm, 0.25 µm CP7598
8140 Organophosphorus pesticides by GC-NPD DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
8141a, 8141b Organophosphorus compounds DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
by gas chromatography: capillary column technique DB-5ms, 30 m x 0.25 mm, 0.25 µm 122-5532
VF-200ms, 30 m x 0.53 mm, 1.00 µm CP8868
VF-35ms, 30 m x 0.53 mm, 1.00 µm CP8888
VF-5ms, 30 m x 0.53 mm, 1.00 µm CP8975
VF-1ms, 30 m x 0.53 mm, 1.00 µm CP8969
8150 Chlorinated herbicides DB-35ms, 30 m x 0.32 mm, 0.25 µm 123-3832
(Continued)
274
AGilent J&W GC Columns
solid Waste
ePA method Application Column Part no.
8151, 8151b Chlorinated herbicides by GC using methylation or DB-CLP1, 30 m x 0.32 mm, 0.25 µm 123-8232
pentafluorobenzylation derivatization: capillary DB-CLP2, 30 m x 0.32 mm, 0.50 µm 123-8336
column technique
DB-35ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-3832UI
DB-5ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 123-5532UI
HP-5ms Ultra Inert, 30 m x 0.32 mm, 0.25 µm 19091S-413UI
VF-5 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9074
VF-5ms, 30 m x 0.32 mm, 1.00 µm CP8957
VF-35ms, 30 m x 0.25 mm, 0.25 µm CP8877
VF-1701 Pesticides, 30 m x 0.25 mm, 0.25 µm CP9070
8240 Volatile chlorinated and aromatic hydrocarbons DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
DB-624 Ultra Inert, 60 m x 0.25 mm, 1.40 µm 122-1364UI
DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
HP-VOC, 60 m x 0.20 mm, 1.10 µm 19091R-306
VF-624ms, 60 m x 0.25 mm, 1.40 µm CP9103
DB-624 Ultra Inert, 60 m x 0.25 mm, 1.40 µm 122-1364UI
8260/CLP-VOCs Volatile organic compounds by gas DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
chromatography/mass spectroscopy (GC/MS): DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
capillary column technique method
DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
8260b Volatile organic compounds by GC/MS DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
VF-5ms, 30 m x 0.25 mm, 1.00 µm CP8946
VF-624ms, 60 m x 0.32 mm, 1.80 µm CP9105
DB-624 Ultra Inert, 60 m x 0.32 mm, 1.80 µm 123-1364UI
8261 Volatile organic compounds by vacuum distillation DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
in combination with GC/MS spectrometry DB-608, 30 m x 0.53 mm, 0.50 µm 125-6837
(VD/GC/MS)
DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
DB-624 Ultra Inert, 20 m x 0.18 mm, 1.00 µm 121-1324UI
VF-624ms, 60 m x 0.25 mm, 1.40 µm CP9103
(Continued)
WWW.AGilent.Com/Chem/GC 275
AGilent J&W GC Columns
solid Waste
ePA method Application Column Part no.
8270, 8270d Semivolatile organic compounds by gas DB-UI 8270D Ultra Inert, 30 m x 0.25 mm, 0.25 µm 122-9732
chromatography/mass spectrometry (GC/MS) DB-UI 8270D, 20 m x 0.18 mm, 0.36 µm 121-9723
HP-5ms, 30 m x 0.25 mm, 0.50 µm 19091S-133
VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
VF-5ms, 30 m x 0.25 mm, 0.50 µm CP8945
VF-5ms, 30 m x 0.25 mm, 1.00 µm CP8946
8275a Semivolatile organic compounds (PAHs and PCBs) DB-5ms, 30 m x 0.25 mm, 1.00 µm 122-5533
in soils/sludges and solid wastes using thermal HP-5ms, 30 m x 0.25 mm, 0.50 µm 19091S-133
extraction/gas chromatography/mass spectrometry
(TE/GC/MS) VF-5ms, 30 m x 0.25 mm, 0.25 µm CP8944
VF-5ms, 30 m x 0.25 mm, 0.50 µm CP8945
VF-5ms, 30 m x 0.25 mm, 1.00 µm CP8946
8280b Polychlorinated dibenzo-p-dioxins (PCDDs) and DB-5ms Ultra Inert, 60 m x 0.25 mm, 0.25 µm 122-5562UI
polychlorinated dibenzofurans (PCDFs) by high CP-Sil 8 CB, 30 m x 0.25 mm, 0.25 µm CP8751
resolution gas chromatography/low resolution
mass spectrometry (HRGC/LRMS)
8290b Polychlorinated dibenzo-p-dioxins (PCDDs) and DB-5ms Ultra Inert, 60 m x 0.25 mm, 0.25 µm 122-5562UI
polychlorinated dibenzofurans (PCDFs) by high CP-Sil 8 CB, 30 m x 0.25 mm, 0.25 µm CP8751
resolution gas chromatography/high resolution
mass spectrometry (HRGC/HRMS) CP-Sil 88 for Dioxins, 50 m x 0.25 mm, 0.20 µm CP7588
8410 Gas chromatography/Fourier transform infrared HP-5ms, 30 m x 0.32 mm, 1.00 µm 19091S-213
(GC/FTIR) spectrometry for semivolatile organics: DB-5ms, 30 m x 0.32 mm, 1.00 µm 123-5533
capillary column
VF-5ms, 30 m x 0.32 mm, 0.25 µm CP8955
8430 Analysis of bis(2-chloroethyl) ether and hydrolysis DB-WAX, 30 m x 0.25 mm, 0.50 µm 122-7033
products by direct aqueous injection (GC/FTIR) HP-INNOWax, 30 m x 0.25 mm, 0.50 µm 19091N-233
VF-WAXms, 30 m x 0.53 mm, 1.00 µm CP9215
276
AGilent J&W GC Columns
WWW.AGilent.Com/Chem/GC 277
AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D1945 Standard Test Method for the Analysis HP-PLOT Molesieve, 15 m x 0.53 mm, 50.00 µm 19095P-MS9
of Natural Gas by GC HP-PLOT Q PT, 15 m x 0.53 mm, 40.00 µm 19095P-QO3PT
CP-Molsieve 5Å, 10 m x 0.53 mm, 50.00 µm CP7537
PoraPLOT Q-HT, 10 m x 0.53 mm, 20.00 µm CP7558
D1946 Standard Test Method for the Analysis HP-PLOT Molesieve, 15 m x 0.53 mm, 50.00 µm 19095P-MS9
of Reformed Gas by GC HP-PLOT Q PT, 15 m x 0.53 mm, 40.00 µm 19095P-QO3PT
CP-Molsieve 5Å, 10 m x 0.53 mm, 50.00 µm CP7537
CP-Molsieve 5Å, 25 m x 0.25 mm, 30.00 µm CP7533
D1983 Standard Test Method for Fatty Acid Composition DB-WAX, 30 m x 0.25 mm, 0.25 µm 122-7032
by Gas-Liquid Chromatography of Methyl Esters
D2163 Standard Test Method for the Analysis of Liquified HP-PLOT Al2O3 KCl PT, 30 m x 0.53 mm, 15.00 µm 19095P-K23PT
Petroleum (LP) Gases and Propene Concentrates by GC HP-PLOT Al2O3 S PT, 30 m x 0.53 mm, 15.00 µm 19095P-S23PT
D2195 Standard Test Methods for Pentaerythritol CP-Sil 5 CB, 30 m x 0.53 mm, 1.50 µm CP8735
D2268 Standard Test Method for Analysis of High-Purity DB-1, 60 m x 0.25 mm, 0.50 µm 122-106E
n-Heptane and Isooctane by Capillary GC
D2306 Standard Test Method for C8 Aromatic Hydrocarbons HP-INNOWax, 60 m x 0.25 mm, 0.25 µm 19091N-136
by GC
D2360 Standard Test Method for Trace Impurities HP-INNOWax, 60 m x 0.32 mm, 0.25 µm 19091N-116
in Monocyclic Aromatic Hydrocarbons by GC
D2426 Standard Test Method for Butadiene Dimer DB-1, 30 m x 0.53 mm, 5.00 µm 125-1035
and Styrene in Butadiene Concentrates by GC CP-Sil 5 CB, 30 m x 0.53 mm, 1.50 µm CP8735
D2427 Standard Test Method for Determination of DB-1, 30 m x 0.53 mm, 5.00 µm 125-1035
C2 through C5 Hydrocarbons in Gasoline by GC GS-Alumina PT, 30 m x 0.53 mm, 115-3532PT
CP-Al2O3/KCl PT, 50 m x 0.53 mm, 10.00 µm CP7518PT
D2245 Standard Test Method for Identification of Oils CP-Sil 88 for FAME, 50 m x 0.25 mm, 0.20 µm CP7488
and Oil Acids in Solvent-Reducible Paints
D2504 Standard Test Method for Noncondensable Gases HP-PLOT Molesieve, 30 m x 0.53 mm, 50.00 µm 19095P-MS0
in C2 and Lighter Hydrocarbon Products by GC CarboBOND, 25 m x 0.53 mm, 10.00 µm CP7374
D2505 Standard Test Method for Ethylene, Other GS-GasPro, 60 m x 0.32 mm 113-4362
Hydrocarbons, and Carbon Dioxide in High-Purity
Ethylene by GC
(Continued)
278
AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D2580 Standard Test Method for Phenols in Water CP-FFAP CB, 25 m x 0.53 mm, 1.00 µm CP7486
by Gas-Liquid Chromatography
D2593 Standard Test Method for Butadiene Purity GS-Alumina PT, 30 m x 0.53 mm 115-3532PT
and Hydrocarbon Impurities by GC CP-Al2O3/KCl PT, 50 m x 0.32 mm, 5.00 µm CP7515PT
CP-Al2O3/KCl PT, 50 m x 0.53 mm, 10.00 µm CP7518PT
D2712 Standard Test Method for Hydrocarbon Traces GS-Alumina PT, 50 m x 0.53 mm 115-3552PT
in Propylene Concentrates by GC
D2743 Standard Practices for Uniformity of Traffic Paint Vehicle CP-Sil 88 for FAME, 50 m x 0.25 mm, 0.20 µm CP7488
Solids by Spectroscopy and Gas Chromatography
D2804 Standard Test Method for Purity of Methyl Ethyl Ketone DB-WAX, 30 m x 0.53 mm, 1.00 µm 125-7032
by GC DB-210, 15 m x 0.53 mm, 1.00 µm 125-0212
CP-Wax 52 CB, 30 m x 0.32 mm, 0.50 µm CP8763
CP-Wax 52 CB, 30 m x 0.53 mm, 1.00 µm CP8738
D2887 Standard Test Method for Boiling Range Distribution DB-2887, 10 m x 0.53 mm, 3.00 µm 125-2814
of Petroleum Fractions by GC CP-SimDist UltiMetal, 5 m x 0.53 mm, 0.88 µm CP7570
CP-SimDist UltiMetal, 10 m x 0.53 mm, 2.65 µm CP7582
CP-SimDist UltiMetal, 5 m x 0.53 mm, 0.17 µm CP7532
Extended Standard Test Method for Boiling Range Distribution HP-1, 10 m x 0.53 mm, 0.88 µm 19095Z-021
D2887 of Petroleum Fractions by GC, to C60 HP-1, 5 m x 0.53 mm, 0.88 µm 19095Z-020
D2908 Standard Practice for Measuring Volatile Organic CP-Select 624 CB, 30 m x 0.32 mm, 1.80 µm CP7414
Matter in Water by Aqueous-Injection GC CP-Select 624 CB, 75 m x 0.53 mm, 3.00 µm CP7417
CP-Wax 52 CB, 30 m x 0.32 mm, 0.50 µm CP8763
CP-Wax 52 CB, 30 m x 0.53 mm, 1.00 µm CP8738
D3054 Standard Test Method for Analysis of Cyclohexane by GC DB-1, 60 m x 0.32 mm, 0.50 µm 123-106E
D3168 Standard Practice for Qualitative Identification of CP-Sil 5 CB, 30 m x 0.32 mm, 1.00 µm CP8760
Polymers in Emulsion Paints CP-Sil 5 CB, 30 m x 0.53 mm, 1.50 µm CP8735
D3257 Standard Test Method for Aromatics in Mineral Spirits DB-624, 30 m x 0.53 mm, 3.00 µm 125-1334
by GC
D3271 Standard Practice for Direct Injection of Solvent- PoraPLOT Q, 25 m x 0.53 mm, 20.00 µm CP7554
Reducible Paints into a Gas Chromatograph CP-Wax 52 CB, 30 m x 0.53 mm, 1.00 µm CP8738
for Solvent Analysis
(Continued)
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AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D3328 Standard Test Methods for Comparison of Waterborne CP-Sil 5 CB, 30 m x 0.32 mm, 3.00 µm CP8687
Petroleum Oils by Gas Chromatography CP-Sil 5 CB, 30 m x 0.53 mm, 3.00 µm CP8677
D3329 Standard Test Method for Purity of Methyl Isobutyl DB-WAX, 30 m x 0.53 mm, 1.00 µm 125-7032
Ketone by GC DB-624, 30 m x 0.45 mm, 2.55 µm 124-1334
CP-Wax 52 CB, 60 m x 0.53 mm, 1.00 µm CP8798
D3432 Standard Test Method for Unreacted Toluene HP-1ms, 30 m x 0.32 mm, 1.00 µm 19091S-713
Diisocyanates in Urethane Prepolymers
and Coating Solutions by GC
D3447 Standard Test Method for Purity DB-624, 30 m x 0.53 mm, 3.00 µm 125-1334
of Halogenated Organic Solvents
D3452 Standard Practice for Rubber – Identification CP-Sil 5 CB, 30 m x 0.53 mm, 1.50 µm CP8735
by Pyrolysis-Gas Chromatography
D3465 Standard Test Method for Purity of CP-Sil 5 CB, 25 m x 0.32 mm, 0.52 µm CP8430
Monomeric Plasticizers by Gas Chromatography CP-Sil 5 CB, 30 m x 0.53 mm, 1.50 µm CP8735
D3524 Standard Test Method for Diesel Fuel Diluent CP-SimDist UltiMetal, 10 m x 0.53 mm, 0.53 µm CP7592
in Used Diesel Engine Oils by Gas Chromatography
D3545 Standard Test Method for Alcohol Content and Purity DB-624, 30 m x 0.53 mm, 3.00 µm 125-1334
of Acetate Esters by GC
D3606 Standard Test Method for Determination of Benzene VF-1ms, 15 m x 0.25 mm, 0.10 µm CP8906
and Toluene in Finished Motor and Aviation Gasoline CP-TCEP for Alcohols in Gasoline, 50 m x 0.25 mm, 0.40 µm CP7525
by Gas Chromatography
D3687 Standard Test Method for Analysis of DB-WAX, 30 m x 0.53 mm, 1.00 µm 125-7032
Organic Vapors Collected by the Activated Charcoal DB-WAX, 30 m x 0.45 mm, 0.85 µm 124-7032
Tube Adsorption Method
CP-Wax 52 CB, 30 m x 0.32 mm, 0.50 µm CP8763
CP-Wax 52 CB, 30 m x 0.53 mm, 1.00 µm CP8738
D3695 Standard Test Method for Volatile Alcohols in Water DB-WAX, 30 m x 0.53 mm, 1.00 µm 125-7032
by Direct Aqueous-Injection GC CP-SimDist UltiMetal, 10 m x 0.53 mm, 0.53 µm CP7592
D3710 Standard Test Method for Boiling Range Distribution DB-2887, 10 m x 0.53 mm, 3.00 µm 125-2814
of Gasoline and Gasoline Fractions by GC
D3749 Standard Test Method for Residual Vinyl Chloride PoraBOND Q, 10 m x 0.32 mm, 5.00 µm CP7350
Monomer in Poly(Vinyl Chloride) Resins by PoraBOND Q PT, 10 m x 0.53 mm, 10.00 µm CP7353PT
Gas Chromatographic Headspace Technique
(Continued)
280
AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D3760 Standard Test Method for Analysis of Isopropylbenzene DB-WAX, 60 m x 0.32 mm, 0.25 µm 123-7062
(Cumene) by GC HP-1, 50 m x 0.32 mm, 0.52 µm 19091Z-115
CP-Xylenes, 50 m x 0.53 mm CP7428
D3792 Standard Test Method for Water Content of Coatings PoraBOND Q PT, 25 m x 0.32 mm, 5.00 µm CP7351PT
by Direct Injection Into a Gas Chromatograph PoraBOND Q PT, 25 m x 0.53 mm, 10.00 µm CP7354PT
D3797 Standard Test Method for Analysis of o-Xylene by GC HP-INNOWax, 60 m x 0.32 mm, 0.50 µm 19091N-216
CP-Xylenes, 50 m x 0.53 mm CP7428
D3798 Standard Test Method for Analysis of p-Xylene by GC HP-INNOWax, 60 m x 0.32 mm, 0.50 µm 19091N-216
CP-Xylenes, 50 m x 0.53 mm CP7428
D3871 Standard Test Method for Purgeable Organic DB-VRX, 75 m x 0.45 mm, 2.55 µm 124-1574
Compounds in Water Using Headspace Sampling
D3876 Standard Test Method for Methoxyl CP-Sil 5 CB, 30 m x 0.32 mm, 1.00 µm CP8760
and Hydroxypropyl Substitution in Cellulose Ether CP-Sil 5 CB, 30 m x 0.53 mm, 1.50 µm CP8735
Products by Gas Chromatography
D3893 Standard Test Method for Purity of Methyl Amyl Ketone DB-VRX, 30 m x 0.45 mm, 2.55 µm 124-1534
and Methyl Isoamyl Ketone by GC
D3973 Standard Test Method for Low-Molecular Weight DB-VRX, 30 m x 0.45 mm, 2.55 µm 124-1534
Halogenated Hydrocarbons in Water
D4059 Standard Test Method for Analysis of Polychlorinated CP-Sil 8 CB for PCB, 50 m x 0.25 mm, 0.25 µm CP7482
Biphenyls in Insulating Liquids by Gas Chromatography
D4275 Standard Test Method for Determination of Butylated CP-Sil 5 CB, 30 m x 0.32 mm, 3.00 µm CP8687
Hydroxy Toluene (BHT) in Polymers of Ethylene CP-Sil 5 CB, 30 m x 0.53 mm, 3.00 µm CP8677
and Ethylene – Vinyl Acetate (EVA) Copolymers
by Gas Chromatography
D4322 Standard Test Method for Residual Acrylonitrile PoraBOND Q PT, 25 m x 0.53 mm, 10.00 µm CP7354PT
Monomer Styrene-Acrylonitrile Copolymers
and Nitrile Rubber by Headspace Gas Chromatography
D4367 Standard Test Method for Benzene in Hydrocarbon VF-1ms, 15 m x 0.25 mm, 0.10 µm CP8906
Solvents by Gas Chromatography CP-TCEP for Alcohols in Gasoline, 50 m x 0.25 mm, 0.40 µm CP7525
D4415 Standard Test Method for Determination of Dimer DB-FFAP, 30 m x 0.32 mm, 0.25 µm 123-3232
in Acrylic Acid
D4424 Standard Test Method for Butylene Analysis by GC HP-PLOT Al2O3 S PT, 50 m x 0.53 mm, 15.00 µm 19095P-S25PT
CP-Al2O3/Na2SO4, 25 m x 0.53 mm, 10.00 µm CP7567
D4443 Standard Test Method for Residual Vinyl Chloride DB-VRX, 30 m x 0.45 mm, 2.55 µm 124-1534
Monomer Content in PPB Range in Vinyl Chloride
Homo- and Co-Polymers by Headspace GC
(Continued)
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AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D4492 Standard Test Method for Analysis of Benzene CP-TCEP for Alcohols in Gasoline, 50 m x 0.25 mm, 0.40 µm CP7525
by Gas Chromatography
D4509 Standard Test Methods for Determining the 24-Hour PoraBOND Q PT, 25 m x 0.32 mm, 5.00 µm CP7351PT
Gas (AIR) Space Acetaldehyde Content of Freshly PoraBOND Q PT, 25 m x 0.53 mm, 10.00 µm CP7354PT
Blown PET Bottles
D4534 Test Method for Benzene Content of Cyclic Products CP-TCEP for Alcohols in Gasoline, 50 m x 0.25 mm, 0.40 µm CP7525
by Gas Chromatography
D4735 Standard Test Method for Determination of Trace DB-FFAP, 30 m x 0.45 mm, 0.85 µm 124-3232
Thiophene in Refined Benzene by GC CP-Wax 58 FFAP CB, 25 m x 0.53 mm, 1.00 µm CP7614
D4768 Standard Test Method for Analysis of CP-Wax 58 FFAP CB, 25 m x 0.53 mm, 1.00 µm CP7614
2,6-Ditertiary-Butyl Para-Cresol and
2,6-Ditertiary-Butyl Phenol in Insulating
Liquids by Gas Chromatography
D4864 Standard Test Method for Determination of Traces DB-WAX, 30 m x 0.45 mm, 0.85 µm 124-7032
of Methanol in Propylene Concentrates by GC
D4947 Standard Test Method for Chlordane and Heptachlor DB-5, 30 m x 0.53 mm, 1.50 µm 125-5032
Residues in Indoor Air DB-608, 30 m x 0.53 mm, 0.83 µm 125-1730
D4961 Standard Test Method for GC Analysis of Major Organic DB-FFAP, 30 m x 0.45 mm, 0.85 µm 124-3232
Impurities in Phenol Produced by the Cumene Process HP-PLOT Q PT, 15 m x 0.53 mm, 40.00 µm 19095P-QO3PT
D4983 Standard Test Method for Cyclohexylamine Morpholine HP-5ms, 30 m x 0.32 mm, 1.00 µm 19091S-213
and Diethylaminoethanol in Water and Condensed CAM, 30 m x 0.53 mm, 1.00 µm 115-2132
Steam by Direct Aqueous Injection GC
D5008 Standard Test Method for Ethyl Methyl Pentonol HP-1, 15 m x 0.53 mm, 5.00 µm 19095Z-621
Content and Purity Value of 2-Ethylhexanol by GC HP-INNOWax, 30 m x 0.32 mm, 0.25 µm 19091N-113
D5060 Standard Test Method for Determining Impurities in HP-INNOWax, 60 m x 0.32 mm, 0.50 µm 19091N-216
High-Purity Ethylbenzene by GC CP-Wax 52 CB, 60 m x 0.32 mm, 0.50 µm CP8773
D5075 Standard Test Method for Nicotine in Indoor Air DB-5, 30 m x 0.53 mm, 1.50 µm 125-5032
DB-5, 30 m x 0.32 mm, 1.00 µm 123-5033
D5134 Standard Test Method for Detailed Analysis of HP-PONA, 50 m x 0.20 mm, 0.50 µm 19091S-001
Petroleum Naphthas Through n-Nonane by Capillary GC CP-Sil PONA for ASTM D5134, 50 m x 0.21 mm, 0.50 µm CP7531
D5135 Standard Test Method for Analysis of Styrene by HP-INNOWax, 60 m x 0.32 mm, 0.50 µm 19091N-216
Capillary GC CP-Wax 52 CB, 60 m x 0.32 mm, 0.50 µm CP8773
D5175 Standard Test Method for Organohalide Pesticides and DB-1, 30 m x 0.32 mm, 1.00 µm 123-1033
Polychlorinated Biphenyls in Water by Microextraction DB-608, 30 m x 0.32 mm, 0.50 µm 123-1730
and GC
DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
(Continued)
282
AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D5303 Standard Test Method for Trace Carbonyl Sulfide GS-GasPro, 30 m x 0.32 mm 113-4332
in Propylene by GC HP-PLOT Q PT, 30 m x 0.53 mm, 40.00 µm 19095P-QO4PT
D5307 Standard Test Method for Determination of Boiling HP-1, 7.5 m x 0.53 mm, 5.00 µm 19095Z-627
Range Distribution of Crude Petroleum by GC
D5310 Standard Test Method for Tar Acid Composition by HP-5ms, 30 m x 0.25 mm, 0.25 µm 19091S-433
Capillary GC DB-225ms, 30 m x 0.25 mm, 0.25 µm 122-2932
D5316 Standard Test Method for 1, 2-Dibromoethane and HP-1ms, 30 m x 0.32 mm, 1.00 µm 19091S-713
1, 2-Dibromo-3-Chloropropane in Water by DB-624, 30 m x 0.45 mm, 2.55 µm 124-1334
Microextraction and GC
D5317 Standard Test Method for Determination of Chlorinated HP-5ms, 30 m x 0.25 mm, 0.25 µm 19091S-433
Organic Acid Compounds in Water by GC with Electron DB-1701, 30 m x 0.25 mm, 0.25 µm 122-7732
Capture Detector
DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
D5320 Standard Test Method for Determination of DB-1, 30 m x 0.53 mm, 3.00 µm 125-1034
1, 1-Trichloroethane and Methylene Chloride in DB-VRX, 30 m x 0.32 mm, 1.80 µm 123-1534
Stabilized Trichloroethylene and Tetrachloroethylene
D5399 Standard Test Method for Boiling Point Distribution of DB-2887, 10 m x 0.53 mm, 3.00 µm 125-2814
Hydrocarbon Solvents by GC
D5441 Standard Test Method for Analysis of Methyl Tert-Butyl HP-PONA, 50 m x 0.20 mm, 0.50 µm 19091S-001
Ether (MTBD) by GC DB-Petro, 100 m x 0.25 mm, 0.50 µm 122-10A6E
D5442 Standard Test Method for Analysis of Petroleum Waxes DB-1, 25 m x 0.32 mm, 0.25 µm 123-1022
by GC DB-5, 15 m x 0.25 mm, 0.25 µm 122-5012
D5475 Standard Test Method for Nitrogen- and Phosphorus- HP-5ms, 30 m x 0.25 mm, 0.25 µm 19091S-433
Containing Pesticides in Water by GC with a Nitrogen DB-1701, 30 m x 0.25 mm, 0.25 µm 122-7732
Phosphorus Detector
DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
D5480 Standard Test Method for Engine Oil Volatility by GC DB-PS1, 15 m x 0.53 mm, 0.15 µm 145-1011
D5501 Standard Test Method for Determination of Ethanol HP-1, 100 m x 0.25 mm, 0.50 µm 19091Z-530
Content of Denatured Fuel Ethanol by GC
D5504 Standard Test Method for Determination of Sulfur DB-Sulfur SCD, 70 m x 0.53 mm, 4.30 µm G3903-63003
Compounds in Natural Gas and Gaseous Fuels by Gas CP-Sil 5 CB for Sulfur, 30 m x 0.32 mm, 4.00 µm CP7529
Chromatography and Chemiluminescence
(Continued)
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AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D5507 Standard Test Method for Determination of Trace HP-PLOT Q PT, 15 m x 0.53 mm, 40.00 µm 19095P-QO3PT
Organic Impurities in Monomer Grade Vinyl Chloride HP-PLOT U PT, 30 m x 0.53 mm, 20.00 µm 19095P-UO4PT
by Capillary Column/Multi-dimensional GC
D5508 Standard Test Method for Determination of Residual HP-PLOT Q PT, 30 m x 0.53 mm, 40.00 µm 19095P-QO4PT
Acrylonitrile Monomer in Styrene-Acrylonitrile
Co-polymer Resins and Nitrile-Butadiene Rubber
by Headspace Capillary GC
D5580 Standard Test Method for Determination of Benzene, DB-1, 30 m x 0.53 mm, 5.00 µm 125-1035
Toluene, Ethylbenzene, p/m-Xylene, C9 and Heavier CP-TCEP for Alcohols in Gasoline, 50 m x 0.25 mm, 0.40 µm CP7525
Aromatics, and Total Aromatics in Finished Gasoline
by GC CP-Sil 5 CB, 30 m x 0.53 mm, 5.00 µm CP8775
VF-1ms, 15 m x 0.25 mm, 0.10 µm CP8906
D5599 Standard Test Method for Determination of Oxygenates DB-5, 30 m x 0.25 mm, 0.25 µm 122-5032
in Gasoline by GC and Oxygen Selective Flame
Ionization Detection
D5623 Standard Test Method for Sulfur Compounds in Light DB-Sulfur SCD, 60 m x 0.32 mm, 4.20 µm G3903-63001
Petroleum Liquids by GC and Sulfur Selective Detection HP-1, 30 m x 0.32 mm, 4.00 µm 19091Z-613
D5713 Standard Test Method for Analysis of High Purity DB-Petro, 50 m x 0.20 mm, 0.50 µm 128-1056
Benzene for Cyclohexane Feedstock by Capillary GC
D5739 Standard Practice for Oil Spill Source Identification by DB-5, 30 m x 0.25 mm, 0.25 µm 122-5032
GC and Positive Ion Electron Impact Low Resolution DB-TPH, 30 m x 0.32 mm, 0.25 µm 123-1632
Mass Spectrometry
D5769 Standard Test Method for Determination of Benzene, HP-1, 60 m x 0.25 mm, 1.00 µm 19091Z-236
Toluene, and Total Aromatics in Finished Gasoline
by GC/MS
D5790 Standard Test Method for Measurement of DB-VRX, 60 m x 0.25 mm, 1.40 µm 122-1564
Purgeable Organic Compounds in Water by DB-VRX, 20 m x 0.18 mm, 1.00 µm 121-1524
Capillary Column GC/MS
DB-624, 60 m x 0.25 mm, 1.40 µm 122-1364
DB-624, 20 m x 0.18 mm, 1.00 µm 121-1324
D5812 Standard Test Method for Determination of HP-5ms, 30 m x 0.25 mm, 0.25 µm 19091S-433
Organochlorine Pesticides in Water DB-1701, 30 m x 0.25 mm, 0.25 µm 122-7732
by Capillary Column GC
DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
DB-35ms, 30 m x 0.25 mm, 0.25 µm 122-3832
(Continued)
284
AGilent J&W GC Columns
Astm methods
method title Recommended Agilent Column Part no.
D5917 Standard Test Method for Trace Impurities in Monocyclic HP-INNOWax, 60 m x 0.32 mm, 0.25 µm 19091N-116
Aromatic Hydrocarbons by GC and External Calibration
D5974 Standard Test Method for Fatty and Rosin Acids in Tall DB-23, 60 m x 0.25 mm, 0.25 µm 122-2362
Oil Fraction Products by Capillary GC
D5986 Standard Test Method for Determination of Oxygenates, HP-1, 60 m x 0.53 mm, 5.00 µm 19095Z-626
Benzene, Toluene, C8-C12 Aromatics and Total Aromatics
in Finished Gasoline by GC/FTIR
D6144 Standard Test Method for Trace Impurities in HP-1, 60 m x 0.25 mm, 1.00 µm 19091Z-236
Alpha-Methylstyrene by Capillary GC
D6159 Standard Test Method for Determination of HP-PLOT Al2O3 KCl PT, 50 m x 0.53 mm, 15.00 µm 19095P-K25PT
Hydrocarbon Impurities in Ethylene by GC GS-Alumina PT, 50 m x 0.53 mm 115-3552PT
DB-1, 30 m x 0.53 mm, 5.00 µm 125-1035
D6160 Standard Test Method for Determination of PCBs in HP-5ms, 30 m x 0.32 mm, 0.25 µm 19091S-413
Waste Materials by GC DB-XLB, 30 m x 0.25 mm, 0.25 µm 122-1232
D6352 Standard Test Method for Boiling Range Distribution DB-HT Sim Dis, 5 m x 0.53 mm, 0.15 µm 145-1001
of Petroleum Distillates in Boiling Range from
174 to 700 °C by GC
D6387 Standard Test Methods for Composition of Turpentine CP-Wax 52 CB, 30 m x 0.32 mm, 0.50 µm CP8763
and Related Terpene Products by Capillary Gas CP-Wax 52 CB, 30 m x 0.53 mm, 1.00 µm CP8738
Chromatography
D6417 Standard Test Method for Estimation of Engine Oil DB-HT Sim Dis, 5 m x 0.53 mm, 0.15 µm 145-1001
Volatility by Capillary GC
D6584 Standard Test Method for Determination of Total Select Biodiesel, 15 m x 0.32 mm, 0.10 µm CP9078
Monoglyceride, Total Diglyceride, Total Triglyceride, and
Free and Total Glycerin in B-100 Biodiesel Methyl Esters
by Gas Chromatography
D6806 Standard Practice for Analysis of Halogenated Organic CP-Sil 5 CB, 50 m x 0.53 mm, 5.00 µm CP7685
Solvents and Their Admixtures by Gas Chromatography
E1616 Standard Test Method for Analysis of Acetic Anhydride HP-1, 50 m x 0.32 mm, 0.52 µm 19091Z-115
Using GC
E1863 Standard Test Method for Analysis of Acrylonitrile by GC DB-WAXetr, 60 m x 0.32 mm, 1.00 µm 123-7364
E0202 Standard Test Method for Analysis of Ethylene Glycols DB-624, 30 m x 0.53 mm, 3.00 µm 125-1334
and Propylene Glycols CP-Wax 57 CB for Glycols and Alcohols, 25 m x 0.25 mm, 0.20 µm CP7615
E0475 Standard Test Method for Assay of Di-tert-Butyl HP-5, 30 m x 0.53 mm, 5.00 µm 19095J-623
Peroxide Using GC
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AGIlent J&W GC ColUmns
GC Capillary Columns
Agilent J&W Ultra Inert GC Columns
Perform trace-level analysis
with the utmost confidence
As the GC industry’s premier measurement company, Agilent is uniquely positioned to ensure the inertness
of the surfaces your sample touches, so you can achieve the parts-per-billion – or parts-per-trillion –
detection levels for your most demanding analyses. Agilent Ultra Inert components work together to
deliver industry-leading results: the Agilent GC instrument, Ultra Inert liner and Agilent J&W Ultra Inert
GC column family.
The Agilent J&W Ultra Inert GC column family pushes industry standards for consistent column inertness
and exceptionally low column bleed, resulting in lower detection limits and more accurate data for difficult
analytes. Each Ultra Inert column is tested with the industry’s most demanding test probe mixture and we
prove it with a performance summary sheet shipped with each column.
pA
DB-35ms Ultra Inert
35
Retention Index of Undecanol
30
1450.0
25
20
15
10
5
0 2 4 6 8 10 12 min
1557.9
pA
DB-35ms
35
Retention Index
30 of Biphenyl
25
20 1449.7
15
10
5
0 2 4 6 8 10 12 min
1557.4
With Agilent J&W Ultra Inert GC columns, selectivity remains the same, allowing you to confidently integrate Ultra Inert columns
into your current methods.
286
AGIlent J&W GC ColUmns
The test probes in Agilent’s Ultra Inert test probe mixture have low molecular weights, low boiling points
and no steric shielding of their active groups. These characteristics allow the probative portion of the test
molecules to penetrate – and fully interact with – the stationary phase and column surface.
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AGIlent J&W GC ColUmns
Agilent’s more demanding Ultra Inert test probe mixture for 5ms, 1ms, and 35ms Ultra Inert columns
Ultra Inert 5ms Columns Ultra Inert 1ms Columns Ultra Inert 35ms Columns
elution Functional elution Functional elution Functional
order test Probe test order test Probe test order test Probe test
1. 1-Propionic acid Basicity 1. 1-Propionic acid Basicity 1. 1-Octene Polarity
2. 1-Octene Polarity 2. 1-Octene Polarity 2. 1-Butyric acid Basicity
3. n-Octane Hydrocarbon 3. n-Octane Hydrocarbon 3. n-Nonane Hydrocarbon
marker marker marker
4. 4-Picoline Acidity 4. 1,2-Butanediol Silanol 4. 4-Picoline Acidity
5. n-Nonane Hydrocarbon 5. 4-Picoline Acidity 5. n-Propylbenzene Polarity
marker
6. Trimethyl phosphate Acidity 6. Trimethyl phosphate Acidity 6. 1-Heptanol Silanol, Polarity
7. 1,2-Pentanediol Silanol 7. n-Propylbenzene Hydrocarbon 7. 1,2-Pentanediol Silanol
marker
8. n-Propylbenzene Hydrocarbon 8. 1-Heptanol Silanol 8. 3-Octanone Polarity
marker
9. 1-Heptanol Silanol 9. 3-Octanone Polarity 9. Trimethyl phosphate Acidity
10. 3-Octanone Polarity 10. tert-Butylbenzene Hydrocarbon 10. tert-Butylbenzene Hydrocarbon
marker marker
11. n-Decane Efficiency 11. n-Decane Efficiency 11. n-Undecane Efficiency
Chemical Structures
OH NH2 CH3
O O
H3C CH3 H3C CH3
H3C
OH H3C OH
N
2,6-Dimethylphenol 2,6-Dimethylaniline 1-Propionic acid 4-Picoline 1-Butyric acid
Weak probe molecules: The acidic and basic portions of these strong probe molecules: The probes in Agilent’s Ultra Inert test
molecules are shielded by the two methyl groups on their phenyl probe mixture are highly probative of the stationary phase and
rings, making them less probative. surface. Note, too, that the active end of each compound is
available to interact with any active sites on the column.
288
AGIlent J&W GC ColUmns
similar Phases: SPB-1, Rtx-1, BP-1, OV-1, OV-101, 007-1(MS), SP-2100, SE-30, ZB-1, AT-1,
MDN-1, ZB-1, ZB-1ms
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AGIlent J&W GC ColUmns
similar Phases: Rtx-5ms, Rxi-5ms, Rxi-5Sil MS, PTE-5, BPX-5, AT-5ms, ZB-5ms, ZB-5MSi, SLB-5ms, Equity-5
similar Phases: Rtx-5ms, Rxi-5ms, Rxi-5Sil MS, PTE-5, BPX-5, AT-5ms, ZB-5ms, SLB-5ms, Equity-7
290
AGIlent J&W GC ColUmns
similar Phases: Rtx-35, Rtx-35ms, Rxi-35Sil MS, SPB-35, AT-35, Sup-Herb, MDN-35, BPX-34,
ZB-35, ZB-35 ht
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AGIlent J&W GC ColUmns
292
AGIlent J&W GC ColUmns
Unlike other manufacturers' 0.1 mm id columns, Agilent's 0.15 and 0.18 mm id High Efficiency Capillary GC
columns are compatible with all standard pressure capillary GC and GC/MS instruments – without
expensive high-pressure modifications. They also give you:
• The flexibility to choose between helium and hydrogen carrier gases. You can stay with a helium
carrier if you wish to simplify method development, or switch to a hydrogen carrier to further
reduce your analysis time.
• The ability to separate samples using less carrier gas, which can lead to longer intervals between
cylinder changes, increased uptime, and a lower cost per sample.
In addition, these flexible columns easily adapt to a wide variety of environmental, petrochemical,
flavor/fragrance, clinical toxicology, and pharmaceutical sample matrices.
The Agilent J&W High Efficiency GC columns throughout this section are displayed using italicized
descriptions and part numbers in the ordering tables.
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AGIlent J&W GC ColUmns
What makes an Agilent J&W low-bleed column exceptional? Unique polymer chemistry and proprietary
surface deactivation, both of which have contributed to columns that adhere to the tightest quality control
specifications in the industry for bleed, inertness, selectivity and efficiency. Agilent J&W "ms" columns utilize
special surface deactivation and siloxane chemistries which enhance the chromatographic performance of
siloxane polymers.
The mass spectrum of septum bleed can look very much like GC column bleed, so the two are often
confused. An easy way to tell the two apart: column bleed will be indicated by a rise in the baseline,
not peaks. If you see bleed peaks, these generally come from lower quality septa or septa being used
beyond their operating limits. To minimize septa contributions to background bleed, use quality Agilent BTO,
Long-Life, or Advanced Green septa.
294
AGIlent J&W GC ColUmns
DB-1ms
CH3
• 100% Dimethylpolysiloxane O Si
• Identical selectivity to DB-1
CH3 100%
• Non-polar
• Very low bleed characteristics, ideal for GC/MS
• Improved acid performance compared to standard 100% dimethylpolysiloxane columns Structure of DB-1ms
• Improved signal-to-noise ratio for better sensitivity and mass spectral integrity
• 340/360 °C upper temperature limit
• Excellent general purpose column
• Bonded and cross-linked
• Solvent rinsable
similar Phases: SPB-1, Rtx-1, BP-1, OV-1, OV-101, 007-1(MS), SP-2100, SE-30, ZB-1, AT-1, MDN-1,
ZB-1, ZB-1ms
DB-1ms
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.10 10 0.10 -60 to 340/360 127-0112 127-0112LTM
0.40 -60 to 340/360 127-0113
20 0.10 -60 to 340/360 127-0122
0.40 -60 to 340/360 127-0123 127-0123LTM
0.18 20 0.18 -60 to 340/360 121-0122 121-0122LTM
0.20 12 0.33 -60 to 340/350 128-0112
25 0.33 -60 to 340/350 128-0122 128-0122E 128-0122LTM
0.25 15 0.25 -60 to 340/360 122-0112 122-0112E 122-0112LTM
30 0.10 -60 to 340/360 122-0131
0.25 -60 to 340/360 122-0132 122-0132E
60 0.25 -60 to 340/360 122-0162
0.32 15 0.25 -60 to 340/360 123-0112
30 0.10 -60 to 340/360 123-0131
0.25 -60 to 340/360 123-0132
60 0.25 -60 to 340/360 123-0162
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 295
AGIlent J&W GC ColUmns
hP-1ms
CH3
O Si • 100% Dimethylpolysiloxane
• Identical selectivity to HP-1
CH3 100%
• Non-polar
• Low bleed characteristics
Structure of HP-1ms • Excellent general purpose column
• Improved signal-to-noise ratio for better sensitivity and mass spectral integrity
• Bonded and cross-linked
• Solvent rinsable
similar Phases: Rtx-1ms, Rxi-1ms, MDN-1, AT-1, ZB-1ms, Equity-1
hP-1ms
ID 7890/6890
(mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 -60 to 325/350 19091S-677 19091S-677LTM
0.20 25 0.33 -60 to 325/350 19091S-602 19091S-602E
0.25 15 0.25 -60 to 325/350 19091S-931
30 0.10 -60 to 325/350 19091S-833 19091S-833LTM
0.25 -60 to 325/350 19091S-933 19091S-933E 19091S-933LTM
0.50 -60 to 325/350 19091S-633 19091S-633LTM
1.00 -60 to 325/350 19091S-733 19091S-733E 19091S-733LTM
60 0.25 -60 to 325/350 19091S-936 19091S-936E
0.32 15 0.25 -60 to 325/350 19091S-911
25 0.52 -60 to 325/350 19091S-612
30 0.25 -60 to 325/350 19091S-913 19091S-913E
1.00 -60 to 325/350 19091S-713 19091S-713LTM
60 0.25 -60 to 325/350 19091S-916
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
296
AGIlent J&W GC ColUmns
VF-1ms
CH3
• Highly inert, non-polar 100% dimethylpolysiloxane phase, low-bleed GC column providing increased O Si
sensitivity over a broad array of applications
• Ultra low bleed specification of 1 pA at 325 °C (30 m, 0.25 mm, 0.25 µm) for trace analysis with MS CH3 100%
• QC test results for retention index, efficiency, selectivity and bleed is reported with every column
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses Structure of VF-1ms
• Supplied with EZ-GRIP to simplify column installation, coupling and operation
similar Phases: Rtx-1ms, Rxi-1ms, MDN-1, AT-1, ZB-1ms, Equity-1
VF-1ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.10 10 0.10 -60 to 325/350 CP8900
0.40 -60 to 325/350 CP8901
20 0.10 -60 to 325/350 CP8902
0.40 -60 to 325/350 CP8903
0.15 10 0.15 -60 to 325/350 CP9030
15 0.15 -60 to 325/350 CP5881
20 0.15 -60 to 325/350 CP9031
0.60 -60 to 325/350 CP9032
0.20 12 0.33 -60 to 325/350 CP8904
25 0.33 -60 to 325/350 CP8905
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
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AGIlent J&W GC ColUmns
VF-1ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 15 0.10 -60 to 325/350 CP8906
0.25 -60 to 325/350 CP8907
1.00 -60 to 325/350 CP8908 CP8908I5
25 0.25 -60 to 325/350 CP8909
0.40 -60 to 325/350 CP8910
30 0.10 -60 to 325/350 CP8911
0.25 -60 to 325/350 CP8912 CP8912I5
Column shown with EZ-GRIP 1.00 -60 to 325/350 CP8913
50 0.25 -60 to 325/350 CP8914
0.40 -60 to 325/350 CP8915
60 0.25 -60 to 325/350 CP8916
1.00 -60 to 325/350 CP8917
0.32 15 0.10 -60 to 325/350
0.25 -60 to 325/350 CP8919
1.00 -60 to 325/350
25 0.25 -60 to 325/350 CP8921
0.40 -60 to 325/350 CP8922
30 0.10 -60 to 325/350 CP8923
0.25 -60 to 325/350 CP8924
0.50 -60 to 325/350 CP8925
1.00 -60 to 325/350 CP8926
50 0.25 -60 to 325/350
0.40 -60 to 325/350 CP8928
60 0.25 -60 to 325/350 CP8929
1.00 -60 to 325/350 CP8930
0.53 15 0.50 -60 to 325/350 CP8965
1.50 -60 to 325/350 CP8967
30 0.50 -60 to 325/350 CP8968
1.00 -60 to 325/350 CP8969
1.50 -60 to 310/335 CP8970
298
AGIlent J&W GC ColUmns
DB-5ms
CH3 CH3 CH3
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AGIlent J&W GC ColUmns
DB-5ms
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 -60 to 325/350 121-5522 121-5522E 121-5522LTM
0.36 -60 to 325/350 121-5523 121-5523LTM
40 0.18 -60 to 325/350 121-5542
0.20 12 0.33 -60 to 325/350 128-5512
25 0.33 -60 to 325/350 128-5522 128-5522LTM
50 0.33 -60 to 325/350 128-5552
0.25 15 0.10 -60 to 325/350 122-5511 122-5511LTM
0.25 -60 to 325/350 122-5512 122-5512LTM
0.50 -60 to 325/350 122-5516
1.00 -60 to 325/350 122-5513
25 0.25 -60 to 325/350 122-5522 122-5522LTM
0.40 -60 to 325/350
30 0.10 -60 to 325/350 122-5531
0.25 -60 to 325/350 122-5532 122-5532E 122-5532LTM
0.50 -60 to 325/350 122-5536 122-5536E
1.00 -60 to 325/350 122-5533 122-5533E 122-5533LTM
50 0.25 -60 to 325/350 122-5552
60 0.10 -60 to 325/350 122-5561
0.25 -60 to 325/350 122-5562 122-5562E
1.00 -60 to 325/350 122-5563
0.32 15 0.10 -60 to 325/350 123-5511
0.25 -60 to 325/350 123-5512 123-5512LTM
1.00 -60 to 325/350 123-5513 123-5513LTM
25 0.52 -60 to 325/350 123-5526
30 0.10 -60 to 325/350 123-5531
0.25 -60 to 325/350 123-5532 123-5532E
0.50 -60 to 325/350 123-5536 123-5536LTM
1.00 -60 to 325/350 123-5533 123-5533LTM
60 0.10 -60 to 325/350 123-5561
0.25 -60 to 325/350 123-5562
0.50 -60 to 325/350 123-5566
1.00 -60 to 325/350 123-5563
0.53 15 1.50 -60 to 300/320 125-5512
30 0.50 -60 to 300/320 125-5537
1.00 -60 to 300/320 125-553J 125-553JLTM
1.50 -60 to 300/320 125-5532 125-5532LTM
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
300
AGIlent J&W GC ColUmns
hP-5ms C6H5
CH3
• (5%-Phenyl)-methylpolysiloxane O Si O Si
• Identical selectivity to HP-5
• Non-polar CH3 86% C6H5 14%
• Improved signal-to-noise ratio for better sensitivity and mass spectral integrity
• Bonded and cross-linked
• Solvent rinsable
• Equivalent to USP Phase G27
similar Phases: Rtx-5ms, Rxi-5ms, Rxi-5Sil MS, PTE-5, BPX-5, AT-5ms, ZB-5ms, SLB-5ms, Equity-5
hP-5ms
ID 7890/6890
(mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 -60 to 325/350 19091S-577 19091S-577LTM
0.20 12 0.33 -60 to 325/350 19091S-101 19091S-101LTM
25 0.33 -60 to 325/350 19091S-102 19091S-102E 19091S-102LTM
50 0.33 -60 to 325/350 19091S-105
0.25 15 0.10 -60 to 325/350 19091S-331 19091S-331LTM
0.25 -60 to 325/350 19091S-431 19091S-431LTM
1.00 -60 to 325/350 19091S-231
30 0.10 -60 to 325/350 19091S-333
0.25 -60 to 325/350 19091S-433 19091S-433E 19091S-433LTM
0.50 -60 to 325/350 19091S-133
1.00 -60 to 325/350 19091S-233 19091S-233E
60 0.10 -60 to 325/350 19091S-336
0.25 -60 to 325/350 19091S-436 19091S-436E
0.32 25 0.52 -60 to 325/350 19091S-112 19091S-112E
30 0.10 -60 to 325/350 19091S-313
0.25 -60 to 325/350 19091S-413 19091S-413E 19091S-413LTM
0.50 -60 to 325/350 19091S-113
1.00 -60 to 325/350 19091S-213
60 0.25 -60 to 325/350 19091S-416
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 301
AGIlent J&W GC ColUmns
VF-5ms
CH3 CH3 CH3
O Si Si O Si • Highly inert 5% phenylmethyl column for increased sensitivity, accuracy and instrument uptime
• Minimal column bleed improves sensitivity – ultra low bleed specification of 1 pA at 325 °C
CH3 CH3 m CH3 n (30 m x 0.25 mm, 0.25 µm)
• Slightly higher polarity than VF-1ms, results in improved selectivity for aromatic compounds;
Structure of VF-5ms selectivity and excellent inertness make these columns applicable for a wide range of semi-polar
and even polar compounds
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses
• QC test results for retention index, efficiency, selectivity and bleed is reported with every column
• Supplied with EZ-GRIP to simplify column installation, coupling and operation
similar Phases: Rtx-5ms, Rxi-5ms, Rxi-5Sil MS, PTE-5, BPX-5, AT-5ms, ZB-5ms, ZB-5MSi, SLB-5ms,
Equity-5
VF-5ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.10 10 0.40 -60 to 325/350 CP8934
0.15 10 0.15 -60 to 325/350 CP9034
15 0.15 -60 to 325/350 CP9035
20 0.15 -60 to 325/350 CP9036
0.30 -60 to 325/350 CP9037
0.60 -60 to 325/350 CP9038
40 0.15 -60 to 325/350 CP9039
0.20 12 0.33 -60 to 325/350 CP8935
25 0.33 -60 to 325/350 CP8936
50 0.33 -60 to 325/350 CP8937
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
302
AGIlent J&W GC ColUmns
VF-5ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 15 0.10 -60 to 325/350 CP8938
0.25 -60 to 325/350 CP8939
0.50 -60 to 325/350 CP8963
1.00 -60 to 325/350 CP8940
25 0.25 -60 to 325/350 CP8941
30 0.10 -60 to 325/350 CP8943
0.25 -60 to 325/350 CP8944 CP8944I5
0.50 -60 to 325/350 CP8945
1.00 -60 to 325/350 CP8946
Column on 5 in cage
50 0.25 -60 to 325/350 CP8947
60 0.10 -60 to 325/350 CP8948
0.25 -60 to 325/350 CP8960
1.00 -60 to 325/350 CP8949
0.32 15 0.10 -60 to 325/350 CP8950
0.25 -60 to 325/350 CP8951
25 0.52 -60 to 325/350 CP8953
30 0.25 -60 to 325/350 CP8955
0.50 -60 to 325/350 CP8956
1.00 -60 to 325/350 CP8957
50 0.25 -60 to 325/350 CP8958
0.40 -60 to 325/350 CP8959
60 0.25 -60 to 325/350 CP8961
1.00 -60 to 325/350 CP8962
0.53 15 0.50 -60 to 325/350 CP8971
30 0.50 -60 to 325/350 CP8974
1.00 -60 to 325/350 CP8975
1.50 -60 to 310/335 CP8976
WWW.AGIlent.Com/Chem/GC 303
AGIlent J&W GC ColUmns
DB-XlB
• Exceptionally low bleed
• Low polarity
• Extended temperature limit of 340/360 °C
• Unique selectivity
• Excellent inertness for active compounds
• Ideal for confirmational analyses
• Excellent for pesticides, herbicides, PCBs and PAHs
• Ideal for GC/MS
• Bonded and cross-linked
• Solvent rinsable
note: DB-XLB is designed for inhibiting column bleed at high temperatures. It also appears to have
inadvertently inherited an exceptional ability for separating many PCB congeners when used with MS
detection. This stellar performance was maximized after careful optimization of the column dimensions,
temperature programs, and carrier gas flow conditions.
DB-XlB
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm II module
0.18 20 0.18 30 to 340/360 121-1222
30 0.18 30 to 340/360 121-1232
0.20 25 0.33 30 to 340/360 128-1222
0.25 15 0.10 30 to 340/360 122-1211 122-1211LTM
0.25 30 to 340/360 122-1212
30 0.10 30 to 340/360 122-1231
0.25 30 to 340/360 122-1232 122-1232LTM
0.50 30 to 340/360 122-1236
1.00 30 to 340/360 122-1233
60 0.25 30 to 340/360 122-1262
0.32 30 0.25 30 to 340/360 123-1232
0.50 30 to 340/360 123-1236
60 0.25 30 to 340/360 123-1262
0.53 15 1.50 30 to 320/340 125-1212
30 1.50 30 to 320/340 125-1232
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
304
AGIlent J&W GC ColUmns
VF-Xms
CH3 CH3 CH3
• High arylene modified phase for accurate results O Si Si O Si
CH3 CH3 CH3
• Isothermal applications up to 340 °C for a broad application range X Y
• Ideal for confirmational analyses – more polar alternative to 5% phenyl columns
• Ultra low bleed delivers ultimate sensitivity and signal-to-noise ratio
• Provides exceptionally high selectivity for semivolatile compounds such as pesticides and delivers Structure of VF-Xms
high resolution with short analysis time
• Very unique selectivity for chlorinated compounds
• QC test results for retention index, efficiency, selectivity and bleed is reported with every column
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: Rtx-XLB, MDN-12, ZB-XLB, ZB-XLB HT
VF-Xms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.15 20 0.15 30 to 340/360 CP9041
0.20 25 0.33 30 to 340/360 CP8801
0.25 30 0.10 30 to 340/360 CP8805
0.25 30 to 340/360 CP8806
0.50 30 to 340/360 CP8807
60 0.25 30 to 340/360 CP8809
0.32 30 0.25 30 to 340/360 CP8813
60 0.25 30 to 340/360 CP8816 Column shown with EZ-GRIP
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 305
AGIlent J&W GC ColUmns
DB-35ms
CH3 CH3 CH3
DB-35ms
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 50 to 340/360 121-3822
0.20 15 0.33 50 to 340/360 128-3812
25 0.33 50 to 340/360 128-3822
0.25 15 0.25 50 to 340/360 122-3812
30 0.15 50 to 340/360 122-3831
30 0.25 50 to 340/360 122-3832 122-3832E 122-3832LTM
60 0.25 50 to 340/360 122-3862
0.32 15 0.25 50 to 340/360 123-3812
30 0.25 50 to 340/360 123-3832 123-3832E
0.53 30 0.50 50 to 320/340 125-3837
30 1.00 50 to 320/340 125-3832
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
306
AGIlent J&W GC ColUmns
VF-35ms
CH3 CH3 CH3
• Stabilized arylene-modified equivalent of a 35% phenylmethyl phase O Si O Si Si O Si
• Ideal for dual column confirmational analyses CH3 CH3 CH3
• Ultra low bleed, highly stable column with a programmable maximum temperature of 360 °C 35% X Y
• Medium polarity column ideal for trace environmental and chemical analyses
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses Structure of VF-35ms
VF-35ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.15 10 0.15 40 to 340/360 CP5887
20 0.15 40 to 340/360 CP5889
0.20 15 0.33 40 to 340/360 CP8872
25 0.33 40 to 340/360 CP8873
0.25 15 0.25 40 to 340/360 CP8874
30 0.10 40 to 340/360 CP8875
0.25 40 to 340/360 CP8877
0.50 40 to 340/360 CP8878
1.00 40 to 340/360 CP8879
60 0.25 40 to 340/360 CP8880
0.32 30 0.25 40 to 340/360 CP8882
0.50 40 to 340/360 CP8883
1.00 40 to 340/360 CP8884
0.53 30 1.00 40 to 325/350 CP8888
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 307
AGIlent J&W GC ColUmns
DB-17ms
CH 3 CH 3 CH 3
DB-17ms
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 40 to 320/340 121-4722 121-4722LTM
0.25 15 0.15 40 to 320/340 122-4711 122-4711LTM
0.25 40 to 320/340 122-4712 122-4712LTM
30 0.15 40 to 320/340 122-4731
0.25 40 to 320/340 122-4732 122-4732E 122-4732LTM
60 0.25 40 to 320/340 122-4762
0.32 15 0.25 40 to 320/340 123-4712
30 0.25 40 to 320/340 123-4732 123-4732LTM
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
308
AGIlent J&W GC ColUmns
VF-17ms
CH3
• 50% phenyl/50% dimethylpolysiloxane, medium polarity phase O Si O Si
• Ultra low bleed CH3
• Proprietary deactivation technology and manufacturing process improves column stability, X Y
resulting in improved column-to-column repeatability and column lifetimes
• Ideal for environmental and clinical methods Structure of VF-17ms
• Ultra low bleed specification at 2 pA at 325 °C (0.25 mm x 30 m, 0.25 µm)
• Ideal EPA confirmation column for ultimate confidence
• Bonded and cross-linked
• Solvent rinsable
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: Rxi-17Sil MS, Rtx-50, 007-17, SP-2250, SPB-50, BPX-50, SPB-17, AT-50
VF-17ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.10 10 0.20 40 to 330/360 CP8977
0.15 10 0.15 40 to 330/360 CP5882
15 0.15 40 to 330/360 CP5883
20 0.15 40 to 330/360 CP5884
0.25 15 0.25 40 to 330/360 CP8979
15 0.50 40 to 330/360 CP8980
30 0.15 40 to 330/360 CP8981
0.25 40 to 330/360 CP8982 CP8982I5
0.50 40 to 330/360 CP8983
60 0.25 40 to 330/360 CP8984
0.32 15 0.15 40 to 330/360 CP8986
30 0.25 40 to 330/360 CP8990
0.50 40 to 330/360 CP8991
0.53 15 1.00 40 to 330/360 CP8996
1.50 40 to 310/340 CP8998
30 1.00 40 to 310/340 CP9001
1.50 40 to 310/340 CP9002
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 309
AGIlent J&W GC ColUmns
C N
VF-23ms
(CH2)3 CH3 CH3
O Si O Si Si • High polarity and highly substituted cyanopropyl low bleed phase
(CH2)3 CH3 CH3 • Engineered for accurate analysis of very polar analytes
C N Y
• 100% bonded phase permits column rinsing to enhance column lifetime
X
• Operating temperature up to 260 °C
Structure of VF-23ms • Expands application ranges to higher molecular weight compounds
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: SP-2330, Rtx-2330, 007-23, AT-Silar, BPX-70, SP-2340
VF-23ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 30 0.15 40 to 260/260 CP8821
0.25 40 to 260/260 CP8822 CP8822I5
60 0.25 40 to 260/260 CP8824 CP8824I5
0.32 30 0.25 40 to 260/260 CP8827
60 0.15 40 to 260/260 CP8828
0.25 40 to 260/260 CP8829
0.53 30 0.50 40 to 245/245 CP8831
310
AGIlent J&W GC ColUmns
VF-200ms CF3
CH2
• Trifluoropropyl phase has very high temperature stability and can be used routinely up to 350 °C CH2 CH3
• Ideally suited for analyses of ketones, aldehydes, nitro- or chloro-containing compounds, PAHs, O Si O Si
unsaturated compounds, silanes, and CFCs CH3 CH3
X Y
• Optimized deactivation for symmetrical peak shape
• Ultra-low bleed for trace analysis Structure of VF-200ms
• 0.15 mm id columns available for high efficiency GC and GC/MS analyses
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: Rtx-200
VF-200ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 20 0.15 0 to 325/350 CP5891
0.60 0 to 325/350 CP5892
0.25 15 0.25 0 to 325/350 CP8855
30 0.10 0 to 325/350 CP8857
0.25 0 to 325/350 CP8858
0.50 0 to 325/350 CP8859 CP8859I5
1.00 0 to 325/350 CP8860
60 0.25 0 to 325/350 CP8861
0.32 30 0.50 0 to 325/350 CP8864
1.00 0 to 325/350 CP8865
0.53 30 0.50 0 to 300/325 CP8867
1.00 0 to 300/325 CP8868
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 311
AGIlent J&W GC ColUmns
DB-225ms
• Virtually equivalent to (50%-cyanopropylphenyl)-methylpolysiloxane
• Mid/high polarity
• Excellent for separations of cis- and trans-fatty acid methyl esters (FAMEs)
• Low bleed
• Bonded and cross-linked
• Solvent rinsable
• Close equivalent to USP Phase G7
similar Phases: SP-2330, Rtx-225, BP-225, OV-225, 007-225, AT-225
DB-225ms
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.25 15 0.25 40 to 240 122-2912 122-2912LTM
30 0.25 40 to 240 122-2932 122-2932E 122-2932LTM
60 0.25 40 to 240 122-2962
0.32 30 0.25 40 to 240 123-2932
312
AGIlent J&W GC ColUmns
VF-WAXms
• Specially designed WAX phase designed for accurate MS results with polar compounds O CH2 CH2 OH
• Operating temperature range of 20 °C to 250 °C n
VF-WAXms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.10 10 0.10 20 to 250/260 CP9219
0.20 20 to 250/260 CP9218
20 0.10 20 to 250/260 CP9229
0.15 15 0.15 20 to 250/260 CP9201
20 0.15 20 to 250/260 CP9220
30 0.15 20 to 250/260 CP9202
0.25 15 0.25 20 to 250/260 CP9203
0.50 20 to 250/260 CP9221
25 0.20 20 to 250/260 CP9204
30 0.25 20 to 250/260 CP9205 CP9205I5
0.50 20 to 250/260 CP9222
1.00 20 to 240 CP9206
60 0.25 20 to 250/260 CP9207
0.50 20 to 240 CP9223
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
WWW.AGIlent.Com/Chem/GC 313
AGIlent J&W GC ColUmns
VF-WAXms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.32 30 0.25 20 to 250/260 CP9212
0.50 20 to 250/260 CP9210
1.00 20 to 240 CP9211
60 0.25 20 to 250/260 CP9214
0.50 20 to 240 CP9225
1.00 20 to 230 CP9213
0.53 15 1.00 20 to 250/260 CP9226
2.00 20 to 240
30 1.00 20 to 240 CP9215
2.00 20 to 230 CP9216
60 1.00 20 to 230 CP9228
2.00 20 to 220 CP9217
314
AGIlent J&W GC ColUmns
VF-624ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 15 0.84 -40 to 280/300 CP9101
20 0.84 -40 to 280/300 CP9100
30 0.84 -40 to 280/300 CP9109
40 0.84 -40 to 280/300 CP9110
0.25 30 1.40 -40 to 280/300 CP9102 CP9102I5
60 1.40 -40 to 280/300 CP9103 CP9103I5
0.32 30 1.80 -40 to 280/300 CP9104 CP9104I5
60 1.80 -40 to 280/300 CP9105
0.53 30 3.00 -40 to 280/300 CP9106 CP9106I5
60 3.00 -40 to 265/280 CP9107
75 3.00 -40 to 265/280 CP9108
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 315
AGIlent J&W GC ColUmns
VF-1301ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.10 10 1.00 -40 to 280/300 CP9066
0.25 30 0.25 -40 to 280/300 CP9053
1.00 -40 to 280/300 CP9054
60 0.25 -40 to 280/300 CP9055
1.00 -40 to 280/300 CP9056
0.32 15 0.25 -40 to 280/300 CP9057
1.00 -40 to 280/300 CP9058
0.53 15 1.00 -40 to 280/300 CP9062
30 1.00 -40 to 280/300 CP9063
1.50 -40 to 280/300 CP9064
316
AGIlent J&W GC ColUmns
VF-1701ms
C N
(CH2)3 CH3 CH3 CH3
• Ultra-low bleed 14% cyanopropyl/phenyl/86% polydimethylsiloxane phase O Si O Si O Si Si
• Mid polarity CH3 CH3 CH3 CH3
• Ideal for pesticides, PCBs and semi-volatile organic compounds X Y Z
VF-1701ms
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 20 0.15 -20 to 280/300 CP9145
0.25 30 0.15 -20 to 280/300 CP9150
0.25 -20 to 280/300 CP9151 CP9151I5
1.00 -20 to 280/300 CP9152 CP9152I5
60 0.25 -20 to 280/300 CP9154
1.00 -20 to 280/300 CP9156
0.32 30 0.25 -20 to 280/300 CP9162
1.00 -20 to 280/300 CP9163
60 0.25 -20 to 280/300 CP9165
1.00 -20 to 280/300 CP9166
0.53 30 0.50 -20 to 280/300 CP9170
1.00 -20 to 280/300 CP9171
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 317
AGIlent J&W GC ColUmns
CH3
Premium Polysiloxane Columns
O Si
Polysiloxanes are the most common stationary phases. They are available in the greatest variety and are
CH3 stable, robust and versatile. Standard polysiloxanes are characterized by the repeating siloxane backbone.
100%
Each silicon atom contains two functional groups. The type and percent level of substitution of the groups
distinguish each stationary phase and its properties.
Structure of DB-1
DB-1
• 100% Dimethylpolysiloxane
• Non-polar
• Excellent general purpose column
• Wide range of applications
• Low bleed
• High temperature limit
• Bonded and cross-linked
• Solvent rinsable
• Wide range of column dimensions available
• Equivalent to USP Phase G2
similar Phases: SPB-1, Rtx-1, BP-1, OV-1, OV-101, 007-1(MS), SP-2100, SE-30, ZB-1, AT-1, MDN-1,
ZB-1
DB-1
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.05 10 0.05 -60 to 325/350 126-1012
0.20 -60 to 325/350 126-1013
0.10 5 0.12 -60 to 325/350 127-100A 127-100ALTM
10 0.10 -60 to 325/350 127-1012 127-1012E
0.40 -60 to 325/350 127-1013 127-1013E 127-1013LTM
20 0.10 -60 to 325/350 127-1022 127-1022E
0.40 -60 to 325/350 127-1023 127-1023LTM
40 0.20 -60 to 325/350 127-1046 127-1046E
0.40 -60 to 325/350 127-1043
(Continued)
318
AGIlent J&W GC ColUmns
DB-1
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.15 10 1.20 -60 to 325/350 12A-1015 12A-1015LTM
0.18 10 0.18 -60 to 325/350 121-1012 121-1012E 121-1012LTM
0.20 -60 to 325/350 121-101A 121-101ALTM
0.40 -60 to 325/350 121-1013 121-1013LTM
20 0.18 -60 to 325/350 121-1022 121-1022E 121-1022LTM
0.40 -60 to 325/350 121-1023 121-1023LTM
40 0.40 -60 to 325/350 121-1043
0.20 12 0.33 -60 to 325/350 128-1012 128-1012LTM
25 0.33 -60 to 325/350 128-1022 128-1022LTM
30 0.80 -60 to 325/350 128-1034
50 0.33 -60 to 325/350 128-1052
0.25 15 0.10 -60 to 325/350 122-1011
0.25 -60 to 325/350 122-1012 122-1012LTM
1.00 -60 to 325/350 122-1013
25 0.25 -60 to 325/350 122-1022 122-1022LTM
30 0.10 -60 to 325/350 122-1031
0.25 -60 to 325/350 122-1032 122-1032E 122-1032LTM*
0.50 -60 to 325/350 122-103E 122-103ELTM
1.00 -60 to 325/350 122-1033 122-1033E 122-1033LTM
50 0.25 -60 to 325/350 122-1052
60 0.10 -60 to 325/350 122-1061
0.25 -60 to 325/350 122-1062
0.50 -60 to 325/350 122-106E
1.00 -60 to 325/350 122-1063
100 0.50 -60 to 325/350 122-10AE
150 1.00 -60 to 325/350 122-10G3
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
WWW.AGIlent.Com/Chem/GC 319
AGIlent J&W GC ColUmns
DB-1
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.32 15 0.10 -60 to 325/350 123-1011 123-1011LTM
0.25 -60 to 325/350 123-1012 123-1012LTM
1.00 -60 to 325/350 123-1013
3.00 -60 to 280/300 123-1014
5.00 -60 to 280/300 123-1015 123-1015LTM
25 0.12 -60 to 325/350 123-1027
0.25 -60 to 325/350 123-1022
0.52 -60 to 325/350 123-1026
1.05 -60 to 325/350 123-102F
30 0.10 -60 to 325/350 123-1031
0.25 -60 to 325/350 123-1032 123-1032LTM
0.50 -60 to 325/350 123-103E 123-103ELTM
1.00 -60 to 325/350 123-1033 123-1033E 123-1033LTM
1.50 -60 to 300/320 123-103B 123-103BLTM
3.00 -60 to 280/300 123-1034
5.00 -60 to 280/300 123-1035 123-1035LTM
50 0.25 -60 to 325/350 123-1052
0.52 -60 to 325/350 123-1056
1.05 -60 to 325/350 123-105F
1.20 -60 to 325/350 123-105C
5.00 -60 to 280/300 123-1055
60 0.10 -60 to 325/350 123-1061
0.25 -60 to 325/350 123-1062 123-1062E
0.50 -60 to 325/350 123-106E
1.00 -60 to 325/350 123-1063 123-1063E
1.50 -60 to 300/320 123-106B 123-106BE
2.00 -60 to 280/300 123-106G
3.00 -60 to 280/300 123-1064 123-1064E
5.00 -60 to 280/300 123-1065 123-1065E
0.45 30 1.27 -60 to 325/350 124-1032
2.55 -60 to 260/280 124-1034
(Continued)
320
AGIlent J&W GC ColUmns
DB-1
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.53 5 2.65 -60 to 325/350 125-100B
5.00 -60 to 325/350 125-1005 125-1005LTM
7.5 1.50 -60 to 325/350 125-1002
10 2.65 -60 to 260/280 125-10HB 125-10HBE 125-10HBLTM
5.00 -60 to 260/280 125-10H5
15 0.15 -60 to 340/360 125-1011 125-1011E 125-1011LTM
0.25 -60 to 320/340 125-101K
0.50 -60 to 300/320 125-1017
1.00 -60 to 300/320 125-101J
1.50 -60 to 300/320 125-1012 125-1012E 125-1012LTM
3.00 -60 to 260/280 125-1014
5.00 -60 to 260/280 125-1015 125-1015LTM
25 1.00 -60 to 300/320 125-102J
5.00 -60 to 260/280 125-1025 125-1025LTM
30 0.10 -60 to 340/360 125-1039
0.25 -60 to 320/340 125-103K 125-103KE 125-103KLTM
0.50 -60 to 300/320 125-1037
1.00 -60 to 300/320 125-103J 125-103JLTM
1.50 -60 to 300/320 125-1032 125-1032LTM
2.65 -60 to 260/280 125-103B
3.00 -60 to 260/280 125-1034 125-1034E 125-1034LTM
5.00 -60 to 260/280 125-1035 125-1035E 125-1035LTM
50 5.00 -60 to 260/280 125-1055
60 1.00 -60 to 300/320 125-106J 125-106JE
1.50 -60 to 300/320 125-1062 125-1062E
3.00 -60 to 260/280 125-1064
5.00 -60 to 260/280 125-1065 125-1065E
105 5.00 -60 to 260/280 125-10B5
WWW.AGIlent.Com/Chem/GC 321
AGIlent J&W GC ColUmns
hP-1
CH3
O Si • 100% Dimethylpolysiloxane
• Non-polar
CH3 100%
• Excellent general purpose column – "Industry Standard"
• Wide range of applications
Structure of HP-1 • Superior performance for low molecular weight alcohols (<C5)
• High temperature limit
• Bonded and cross-linked
• Solvent rinsable
• Wide range of column dimensions available
• Equivalent to USP Phase G2
similar Phases: SPB-1, Rtx-1, BP-1, OV-1, OV-101, 007-1(MS), SP-2100, SE-30, ZB-1, AT-1, MDN-1,
ZB-1
hP-1
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 -60 to 325/350 19091Z-577 19091Z-577E
0.20 12 0.33 -60 to 325/350 19091-60312
17 0.11 -60 to 325/350 19091Z-008
25 0.11 -60 to 325/350 19091Z-002 19091Z-002LTM
0.33 -60 to 325/350 19091Z-102 19091Z-102E
0.50 -60 to 325/350 19091Z-202 19091Z-202LTM
50 0.11 -60 to 325/350 19091Z-005
0.33 -60 to 325/350 19091Z-105
0.50 -60 to 325/350 19091Z-205
0.25 15 0.10 -60 to 325/350 19091Z-331
0.25 -60 to 325/350 19091Z-431
1.00 -60 to 325/350 19091Z-231
30 0.10 -60 to 325/350 19091Z-333
0.25 -60 to 325/350 19091Z-433 19091Z-433E
1.00 -60 to 325/350 19091Z-233 19091Z-233E
60 0.25 -60 to 325/350 19091Z-436
1.00 -60 to 325/350 19091Z-236 19091Z-236E
100 0.50 -60 to 325/350 19091Z-530 19091Z-530E
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
322
AGIlent J&W GC ColUmns
hP-1
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.32 15 0.25 -60 to 325/350 19091Z-411
1.00 -60 to 325/350 19091Z-211
25 0.17 -60 to 325/350 19091Z-012 19091Z-012LTM
0.52 -60 to 325/350 19091Z-112 19091Z-112E
1.05 -60 to 325/350 19091Z-212
30 0.10 -60 to 325/350 19091Z-313 19091Z-313LTM
0.25 -60 to 325/350 19091Z-413 19091Z-413E
1.00 -60 to 325/350 19091Z-213 19091Z-213E
3.00 -60 to 260/280 19091Z-513 19091Z-513E
4.00 -60 to 260/280 19091Z-613 19091Z-613LTM
5.00 -60 to 260/280 19091Z-713 19091Z-713E 19091Z-713LTM
50 0.17 -60 to 325/350 19091Z-015
0.52 -60 to 325/350 19091Z-115 19091Z-115E
1.05 -60 to 325/350 19091Z-215
60 0.25 -60 to 325/350 19091Z-416
1.00 -60 to 325/350 19091Z-216 19091Z-216E
5.00 -60 to 260/280 19091Z-716
0.53 5 0.15 -60 to 320/400 19095Z-220
0.88 -60 to 320/400 19095Z-020
2.65 -60 to 260/280 19095S-100 19095S-100E
7.5 5.00 -60 to 260/280 19095Z-627
10 0.88 -60 to 300/320 19095Z-021 19095Z-021E 19095Z-021LTM
2.65 -60 to 260/280 19095Z-121 19095Z-121E 19095Z-121LTM
15 0.15 -60 to 320/400 19095Z-221 19095Z-221E
1.50 -60 to 300/320 19095Z-321
3.00 -60 to 260/280 19095Z-421
5.00 -60 to 260/280 19095Z-621
30 0.88 -60 to 300/320 19095Z-023 19095Z-023E 19095Z-023LTM
1.50 -60 to 300/320 19095Z-323 19095Z-323E
2.65 -60 to 260/280 19095Z-123 19095Z-123E 19095Z-123LTM
3.00 -60 to 260/280 19095Z-423 19095Z-423E
5.00 -60 to 260/280 19095Z-623 19095Z-623E 19095Z-623LTM
60 5.00 -60 to 260/280 19095Z-626
WWW.AGIlent.Com/Chem/GC 323
AGIlent J&W GC ColUmns
CP-sil 5 CB
CH3
O Si • 100% Dimethylpolysiloxane
• Non-polar
CH3 100%
• General purpose phase
• Bonded and cross-linked
Structure of CP-Sil 5 CB • Solvent rinsable
• Available in fused silica or UltiMetal
• Separation almost entirely based on boiling points, making this column suitable
for a wide range of applications with a broad temperature range
• High temperature limit
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: SPB-1, Rtx-1, BP-1, OV-1, OV-101, 007-1(MS), SP-2100, SE-30, ZB-1, AT-1, MDN-1,
ZB-1
CP-sil 5 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.10 10 0.10 -60 to 330/350 CP7311
0.12 -60 to 330/350 CP7310
0.15 10 0.12 -60 to 330/350 CP7684
2.00 -60 to 325/350 CP7682
25 0.12 -60 to 330/350 CP7694
1.20 -60 to 325/350 CP7693
2.00 -60 to 325/350 CP7692
0.20 25 0.33 -60 to 325/350 CP7622
0.25 10 0.12 -60 to 330/350 CP7700
15 0.25 -60 to 330/350 CP8510
25 0.12 -60 to 330/350 CP7710
0.25 -60 to 330/350 CP7441
0.40 -60 to 325/350 CP7709
1.20 -60 to 325/350 CP7670 CP7670I5
30 0.10 -60 to 330/350 CP8710
0.25 -60 to 330/350 CP8741 CP8741I5
1.00 -60 to 325/350 CP8770
50 0.12 -60 to 330/350 CP7720
0.25 -60 to 330/350 CP7443 CP7443I5
0.40 -60 to 325/350 CP7719
60 0.25 -60 to 330/350 CP8743
1.00 -60 to 325/350 CP8780
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
324
AGIlent J&W GC ColUmns
CP-sil 5 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.32 10 0.12 -60 to 330/350 CP7730
1.20 -60 to 325/350 CP7758
15 0.10 -60 to 330/350 CP8529
0.25 -60 to 325/350 CP8530
3.00 -60 to 325/350 CP8550
1.00 -60 to 325/350 CP8540
5.00 -60 to 300/325 CP8560
25 0.12 -60 to 330/350 CP7740
0.25 -60 to 325/350 CP7442
0.40 -60 to 325/350 CP7739
0.52 -60 to 325/350 CP8430
1.20 -60 to 325/350 CP7760
5.00 -60 to 300/325 CP7680 CP7680I5
30 0.25 -60 to 325/350 CP8742
1.00 -60 to 325/350 CP8760
3.00 -60 to 310/335 CP8687 CP8687I5
5.00 -60 to 300/325 CP8688 CP8688I5
50 0.12 -60 to 330/335 CP7750 CP7750I5
0.25 -60 to 325/350 CP7444
0.40 -60 to 325/350 CP7749 CP7749I5
1.20 -60 to 325/350 CP7770 CP7770I5
5.00 -60 to 300/325 CP7690 CP7690I5
60 0.25 -60 to 325/350 CP8744
1.00 -60 to 325/350 CP8870
3.00 -60 to 310/335 CP8689
5.00 -60 to 300/325 CP8690 CP8690I5
(Continued)
WWW.AGIlent.Com/Chem/GC 325
AGIlent J&W GC ColUmns
CP-sil 5 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.53 10 1.00 -60 to 315/340 CP7625
2.00 -60 to 305/330 CP7620
5.00 -60 to 290/325 CP7645
15 0.15 -60 to 330/350 CP8673
1.50 -60 to 305/330 CP8674
3.00 -60 to 300/325 CP8675
5.00 -60 to 290/325 CP8676
20 5.00 -60 to 290/325 CP8774
25 1.00 -60 to 315/340 CP7635
2.00 -60 to 305/330 CP7630
5.00 -60 to 290/325 CP7675
30 1.50 -60 to 305/330 CP8735 CP8735I5
2.00 -60 to 305/330 CP8730
3.00 -60 to 300/325 CP8677
5.00 -60 to 290/325 CP8775
50 1.00 -60 to 315/340 CP7695
2.00 -60 to 305/330 CP7640
5.00 -60 to 290/325 CP7685 CP7685I5
60 1.50 -60 to 305/330 CP8799
5.00 -60 to 290/325 CP8685
100 0.50 -60 to 325/350 CP7608
5.00 -60 to 290/325 CP7688
CP-sil 5 CB Ultimetal
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.53 10 2.00 -60 to 325/350 CP7150
5.00 -60 to 325/350 CP6666
25 0.50 -60 to 325/350 CP7135
2.00 -60 to 325/350 CP7160
5.00 -60 to 325/350 CP6670
50 1.00 -60 to 325/350 CP7140
2.00 -60 to 325/350 CP7170
5.00 -60 to 325/350 CP6671
326
AGIlent J&W GC ColUmns
Ultra 1
CH3
• 100% Dimethylpolysiloxane O Si
• Non-polar
CH3 100%
• Equivalent to HP-1 with tighter specifications for retention index and capacity factors
• Bonded and cross-linked
• Solvent rinsable Structure of Ultra 1
Ultra 1
length
ID (mm) (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.20 12 0.33 -60 to 325/350 19091A-101
17 0.11 -60 to 325/350 19091A-008
0.33 -60 to 325/350 19091A-108
25 0.11 -60 to 325/350 19091A-002
0.33 -60 to 325/350 19091A-102 19091A-102E
50 0.11 -60 to 325/350 19091A-005
0.33 -60 to 325/350 19091A-105
0.32 25 0.17 -60 to 325/350 19091A-012
0.52 -60 to 325/350 19091A-112
50 0.17 -60 to 325/350 19091A-015
0.52 -60 to 325/350 19091A-115
WWW.AGIlent.Com/Chem/GC 327
AGIlent J&W GC ColUmns
C6H5
Ultra 2
CH3
O Si O Si • (5%-Phenyl)-methylpolysiloxane
• Non-polar
CH3 86% C6H5 14% • Equivalent to HP-5 with tighter specifications for retention index and capacity factors
• Bonded and cross-linked
Structure of Ultra 2 • Solvent rinsable
similar Phases: SPB-5, Rtx-5, BP-5, CB-5, 007-5, 2B-5
Ultra 2
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.20 12 0.33 -60 to 325/350 19091B-101 19091B-101LTM
25 0.11 -60 to 325/350 19091B-002
0.33 -60 to 325/350 19091B-102 19091B-102E 19091B-102LTM
50 0.11 -60 to 325/350 19091B-005
0.33 -60 to 325/350 19091B-105 19091B-105E
0.32 25 0.17 -60 to 325/350 19091B-012 19091B-012E
0.52 -60 to 325/350 19091B-112 19091B-112LTM
50 0.17 -60 to 325/350 19091B-015
0.52 -60 to 325/350 19091B-115 19091B-115E
328
AGIlent J&W GC ColUmns
DB-5 C6H5
CH3
• (5%-Phenyl)-methylpolysiloxane O Si O Si
• Non-polar
• Excellent general purpose column CH3 86% C6H5 14%
DB-5
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.10 10 0.10 -60 to 325/350 127-5012 127-5012E 127-5012LTM
0.17 -60 to 325/350 127-501E 127-501ELTM
0.33 -60 to 325/350 127-501N
0.40 -60 to 325/350 127-5013 127-5013LTM
20 0.10 -60 to 325/350 127-5022
0.40 -60 to 325/350 127-5023
0.15 10 1.20 -60 to 300/320 12A-5015 12A-5015LTM
0.18 10 0.18 -60 to 325/350 121-5012 121-5012E 121-5012LTM
0.40 -60 to 325/350 121-5013 121-5013LTM
20 0.18 -60 to 325/350 121-5022 121-5022E 121-5022LTM
0.40 -60 to 325/350 121-5023 121-5023LTM
40 0.18 -60 to 325/350 121-5042
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
WWW.AGIlent.Com/Chem/GC 329
AGIlent J&W GC ColUmns
DB-5
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.20 12 0.33 -60 to 325/350 128-5012
15 0.20 -60 to 325/350 128-50H7
25 0.33 -60 to 325/350 128-5022 128-5022LTM
50 0.33 -60 to 325/350 128-5052
0.25 15 0.10 -60 to 325/350 122-5011
0.25 -60 to 325/350 122-5012 122-5012LTM
0.50 -60 to 325/350 122-501E
1.00 -60 to 325/350 122-5013
25 0.25 -60 to 325/350 122-5022
30 0.10 -60 to 325/350 122-5031
0.25 -60 to 325/350 122-5032 122-5032E 122-5032LTM
0.50 -60 to 325/350 122-503E 122-503ELTM
1.00 -60 to 325/350 122-5033 122-5033E 122-5033LTM
50 0.25 -60 to 325/350 122-5052
60 0.10 -60 to 325/350 122-5061
0.25 -60 to 325/350 122-5062
0.50 -60 to 325/350 122-506E
1.00 -60 to 325/350 122-5063
0.32 10 0.50 -60 to 325/350 123-500E 123-500ELTM
15 0.10 -60 to 325/350 123-5011 123-5011LTM
0.25 -60 to 325/350 123-5012 123-5012E 123-5012LTM
1.00 -60 to 325/350 123-5013 123-5013E 123-5013LTM
25 0.17 -60 to 325/350 123-502D
0.25 -60 to 325/350 123-5022 123-5022LTM
0.52 -60 to 325/350 123-5026
1.05 -60 to 325/350 123-502F
30 0.10 -60 to 325/350 123-5031
0.25 -60 to 325/350 123-5032 123-5032E 123-5032LTM
0.50 -60 to 325/350 123-503E 123-503ELTM
1.00 -60 to 325/350 123-5033 123-5033E
1.50 -60 to 325/350 123-503B 123-503BLTM
50 0.25 -60 to 325/350 123-5052
0.52 -60 to 325/350 123-5056
1.00 -60 to 325/350 123-5053
60 0.25 -60 to 325/350 123-5062
1.00 -60 to 325/350 123-5063
(Continued)
330
AGIlent J&W GC ColUmns
DB-5
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.45 30 0.42 -60 to 300/320 124-5037
1.27 -60 to 300/320 124-5032
0.53 10 2.65 -60 to 260/280 125-50HB
15 0.25 -60 to 300/320 125-501K
0.50 -60 to 300/320 125-5017
1.00 -60 to 300/320 125-501J
1.50 -60 to 300/320 125-5012 125-5012E 125-5012LTM
25 5.00 -60 to 260/280 125-5025
30 0.25 -60 to 300/320 125-503K
0.50 -60 to 300/320 125-5037
0.88 -60 to 300/320 125-503D
1.00 -60 to 300/320 125-503J
1.50 -60 to 300/320 125-5032 125-5032E 125-5032LTM
2.65 -60 to 260/280 125-503B
3.00 -60 to 260/280 125-5034
5.00 -60 to 260/280 125-5035 125-5035E 125-5035LTM
60 1.50 -60 to 300/320 125-5062
5.00 -60 to 260/280 125-5065 125-5065E
WWW.AGIlent.Com/Chem/GC 331
AGIlent J&W GC ColUmns
hP-5
CH3 C6H5
O Si O Si • (5%-Phenyl)-methylpolysiloxane
• Non-polar
CH3 C6H5
95% 5%
• Excellent general purpose column
• Wide range of applications
Structure of HP-5 • High temperature limit
• Bonded and cross-linked
• Solvent rinsable
• Wide range of column dimensions available
• Equivalent to USP Phase G27
similar Phases: SPB-5, Rtx-5, BP-5, OV-5, 007-2(MPS-5), SE-52, SE-54, XTI-5, PTE-5, ZB-5, AT-5,
MDN-5, ZB-5
hP-5
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.18 -60 to 325/350 19091J-577 19091J-577E 19091J-577LTM
0.20 12 0.33 -60 to 325/350 19091J-101
17 0.33 -60 to 325/350 19091J-108
25 0.11 -60 to 325/350 19091J-002
0.33 -60 to 325/350 19091J-102 19091J-102E
0.50 -60 to 325/350 19091J-202
50 0.11 -60 to 325/350 19091J-005
0.33 -60 to 325/350 19091J-105 19091J-105E
0.50 -60 to 325/350 19091J-205
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
332
AGIlent J&W GC ColUmns
hP-5
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.25 5 0.10 -60 to 325/350 19091J-330 19091J-330LTM
15 0.25 -60 to 325/350 19091J-431 19091J-431E
1.00 -60 to 325/350 19091J-231
30 0.10 -60 to 325/350 19091J-333
0.25 -60 to 325/350 19091J-433 19091J-433E 19091J-433LTM
1.00 -60 to 325/350 19091J-233 19091J-233LTM
60 0.25 -60 to 325/350 19091J-436 19091J-436E
1.00 -60 to 325/350 19091J-236
0.32 15 0.25 -60 to 325/350 19091J-411 19091J-411LTM
25 0.17 -60 to 325/350 19091J-012
0.52 -60 to 325/350 19091J-112 19091J-112E
1.05 -60 to 325/350 19091J-212
30 0.10 -60 to 325/350 19091J-313
0.25 -60 to 325/350 19091J-413 19091J-413E 19091J-413LTM
0.50 -60 to 325/350 19091J-113 19091J-113E 19091J-113LTM
1.00 -60 to 325/350 19091J-213 19091J-213E
50 0.17 -60 to 325/350 19091J-015
0.52 -60 to 325/350 19091J-115 19091J-115E tIPs & tools
1.05 -60 to 325/350 19091J-215 19091J-215E Learn more about Agilent’s
60 0.25 -60 to 325/350 19091J-416 top-ranked service and support at
1.00 -60 to 325/350 19091J-216 19091J-216E www.agilent.com/chem/services
0.53 10 2.65 -60 to 260/280 19095J-121 19095J-121E 19095J-121LTM
15 1.50 -60 to 300/320 19095J-321
5.00 -60 to 260/280 19095J-621
30 0.88 -60 to 300/320 19095J-023 19095J-023E
1.50 -60 to 300/320 19095J-323 19095J-323E
2.65 -60 to 260/280 19095J-123 19095J-123E
5.00 -60 to 260/280 19095J-623 19095J-623E
WWW.AGIlent.Com/Chem/GC 333
AGIlent J&W GC ColUmns
C6H5
CP-sil 8 CB
CH3
O Si O Si • (5%-Phenyl)-methylpolysiloxane
• Non-polar
CH3 86% C6H5 14% • General purpose phase
• Bonded and cross-linked
Structure of CP-Sil 8 CB • Solvent rinsable
• Low bleed
• High column-to-column reproducibility
• Wide choice of dimensions available
• Available in fused silica and UltiMetal
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: SPB-5, Rtx-5, BP-5, OV-5, 007-2(MPS-5), SE-52, SE-54, XTI-5, PTE-5, ZB-5, AT-5,
MDN-5, ZB-5
CP-sil 8 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 10 0.12 -60 to 330/350 CP7884
0.25 15 0.25 -60 to 330/350 CP8511
1.00 -60 to 325/350 CP8521
25 0.12 -60 to 330/350 CP7711
0.25 -60 to 330/350 CP7451
1.20 -60 to 325/350 CP7671
30 0.25 -60 to 330/350 CP8751
1.00 -60 to 325/350 CP8771
50 0.12 -60 to 330/350 CP7721
0.25 -60 to 330/350 CP7453 CP7453I5
0.40 -60 to 325/350 CP7769
60 0.10 -60 to 325/350 CP8750
0.25 -60 to 330/350 CP8753
1.00 -60 to 325/350 CP8781
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
(Continued)
334
AGIlent J&W GC ColUmns
CP-sil 8 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.32 10 0.12 -60 to 330/350 CP7731
5.00 -60 to 300/325 CP8014
15 0.25 -60 to 325/350 CP8531
1.00 -60 to 325/350 CP8541
25 0.12 -60 to 330/350 CP7741 CP7741I5
0.25 -60 to 325/350 CP7452
0.40 -60 to 325/350 CP7779
0.52 -60 to 325/350 CP8431 Column shown with EZ-GRIP
1.20 -60 to 325/350 CP7761
5.00 -60 to 300/325 CP7681
30 0.10 -60 to 330/350 CP8791
0.25 -60 to 325/350 CP8752
1.00 -60 to 325/350 CP8761
50 0.12 -60 to 330/350 CP7751 CP7751I5
0.25 -60 to 325/350 CP7454
0.40 -60 to 325/350 CP7789
1.20 -60 to 325/350 CP7771
5.00 -60 to 300/325 CP7691 CP7691I5
60 0.25 -60 to 325/350 CP8754
1.00 -60 to 325/350 CP8871
0.53 10 2.00 -60 to 305/330 CP7621
5.00 -60 to 290/325 CP7646
15 1.50 -60 to 305/330 CP8678
25 2.00 -60 to 305/330 CP7631
1.00 -60 to 315/340 CP7636
5.00 -60 to 290/325 CP7656
30 0.50 -60 to 325/350 CP8716
1.50 -60 to 305/330 CP8736 CP8736I5
5.00 -60 to 290/325 CP8756
50 1.00 -60 to 315/340 CP7696
2.00 -60 to 305/330 CP7641
5.00 -60 to 290/325 CP7666
60 1.50 -60 to 305/330 CP8796
100 5.00 -60 to 290/325 CP7676
CP-sil 8 CB Ultimetal
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.53 25 5.00 -60 to 325/350 CP6680
50 0.50 -60 to 325/350 CP7196
WWW.AGIlent.Com/Chem/GC 335
AGIlent J&W GC ColUmns
C6H5
CP-sil 13 CB
CH3
CP-sil 13 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 25 0.40 -25 to 300/330 CP7813
0.25 25 0.20 -25 to 300/330 CP7906
1.20 -25 to 300/330 CP7977
50 0.20 -25 to 300/330 CP7907
0.40 -25 to 300/330 CP7917
0.32 25 0.20 -25 to 300/330 CP7926 CP7926I5
0.40 -25 to 300/330 CP7936
1.20 -25 to 300/330 CP7946
50 0.40 -25 to 300/330 CP7937
1.20 -25 to 300/330 CP7947
0.53 25 1.00 -25 to 300/330 CP7619
2.00 -25 to 300/330 CP7649
50 1.00 -25 to 300/330 CP7629
2.00 -25 to 300/330 CP7659
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
336
AGIlent J&W GC ColUmns
DB-35
CH3 C6H5
• (35%-Phenyl)-methylpolysiloxane O Si O Si
• Mid polarity – slightly more polar than HP-35
CH3 C6H5
• Low bleed 65% 35%
DB-35
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.25 30 0.25 40 to 300/320 122-1932
60 0.25 40 to 300/320 122-1962
0.32 30 0.25 40 to 300/320 123-1932
0.50 40 to 300/320 123-1933 123-1933E 123-1933LTM
0.53 15 1.00 40 to 280/300 125-1912
30 0.50 40 to 280/300 125-1937
1.00 40 to 280/300 125-1932 125-1932LTM
WWW.AGIlent.Com/Chem/GC 337
AGIlent J&W GC ColUmns
hP-35
CH3 C6H5
O Si O Si • (35%-Phenyl)-methylpolysiloxane
• Mid polarity – slightly less polar than DB-35
CH3 C6H5
65% 35%
• Inert to active solutes
• Ideal for confirmational analyses
Structure of HP-35 • Bonded and cross-linked
• Solvent rinsable
• Equivalent to USP Phase G42
similar Phases: Rtx-35ms, Rxi-35Sil MS, SPB-35, AT-35, Sup-Herb, MDN-35, BPX-34, ZB-35, ZB-35 ht
hP-35
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.25 15 0.25 40 to 300/320 19091G-131 19091G-131E 19091G-131LTM
30 0.25 40 to 300/320 19091G-133
0.32 30 0.25 40 to 300/320 19091G-113
0.50 40 to 300/320 19091G-213
338
AGIlent J&W GC ColUmns
DB-17
CH3 C6H5
• (50%-Phenyl)-methylpolysiloxane O Si O Si
• Mid polarity – slightly more polar than HP-50+
CH3 C6H5
• Excellent for confirmational analyses 50% 50%
DB-17
length 7890/6890
ID (mm) (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.10 10 0.10 40 to 280/300 127-1712 127-1712LTM
0.20 40 to 280/300 127-1713
20 0.10 40 to 280/300 127-1722
0.18 20 0.18 40 to 280/300 121-1722 121-1722LTM
0.30 40 to 280/300 121-1723
0.25 15 0.25 40 to 280/300 122-1712
0.50 40 to 280/300 122-1713 122-1713E
30 0.15 40 to 280/300 122-1731 122-1731E
0.25 40 to 280/300 122-1732 122-1732E 122-1732LTM
0.50 40 to 280/300 122-1733
60 0.25 40 to 280/300 122-1762
0.32 15 0.15 40 to 280/300 123-1711
0.25 40 to 280/300 123-1712
0.50 40 to 280/300 123-1713
30 0.15 40 to 280/300 123-1731
0.25 40 to 280/300 123-1732 123-1732E 123-1732LTM
0.50 40 to 280/300 123-1733 123-1733E
60 0.25 40 to 280/300 123-1762
0.53 5 2.00 40 to 280/300 125-1704
15 0.25 40 to 260/280 125-1711
0.50 40 to 260/280 125-1717
1.00 40 to 260/280 125-1712 125-1712LTM
1.50 40 to 260/280 125-1713 125-1713LTM
30 0.25 40 to 260/280 125-1731
0.50 40 to 260/280 125-1737
1.00 40 to 260/280 125-1732 125-1732E 125-1732LTM
1.50 40 to 260/280 125-1733
60 1.00 40 to 260/280 125-1762
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 339
AGIlent J&W GC ColUmns
hP-50+
CH3 C6H5
O Si O Si • (50%-Phenyl)-methylpolysiloxane
• Mid polarity – slightly less polar than DB-17
CH3 50% C6H5 50% • Excellent for confirmational analyses
• Bonded and cross-linked
Structure of HP-50+ • Solvent rinsable
• Equivalent to USP Phase G3
similar Phases: Rtx-50, 007-17(MPS-50), SP-2250, SPB-50, ZB-50, AT-50
hP-50+
length 7890/6890
ID (mm) (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.20 12 0.31 40 to 280/300 19091L-101
0.25 5 0.15 40 to 280/300 19091L-330 19091L-330LTM
15 0.25 40 to 280/300 19091L-431 19091L-431LTM
30 0.15 40 to 280/300 19091L-333
0.25 40 to 280/300 19091L-433 19091L-433LTM
0.50 40 to 280/300 19091L-133
0.32 30 0.25 40 to 280/300 19091L-413 19091L-413E
0.50 40 to 280/300 19091L-113 19091L-113E
60 0.25 40 to 280/300 19091L-416
0.53 15 1.00 40 to 260/280 19095L-021 19095L-021LTM
30 0.50 40 to 260/280 19095L-523
1.00 40 to 260/280 19095L-023 19095L-023E
340
AGIlent J&W GC ColUmns
CP-sil 24 CB
CH3 C6H5
CP-sil 24 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 15 0.25 40 to 280/300 CP7820
30 0.25 40 to 280/300 CP7821
0.50 40 to 280/300 CP7824
60 0.25 40 to 280/300 CP7822 CP7822I5
0.32 15 0.25 40 to 280/300 CP7830
30 0.25 40 to 280/300 CP7831
60 0.25 40 to 280/300 CP7832
0.53 30 0.50 40 to 280/300 CP7834 CP1834I5
1.00 40 to 265/290 CP7871 CP7871I5
WWW.AGIlent.Com/Chem/GC 341
AGIlent J&W GC ColUmns
CN DB-23
CH2
• (50%-Cyanopropyl)-methylpolysiloxane
CH2 • High polarity
CH2 • Designed for separation of fatty acid methyl esters (FAMEs)
• Excellent resolution for cis- and trans-isomers
O Si
• Bonded and cross-linked
CH3 n • Solvent rinsable
Structure of DB-23
• Replaces HP-23
• Close equivalent to USP Phase G5
similar Phases: SP-2330, Rtx-2330, 007-23, AT-Silar, BPX-70, SP-2340
DB-23
length 7890/6890
ID (mm) (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.18 20 0.20 40 to 250/260 121-2323
0.25 15 0.25 40 to 250/260 122-2312
30 0.15 40 to 250/260 122-2331
0.25 40 to 250/260 122-2332 122-2332E 122-2332LTM
60 0.15 40 to 250/260 122-2361 122-2361E
0.25 40 to 250/260 122-2362 122-2362E
0.32 30 0.25 40 to 250/260 123-2332 123-2332E
60 0.25 40 to 250/260 123-2362
0.53 15 0.50 40 to 230/240 125-2312
30 0.50 40 to 230/240 125-2332
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
342
AGIlent J&W GC ColUmns
DB-200
CF 3
• (35% Trifluoropropyl)-methylpolysiloxane CH 2
• 300/320 °C temperature limit CH 2
• Mid polarity – more polar than DB-1701 or DB-17 O Si
• Ideal for difficult-to-separate positional isomers
CH 3 n
• Unique interactions with compounds containing nitro, halogen and carbonyl groups
• Low ECD bleed
• Unique selectivity Structure of DB-200
• Close equivalent to USP Phase G6
similar Phases: Rtx-200
DB-200
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm II module
0.25 30 0.25 30 to 300/320 122-2032 122-2032LTM
0.50 30 to 300/320 122-2033 122-2033LTM
0.32 30 0.25 30 to 300/320 123-2032
0.50 30 to 300/320 123-2033
0.53 30 1.00 30 to 280/300 125-2032
WWW.AGIlent.Com/Chem/GC 343
AGIlent J&W GC ColUmns
DB-210
CF 3
CH 2
• (50%-Trifluoropropyl)-methylpolysiloxane
CH 2
• High polarity
O Si
• Excellent for US EPA Methods 8140 and 609
• Bonded and cross-linked
CH 3 n
• Solvent rinsable
• Exact replacement of HP-210
Structure of DB-210
• Close equivalent to USP Phase G6
similar Phases: SP-2401
DB-210
length 7890/6890
ID (mm) (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.25 15 0.25 45 to 240/260 122-0212
30 0.25 45 to 240/260 122-0232 122-0232E
0.50 45 to 240/260 122-0233
0.32 15 0.50 45 to 240/260 123-0213
30 0.25 45 to 240/260 123-0232
0.50 45 to 240/260 123-0233
0.53 15 1.00 45 to 220/240 125-0212
30 1.00 45 to 220/240 125-0232 125-0232LTM
344
AGIlent J&W GC ColUmns
DB-225 CN 25%
CH2
• (50%-Cyanopropylphenyl)-dimethylpolysiloxane
• Mid/high polarity CH2
• Excellent for separations of cis- and trans-fatty acid methyl esters (FAMEs) CH3 CH2
• Bonded and cross-linked
O Si O Si
• Solvent rinsable
• Exact replacement of HP-225 CH3
50%
C6H5
25%
• Close equivalent to USP Phase G7 Structure of DB-225
DB-225
length 7890/6890
ID (mm) (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.10 20 0.10 40 to 220/240 127-2222
0.18 20 0.20 40 to 220/240 121-2223
0.25 15 0.25 40 to 220/240 122-2212 122-2212LTM
30 0.15 40 to 220/240 122-2231
0.25 40 to 220/240 122-2232 122-2232LTM
0.32 30 0.25 40 to 220/240 123-2232 123-2232E
0.53 15 1.00 40 to 200/220 125-2212
30 0.50 40 to 200/220 125-2237
1.00 40 to 200/220 125-2232
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 345
AGIlent J&W GC ColUmns
CN 25% CP-sil 43 CB
CH2
• 25% Cyanopropyl/25% phenyl/50% dimethylpolysiloxane phase
CH2 • Mid polarity
CH3 CH2 • Separates aromatic from aliphatic hydrocarbons with selectivity equivalent to OV-255
• Bonded and cross-linked
O Si O Si
• Solvent rinsable
CH3
50%
C6H5
25% • Supplied with an EZ-GRIP to simplify column installation, coupling and operation
Structure of CP-Sil 43 CB
similar Phases: SP-2330, Rtx-225, BP-225, OV-225, 007-225, AT-225
CP-sil 43 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 25 0.20 45 to 200/225 CP7715
50 0.20 45 to 200/225 CP7725
0.32 25 0.20 45 to 200/225 CP7745
346
AGIlent J&W GC ColUmns
DB-1301 CN
CH2
• (6%-Cyanopropyl-phenyl) methylpolysiloxane
CH2
• Equivalent to USP Phase G43
• Low/mid polarity CH3 CH2
• Bonded and cross-linked
O Si Si
• Exact replacement of HP-1301 and HP-1701
• Solvent rinsable CH3 C6H5
6%
Structure of DB-1301
similar Phases: Rtx-1301, PE-1301
DB-1301
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.25 30 0.25 -20 to 280/300 122-1332 122-1332E
1.00 -20 to 280/300 122-1333
60 0.25 -20 to 280/300 122-1362
1.00 -20 to 280/300 122-1363 122-1363E
0.32 30 0.25 -20 to 280/300 123-1332
1.00 -20 to 280/300 123-1333
60 1.00 -20 to 280/300 123-1363
0.53 15 1.00 -20 to 260/280 125-1312
30 1.00 -20 to 260/280 125-1332
1.50 -20 to 260/280 125-1333 125-1333LTM
WWW.AGIlent.Com/Chem/GC 347
AGIlent J&W GC ColUmns
CN CP-1301
CH2
• 6% Cyanopropyl-phenyl/94% dimethylpolysiloxane
CH2
• Mid polarity
CH3 CH2 • Ideal for analysis of herbicides, pesticides and many pharmaceutical products
• High column-to-column reproducibility
O Si Si
• Good inertness for better quality of data, even with thick films
CH3 C6H5 • Supplied with an EZ-GRIP to simplify column installation, coupling and operation
6%
Structure of CP-1301
• Bonded and cross-linked
• Solvent rinsable
similar Phases: Rtx-1301, PE-1301
CP-1301
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 60 1.00 -25 to 265/280 CP8605
0.32 30 0.25 -25 to 280/280 CP8607
1.00 -25 to 265/280 CP8610
0.53 30 1.00 -25 to 265/280 CP8613
348
AGIlent J&W GC ColUmns
DB-1701 CN
CH2
• (14% Cyanopropyl-phenyl)-methylpolysiloxane
CH2
• Low/mid polarity
• Bonded and cross-linked CH3 CH2
• Exact replacement of HP-1301 and HP-1701
O Si Si
• Solvent rinsable
CH3 C6H5
14%
similar Phases: SPB-1701, Rtx-1701, BP-10, OV-1701, 007-1701, ZB-1701
Structure of DB-1701
DB-1701
7890/6890
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm II module
0.10 20 0.10 -20 to 280/300 127-0722
0.40 -20 to 280/300 127-0723
0.18 10 0.40 -20 to 280/300 121-0713
20 0.18 -20 to 280/300 121-0722 121-0722LTM
0.25 15 0.25 -20 to 280/300 122-0712
1.00 -20 to 280/300 122-0713 122-0713LTM
30 0.15 -20 to 280/300 122-0731
0.25 -20 to 280/300 122-0732 122-0732E 122-0732LTM
1.00 -20 to 280/300 122-0733 122-0733E 122-0733LTM
60 0.15 -20 to 280/300 122-0761
0.25 -20 to 280/300 122-0762
0.50 -20 to 280/300 122-0766 tIPs & tools
1.00 -20 to 280/300 122-0763 122-0763E
Agilent also offers DB-624 columns for
0.32 15 0.25 -20 to 280/300 123-0712 123-0712LTM the analysis of volatile priority pollutants
1.00 -20 to 280/300 123-0713 and residual solvents.
30 0.15 -20 to 280/300 123-0731
0.25 -20 to 280/300 123-0732 123-0732E
1.00 -20 to 280/300 123-0733 123-0733E
50 1.00 -20 to 280/300 123-0753
60 0.25 -20 to 280/300 123-0762
1.00 -20 to 280/300 123-0763 123-0763E
0.53 15 1.00 -20 to 260/280 125-0712 125-0712E 125-0712LTM
30 0.25 -20 to 260/280 125-0731
0.50 -20 to 260/280 125-0737
1.00 -20 to 260/280 125-0732 125-0732E
1.50 -20 to 260/280 125-0733
60 1.00 -20 to 260/280 125-0762 125-0762E
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
WWW.AGIlent.Com/Chem/GC 349
AGIlent J&W GC ColUmns
CN CP-sil 19 CB
CH2
• 14% Cyanopropyl-phenyl/86% dimethylpolysiloxane
CH2
• Mid polarity
CH3 CH2 • Ideal for many environmental, food and beverage, and pharmaceutical applications
• Useful as confirmation column
O Si Si
• Bonded and cross-linked
CH3 C6H5 • Solvent rinsable
14%
Structure of CP-Sil 19 CB
• Broad range of configurations available
• Supplied with an EZ-GRIP to simplify column installation, coupling and operation
similar Phases: SPB-1701, Rtx-1701, BP-10, OV-1701, 007-1701, ZB-1701
CP-sil 19 CB
ID (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.15 25 0.50 -25 to 275/300 CP7340
0.25 10 0.20 -25 to 275/300 CP7702
25 0.20 -25 to 275/300 CP7712
0.40 -25 to 275/300 CP7809
1.20 -25 to 275/300 CP7672
30 0.25 -25 to 275/300 CP8712
1.00 -25 to 275/300 CP8562
50 0.20 -25 to 275/300 CP7722
60 0.25 -25 to 275/300 CP8722
0.32 10 0.20 -25 to 275/300 CP7732
15 0.25 -25 to 275/300 CP8542
25 0.20 -25 to 275/300 CP7742
0.40 -25 to 275/300 CP7829
1.20 -25 to 275/300 CP7762
30 0.25 -25 to 275/300 CP8842
1.00 -25 to 275/300 CP8762
50 0.20 -25 to 275/300 CP7752
0.40 -25 to 275/300 CP7839
1.20 -25 to 275/300 CP7772
60 0.15 -25 to 275/300 CP8662
1.00 -25 to 275/300 CP8772
0.53 10 2.00 -25 to 275/300 CP7647
25 1.00 -25 to 275/300 CP7637
2.00 -25 to 275/300 CP7657
30 1.00 -25 to 275/300 CP8737
50 2.00 -25 to 275/300 CP7667
1.00 -25 to 275/300 CP7697
Agilent J&W High Efficiency GC columns are displayed using italicized descriptions and part numbers
350
AGilEnt J&W GC Columns
-HO C C O H
AgilentoffersafullrangeofPEGcolumns.Eventhougheachphaseisbasedonthepolyethyleneglycol
polymer,strictcontrolofthecross-linkinganddeactivationprocessesresultinavarietyofuniquephase
characteristicstomeetyourvaryinganalysisneeds. H H n
Structureofpolyethyleneglycol(PEG)
Thisstructureisapplicableforall
WAXandFFAPphases.
DB-WAX and DB-WaxFF
• Polyethyleneglycol(PEG)
• EquivalenttoUSPPhaseG16
• Highpolarity
• Lowertemperaturelimitof20°CisthelowestofanybondedPEGphase;improvesresolution
oflowboilingpointanalytes
• Column-to-columnreproducibility
• Bondedandcross-linked
• ExactreplacementofHP-WAX
• Solventrinsable
• DB-WaxFFisahighlyreproducible,speciallytestedmicroboreDB-Waxforfragranceanalysis
WWW.AGilEnt.Com/ChEm/GC 351
AGilEnt J&W GC Columns
(Continued)
352
AGilEnt J&W GC Columns
WWW.AGilEnt.Com/ChEm/GC 353
AGilEnt J&W GC Columns
DB-WAXetr
• Polyethyleneglycol(PEG)
• Extendedtemperaturerange(etr)
• Highpolarity
• Excellentcolumn-to-columnrepeatability
• Bondedandcross-linked
• Solventrinsable
• EquivalenttoUSPPhaseG16
similar Phases: SUPELCOWAX10,SUPEROXII,CB-WAX,Stabilwax,BP-20,007-CW,Carbowax,
Rtx-WAX,ZB-WAX,ZB-WAXplus
DB-WAXetr
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.20 25 0.40 30to250/260 128-7323
0.25 30 0.25 30to260/280 122-7332 122-7332E 122-7332LTM
0.50 30to250/260 122-7333
60 0.25 30to260/280 122-7362
0.50 30to250/260 122-7363
0.32 15 0.25 30to260/280 123-7312
1.00 30to250/260 123-7314
30 0.25 30to260/280 123-7332
0.50 30to250/260 123-7333
1.00 30to250/260 123-7334 123-7334LTM
50 1.00 30to250/260 123-7354 123-7354E
60 0.25 30to260/280 123-7362
0.50 30to250/260 123-7363
1.00 30to250/260 123-7364
0.53 15 1.00 30to240/260 125-7312
2.00 50to230/250 125-7314
30 1.00 30to240/260 125-7332 125-7332E
1.50 30to230/240 125-7333 125-7333LTM
2.00 50to230/250 125-7334 125-7334E
60 1.00 30to240/260 125-7362
354
AGilEnt J&W GC Columns
hP-innoWax
• Polyethyleneglycol(PEG)
• Highpolarity
• HighestuppertemperaturelimitsofthebondedPEGphases
• Column-to-columnrepeatability
• Bondedandcross-linked
• Solventrinsable
• CloseequivalenttoUSPPhaseG16
similar Phases: SUPELCOWAX10,SUPEROXII,CB-WAX,Stabilwax,BP-20,007-CW,Carbowax,
ZB-WAX,ZB-WAX+
hP-innoWax
temp limits 7890/6890
iD (mm) length (m) Film (µm) (°C) 7 in Cage 5 in Cage ltm ii module
0.18 20 0.18 40 to 260/270 19091N-577 19091N-577E 19091N-577LTM
0.20 25 0.20 40to260/270 19091N-102 19091N-102LTM
0.40 40to260/270 19091N-202
50 0.20 40to260/270 19091N-105 19091N-105E
0.40 40to260/270 19091N-205 19091N-205E
0.25 5 0.15 40to260/270 19091N-030 19091N-030LTM
15 0.10 40to260/270 19091N-331
0.25 40to260/270 19091N-131 19091N-131E
0.50 40to260/270 19091N-231
30 0.15 40to260/270 19091N-033
0.25 40to260/270 19091N-133 19091N-133E 19091N-133LTM
0.50 40to260/270 19091N-233 19091N-233E
60 0.15 40to260/270 19091N-036
0.25 40to260/270 19091N-136 19091N-136E
0.50 40to260/270 19091N-236
0.32 15 0.25 40to260/270 19091N-111
30 0.15 40to260/270 19091N-013 19091N-013LTM
0.25 40to260/270 19091N-113 19091N-113E
0.50 40to260/270 19091N-213 19091N-213E
60 0.25 40to260/270 19091N-116
0.50 40to260/270 19091N-216 19091N-216E
0.53 15 1.00 40to240/250 19095N-121
30 1.00 40to240/250 19095N-123 19095N-123E 19095N-123LTM
60 1.00 40to240/250 19095N-126
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
WWW.AGilEnt.Com/ChEm/GC 355
AGilEnt J&W GC Columns
CP-Wax 52 CB
• Polyethyleneglycolphase
• Highpolarity
• Widertemperaturerangethannon-bondedpolyethyleneglycols
• Bondedandcross-linked
• Solventrinsable
• Highresolutionoflowboilingpointanalytes
ColumnshownwithEZ-GRIP • Highpolarityprovidesseparationsforabroadrangeofapplications
• ExcellentreproducibilityandtemperaturestabilityforavarietyofEPAandASTMmethods
• SuppliedwithanEZ-GRIPtosimplifycolumninstallation,couplingandoperation
note: WerecommendtheUltiMetalcolumnwhenworkinginruggedenvironmentswithprocess
orportableinstruments.
CP-Wax 52 CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.10 10 0.10 20to250/265 CP7334
0.20 20to250/265 CP7335
0.15 15 0.12 20 to 250/265 CP7791
25 0.25 20 to 250/265 CP7792
0.20 30 0.20 20to250/265 CP7775
50 0.20 20to250/265 CP7785
0.25 10 0.20 20to250/265 CP7703
15 0.25 20to250/265 CP8513
25 0.20 20to250/265 CP7713 CP7713I5
1.20 20to250/265 CP7673 CP7673I5
30 0.15 20to250/265 CP8745
0.25 20to250/265 CP8713 CP8713I5
0.50 20to250/265 CP8746
50 0.20 20to250/265 CP7723 CP7723I5
60 0.25 20to250/265 CP8723
0.50 20to250/265 CP8748
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
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356
AGilEnt J&W GC Columns
CP-Wax 52 CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.32 10 1.00 20to250/265 CP7628
15 0.15 20to250/265 CP8533
0.25 20to250/265 CP8543
0.50 20to250/265 CP8553
25 0.20 20to250/265 CP7743
0.40 20to250/265 CP7879
1.20 20to250/265 CP7763
30 0.25 20to250/265 CP8843
0.50 20to250/265 CP8763
50 0.20 20to250/265 CP7753
0.40 20to250/265 CP7889
1.20 20to250/265 CP7773 CP7773I5
60 0.25 20to250/265 CP8853
0.50 20to250/265 CP8773
1.20 20to250/265 CP8073 CP8073I5
0.53 10 2.00 20to250/265 CP7648
15 1.00 20to250/265 CP8718
25 1.00 20to250/265 CP7638
2.00 20to250/265 CP7658 CP7658I5
30 1.00 20to250/265 CP8738 CP8738I5
50 1.00 20to250/265 CP7698 CP7698I5
2.00 20to250/265 CP7668
60 1.00 20to250/265 CP8798
100 2.00 20to250/265 CP7678
CP-Wax 52 CB ultimetal
iD (mm) length (m) Film (µm) temp limits (°C) Part no.
0.53 10 0.50 20to250/275 CP7128
1.00 20to250/275 CP7148
25 2.00 20to250/275 CP7178
50 1.00 20to250/275 CP7168
2.00 20to250/275 CP7179
WWW.AGilEnt.Com/ChEm/GC 357
AGilEnt J&W GC Columns
DB-FFAP
• Nitroterephthalicacidmodifiedpolyethyleneglycol
• Highpolarity
• Temperaturerangefrom40°Cto250°C
• Designedfortheanalysisofvolatilefattyacidsandphenols
• ReplacesOV-351
• Bondedandcross-linked
• Solventrinsable
• CloseequivalenttoUSPPhaseG35
note: WedonotrecommendtheuseofwaterormethanoltorinseDB-FFAPGCcolumns.
DB-FFAP
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.10 10 0.10 40to250 127-3212 127-3212LTM
15 0.10 40to250 127-32H2 127-32H2LTM
0.25 15 0.25 40to250 122-3212
30 0.25 40to250 122-3232 122-3232E 122-3232LTM
0.50 40to250 122-3233
60 0.25 40to250 122-3262 122-3262E
0.50 40to250 122-3263
0.32 15 0.25 40to250 123-3212
25 0.50 40to250 123-3223
30 0.25 40to250 123-3232 123-3232E 123-3232LTM
0.50 40to250 123-3233 123-3233LTM
1.00 40to250 123-3234 123-3234LTM
50 0.50 40to250 123-3253
60 0.25 40to250 123-3262
0.50 40to250 123-3263
1.00 40to250 123-3264
0.45 30 0.85 40to250 124-3232
0.53 10 1.00 40to250 125-32H2
15 0.50 40to250 125-3217 125-3217LTM
1.00 40to250 125-3212
30 0.25 40to250 125-3231
0.50 40to250 125-3237
1.00 40to250 125-3232 125-3232E
1.50 40to250 125-3233
60 1.00 40to250 125-3262
358
AGilEnt J&W GC Columns
hP-FFAP
• Nitroterephthalicacidmodifiedpolyethyleneglycol
• Highpolarity
• Temperaturerangefrom60°Cto240/250°C(230/240°Cfor0.53mm)
• Designedfortheanalysisofvolatilefattyacidsandphenols
• ReplacesOV-351
• Bondedandcross-linked
• Solventrinsable
• CloseequivalenttoUSPPhaseG35
note: WedonotrecommendtheuseofwaterormethanoltorinseHP-FFAPGCcolumns.
hP-FFAP
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.20 25 0.33 60to240/250 19091F-102 19091F-102E 19091F-102LTM
50 0.33 60to240/250 19091F-105 19091F-105E
0.25 30 0.25 60to240/250 19091F-433 19091F-433E 19091F-433LTM tiPs & tools
0.32 25 0.50 60to240/250 19091F-112 19091F-112E 19091F-112LTM
AgilentalsooffersCAMcolumns
30 0.25 60to240/250 19091F-413 foramineanalysis.
50 0.50 60to240/250 19091F-115 19091F-115E
0.53 10 1.00 60to240 19095F-121 19095F-121LTM
15 1.00 60to240 19095F-120 19095F-120E
30 1.00 60to240 19095F-123 19095F-123E 19095F-123LTM
WWW.AGilEnt.Com/ChEm/GC 359
AGilEnt J&W GC Columns
CP-Wax 58 FFAP CB
• Nitroterephthalicacid-modifiedpolyethyleneglycolphase
• Highpolarity
• Idealforanalysisofacidiccompounds,suchasphenols,underivatizedandderivatizedfreefattyacids
• Highestpolaritybondedwaxcolumnforanalyzingpolarcompounds
• Chemically-bonded
• Solventrinsable
• Highinertnessprovidesexcellentpeakshape
• SuppliedwithanEZ-GRIPtosimplifycolumninstallation,couplingandoperation
similar Phases: SUPELCOWAX10,SUPEROXII,CB-WAX,Stabilwax,BP-20,007-CW,Carbowax,
Rtx-WAX,ZB-WAX
CP-Wax 58 FFAP CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.20 25 0.30 20to250/275 CP7787
50 0.30 20to250/275 CP7797
0.25 25 0.20 20to250/275 CP7717 CP7717I5
50 0.20 20to250/275 CP7727
0.32 25 0.20 20to250/275 CP7747
1.20 20to250/275 CP7767
50 0.20 20to250/275 CP7757
0.50 20to250/275 CP7778
1.20 20to250/275 CP7777
0.53 15 0.50 20to250/275 CP7665
25 1.00 20to250/275 CP7614
2.00 20to250/275 CP7654
50 1.00 20to250/275 CP7624
2.00 20to250/275 CP7664
360
AGilEnt J&W GC Columns
BecausetheCarbowax20MandtheHP-20Marenotbondedorcross-linked,wedonotrecommend
solventrinsing.DB-WAXistherecommendedbondedalternatefortheHP-20M.
Carbowax 20m
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm ii module
0.25 30 0.25 60to220/240 112-2032 112-2032LTM
0.32 30 0.25 60to220/240 113-2032
hP-20m
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.20 25 0.10 60to220 19091W-102
50 0.10 60to220 19091W-105
0.32 25 0.30 60to220 19091W-012 19091W-012E 19091W-012LTM
50 0.30 60to220 19091W-015 19091W-015E
0.53 10 1.33 60to220 19095W-121
30 1.33 60to220 19095W-123
WWW.AGilEnt.Com/ChEm/GC 361
AGilEnt J&W GC Columns
specialty Columns
Agilentchemistshavedevelopedmanycolumnswithuniquecharacteristicsdesignedtosolvethemost
difficultseparationproblemsofagivenmethod.Asaresult,weofferacomprehensivelineofspecialty
or"select"columnsforavarietyofapplicationstoenhancethestandardphaseportfolio.Withcolumns
forvolatiles,pesticides,petrochemicalsandmore–AgilentexceedsstandardQA/QCproceduresforthe
manufacturingandtestingofallofourspecialtycolumnstoensuretheymeetthestringentdemandsfor
theirapplication.Thesecolumnsofferreliable,accurateresultswiththeshortestruntimespossibleon
complexsamplelistsandmatrixes.
DB-1ht
• 100%Dimethylpolysiloxane
• Non-polar
• Speciallyprocessedforextendedtemperaturelimitof400°C
• Hightemperature,polyimide-coated,fusedsilicatubing
• Excellentpeakshapeandfasterelutiontimesforhighboilers
• Bondedandcross-linked
• Solventrinsable
similar Phases: Rxi-1HT,Stx-1ht,ZB-1ht
DB-1ht
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.25 15 0.10 -60to400 122-1111 122-1111E
30 0.10 -60to400 122-1131
0.32 15 0.10 -60to400 123-1111 123-1111LTM
30 0.10 -60to400 123-1131 123-1131E
0.53 30 0.17 -60to400 125-1131
362
AGilEnt J&W GC Columns
DB-5ht
• (5%-Phenyl)-methylpolysiloxane
• Non-polar
• Speciallyprocessedforextendedtemperaturelimitof400°C
• Hightemperature,polyimide-coated,fusedsilicatubing
• Excellentpeakshapeandfasterelutiontimesforhighboilers
• Bondedandcross-linked
• Solventrinsable
similar Phases: HT5,Stx-5ht,ZB-5ht
DB-5ht
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.25 15 0.10 -60to400 122-5711 122-5711E 122-5711LTM
30 0.10 -60to400 122-5731 122-5731LTM
0.32 10 0.10 -60to400 123-5701 123-5701LTM
15 0.10 -60to400 123-5711 123-5711E
30 0.10 -60to400 123-5731 123-5731E
WWW.AGilEnt.Com/ChEm/GC 363
AGilEnt J&W GC Columns
DB-17ht
• (50%-Phenyl)-methylpolysiloxane
• Mid-polarity
• Extendeduppertemperaturelimitof365°C
• Hightemperature,polyimide-coated,fusedsilicatubing
• Excellentpeakshapeandfasterelutiontimesforhighboilers
• Improvedresolutionfortriglycerides
• Idealforconfirmationalanalyses
• Bondedandcross-linked
• Solventrinsable
similar Phases: Rtx-65TG,BPX50
DB-17ht
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm ii module
0.25 5 0.15 40to340/365 122-1801 122-1801LTM
15 0.15 40to340/365 122-1811
30 0.15 40to340/365 122-1831 122-1831LTM
0.32 15 0.15 40to340/365 123-1811
30 0.15 40to340/365 123-1831
60 0.15 40to340/365 123-1861
364
AGilEnt J&W GC Columns
VF-5ht
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 15 0.10 -60to400/400 CP9045
30 0.10 -60to400/400 CP9046
0.32 10 0.10 -60to400/400 CP9044
15 0.10 -60to400/400 CP9047
30 0.10 -60to400/400 CP9048
VF-5ht ultimetal
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 15 0.10 -60to430/450 CP9090
0.10 -60to430/450 CP9091*
30 0.10 -60to430/450 CP9092
0.10 -60to430/450 CP9093*
0.32 15 0.10 -60to430/450 CP9094 CP9094I5
0.10 -60to430/450 CP9095*
30 0.10 -60to430/450 CP9096
0.10 -60to430/450 CP9097*
*Theseconfigurationsincludea2mx0.53mmidUltiMetalretentiongapwhicharepre-connectedtotheVF-5htUltiMetal
columnwithahightemperaturecolumnconnector.
WWW.AGilEnt.Com/ChEm/GC 365
AGilEnt J&W GC Columns
Petroleum Columns
Petroleumapplicationsvarygreatlyincharacter.Fromnoblegasestosimulateddistillation,Agilentoffers
abroadrangeofcolumnsdesignedtomeettheneedsofthepetroleum/petrochemicalchromatographer.
RefertothePLOTcolumnsectionforcolumnsfortheanalysisoflightgases.
lowox
• Uniqueselectivityforawiderangeofoxygenates
• Minimalparticlelosspreservesdetectorperformance
• IndustryprovenforprocessandportableGCapplications(ASTMD7059)
• Analyzetraceleveloxygenateimpuritiesingasandliquidhydrocarbonstreams
• Highpolarity
• Idealformonitoringcatalystcontaminationbyoxygenates
lowox
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.53 10 10.00 0to350/350 CP8587 CP8587I5
Gs-oxyPlot
• Accurateanalysisofppm/ppbleveloxygenatesinC1 toC10 hydrocarbons
• Strongselectivityforawiderangeofoxygenates(ethers,alcohols,aldehydes,andketones)incomplex
matrixessuchasgaseoushydrocarbons,motorfuels,andcrudeoil
• SuitableforASTMmethodsforoxygenates
• Veryhighcolumnstability(uppertemperaturelimitof350°C)withnocolumnbleed
• Stablephasecoatingvirtuallyeliminatesparticlegenerationanddetectorspiking
• Excellentforlowconcentration,quantitativeGCanalysis
• Idealforselectiveheart-cuttingapplications
Gs-oxyPlot
iD (mm) length (m) temp limits (°C) 7 in Cage 5 in Cage
0.53 10 350 115-4912 115-4912E
366
AGilEnt J&W GC Columns
hP-PonA
CH3
• 100%Dimethylpolysiloxane O Si
• Configuredfortheanalysisofpetroleumprocessproducts
CH3 100%
• Testedtoensuretheresolutionofm-xylenefromp-xyleneandofcyclopentanefrom
2,3-dimethylbutane
• PONA,PIANO StructureofHP-PONA
• Highresolution
• Bondedandcross-linked
• Solventrinsable
note: 100psiregulatorrequiredtoreachoptimumcarriergasvelocity
hP-PonA
Description iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
HP-PONA 0.20 50 0.50 -60to325/350 19091S-001 19091S-001E
HP-1 0.20 50 0.50 -60to325/350 19091Z-205 19091Z-205E
HP-1 0.25 100 0.50 -60to325/350 19091Z-530 19091Z-530E
WWW.AGilEnt.Com/ChEm/GC 367
AGilEnt J&W GC Columns
CP-sil PonA CB
CH3
O Si • Highresolutionanalysisofparaffins,olefins,naphthalenesandaromatics
incomplexhydrocarbonmixtures
CH3 100% • EngineeredforhydrocarbonanalysisaccordingtoASTM(DHAmethod)
• Inerttopolarcompoundsforhighlyaccuratedata
StructureofCP-SilPONACB • Excellentcolumn-to-columnreproducibility
similar Phases: PetrocolDH,SPB-1,007-1,Rtx-1,MXT-1
CP-sil PonA CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.21 50 0.50 250/275 CP7531 CP7531I5
0.25 100 0.50 250/275 CP7530
0.25 150 1.00 250/275 CP7945
368
AGilEnt J&W GC Columns
DB-Petro
CH3
• 100%Dimethylpolysiloxane O Si
• Configuredfortheanalysisofpetroleumprocessproducts
CH3 100%
• PONA,PIANO
• Highresolution
• Bondedandcross-linked StructureofDB-Petro
• Solventrinsable
note: 100psiregulatorrequiredtoreachoptimumcarriergasvelocity
DB-Petro
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.20 50 0.50 -60to325/350 128-1056
0.25 100 0.50 -60to325/350 122-10A6 122-10A6E
WWW.AGilEnt.Com/ChEm/GC 369
AGilEnt J&W GC Columns
DB-2887
• 100%Dimethylpolysiloxane
• SpecificallydesignedforsimulateddistillationusingASTMMethodD2887
• Rapidconditioning,fastruntimeandlowbleedwhencomparedtopackedcolumns
• Bondedandcross-linked
• Solventrinsable
similar Phases: PetrocolEX2887,MXT-2887,MXT-1,Rtx-2887
DB-2887
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.53 10 3.00 -60to350 125-2814 125-2814E 125-2814LTM
DB-ht simDis
• 100%Dimethylpolysiloxane
• "Boilingpoint"phaseforhightemperaturesimulateddistillation
• Durablestainlesssteeltubing
• 430°Cuppertemperaturelimit
• DistillationrangeofC6 toC110+
• Lowbleed,evenat430°C
• Bondedandcross-linked
• Solventrinsable
similar Phases: PetrocolEX2887,MXT-2887,Rtx-2887,ACControlsHighTempSimDist,AT-2887,
ZB-1XTSimDist
370
AGilEnt J&W GC Columns
CP-simDist
CH3
• ForsimulateddistillationanalysisuptoC100 O Si
• Hightemperaturenon-polarstationaryphase
CH3 100%
• Lowbleedimprovesquantitation
• Hightemperaturepolyimidecoatingextendslifetime
StructureofCP-SimDist
CP-SimDistfusedsilicacolumnsareguaranteedforsimulateddistillationuptoC100.Thesecolumnsarelow
bleed,typicallyonly4-5pAat400°C.Thehightemperaturestationaryphaseandpolyimidecoatingextend
columnlifetime.
CP-simDist
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.32 10 0.10 375/400 CP7521
0.53 5 0.17 375/400 CP7522 CP7522I5
10 0.10 375/400 CP7541
WWW.AGilEnt.Com/ChEm/GC 371
AGilEnt J&W GC Columns
CP-simDist ultimetal
• DesignedforASTMD2887andtheextendedD2887methodcompliance
• Lowbleed
• ExtendedanalysistoC120 withmaximumtemperatureof450°C
• UltiMetaltubingforexcellentdurability(sameidas0.53mmidfusedsilica)
• ExcellentretentiontimerepeatabilityandcolumnlifetimeduetospecialdeactivationofUltiMetalsurface
similar Phases: PetrocolEX2887,MXT-2887,Rtx-2887,ACControlsHighTempSimDist,AT-2887,
ZB-1XTSimDist
CP-simDist ultimetal
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.53 5 0.09 450/450 CP7569 CP7569I5
0.17 450/450 CP7532 CP7532I5
0.88 450/450 CP7570
2.65 400/400 CP7571
10 0.17 450/450 CP7542
0.06 450/450 CP6540
0.53 450/450 CP7592
0.88 450/450 CP7512 CP7512I5
1.20 450/450 CP7562
2.65 400/400 CP7582
5.00 400/400 CP7572
20 0.11 450/450 CP7593
25 0.06 450/450 CP6550
372
AGilEnt J&W GC Columns
CP-sil 2 CB
• Lowestpolaritybondedstationaryphaseavailable
• Superiorreplacementtosqualane
• Uniqueselectivitytowardcyclichydrocarbons
• Separationalmostentirelybasedonboilingpoint
• Stableattemperaturesupto200°C
CP-sil 2 CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 25 0.25 25to200/200 CP7714
0.32 50 0.25 25to200/200 CP7754
25 1.20 25to200/200 CP7764
CP-tCEP
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 50 0.40 135/140 CP7525 CP7525I5
WWW.AGilEnt.Com/ChEm/GC 373
AGilEnt J&W GC Columns
DB-sulfur sCD
• Engineeredforsulfurchemiluminescencedetection(SCD)toprovidelowbleedperformance
andreducedSCDceramictubefouling
• ExtendsSCDsignalstabilitywhichgreatlyreducesinstrumentdowntimeandoperationalcost
fordetectormaintenance
• ExcellentpeakshapeforawiderangeofreactivesulfurcompoundsfromH2S,COS,
mercaptansandthiophenes
• 100%Dimethylpolysiloxanestationaryphase(PDMS)asspecifiedinASTMmethods
suchasD5623andD5504
• Customconfigurationsareavailablethroughthecustomcolumnshop,
www.agilent.com/chem/CustomColumn
DB-sulfur sCD
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.32 40 0.75 -60to270/290 G3903-63002
40 3.00 -60to25/270 G3903-63004
60 4.20 -60to25/270 G3903-63001
0.53 70 4.30 -60to25/270 G3903-63003
374
AGilEnt J&W GC Columns
WWW.AGilEnt.Com/ChEm/GC 375
AGilEnt J&W GC Columns
376
AGilEnt J&W GC Columns
WWW.AGilEnt.Com/ChEm/GC 377
AGilEnt J&W GC Columns
378
AGilEnt J&W GC Columns
select Biodiesel
• Completesetofbiodieselcolumnsforfullcomplianceandease-of-use
• UltiMetalstainlesssteeltechnologyprovideshighaccuracyandlongevity
• Pre-testedforcompleteconfidenceinresults
• Goodcolumnlifetimewhenoperatingattemperaturesupto400°C
• UltiMetalstainlesssteelcolumnwithultrastablestationaryphase
• Convenientpre-coupledretentiongapthatisleaktested
technical specifications
method Analytes Column injector type Analysis time (min)
ASTMD6584 Freeandtotalglycerine SelectBiodieselforGlycerides On-column 32
EN14103 Esterandlinoleicacidmethylesters SelectBiodieselforFAME Split/splitless 30
EN14105 Freeandtotalglycerine;mono,di-andtri-glycerides SelectBiodieselforGlycerides On-column 35
EN14106 Freeglycerol SelectBiodieselforGlycerides Split/splitless 10
EN14110 Methanol SelectBiodieselforMethanol Headspacewith 10
split/splitless
select Biodiesel
Description iD (mm) length (m) Film (µm) 7 in Cage
Forglycerides,UltiMetal,with2mretentiongap 0.32 15 0.10 CP9078
Forglycerides,UltiMetal 0.32 15 0.10 CP9079
Forglycerides,UltiMetal,with2mretentiongap 0.32 10 0.10 CP9076
Forglycerides,UltiMetal 0.32 10 0.10 CP9077
ForFAME,fusedsilica 0.32 30 0.25 CP9080
ForMethanol,fusedsilica 0.32 30 3.00 CP9083
UltiMetalretentiongap,methyldeactivated 0.53 2 CP6530
WWW.AGilEnt.Com/ChEm/GC 379
AGilEnt J&W GC Columns
select silanes
• Stabilizedtrifluoropropyl-methylpolysiloxanephaseforoptimizedppmlevelanalysisofsilanes
• Highcapacityandretention
• Lowbleed
• Reducedsurfaceactivityprovidesexcellentpeakshape
• Thickfilmoffershighsampleloadingcapacityandretention
• Typicalapplicationsincludealkylatedchlorosilanesat%levelsaswellasimpurityanalysis
• Valved,directandsplit/splitlessinjectionsarepossible
select silanes
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.32 30 1.80 0to270/300 CP7434
60 1.80 0to270/300 CP7435
0.53 60 3.00 0to270/300 CP7437
380
AGilEnt J&W GC Columns
CP-Volamine
• Non-polarstationaryphase
• Excellentstabilityforsamplescontainingwaterexpandstheapplicationrange
• Maximumtemperatureof265°Cforenhancedproductivity
• Highlyinertprovidingsharpaminepeaksforaccurateresults
• ProducessymmetricalpeaksduetoMPD(Multi-PurposeDeactivation)technology
• Excellentperformanceevenwhenthesamplecontainshighpercentagesofwater
• IdealforanalyzingvolatileamineslikeMMA,DMAandTMA(monomethyl,dimethyl
andtrimethylamine)
CP-Volamine
iD (mm) length (m) temp limits (°C) 7 in Cage 5 in Cage
0.32 15 265/300 CP7446
30 265/300 CP7447 CP7447I5
60 265/275 CP7448 CP7448I5
WWW.AGilEnt.Com/ChEm/GC 381
AGilEnt J&W GC Columns
382
AGilEnt J&W GC Columns
PoraPlot Amines
• UniquePLOTcolumnsspeciallydesignedforhighretentionofveryvolatileamines
• Highefficiencyattemperaturesaboveambienteliminatestheneedforcryogenics
• Highsensitivityforaminesandammonia
PoraPlot Amines
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.32 25 10.00 -100to220/220 CP7591
0.53 25 20.00 -100to220/220 CP7594
WWW.AGilEnt.Com/ChEm/GC 383
AGilEnt J&W GC Columns
Pesticides Columns
AgilentJ&Wlow-bleedcolumnsareidealfortheanalysisofpesticides.Notonlydotheyproducelessbleed
thanastandardpolymer,whichimprovesthesignal-to-noiseratioandminimumdetectablequantities,but
theyalsohavehigheruppertemperaturelimitswhichallowforfasterruntimes.Agilentalsooffersseveral
commonphaseswithadditionalpesticide-specifictestingtoensureperformanceforyourapplication.
note: ForCLPpesticidesandothermethodsusingelectroncapturedetectors,seeDB-35ms,DB-17ms
andDB-XLB.
384
AGilEnt J&W GC Columns
VF-5 Pesticides
• Speciallydesignedforthedeterminationoftracelevelsofpesticideresidue
• HighlyinertforenhancedECDandMSdetection
• Testedwithkeypesticidesincludingendrinandaldrinforoptimalperformance
andconsistencyofresults
• Lowbleed
VF-5 Pesticides
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 30 0.25 -60to325/350 CP9074
50 0.25 -60to325/350 CP9073
0.32 30 0.25 -60to325/350 CP9075
• It’simportanttouseferrulesandnutsappropriateforyourapplication,sographite/polyimide
ferrulesandAgilentSelfTighteningcolumnnutsforoxygendetectors,orUltiMetalPlusFlexible
Metalferrulesforultimateflowpathinertness
• Neverovertightenfittingstoavoidsoftferrulesextrudingintothefitting,contaminatingor
creatingactivesitesintheflowpath
• Installcolumnatthecorrectandconsistentheight,criticalforaccurateandreproducibleresults
• ReduceandeliminateleaksattheMSinterfacewiththeAgilentSelfTighteningcolumnnuts
thatgiveyouatightconnectionwithoutexpensiveupgradesoradaptors
WatchtheanimationthatshowshowtomakebettercolumnconnectionsinaGCorGC/MS,at
www.agilent.com/chem/mbcvideo
WWW.AGilEnt.Com/ChEm/GC 385
AGilEnt J&W GC Columns
DB-1701P
• Low/mid-polarity
• ExactreplacementofHP-PAS1701
• Specificallydesignedandprocessedfortheanalysisoforganochlorinepesticides
• ECDtestedtoensureminimalpesticidebreakdownandlowECDbleed
• Bondedandcross-linked
• Solventrinsable
similar Phases: SPB-1701,Rtx-1701,BP-10,CB-1701,OV-1701,007-1701,ZB-1701P
DB-1701P
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm ii module
0.25 30 0.25 -20to280/300 122-7732 122-7732LTM
0.32 25 0.25 -20to280/300 123-7722
30 0.25 -20to280/300 123-7732
0.53 30 1.00 -20to260/280 125-7732
VF-1701 Pesticides
• Speciallydesignedforthedeterminationoftracelevelsofpesticideresidues
• Columnsindividuallytestedwithkeypesticides,includingendrinandaldrin
• Highlyinertforimproveddetectionlimitsfortracepesticidedetermination
• ProvenperformancewithECDorMSdetection
• Ultralowbleedtoimprovesensitivity
VF-1701 Pesticides
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 30 0.25 -20to280/300 CP9070
50 0.25 -20to280/300 CP9072
0.32 30 0.25 -20to280/300 CP9071
386
AGilEnt J&W GC Columns
WWW.AGilEnt.Com/ChEm/GC 387
AGilEnt J&W GC Columns
DB-608
• SpecificallydesignedfortheanalysisofchlorinatedpesticidesandPCBs
• USEPAMethods:608,508,8080
• Excellentinertnessandrecoverieswithoutpesticidebreakdown
• Bondedandcross-linked
• Solventrinsable
• ExactreplacementofHP-608
similar Phases: SPB-608,NON-PAKDPesticide,007-608
DB-608
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm ii module
0.25 30 0.25 40to280/300 122-6832
0.32 30 0.50 40to280/300 123-1730 123-1730LTM
0.53 30 0.50 40to260/280 125-6837
0.83 40to260/280 125-1730
hP-PAs5
• Non-polar
• Specificallydesignedandprocessedfortheanalysisoforganochlorinepesticides
• ECDtestedtoensureminimalpesticidebreakdownandlowECDbleed
• Bondedandcross-linked
• Solventrinsable
similar Phases: SPB-5,RSL-200,Rtx-5,BP-5,CB-5,OV-5,007-2(MPS-5),SE-52,SE-54,XTI-5,PTE-5,
CC-5,ZB-5
hP-PAs5
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.32 25 0.52 -60to325/350 19091S-010
388
AGilEnt J&W GC Columns
Rapid-ms
• Equivalentto5%phenyl,95%dimethylpolysiloxane
• Fastanalysistimeimprovesproductivity
• Reduceanalysistimeby3-5xfortemperatureprogrammed,andupto10xforisothermalruns
• Thefilmthicknessfrom0.1to1µmensureshighloadabilityandhighersensitivity
• Lowbleed
note: Rapid-MScolumnsutilizethehighoptimalcarriergasvelocityobtainedwhenaseparationis
performedunderreducedpressureforfastanalysistimes
Rapid-ms
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.53 10 0.12 -60to325/325 CP8131
0.25 -60to325/325 CP8132
0.50 -60to325/325 CP8133
1.00 -60to325/325 CP8134
WWW.AGilEnt.Com/ChEm/GC 389
AGilEnt J&W GC Columns
PAH Columns
select PAh
• FullseparationforallPAHisomersavoidsfalsepositivesandinaccurateresults
• FullseparationofEPAPAHsinlessthan7minutesandEUPAHsinlessthan30minutes,including
separationofchrysene,triphenyleneandbenzofluoranthene(typeb,j,andk)
• Fastresultswithnoneedforfurtheranalysis
• Lowbleedenhancessensitivity
select PAh
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.15 15 0.10 40 to 325/350 CP7461
0.25 30 0.15 40to325/350 CP7462
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
DB-EuPAh
• SpeciallydesignedforanalysisofEUregulatedPAHs
• Individuallytestedwithapplication-specificQCtestprobemixture
• Greatresolutionofcriticalisomers,e.g.benzo(b,j,k)fluoranthenes
• SuperbthermalstabilityforaccurateanalysisofhighboilingPAHs,e.g.dibenzopyrenes
• Excellentsignal-to-noiseratio
• Optimizedcolumndimensionsforprovenperformance
DB-EuPAh
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.18 20 0.14 40 to 320/340 121-9627
0.25 60 0.25 40to320/340 122-96L2
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
390
AGilEnt J&W GC Columns
WWW.AGilEnt.Com/ChEm/GC 391
AGilEnt J&W GC Columns
Semivolatiles Columns
Semivolatilesareusuallyextractedfromsoilsamplesorotherenvironmentalmatrixes.GCcolumnswith
preciseretentiontimereproducibilityandgoodmassspectrometerperformancearekeyenablersforthese
oftendemandinganalyses.
392
AGilEnt J&W GC Columns
WWW.AGilEnt.Com/ChEm/GC 393
AGilEnt J&W GC Columns
DB-5.625
• Closeequivalenttoa(5%-Phenyl)-methylpolysiloxane
• Non-polar
• SpeciallyprocessedtoexhibitexcellentinertnessforEPASemivolatilesMethods625,
1625,8270andCLPprotocols*
• SurpassesEPAperformancecriteriaforsemivolatiles
• Inertforbase,neutralandacidiccompounds
• Hightemperaturelimitwithexcellentthermalstabilityandlowbleed
• Bondedandcross-linked
• Solventrinsable
*Pentachlorophenol,2,4-dinitrophenol,carbazole,andN-nitrosodiphenylamineusedtotestresponsefactors.
DB-5.625
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.18 20 0.18 -60 to 325/350 121-5621
0.36 -60 to 325/350 121-5622
0.25 30 0.25 -60to325/350 122-5631
0.50 -60to325/350 122-5632
1.00 -60to325/350 122-5633
60 0.25 -60to325/350 122-5661
0.32 30 0.25 -60to325/350 123-5631
0.50 -60to325/350 123-5632
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
394
AGilEnt J&W GC Columns
hP-5ms semivolatile
• (5%-Phenyl)-methylpolysiloxane,identicalselectivitytoHP-5
• Non-polar
• Verylowbleedcharacteristics,idealforGC/MS
• Specificallytestedforinertnessforactivecompoundsincludingacidicandbasiccompounds
• Improvedsignal-to-noiseratioforbettersensitivityandmassspectralintegrity
• Bondedandcross-linked
• Solventrinsable
• EquivalenttoUSPPhaseG27
similar Phases: Rtx-5ms,Rxi-5ms,Rxi-5SilMS,PTE-5,BPX-5,AT-5ms,ZB-5ms,SLB-5ms,Equity-6
hP-5ms semivolatile
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 30 0.50 -60to325/350 19091S-139
WWW.AGilEnt.Com/ChEm/GC 395
AGilEnt J&W GC Columns
DB-Dioxin
• Specificallyengineeredfortheanalysisofpolychlorinateddibenzodioxins(PCDDs)
anddibenzofurans(PCDFs)
• Resolves2,3,7,8-TCDDand2,3,7,8-TCDFfromallotherisomersinonerun
• Lowbleed
• Bondedandcross-linked
• Solventrinsable
note: 100psiregulatorrequiredtoreachoptimumcarriergasvelocity
DB-Dioxin
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 60 0.15 40to250/270 122-2461
0.25 40to250/270 122-2462
396
AGilEnt J&W GC Columns
Volatiles Columns
Agilentoffersaselectionofadvancedpolymerchemistriesforincreasinglydemandingvolatilesapplications.
Whetherforaprimaryanalyticalcolumnorasacomplementaryconfirmationcolumn,AgilentJ&W
capillariesarechromatographers'firstchoice.
WWW.AGilEnt.Com/ChEm/GC 397
AGilEnt J&W GC Columns
DB-624
• Specificallydesignedfortheanalysisofvolatileprioritypollutantsandresidualsolvents
• NocryogenicsneededforUSEPAMethod502.2
• ExcellentforUSEPAMethods:501.3,502.2,503.1,524.2,601,602,8010,8015,8020,
8240,8260,andUSP467
• Excellentinertnessforactivecompounds
• Bondedandcross-linked
• Solventrinsable
• ExactreplacementofHP-624
• EquivalenttoUSPPhaseG43
similar Phases: AT-624,Rxi-624SilMS,Rtx-624,PE-624,007-624,007-502,ZB-624
DB-624
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.18 20 1.00 -20 to 260 121-1324 121-1324E 121-1324LTM
0.20 25 1.12 -20to260 128-1324 128-1324E 128-1324LTM
0.25 30 1.40 -20to260 122-1334 122-1334E 122-1334LTM
60 1.40 -20to260 122-1364 122-1364E
0.32 30 1.80 -20to260 123-1334 123-1334E 123-1334LTM
60 1.80 -20to260 123-1364 123-1364E
0.45 30 2.55 -20to260 124-1334 124-1334LTM
75 2.55 -20to260 124-1374
0.53 15 3.00 -20to260 125-1314
30 3.00 -20to260 125-1334 125-1334E 125-1334LTM
60 3.00 -20to260 125-1364 125-1364E
75 3.00 -20to260 125-1374 125-1374E
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
398
AGilEnt J&W GC Columns
CP-select 624 CB
• 6%Cyanopropyl,94%dimethylpolysiloxane
• EPAvolatilesmethods524.2,624and8015
• SpecifiedbyPharmacopoeiaV.3.3.9forresidualsolvents
• Excellentcolumn-to-columnreproducibility
• Lowbleed
similar Phases: AT-624,Rtx-624,PE-624,007-624,007-502,ZB-624
CP-select 624 CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 25 0.84 265/280 CP7411
0.25 30 1.40 265/280 CP7412
60 1.40 265/280 CP7413
0.32 30 1.80 265/280 CP7414
60 1.80 265/280 CP7415
0.53 30 3.00 265/280 CP7416 CP7416I5
75 3.00 265/280 CP7417
105 3.00 265/280 CP7418
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
WWW.AGilEnt.Com/ChEm/GC 399
AGilEnt J&W GC Columns
DB-VRX
• Uniqueselectivityengineeredforoptimumresolutionofvolatilesanalysis:
USEPAMethods502.2,524.2and8260
• 0.45mmidcolumnsprovidemoreplatespermetercomparedto0.53mmidcolumns
forthefewestco-elutionsforGCmethod(anindustryfirst)*
• Nosubambientcoolingrequiredtoresolvethesix"gases"
• Fastruntime:
<30minutesforoptimumsamplethroughput
<8minuteswith0.18mmid
• Lowpolarity
• Excellentpeakshape
• Bondedandcross-linked
• Solventrinsable
*Twoco-elutions:1)m-andp-xylene,forwhichUSEPAdoesnotrequireseparation,and
2)1,1,2,2-tetrachloroethaneando-xylenewhichareseparatedbydetectorsPIDandELCD,
respectively.note to GC/ms analysts: Theseco-elutingcompoundshavedifferentprimary
characteristicionsof83and106,respectively.
DB-VRX
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.18 20 1.00 -10 to 260 121-1524 121-1524LTM
40 1.00 -10 to 260 121-1544 121-1544E
0.25 30 1.40 -10to260 122-1534 122-1534LTM
60 1.40 -10to260 122-1564 122-1564E
0.32 30 1.80 -10to260 123-1534
60 1.80 -10to260 123-1564
0.45 30 2.55 -10to260 124-1534
75 2.55 -10to260 124-1574
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
400
AGilEnt J&W GC Columns
hP-VoC
• SelectivityengineeredforUSEPAMethods502.2,524.2and8260
• Lowpolarity–slightlymorepolarthanDB-VRX
• Excellentpeakshape
• Bondedandcross-linked
• Solventrinsable
similar Phases: NON-PAKD,Rtx-Volatiles,PE-Volatiles,007-624,Rtx-VRX,Rtx-VGC
hP-VoC
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.20 30 1.10 -60to280/290 19091R-303
60 1.10 -60to280/290 19091R-306
0.32 60 1.80 -60to280/290 19091R-316
90 1.80 -60to280/290 19091R-319
0.53 90 3.00 -60to280/290 19095R-429
105 3.00 -60to280/290 19095R-420
WWW.AGilEnt.Com/ChEm/GC 401
AGilEnt J&W GC Columns
DB-502.2
• Availablein105mforvolatilesanalyses
• Excellentpeakshape
• Bondedandcross-linked
• Solventrinsable
DB-502.2
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.32 60 1.80 0to260/280 123-1464
0.53 105 3.00 0to260/280 125-14A4
DB-mtBE
• Lowpolaritystationaryphase
• ResolvesMTBEfrom2-methylpentaneand3-methylpentaneforbetterquantitation
• Engineeredforpurgeandtrapinjectionwithouttheneedforcryofocusing
• Bondedandcross-linked
• Solventrinsable
DB-mtBE
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.45 30 2.55 35to260/280 124-0034
402
AGilEnt J&W GC Columns
DB-tPh
• Specificallydesignedfortheanalysisoftotalpetroleumhydrocarbons(TPHs),soilanalysis,andLUFT
• Threeanalysesinoneinjection–gasrangeorganics,dieselrangeorganicsandmotoroil
• Fastruntime
• Bondedandcross-linked
• Solventrinsable
DB-tPh
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.32 30 0.25 -10to320 123-1632
WWW.AGilEnt.Com/ChEm/GC 403
AGilEnt J&W GC Columns
404
AGilEnt J&W GC Columns
hP-88
• (88%-Cyanopropyl)aryl-polysiloxane
• 250/320°Cuppertemperaturelimits
• Highpolarity
• Designedforseparationofcis-transfattyacidmethylesters(FAMEs)
• EvenbetterseparationthanDB-23ofcis-transisomers C
N
Me Me Me Me
note: BecauseHP-88isnotbondedorcross-linked,wedonotrecommendsolventrinsing. Si Me O Si Si O Si C Si Me
Me Me Me Me
m
C
similar Phases: SP-2560,SP-2340,SP-2330,BPX-70,BPX-90 N n
StructureofHP-88
hP-88
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.25 100 0.20 0to250/260 112-88A7 112-88A7E
60 0.20 0to250/260 112-8867 112-8867E
30 0.20 0to250/260 112-8837 112-8837E 112-8837LTM
WWW.AGilEnt.Com/ChEm/GC 405
AGilEnt J&W GC Columns
CP-sil 88
• Highselectivitytowardspositionalandgeometricisomersforease-of-use
• Highlysubstitutedcyanopropylphase
• Highestpolarity,non-chemicallybondedandstabilized
similar Phases: SP-2560,SP-2340,SP-2330,BPX-70,BPX-90
CP-sil 88
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 25 0.20 50to225/240 CP6172
50 0.20 50to225/240 CP6173
0.32 25 0.20 50to225/240 CP6174
50 0.20 50to225/240 CP6175
406
AGilEnt J&W GC Columns
select FAmE
• Tunedforoptimalcis-tansseparationofFAMEs,especiallyC18 isomers
• ExcellentpeakshapeandseparationforFAMEisomers–especiallyifonecomponentispresent
atahigherconcentration
• Bondedandcross-linked
• Lowbleed
• Highefficiencyandcolumnloadability
• Columnlengthupto200mavailablefordetailedanalysisoftheC18:1 isomercluster
select FAmE
iD (mm) length (m) temp limits (°C) 7 in Cage 5 in Cage
0.25 50 275/290 CP7419 CP7419I5
100 275/290 CP7420
200 275/290 CP7421
WWW.AGilEnt.Com/ChEm/GC 407
AGilEnt J&W GC Columns
CP-Wax 57 CB
• Uniquehighpolaritybondedwaxcolumn
• Industryprovenfortheanalysisofalcoholsinthebrewingandwine/spiritsindustry
• Excellentinertnessforoptimumpeakshapeofalcoholsandglycols
• Offeredin0.15mmidforsignificantlyhighspeedthroughput
similar Phases: SUPELCOWAX10,SUPEROXII,CB-WAX,Stabilwax,BP-20,007-CW,Carbowax,
Rtx-WAX,ZB-WAX
CP-Wax 57 CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 30 0.12 20 to 200/225 CP97721
0.25 25 0.20 20to200/225 CP97713
50 0.20 20to200/225 CP97723 CP97723I5
60 0.40 20to200/225 CP8120
0.32 25 0.20 20to200/225 CP97743
1.20 20to200/225 CP97763
50 0.20 20to200/225 CP97753 CP97753I5
1.20 20to200/225 CP97773
0.53 25 1.00 20to200/225 CP97638
25 2.00 20to200/225 CP97658
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
408
AGilEnt J&W GC Columns
CP-tAP CB ultimetal
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage
0.25 25 0.10 355/370 CP7463
WWW.AGilEnt.Com/ChEm/GC 409
AGilEnt J&W GC Columns
CP-FFAP CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.15 25 0.25 250/275 CP7686
0.32 25 0.30 250/275 CP7485 CP7485I5
0.53 25 1.00 250/275 CP7486
AgilentJ&WHighEfficiencyGCcolumnsaredisplayedusingitalicizeddescriptionsandpartnumbers
Si
O Si
Cyclosil-B
O O
O O
O
Si O
O O
O
O O O O • 30%Heptakis(2,3-di-O-methyl-6-O-t-butyldimethylsilyl)-b-cyclodextrininDB-1701
O
O O
O O O
• Chiralseparationswithoutchiral-specificderivatization
O
O
O O
O Si
• Newstationaryphaseforimprovedresolutionofmanychiralseparations
O
Si O O O
O
O
O
• Idealformanychiralg-lactonesandterpenes
O O
Si
O
Si note: BecauseCycloSil-BGCcolumnsarenotbondedorcross-linked,wedonotrecommendsolventrinsing.
Cyclosil-B
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage ltm ii module
0.25 30 0.25 35to260/280 112-6632 112-6632LTM
0.32 30 0.25 35to260/280 113-6632 113-6632LTM
410
AGilEnt J&W GC Columns
Cyclodex-B
• 10.5%b-cyclodextrininDB-1701
• Chiralseparationswithoutchiral-specificderivatization
• Broadrangeofresolvingpotential
• Excellentpeakshape
note: BecauseCyclodex-BGCcolumnsarenotbondedorcross-linked,wedonotrecommendsolventrinsing.
Cyclodex-B
7890/6890
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage ltm ii module
0.25 30 0.25 50to230/250 112-2532 112-2532E 112-2532LTM
60 0.25 50to230/250 112-2562
0.32 30 0.25 50to230/250 113-2532 113-2532E
hP-Chiral b
• b-cyclodextrinin(35%-phenyl)-methylpolysiloxane
• Chiralseparationswithoutchiral-specificderivatization
• Phenyl-basedpolymerprovideslowbleedanddoesnotinterferewithnitrogen-specificdetectors
• Availableintwoconcentrationsofb-cyclodextrin:10%and20%
• 20%b-cyclodextrinbestchoiceforinitialscreening
similar Phases: LIPODEXC,Rt-b DEXm,b-DEX110,b-DEX120
hP-Chiral b
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
hP-Chiral 10b
0.25 30 0.25 30to240/250 19091G-B133
hP-Chiral 20b
0.25 30 0.25 30to240/250 19091G-B233 19091G-B233E
0.32 30 0.25 30to240/250 19091G-B213
WWW.AGilEnt.Com/ChEm/GC 411
AGilEnt J&W GC Columns
CP-Chirasil Val
• Designedforseparationsofopticallyactivecompoundsincludingaminoacids
• Bothantipodephasesareavailable(DandL)formaximumversatility
• Stabilizedchiralphase,over50%cross-linkedforlongevity
• Testedforseparationofaminoacidenantiomers
• Lowbleed
note: OnChirasil-LVal,D-aminoacidselutebeforetheL-aminoacids,whileonChirasil-D-Val,thiselution
orderisreversed.Thisisespeciallyvaluablewhendeterminingtheopticalpurityofthesecompounds.
Selectingthecolumnfromwhichtheminorcompoundelutesbeforethemajorenantiomersresults
inthelowestdetectionlevels.
CP-Chirasil Val
Description iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
AntipodeD 0.25 25 0.08 200/200 CP7494
AntipodeL 0.25 25 0.12 200/200 CP7495 CP7495I5
CP-Chirasil-Dex CB
• Cyclodextrinbondedtodimethylpolysiloxaneforhomogeneousenantioselectivity
throughoutthecolumn
• Highresolutionfactorbetweenisomersacrossabroadapplicationrange
• Chemicallybondedphaseforexcellentlongevity
• Noneedforderivatizationimprovedproductivity
• Lowelutiontemperatureofpolarcompounds
• Suitableforallinjectiontechniques
similar Phases: LIPODEXC,Rt-b DEXm,b-DEX110,b-DEX120
CP-Chirasil-Dex CB
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 25 0.25 200/200 CP7502 CP7502I5
0.32 25 0.25 200/200 CP7503
412
AGilEnt J&W GC Columns
CP-Cyclodextrin-b-2,3,6-m-19
• Uniqueselectivityforopticalandpositionalisomerseparations
• Highefficiencyenableswiderangeofapplications
• Separateso-,m-,andp-xylenes
• Excellentpeakshapeforunderivatizedpolarcompounds
CP-Cyclodextrin-b-2,3,6-m-19
iD (mm) length (m) Film (µm) temp limits (°C) 7 in Cage 5 in Cage
0.25 25 0.25 225/250 CP7500 CP7500I5
50 0.25 225/250 CP7501
WWW.AGilEnt.Com/ChEm/GC 413
AgilenT J&W gC ColuMns
414
AgilenT J&W gC ColuMns
VF-DA
• Engineered for drugs of abuse confirmation testing
• High recovery for trace level analysis and excellent resistance to direct methanol injections
• Ultra low bleed
VF-DA
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.20 12 Optimized -60 to 325/350 CP8964
DB-5ms eVDX
• Specially configured and tested for drugs of abuse confirmation
• Drug test mix included: caffeine, glutethimide, lidocaine, phenobarbital, EDDP, methaqualone,
methadone, cocaine, desipramine, carbamazepine
• DB-5ms EVDX is equivalent to (5%-phenyl)-methylpolysiloxane
• Consistent retention and peak shape
• Low bleed for GC/MS analysis
• Bonded and cross-linked
• Solvent rinsable
DB-5ms eVDX
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.20 25 0.33 -60 to 325/350 128-8522
WWW.AgilenT.CoM/CheM/gC 415
AgilenT J&W gC ColuMns
416
AgilenT J&W gC ColuMns
Metal Columns
DB-ProSteel and UltiMetal columns are engineered to combine the robustness of stainless steel
with advanced surface deactivation for excellent peak shape.
Metal Columns
phase iD (mm) length (m) Film (µm) 7 in Cage 5 in Cage
simulated distillation/high temperature
DB-HT Sim Dis 0.53 5 0.10 145-1009
0.15 145-1001
DB-PS2887 0.53 10 3.00 145-2814
CP-SimDist UltiMetal 0.53 5 0.09 CP7569 CP7569I5
0.17 CP7532 CP7532I5
0.88 CP7570
2.65 CP7571
10 0.06 CP6540
0.17 CP7542
0.53 CP7592
0.88 CP7512
1.20 CP7562
2.65 CP7582
5.00 CP7572
20 0.11 CP7593
25 0.06 CP6550
VF-5ht UltiMetal 0.25 15 0.10 CP9090
0.32 15 0.10 CP9094 CP9094I5
0.25 30 0.10 CP9092
0.32 30 0.10 CP9096
(Continued)
WWW.AgilenT.CoM/CheM/gC 417
AgilenT J&W gC ColuMns
Metal Columns
phase iD (mm) length (m) Film (µm) 7 in Cage 5 in Cage
simulated distillation/high temperature
VF-5ht UltiMetal 0.25 15 0.10 CP9091
with retention gap UltiMetal 0.32 15 0.10 CP9095
0.25 30 0.10 CP9093
0.32 30 0.10 CP9097
standard phases and peg
DB-PS1 0.53 15 0.15 145-1011
30 1.50 145-1032
CP-Sil 5 CB 0.53 10 2.00 CP7150
5.00 CP6666
25 0.50 CP7135
1.00 CP7130
2.00 CP7160
5.00 CP6670
50 1.00 CP7140
2.00 CP7170
5.00 CP6671
DB-HT Sim Dis 0.53 5 0.10 145-1009
0.15 145-1001
DB-PS2887 0.53 10 3.00 145-2814
CP-SimDist UltiMetal, 6/pk 0.53 5 0.09 CP67569
CP-SimDist UltiMetal 0.53 5 0.09 CP7569
0.17 CP7532
0.88 CP7570
2.65 CP7571
10 0.06 CP6540
0.17 CP7542
0.53 CP7592
0.88 CP7512
1.20 CP7562
2.65 CP7582
5.00 CP7572
20 0.11 CP7593
25 0.06 CP6550
(Continued)
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AgilenT J&W gC ColuMns
Metal Columns
phase iD (mm) length (m) Film (µm) 7 in Cage 5 in Cage
standard phases and peg
CP-Sil 8 CB UltiMetal 0.53 25 5.00 CP6680
50 0.50 CP7196
CP6681
CP-Sil 13 CB UltiMetal 0.53 25 1.00 CP7141
DB-PSWAX 0.53 30 1.00 145-7032
CP-Wax 52 CB UltiMetal 0.53 10 1.00 CP7148
25 2.00 CP7178
50 1.00 CP7168
2.00 CP7179
ploT columns
PoraPLOT Q UltiMetal 0.53 10 20.00 CP6953
25 20.00 CP6954
CP-Al2O3/KCl UltiMetal 0.53 50 10.00 CP6918
CP-Al2O3/Na2SO4 UltiMetal 0.53 50 10.00 CP6968
CP-Molsieve 5Å UltiMetal 0.53 10 50.00 CP6937
25 50.00 CP6938 CP6938I5
select application columns
DB-PS624 0.53 30 3.00 145-1334
CP-Sil PAH CB UltiMetal 0.25 25 0.12 CP7440
CP-TAP CB 0.25 25 0.10 CP7463
Select Biodiesel 0.32 10 0.10 CP9076
With retention gap 15 0.10 CP9078
Select Biodiesel 0.32 10 0.10 CP9077
15 0.10 CP9079
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AgilenT J&W gC ColuMns
ploT Columns
PLOT columns are ideal for separating compounds that are gases at room temperatures. Agilent
Technologies offers a comprehensive line of PLOT columns for analysis of fixed gases, low molecular
weight hydrocarbon isomers, volatile polar compounds and reactive analytes such as sulfur gases,
amines and hydrides. Our PLOT phases are offered in dimensions from 0.25 to 0.53 mm id, allowing
for easy column selection for various detector and system requirements. For GC/MS systems, we offer
several small diameter columns with truly bonded and immobilized stationary phases, eliminating
potential detector fouling due to particle generation.
Column shown with EZ-GRIP
ploT pT
Agilent J&W PLOT PT columns are engineered to improve lab operations. Unlike current techniques used
to prevent PLOT stationary phase particles from shedding downstream, the integral particle traps of the
PLOT PT columns remove the aggravation of connecting separate traps. Operation is more convenient
and there is no risk from leaks. The integrated particle-trapping technology on both ends of PLOT PT GC
columns reduces downtime. What’s more, with PLOT PT you can now use GC/MS for detailed, qualitative
and quantitative analysis and due to the dual ended particle traps the PLOT PT columns can also be used
for backflush applications. No other PLOT column offers this level of worry-free operation for your GC or
GC/MS system.
Agilent J&W PLOT PT columns are available in porous polymers Q and U, Aluminum oxide and Molesieve
stationary phases.
particle trap
ploT phase
particle trap
420
AgilenT J&W gC ColuMns
WWW.AgilenT.CoM/CheM/gC 421
AgilenT J&W gC ColuMns
poraBonD Q
• Bonded PLOT column for more reliable results for analysis of volatile solvents and hydrocarbons
• Extended analysis offers broad application range
• 300/320 °C temperature limits
• Engineered for high stability, withstands repeated water injections
• Proprietary manufacturing technique results in very pure porous polymer with virtually no catalytic
activity, allowing operation to 320 °C without decomposition
• Bonding technology results in greatly reduced particle shedding, reduces the needs for particle traps
similar phases: Rt-Q BOND, Rt-QPLOT, SupelQ PLOT
poraBonD Q
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT
0.25 10 3.00 -100 to 300/300 CP7347 CP7348PT
25 3.00 -100 to 300/320 CP7348
0.32 10 5.00 -100 to 300/320 CP7350 CP7350I5
25 5.00 -100 to 300/320 CP7351 CP7351I5 CP7351PT
50 5.00 -100 to 300/320 CP7352 CP7352I5 CP7352PT
0.53 10 10.00 -100 to 300/320 CP7353 CP7353I5 CP7353PT
25 10.00 -100 to 300/320 CP7354 CP7354I5 CP7354PT
50 10.00 -100 to 300/320 CP7355
422
AgilenT J&W gC ColuMns
poraBonD u
• Highly stable polar-bonded porous polymer with maximum operating temperature of 300 °C
• Reduced bleed for low detection limits and fast stabilization time
• Bonded PLOT column for excellent longevity
• Ideal for use with method that pressure programs or valve switching
similar phases: Rt-U-BOND
poraBonD u
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.32 25 7.00 -100 to 300/300 CP7381
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AgilenT J&W gC ColuMns
poraploT Q
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT
0.25 10 8.00 -100 to 250/250 CP7548
25 8.00 -100 to 250/250 CP7549
0.32 10 10.00 -100 to 250/250 CP7550 CP7550I5 CP7550PT
25 10.00 -100 to 250/250 CP7551 CP7551I5 CP7551PT
50 10.00 -100 to 250/250 CP7552
0.53 10 20.00 -100 to 250/250 CP7553
25 20.00 -100 to 250/250 CP7554 CP7554I5 CP7554PT
50 20.00 -100 to 250/250 CP7555
poraploT Q ultiMetal
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 10 20.00 -100 to 250/250 CP6953
25 20.00 -100 to 250/250 CP6954
poraploT Q-hT
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage ploT pT
0.32 10 10.00 -100 to 290/290 CP7556
25 10.00 -100 to 290/290 CP7557 CP7557PT
0.53 10 20.00 -100 to 290/290 CP7558
25 20.00 -100 to 290/290 CP7559
424
AgilenT J&W gC ColuMns
hp-ploT Q
• Bonded polystyrene-divinylbenzene based column
• Polarity between Porapak-Q and Porapak-N
• Excellent column for C1-C3 isomers and alkanes to C12, CO2, methane, air/CO,
oxygenated compounds, sulfur compounds and solvents
• Replaces packed gas-solid columns
• Separates ethane, ethylene and ethyne (acetylene)
• Improved resolution in less time than conventional packed columns
• Minimal conditioning time required – 1 hour
• Preferred "Q" column due to its robust nature
similar phases: Rt-QPLOT, SupelQ PLOT
hp-ploT Q
7890/6890
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage lTM ii Module ploT pT
0.32 15 20.00 -60 to 270/290 19091P-QO3 19091P-QO3LTM 19091P-QO3PT
30 20.00 -60 to 270/290 19091P-QO4 19091P-QO4E 19091P-QO4LTM 19091P-QO4PT
0.53 15 40.00 -60 to 270/290 19095P-QO3 19095P-QO3E 19095P-QO3LTM 19095P-QO3PT
30 40.00 -60 to 270/290 19095P-QO4 19095P-QO4E 19095P-QO4LTM 19095P-QO4PT
WWW.AgilenT.CoM/CheM/gC 425
AgilenT J&W gC ColuMns
gs-Q
• Porous divinylbenzene homopolymer
• Polarity between Porapak-Q and Porapak-N
• Separates ethane, ethylene and ethyne (acetylene)
• Not recommended for quantification of polar compounds
• Minimal conditioning time required – 1 hour
similar phases: Rt-QPLOT, SupelQ PLOT
gs-Q
7890/6890
iD (mm) length (m) Temp limits (°C) 7 in Cage 5 in Cage ploT pT lTM ii Module
0.32 30 -60 to 250 113-3432 113-3432E 113-3432LTM
0.53 10 -60 to 250 115-34H2
15 -60 to 250 115-3412
25 -60 to 250 115-3422
30 -60 to 250 115-3432 115-3432E 115-3432PT
426
AgilenT J&W gC ColuMns
PoraPLOT U
similar phases: Rt-U-BOND
poraploT u
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage ploT pT
0.25 25 8.00 -100 to 190/190 CP7579
0.32 10 10.00 -100 to 190/190 CP7580
25 10.00 -100 to 190/190 CP7581
0.53 10 20.00 -100 to 190/190 CP7583
25 20.00 -100 to 190/190 CP7584 CP7584PT
PoraPLOT S
• Divinylbenzene/vinylpyridine polymer for hydrocarbons and ketones
• Ideal for the analysis of medium polarity volatile including hydrocarbons and ketones
• Higher temperature limit than PoraPLOT U
similar phases: Rt-S-BOND, MXT-SBOND
poraploT s
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 25 20.00 -100 to 250/250 CP7574
WWW.AgilenT.CoM/CheM/gC 427
AgilenT J&W gC ColuMns
hp-ploT u
• Bonded divinylbenzene/ethylene glycol dimethacrylate
• More polar than HP-PLOT Q
• Excellent column for C1-C7 hydrocarbons, CO2, methane, air/CO, water,
oxygenates, amines, solvents, alcohols, ketones, and aldehydes
• Improved resolution in less time than conventional packed columns
similar phases: RTU PLOT
hp-ploT u
7890/6890
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT lTM ii Module
0.32 30 10.00 -60 to 190 19091P-UO4 19091P-UO4E 19091P-UO4LTM
0.53 15 20.00 -60 to 190 19095P-UO3
30 20.00 -60 to 190 19095P-UO4 19095P-UO4E 19095P-UO4PT 19095P-UO4LTM
428
AgilenT J&W gC ColuMns
gs-Alumina KCl
• Least "polar" alumina phase
• Aluminum oxide deactivated with KCl
• Good choice for light hydrocarbon analysis
• Good resolution of propadiene and butadiene from ethylene and propylene streams
similar phases: Al2O3/KCl, Al2O3/Na2SO4, Rt-Alumina PLOT, Alumina PLOT, AB-PLOT Al2O3 KCl,
AT-Alumina
gs-Alumina KCl
iD (mm) length (m) Temp limits (°C) 7 in Cage 5 in Cage ploT pT
0.53 30 -60 to 200 115-3332
50 -60 to 200 115-3352 115-3352E 115-3352PT
WWW.AgilenT.CoM/CheM/gC 429
AgilenT J&W gC ColuMns
similar phases: Al2O3/KCl, Rt-Alumina PLOT, Alumina PLOT, RT-Alumina BOND/KCl, Alumina chloride
PLOT, AB-PLOT Al2O3 KCl
Cp-Al2o3/KCl
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT
0.25 25 4.00 -100 to 200/200 CP7576
50 4.00 -100 to 200/200 CP7577
0.32 10 5.00 -100 to 200/200 CP7511
25 5.00 -100 to 200/200 CP7519
50 5.00 -100 to 200/200 CP7515 CP7515I5 CP7515PT
0.53 25 10.00 -100 to 200/200 CP7517 CP7517PT
50 10.00 -100 to 200/200 CP7518 CP7518PT
430
AgilenT J&W gC ColuMns
Cp-Al2o3/KCl ultiMetal
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 50 10.00 -100 to 200/200 CP6918
Cp-Al2o3/na2so4
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT
0.25 25 4.00 -100 to 200/200 CP7586
50 4.00 -100 to 200/200 CP7587
0.32 50 5.00 -100 to 200/200 CP7565 CP7565I5 CP7565PT
0.53 25 10.00 -100 to 200/200 CP7567
50 10.00 -100 to 200/200 CP7568 CP7568PT
Cp-Al2o3/na2so4 ultiMetal
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 50 10.00 -100 to 200/200 CP6968
WWW.AgilenT.CoM/CheM/gC 431
AgilenT J&W gC ColuMns
hp-ploT Al2o3 s
• Middle range of "polarity" for alumina phases
• Aluminum oxide deactivated with sodium sulfate
• Excellent general use column for light hydrocarbon analysis – C1-C8 hydrocarbon isomers
• Best for resolving acetylene from butane and propylene from isobutane
similar phases: Al2O3/Na2SO4, Rt-Alumina PLOT, Alumina PLOT, Rt-Alumina BOND/Na2SO4,
MXT-AluminaBOND/Na2SO4, Alumina sulfate PLOT, AT-Alumina
hp-ploT Al2o3 s
7890/6890
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT lTM ii Module
0.25 30 5.00 -60 to 200 19091P-S33
0.32 25 8.00 -60 to 200 19091P-S12 19091P-S12PT 19091P-S12LTM
50 8.00 -60 to 200 19091P-S15 19091P-S15E 19091P-S15PT
0.53 15 15.00 -60 to 200 19095P-S21
30 15.00 -60 to 200 19095P-S23 19095P-S23PT
50 15.00 -60 to 200 19095P-S25 19095P-S25E 19095P-S25PT
432
AgilenT J&W gC ColuMns
gs-Alumina
• Most "polar" alumina phase
• Aluminum oxide with proprietary deactivation
• Excellent general use column for light hydrocarbon analysis – C1-C8 hydrocarbon isomers
• Separates C1-C4 saturated and unsaturated hydrocarbons
• Best for resolving cyclopropane from propylene
• Faster, more efficient, and provides more sensitivity than packed equivalents
• Minimal conditioning time required
• Preferred substitution for sodium sulfate deactivated Alumina because of its regenerative nature
note: Alumina columns have a tendency to adsorb water and CO2 which, over time, results in changes in
retention time. We use an advanced, proprietary deactivation process which allows for rapid regeneration.
Fully water saturated GS-Alumina columns regenerate in 7 hours or less at 200 °C.
similar phases: Al2O3/KCl, Al2O3/Na2SO4, Rt-Alumina PLOT, Alumina PLOT, AB-PLOT Al2O3 KCl,
AT-Alumina
gs-Alumina
iD (mm) length (m) Temp limits (°C) 7 in Cage ploT pT
0.53 30 -60 to 200 115-3532 115-3532PT
50 -60 to 200 115-3552 115-3552PT
WWW.AgilenT.CoM/CheM/gC 433
AgilenT J&W gC ColuMns
hp-ploT Al2o3 M
• Most "polar" alumina phase (similar to GS-Alumina)
• Aluminum oxide deactivated with proprietary deactivation
• Good general use column for light hydrocarbon analysis – C1-C8 hydrocarbon isomers
• Good for resolving acetylene from butane and propylene from isobutane
similar phases: AB-PLOT Al2O3 M, BGB-PLOT Al2O3 M, AT-Alumina
hp-ploT Al2o3 M
iD
(mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT
0.32 50 8.00 -60 to 200 19091P-M15 19091P-M15E
0.53 30 15.00 -60 to 200 19095P-M23
50 15.00 -60 to 200 19095P-M25 19095P-M25PT
gs-gaspro
• Unique bonded silica PLOT column technology
• Excellent choice for light hydrocarbons and sulfur gases
• Retention stability not affected by water
• Separates CO and CO2 on a single column
• Ideal PLOT column for GC/MS – no particles
similar phases: CP-Silica PLOT
gs-gaspro
iD (mm) length (m) Temp limits (°C) 7 in Cage
0.32 5 -80 to 260/300 113-4302
15 -80 to 260/300 113-4312
30 -80 to 260/300 113-4332
60 -80 to 260/300 113-4362
434
AgilenT J&W gC ColuMns
Cp-silicaploT
• No influence of water on retention times
• Elution of CO2 and sulfur gases at ppm levels
• Separates cyclopropane from propylene
• Ideal for a wide range of applications such as COS in ethylene, freons, hydrocarbons,
propylene and sulfur compounds
• High selectivity for C1-C4 isomers in the presence of water
• No negative influence on retention or peak shape when water is present in the sample
• Inert surface preparation results in no decomposition pentadienes or freons
similar phases: GS-GasPro
Cp-silicaploT
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage
0.25 30 3.00 -80 to 225/225 CP8564
0.32 15 4.00 -80 to 225/225 CP8566
30 4.00 -80 to 225/225 CP8567
60 4.00 -80 to 225/225 CP8568
0.53 30 6.00 -80 to 225/225 CP8570 CP8570I5
60 6.00 -80 to 225/225 CP8571
WWW.AgilenT.CoM/CheM/gC 435
AgilenT J&W gC ColuMns
CarboBOND
CarboBonD
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 25 5.00 -100 to 200/300 CP7371
10.00 -100 to 200/300 CP7374
50 5.00 -100 to 200/300 CP7372
10.00 -100 to 200/300 CP7375
CarboPLOT P7
CarboploT p7
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 10 25.00 -200 to 115/115 CP7513
25 25.00 -200 to 115/115 CP7514
436
AgilenT J&W gC ColuMns
gs-CarbonploT
• High stability, bonded carbon layer stationary phase
• Unique selectivity for inorganic and organic gases
• Extended temperature limit of 360 °C
• Ideal for GC/MS – no particle generation
• Retention stability not affected by water
similar phases: Carbopack, CLOT, Carboxen-1006 PLOT
gs-CarbonploT
7890/6890
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage lTM ii Module
0.32 15 1.50 0 to 360 113-3112
30 1.50 0 to 360 113-3132
3.00 0 to 360 113-3133 113-3133LTM
60 1.50 0 to 360 113-3162
0.53 15 3.00 0 to 360 115-3113
30 3.00 0 to 360 115-3133 115-3133LTM
WWW.AgilenT.CoM/CheM/gC 437
AgilenT J&W gC ColuMns
hp-ploT Molesieve
• A PLOT column for the analysis of permanent gases
• O2, N2, CO and CH4 resolve in less than 5 min
• Durable molecular sieve 5Å coating minimizes baseline spiking and damage to multiport valves
• Select a thick film for Ar/O2 separation without cryogenic cooling
• Select thin film HP-PLOT Molesieve columns for routine air monitoring applications
• Replaces GS-Molesieve
note: Molecular sieve columns will absorb water, which, over time results in changes in retention time.
We use an advanced, proprietary deactivation process which allows for rapid regeneration. Fully saturated
HP-PLOT Molesieve columns regenerate in 7 hours or less at 200 °C.
hp-ploT Molesieve
Temp limits 7890/6890
iD (mm) length (m) Film (µm) (°C) 7 in Cage 5 in Cage lTM ii Module
0.32 15 25.00 -60 to 300 19091P-MS7 19091P-MS7LTM
30 12.00 -60 to 300 19091P-MS4 19091P-MS4E
25.00 -60 to 300 19091P-MS8 19091P-MS8LTM
0.53 15 25.00 -60 to 300 19095P-MS5
50.00 -60 to 300 19095P-MS9
30 25.00 -60 to 300 19095P-MS6 19095P-MS6E
50.00 -60 to 300 19095P-MS0 19095P-MS0E 19095P-MS0LTM
438
AgilenT J&W gC ColuMns
Cp-Molsieve 5Å
• Separate argon and oxygen at ambient temperature to reduce costs
• High efficiency for increased productivity
• Symmetrical peaks for accurate results
similar phases: Rt-Msieve 5A, MXT-Msieve 5A, Mol Sieve 5A PLOT
Cp-Molsieve 5Å
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage ploT pT*
0.25 25 30.00 -200 to 350/350 CP7533
0.32 10 30.00 -200 to 350/350 CP7535 CP7535I5
25 30.00 -200 to 350/350 CP7536 CP7536PT
30 10.00 -200 to 350/350 CP7534 CP7534I5 CP7534PT
50 30.00 -200 to 350/350 CP7540 CP7540I5
0.53 10 50.00 -200 to 350/350 CP7537
15 15.00 -200 to 350/350 CP7543
25 50.00 -200 to 350/350 CP7538 CP7538I5 CP7538PT
30 15.00 -200 to 350/350 CP7544
50 50.00 -200 to 350/350 CP7539 CP7539PT
* CP-Molsieve 5Å PT columns have a lower operating temperature of 300 ºC
Cp-Molsieve 5Å ultiMetal
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage
0.53 10 50.00 -200 to 350/350 CP6937
25 50.00 -200 to 350/350 CP6938 CP6938I5
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440
AgilenT J&W gC ColuMns
hp-101
• 100% Dimethylpolysiloxane
Because HP-101 columns are not bonded or cross-linked, we do not recommend solvent rinsing.
hp-101
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage 5 in Cage
0.20 25 0.20 -60 to 280 19091Y-102
0.32 25 0.30 -60 to 280 19091Y-012 19091Y-012E
50 0.30 -60 to 280 19091Y-015
hp-17
• 50% Phenyl and 50% methyl siloxane
Because HP-17 columns are not bonded or cross-linked, we do not recommend solvent rinsing.
hp-17
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.53 10 2.00 25 to 260/280 19095L-121
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CAM
• Base deactivated polyethylene glycol
• Specifically designed for amine analysis
• Excellent peak shape for primary amines
• Replaces HP-Basicwax
Because CAM columns are not bonded or cross-linked, we do not recommend solvent rinsing.
CAM
7890/6890
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage lTM ii Module
0.25 15 0.25 60 to 220/240 112-2112
30 0.25 60 to 220/240 112-2132
0.50 60 to 220/240 112-2133 112-2133LTM
60 0.25 60 to 220/240 112-2162
0.32 30 0.25 60 to 220/240 113-2132 113-2132LTM
0.50 60 to 220/240 113-2133
0.53 30 1.00 60 to 200/220 115-2132 115-2132LTM
442
AgilenT J&W gC ColuMns
Because DX series GC columns are not bonded and cross-linked, we do not recommend solvent rinsing.
DX-1
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.32 30 1.00 50 to 250/270 123-6133
DX-4
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.25 30 0.25 50 to 250/270 122-6432
60 0.25 50 to 250/270 122-6462
0.32 15 0.25 50 to 250/270 123-6412
30 0.25 50 to 250/270 123-6432
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AgilenT J&W gC ColuMns
Because SE series GC columns are not bonded or cross-linked, we do not recommend solvent rinsing.
se-30
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.32 30 0.25 0 to 325/350 113-3032
se-54
iD (mm) length (m) Film (µm) Temp limits (°C) 7 in Cage
0.25 30 0.25 0 to 325/350 112-5432
60 0.25 0 to 325/350 112-5462
0.32 30 0.25 0 to 325/350 113-5432
444
AgilenT J&W gC ColuMns
guard Columns
• DuraGuard and EZ-Guard columns with "built-in" guard columns, no press-fit connectors
• Minimize front-end contamination and increase column lifetime
• Aid in focusing sample onto the front of the column for better peak shape
• Minimize MSD contamination originating from the column (when used as transfer line
to the MS detector)
Guard columns (or retention gaps) are often added to the front of the analytical column to protect
against contamination, or to act as a band-focusing device for liquid samples introduced by on-column
and splitless injection techniques.
When resolution or response in a chromatogram diminishes, remove a coil from the guard column
so that peak shapes will improve. By removing a coil, the column length is shortened and peaks will
elute somewhat faster. For best results, check the integration time windows of your data system.
WWW.AgilenT.CoM/CheM/gC 445
AgilenT J&W gC ColuMns
EZ-Guard
eZ-guard
phase iD (mm) length (m) Film (µm) guard length (m) part no.
VF-1ms 0.20 12 0.33 5 CP9023
0.25 30 0.25 5 CP9010
0.25 10 CP9011
A special tab clearly distinguishes the EZ-Guard VF-5ms 0.25 15 0.25 5 CP9021
guard column section from the analytical column
30 0.25 5 CP9012
0.25 10 CP9013
0.50 5 CP9014
0.50 10 CP9015
60 0.25 5 CP9016
VF-Xms 0.25 30 0.10 10 CP9022
0.25 10 CP9019
VF-17ms 0.25 30 0.25 5 CP9024
0.25 10 CP9025
VF-1701ms 0.25 30 0.25 5 CP9176
0.25 10 CP9177
VF-35ms 0.25 30 0.25 5 CP9026
0.25 10 CP9027
446
AgilenT J&W gC ColuMns
Agilent offers LTM technology for our popular 7890 and 6890 Series GC systems, and the 5975T GC/MS.
For more information, visit www.agilent.com/chem/lTMcol LTM II standard format with 5 in column toroid
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lTM ii Columns
phase Description iD (mm) length (m) Film (µm) part no.
DB-17ms 5 m DuraGuard and long legs 0.25 15 0.25 G3900-65001
DB-1ms With long column legs 0.25 15 0.25 G3903-65002
DB-1 Transfer line 0.15 1 1.20 G3903-61004
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lTM ii Columns
phase Description iD (mm) length (m) Film (µm) part no.
DB-Sim-Dist LTM II 0.25 4 0.25 G3900-65004
DB-Sim-Dist LTM II 0.25 4 0.50 G3900-65003
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2. Lowering the ramp rate during heating 5975T complete column module
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• Long legs 30 cm column ends (total column length includes the 30 cm column ends)
• note: Long legs are standard for 5975T LTM columns
• Non-standard columns – custom column length, 3 in small format and other
special request LTM columns
note: When requesting quote for custom LTM columns, please specify the following:
• Instrument model, e.g. 7890 or 5975T
• LTM column format: 5 in standard or 3 in small format
• For 5975T, please indicate whether it is for a complete column module or replacement column toroid
Contact your local Agilent office or Authorized Agilent Distributor to receive a quote for your custom column
needs. You can find order forms in the back of Agilent's Essential Chromatography Catalog.
Customers in the United States, Canada, and Puerto Rico can request a custom column quote online at
www.agilent.com/chem/CustomColumn
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Agilent J&W lTM Column Modules for Transportable 5975T gC/MsD systems
Toroid Column
phase iD (mm) length (m) Film (µm) Assembly Module
DB-5ms Ultra Inert 0.18 20 0.18 221-5522UILTM G3900-63014
0.25 15 0.25 222-5512UILTM G3900-63031
30 0.25 222-5532UILTM G3900-63005
HP-5ms Ultra Inert 0.18 20 0.18 29091S-577UILTM G3900-63039
0.25 15 0.25 29091S-431UILTM G3900-63038
30 0.25 29091S-433UILTM G3900-63001
Replacement column toroid DB-1 0.25 30 0.25 222-1032LTM G3900-63002
for LTM 5975T column modules
DB-1ms 0.18 20 0.18 221-0122LTM G3900-63009
0.25 15 0.25 222-0112LTM G3900-63016
30 0.25 222-0132LTM G3900-63017
DB-1ht 0.25 15 0.10 222-1111LTM G3900-63018
30 0.10 222-1131LTM G3900-63019
HP-1ms 0.18 20 0.18 29091S-677LTM G3900-63040
0.25 30 0.10 29091S-833LTM G3900-63041
15 0.25 29091S-931LTM G3900-63042
DB-5ms 0.18 20 0.18 221-5522LTM G3900-63013
0.25 15 0.25 222-5512LTM G3900-63030
30 0.25 222-5532LTM G3900-63004
DB-5ht 0.25 30 0.10 222-5731LTM G3900-63033
15 0.10 222-5711LTM G3900-63032
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Agilent J&W lTM Column Modules for Transportable 5975T gC/MsD systems
Toroid Column
phase iD (mm) length (m) Film (µm) Assembly Module
HP-5ms 0.25 30 0.25 29091S-433LTM G3900-63007
DB-35ms 0.18 20 0.18 221-3822LTM G3900-63011
0.25 15 0.25 222-3812LTM G3900-63026
30 0.25 222-3832LTM G3900-63027
DB-17ms 0.18 20 0.18 221-4722LTM G3900-63012
0.25 15 0.25 222-4712LTM G3900-63028
30 0.25 222-4732LTM G3900-63029
DB-225ms 0.25 15 0.25 222-2912LTM G3900-63022
30 0.25 222-2932LTM G3900-63023
DB-1701 0.25 30 0.25 222-0732LTM G3900-63003
DB-WAX 0.25 15 0.50 222-7013LTM G3900-63034
30 0.50 222-7033LTM G3900-63035
HP-INNOWax 0.18 20 0.18 29091N-577LTM G3900-63036
0.25 30 0.25 29091N-133LTM G3900-63008
DB-FFAP 0.25 15 0.25 222-3212LTM G3900-63024
30 0.25 222-3232LTM G3900-63025
DB-608 0.18 20 0.18 221-6822LTM G3900-63015
DB-VRX 0.18 20 1.00 221-1524LTM G3900-63006
0.25 30 1.40 222-1534LTM G3900-63021
DB-624 0.18 20 1.00 221-1324LTM G3900-63010
0.25 30 1.40 222-1334LTM G3900-63020
HP-VOC 0.20 30 1.12 29091R-303LTM G3900-63037
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Retention gaps
iD (mm) oD (mm) length (m) Connector unit part no.
0.25 0.36 2.5 Universal 5/pk CP8007
0.32 0.45 2.5 Universal 5/pk CP8008
2.5 0.32/0.25 5/pk CP8129
2.5 0.32/0.32 5/pk CP8128
0.53 0.70 2.5 Universal 5/pk CP8009
2.5 0.53/0.25 5/pk CP8135
2.5 0.53/0.32 5/pk CP8134
4.0 Universal 3/pk CP8015
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prosteel Deactivated
iD (mm) oD (mm) length (m) part no.
0.53 0.67 5 160-4535-5
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The highly efficient and rigorous packing technology used in Agilent J&W Packed GC Columns assures
column-to-column reproducibility and ultimate efficiency, while the UltiMetal treated stainless steel tubing
allows for improved inertness and peak shape performance.
You can choose from a wide range of tubing materials – including stainless steel, UltiMetal, nickel, glass,
copper and PTFE – plus hundreds of stationary phases, packings, and supports. All Agilent J&W Packed
GC Columns can bend to fit Agilent and non-Agilent instruments with no impact on performance.
Carbosieve s-ii
length oD (in) iD (mm) Mesh ultiMetal stainless steel
20 in (0.51 m) 1/8 2 80/100 G3591-81105 G3591-80105
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Carboxen-1000
length oD (in) iD (mm) Mesh ultiMetal stainless steel
10 ft (3.05 m) 1/8 2 60/80 G3591-81055 G3591-80055
Chromosorb 101
length oD (in) iD (mm) Mesh ultiMetal stainless steel
6 ft (1.83 m) 1/8 2 80/100 G3591-81021 G3591-80021
Chromosorb 102
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
2 ft (0.61 m) 1/8 2 80/100 G3591-81139 G3591-80139 G3591-82139
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30% DC 200/500
length oD (in) iD (mm) support Mesh ultiMetal stainless steel
2 ft (0.61 m) 1/8 2 Chromosorb PAW 60/80 G3591-81160 G3591-80160
30 ft (9.14 m) 1/8 2 Chromosorb PAW 60/80 G3591-81161 G3591-80161
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hayesep A
length oD (in) iD (mm) Mesh ultiMetal
1.31 ft (0.4 m) 1/8 2.1 80/100 G3591-81211**
2 ft (0.61 m) 1/16 1 80/100 G3591-81212*
5 ft (1.52 m) 1/8 2.1 80/100 G3591-81210*
5.58 ft (1.7 m) 1/16 1 80/100 G3591-81213*
*Specially coiled for Large Valve Oven, 41 mm mandrel
**Specially coiled for Large Valve Oven, 25 mm mandrel
hayesep D
length oD (in) iD (mm) Mesh stainless steel
6.56 ft (2 m) 1/8 2 80/100 G3591-80158
hayesep DB
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
30 ft (9.14 m) 1/8 2 100/120 G3591-81088 G3591-80088 G3591-82088
hayesep n
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
1.64 ft (0.5 m) 1/8 2 80/100 G3591-81156 G3591-80156
1.64 ft (0.5 m) 1/16 1 80/100 CP1307*
6 ft (1.83 m) 1/8 2 80/100 G3591-81037 G3591-80037 G3591-82037
6 ft (1.83 m) 1/8 2 80/100 CP2068*
7 ft (2.13 m) 1/8 2 60/80 G3591-81060 G3591-80060
8 ft (2.44 m) 1/8 2 80/100 G3591-81011 G3591-80011 G3591-82011
20 ft (6.1 m) 1/8 2 80/100 G3591-81045 G3591-80045
*Preconditioned and pretested
hayesep p
length oD (in) iD (mm) Mesh ultiMetal
6 ft (1.83 m) 1/8 2 80/100 CP2062
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hayesep Q
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
0.82 ft (0.25 m) 1/16 1 80/100 CP1308*
1.64 ft (0.5 m) 1/8 2 80/100 G3591-81023 G3591-80023 G3591-82023
1.64 ft (0.5 m) 1/8 2 80/100 CP81073*
3 ft (0.91 m) 1/8 2 80/100 G3591-81020 G3591-80020 G3591-82020
3.28 ft (1 m) 1/8 2 80/100 G3591-81146 G3591-70007
3.28 ft (1 m) 1/8 2 80/100 CP81069*
3.9 ft (1.2 m) 1/8 2 80/100 G3591-82159
4 ft (1.22 m) 1/8 2 80/100 G3591-81019 G3591-80019
4.92 ft (1.5 m) 1/16 1 80/100 CP1305*
5.91 ft (1.8 m) 1/8 2 80/100 G3591-70011
6 ft (1.83 m) 1/8 2 80/100 G3591-81004 G3591-80004 G3591-82004
6.56 ft (2 m) 1/8 2 80/100 G3591-70005
8 ft (2.44 m) 1/8 2 80/100 G3591-81047 G3591-80047
9 ft (2.74 m) 1/8 2 80/100 G3591-81033 G3591-80033 G3591-82033
9.84 ft (3 m) 1/8 2 80/100 G3591-70006
10 ft (3.05 m) 1/8 2 80/100 G3591-81002 G3591-80002 G3591-82002
12 ft (3.66 m) 1/8 2 80/100 G3591-81121 G3591-80121 G3591-82121
*Preconditioned and pretested
hayesep R
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
3.28 ft (1 m) 1/8 2 80/100 CP86678*
6 ft (1.83 m) 1/8 2 80/100 G3591-81102 G3591-80124 G3591-82102
8.53 ft (2.6 m) 1/8 2 80/100 CP86677*
12 ft (3.66 m) 1/8 2 80/100 G3591-81100 G3591-80100
12 ft (3.66 m) 1/8 2 80/100 CP2055*
*Preconditioned and pretested
hayesep T
length oD (in) iD (mm) Mesh ultiMetal pTFe
1.64 ft (0.5 m) 1/8 2 80/100 G3591-81143
1.64 ft (0.5 m) 1/8 2.4 60/80 G3591-74001
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Molsieve 5Å
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
1 ft (0.30 m) 1/8 2 60/80 G3591-81077 G3591-80077
1.64 ft (0.5 m) 1/8 2 60/80 G3591-81147
1.97 ft (0.6 m) 1/4 4 80/100 G3591-70004
3 ft (0.91 m) 1/8 2 60/80 G3591-81103 G3591-80103
3 ft (0.91 m) 1/8 2 80/100 G3591-81074 G3591-80074
3 ft (0.91 m) 1/8 2 100/120 G3591-81075 G3591-80075
3.28 ft (1 m) 1/8 2 80/100 G3591-70008
3.28 ft (1 m) 1/8 2 60/80 CP81025*
3.28 ft (1 m) 1/8 2 60/80 G3591-81149
4 ft (1.22 m) 1/8 2 45/60 G3591-81090 G3591-80090
4 ft (1.22 m) 1/8 2 60/80 G3591-81104 G3591-80104 G3591-82104
4.92 ft (1.5 m) 1/16 1 80/100 CP1306*
5 ft (1.52 m) 1/8 2 80/100 CP2046
6 ft (1.83 m) 1/8 2 45/60 CP2065
6 ft (1.83 m) 1/8 2 60/80 G3591-81017 G3591-80017 G3591-82017
6.56 ft (2 m) 1/8 2 45/60 G3591-70013
6.56 ft (2 m) 1/8 2 60/80 G3591-70002
6.56 ft (2 m) 1/8 2 80/100 G3591-70003
7 ft (2.13 m) 1/8 2 45/60 G3591-81062 G3591-80062
7 ft (2.13 m) 1/8 2.1 60/80 G3591-81209**
8 ft (2.44 m) 1/8 2 60/80 G3591-81022 G3591-80022 G3591-82022
9 ft (2.74 m) 1/8 2 60/80 G3591-81046 G3591-80046
9 ft (2.74 m) 1/8 2 80/100 G3591-81064 G3591-80064 G3591-82064
10 ft (3.05 m) 1/8 2 80/100 CP2045
13.1 ft (4 m) 1/8 2 80/100 CP1483*
15 ft (4.57 m) 1/8 2 45/60 G3591-81061 G3591-80061
20 ft (6.1 m) 1/8 2 45/60 G3591-80107
20 ft (6.1 m) 1/8 2 60/80 G3591-81056 G3591-80056
25 ft (7.62 m) 1/8 2 60/80 G3591-81065 G3591-80065
*Preconditioned and pretested
**Specially coiled for Large Valve Oven, 41 mm mandrel
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Molsieve 13X
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
2 ft (0.61 m) 1/8 2 45/60 G3591-81031 G3591-80031
3 ft (0.91 m) 1/8 2 45/60 G3591-81028 G3591-80028
3 ft (0.91 m) 1/8 2 45/60 CP2059*
3.94 ft (1.2 m) 1/16 1 80/100 CP1309*
4 ft (1.22 m) 1/8 2 45/60 G3591-81012 G3591-80012 G3591-82012
4.9 ft (1.5 m) 1/8 2 80/100 G3591-81085 G3591-80085
4.92 ft (1.5 m) 1/8 2 80/100 CP81071*
6 ft (1.83 m) 1/8 2 60/80 G3591-81035 G3591-80035 G3591-82035
6.56 ft (2 m) 1/16 1 80/100 G3591-81214*
9 ft (2.74 m) 1/8 2 45/60 G3591-81054 G3591-80054
9.84 ft (3 m) 1/8 2 45/60 G3591-70017
9.84 ft (3 m) 1/8 2 80/100 G3591-70015
10 ft (3.05 m) 1/8 2 45/60 G3591-81003 G3591-80003 G3591-82003
10 ft (3.05 m) 1/16 1 60/80 G3591-81097 G3591-80097
10 ft (3.05 m) 1/8 2 60/80 G3591-81101 G3591-80101 G3591-82101
10 ft (3.05 m) 1/8 2 80/100 G3591-81043 G3591-80043 G3591-82043
12 ft (3.66 m) 1/8 2 60/80 G3591-81058 G3591-80058
15 ft (4.57 m) 1/8 2 45/60 G3591-81098 G3591-80098
*Preconditioned and pretested
**Specially coiled for Large Valve Oven, 41 mm mandrel
1.5% oV-101
length oD (in) iD (mm) support Mesh ultiMetal stainless steel
2 ft (0.61 m) 1/8 2 Chromosorb GHP 100/120 G3591-81162 G3591-80162
10% oV-101
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
2.6 ft (0.79 m) 1/8 2 Chromosorb WHP 60/80 G3591-81048 G3591-80048 G3591-82048
5 ft (1.52 m) 1/8 2 Chromosorb PAW 80/100 G3591-81093 G3591-80093 G3591-82093
20% oV-101
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
4 ft (1.22 m) 1/8 2 Chromosorb WHP 80/100 G3591-81025 G3591-80025 G3591-82025
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10% peg-20M
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
6.56 ft (2 m) 1/8 2 Chromosorb W 80/100 G3591-81119 G3591-80119 G3591-82119
20% peg-20M
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
6.56 ft (2 m) 1/8 2 Chromosorb W 80/100 G3591-81122 G3591-80122 G3591-82122
13.1 ft (4 m) 1/8 2 Chromosorb W 80/100 G3591-81123 G3591-80123 G3591-82123
porapak n
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
3 ft (0.91 m) 1/8 2 80/100 G3591-81072 G3591-80072 G3591-82072
3.9 ft (1.2 m) 1/8 2 60/80 G3591-81087 G3591-80087 G3591-82087
6 ft (1.83 m) 1/8 2 80/100 G3591-81036 G3591-80036 G3591-82036
8.2 ft (2.5 m) 1/8 2 50/80 G3591-81086 G3591-80086
9 ft (2.74 m) 1/8 2 80/100 G3591-81044 G3591-80044 G3591-82044
12 ft (3.66 m) 1/8 2 60/80 G3591-81059 G3591-80059
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porapak Q
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
3 ft (0.91 m) 1/8 2 80/100 G3591-81135 G3591-80135 G3591-82135
3.28 ft (1 m) 1/8 2 80/100 G3591-70014
5.91 ft (1.8 m) 1/8 2 80/100 G3591-70010
6 ft (1.83 m) 1/8 2 60/80 G3591-81136 G3591-80136 G3591-82136
6 ft (1.83 m) 1/8 2 80/100 G3591-81013 G3591-80013 G3591-82013
6.56 ft (2 m) 1/8 2 80/100 G3591-70001
8 ft (2.44 m) 1/8 2 60/80 G3591-81137 G3591-80137 G3591-82137
8.2 ft (2.5 m) 1/8 2 80/100 G3591-81083 G3591-80083
9 ft (2.74 m) 1/8 2 80/100 G3591-81016 G3591-80016 G3591-82016
9.84 ft (3 m) 1/8 2 80/100 G3591-70009
13 ft (3.96 m) 1/8 2 80/100 G3591-81053 G3591-80053 G3591-82053
15 ft (4.57 m) 1/8 2 80/100 G3591-81066 G3591-80066
25 ft (7.62 m) 1/8 2 100/120 G3591-81052 G3591-80052
30 ft (9.14 m) 1/16 1 80/100 G3591-81096 G3591-80096
porapak Qs
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
4.92 ft (1.5 m) 1/8 2 50/80 G3591-70018
6.56 ft (2 m) 1/8 2 80/100 G3591-81157 G3591-80157
8 ft (2.44 m) 1/8 2 80/100 G3591-81051 G3591-80051 G3591-82051
porapak R
length oD (in) iD (mm) Mesh ultiMetal stainless steel nickel
6 ft (1.83 m) 1/8 2 60/80 G3591-81106 G3591-80106 G3591-82106
porapak T
length oD (in) iD (mm) Mesh ultiMetal stainless steel
1.5 ft (0.46 m) 1/8 2 80/100 G3591-81138 G3591-80138
6.56 ft (2 m) 1/8 2 80/100 G3591-81120 G3591-80120
10% se-30
length oD (in) iD (mm) support Mesh ultiMetal
2.5 ft (0.76 m) 1/8 2 Chromosorb W 80/100 CP2073
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20% sebaconitrile
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
2 ft (0.61 m) 1/8 2 Chromosorb PAW 80/100 G3591-81029 G3591-80029 G3591-82029
19.7 ft (6 m) 1/8 2 Chromosorb PAW 80/100 G3591-81071 G3591-80071
30 ft (9.14 m) 1/8 2 Chromosorb PAW 60/80 G3591-81176 G3591-80176 G3591-82176
30 ft (9.14 m) 1/8 2 Chromosorb PAW 80/100 G3591-81026 G3591-80026 G3591-82026
silica gel
length oD (in) iD (mm) Mesh ultiMetal stainless steel
2 ft (0.61 m) 1/8 2 60/80 G3591-81141 G3591-80141
4 ft (1.22 m) 1/8 2 60/80 G3591-81142 G3591-80142
6 ft (1.83 m) 1/8 2 60/80 G3591-80108
10 ft (3.05 m) 1/8 2 60/80 CP2050
0.1% sp-1000
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
7 ft (2.13 m) 1/8 2 Carbopak C 80/100 G3591-81063 G3591-80063 G3591-82063
15% sp-2100
length oD (in) iD (mm) support Mesh stainless steel
1.64 ft (0.5 m) 1/16 1 Chromosorb PAW 80/100 G3591-80170
7.22 ft (2.2 m) 1/16 1 Chromosorb PAW 80/100 G3591-80171
25% sp-2100
length oD (in) iD (mm) support Mesh ultiMetal stainless steel
1.64 ft (0.5 m) 1/16 1 Chromosorb PAW 80/100 G3591-81007 G3591-80007
5.7 ft (1.75 m) 1/16 1 Chromosorb PAW 80/100 G3591-81008 G3591-80008
15 ft (4.57 m) 1/8 2 Chromosorb PAW 80/100 G3591-81068 G3591-80068
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20% TCep
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
1.84 ft (0.56 m) 1/16 0.75 Chromosorb PAW 80/100 G3591-81215*
1.84 ft (0.56 m) 1/16 1 Chromosorb PAW 80/100 G3591-81006 G3591-80006
5 ft (1.52 m) 1/8 2 Chromosorb PAW 80/100 G3591-81094 G3591-80094
15 ft (4.57 m) 1/8 2 Chromosorb PAW 80/100 G3591-81049 G3591-80049 G3591-82049
* Specially coiled for Large Valve Oven, 41 mm mandrel
10% uC W982
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
1.5 ft (0.46 m) 1/8 2 Chromosorb PAW 80/100 G3591-81034 G3591-80034
2 ft (0.61 m) 1/8 2 Chromosorb PAW 80/100 G3591-81040 G3591-80040 G3591-82040
12% uC W982
length oD (in) iD (mm) support Mesh ultiMetal stainless steel nickel
2 ft (0.61 m) 1/8 2 Chromosorb PAW 80/100 G3591-81000 G3591-80000 G3591-82000
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• We can create DuraGuard or EZ-Guard columns with an integrated guard column (retention gap).
Most phases can be manufactured with a built-in guard column, which means you get the advantages
of a guard column without the union. Available in DB, CP and VF phases.
Custom columns are ordered using the p/ns below. Be sure to provide the details of your desired custom
service or column including phase, length, id, and film thickness.
Customers in the United States, Canada, and Puerto Rico can request
a custom column quote online at www.agilent.com/chem/CustomColumn
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In this section, you’ll discover tips, techniques, and easy reference guides that will help you:
• Confidently install any capillary column
• Condition and test new columns
• Alleviate and avoid column performance degradation due to thermal damage, oxygen damage,
and other factors
• Pinpoint and fix the most common column problems
So you’ll expand your hours of continuous operation, decrease downtime, and get the reproducible results
that your lab demands.
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5. Make a clean break. Grasp the column between the thumb and forefinger as close to the score point
as possible. Gently pull and bend the column. The column should part easily. If the column does not
break easily, do not force it. Score the column again in a different place (farther from the end than
before) and try again for a clean break.
6. Use a magnifying loupe to inspect the cut. Make sure the cut is square across the tubing with no
polyimide or "glass" fragments at the end of the tube.
7. Install the column in the inlet. Check the GC manufacturer’s instrument manual for the correct insertion
distance in the injection port type being used. Slide the column nut and ferrule to the proper distance
and then mark the correct distance on the column with typewriter correction fluid just behind the
column nut. Allow the fluid to dry. Insert the column into the injector. Finger tighten the column nut until
it starts to grab the column, and then tighten the nut an additional 1/4 to 1/2 turn, so that the column
cannot be pulled from the fitting when gentle pressure is applied. Verify that the correct column
insertion distance has been maintained by looking at the typewriter correction fluid mark.
8. Turn on the carrier gas and establish the proper flow rate. Set head pressure, split flow, and septum
purge flow to appropriate levels. See Table 7 for nominal head pressures. If fusing a split/splitless inlet,
check that the purge (split) valve is "on" (open).
9. Confirm carrier gas flow through the column. Immerse the end of the column in a vial of solvent
and check for bubbles.
10. Install the column into the detector. Check the instrument manufacturer’s manual for the proper
insertion distance.
11. Check for leaks. This is very important. Do not heat the column without thoroughly checking
for leaks.
12. Establish proper injector and detector temperatures.
13. Establish proper makeup and detector gas flows. Ignite or turn "on" the detector.
Tips & Tools 14. Purge the column for a minimum of 10 min at ambient temperature. Add the appropriate additional
Learn more about Agilent’s top-ranked purge time following inlet or trap maintenance.
service and support at 15. Inject non-retained substance to check for proper injector installation. Examples: butane or methane
www.agilent.com/chem/services (FID), headspace vapors from acetonitrile (NPD), headspace vapors from methylene chloride (ECD),
air (TCD), argon (mass spectrometer). Proper installation is indicated by a symmetrical non-retained
peak. If tailing is observed, reinstall the column into the inlet.
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Table 7:
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Column Breakage
Fused silica columns break wherever there is a weak point in the polyimide coating. The polyimide coating
protects the fragile but flexible fused silica tubing. The continuous heating and cooling of the oven,
vibrations caused by the oven fan, and being wound on a circular cage all place stress on the tubing.
Eventually breakage occurs at a weak point. Weak spots are created where the polyimide coating is
scratched or abraded. This usually occurs when a sharp point or edge is dragged over the tubing.
Column hangers and tags, metal edges in the GC oven, column cutters, and miscellaneous items on
the lab bench are just some of the common sources of sharp edges or points.
It is rare for a column to spontaneously break. Column manufacturing practices tend to expose any weak
tubing and eliminate it from use in finished columns. Larger diameter columns are more prone to breakage.
This means that greater care and prevention against breakage must be taken with 0.45-0.53 mm id tubing
than with 0.18-0.32 mm id tubing.
A broken column is not always fatal. If a broken column was maintained at a high temperature either
continuously or with multiple temperature program runs, damage to the column is very likely. The back half
of the broken column has been exposed to oxygen at elevated temperatures which rapidly damages the
stationary phase. The front half is fine since carrier gas flowed through this length of column. If a broken
column has not been heated or only exposed to high temperatures or oxygen for a very short time, the back
half has probably not suffered any significant damage.
A union can be installed to repair a broken column. Any suitable union will work to rejoin the column.
Problems with dead volume (peak tailing) may occur with improperly installed unions.
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Thermal Damage
Exceeding a column’s upper temperature limit results in accelerated degradation of the stationary phase
and tubing surface. This results in the premature onset of excessive column bleed, peak tailing for active
compounds and/or loss of efficiency (resolution). Fortunately, thermal damage is a slower process, thus
prolonged times above the temperature limit are required before significant damage occurs. Thermal
damage is greatly accelerated in the presence of oxygen. Overheating a column with a leak or high oxygen
levels in the carrier gas results in rapid and permanent column damage.
Setting the GC’s maximum oven temperature at or only a few degrees above the column’s temperature
limit is the best method to prevent thermal damage. This prevents the accidental overheating of the column.
If a column is thermally damaged, it may still be functional. Remove the column from the detector. Heat
the column for 8-16 hours at its isothermal temperature limit. Remove 10-15 cm from the detector end
of the column. Reinstall the column and condition as usual. The column usually does not return to its
original performance; however, it is often still functional. The life of the column will be reduced after
thermal damage.
oxygen Damage
Oxygen is an enemy to most capillary GC columns. While no column damage occurs at or near ambient
temperatures, severe damage occurs as the column temperature increases. In general, the temperature and
oxygen concentration at which significant damage occurs is lower for polar stationary phases. It is constant
exposure to oxygen that is the problem. Momentary exposure such as an injection of air or a very short
duration septum nut removal is not a problem.
A leak in the carrier gas flow path (e.g., gas lines, fittings, injector) is the most common source of
oxygen exposure. As the column is heated, very rapid degradation of the stationary phase occurs.
This results in the premature onset of excessive column bleed, peak tailing for active compounds and/or
loss of efficiency (resolution). These are the same symptoms as for thermal damage. Unfortunately, by the
time oxygen damage is discovered, significant column damage has already occurred. In less severe cases,
the column may still be functional but at a reduced performance level. In more severe cases, the column
is irreversibly damaged.
Maintaining an oxygen and leak-free system is the best prevention against oxygen damage. Good GC
system maintenance includes periodic leak checks of the gas lines and regulators, regular septa changes,
using high quality carrier gases, installing and changing oxygen traps, and changing gas cylinders before
they are completely empty.
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Chemical Damage
There are relatively few compounds that damage stationary phases. Introducing nonvolatile compounds
(e.g., salts) in a column often degrades performance, but damage to the stationary phase does not occur.
These residues can often be removed and performance returned by solvent rinsing the column.
Inorganic or mineral bases and acids are the primary compounds to avoid introducing into a column.
The acids include hydrochloric (HCl), sulfuric (H2S04), nitric (HNO3), phosphoric (H3PO4), and chromic
(CrO3). The bases include potassium hydroxide (KOH), sodium hydroxide (NaOH), and ammonium
hydroxide (NH4OH). Most of these acids and bases are not very volatile and accumulate at the front of the
column. If allowed to remain, the acids or bases damage the stationary phase. This results in the premature
onset of excessive column bleed, peak tailing for active compounds and/or loss of efficiency (resolution).
The symptoms are very similar to thermal and oxygen damage. Hydrochloric acid and ammonium hydroxide
are the least harmful of the group. Both tend to follow any water that is present in the sample. If the water
is not or only poorly retained by the column, the residence time of the HCl and NH4OH in the column is
short. This tends to eliminate or minimize any damage by these compounds. Thus, if HCl or NH4OH are
present in a sample, using conditions or a column with no water retention will render these compounds
relatively harmless to the column.
The only organic compounds that have been reported to damage stationary phases are perfluoroacids.
Examples include trifluoroacetic, pentafluoropropanoic, and heptafluorobutyric acid. They need to be
present at high levels (e.g., 1% or higher). Most of the problems are experienced with splitless or megabore
direct injections where large volumes of the sample are deposited at the front of the column.
Since chemical damage is usually limited to the front of the column, trimming or cutting 0.5-1 m from the
front of the column often eliminates any chromatographic problems. In more severe cases, five or more
meters may need to be removed. The use of a guard column or retention gap will minimize the amount of
column damage; however, frequent trimming of the guard column may be necessary. The acid or base
often damages the surface of the deactivated fused silica tubing which leads to peak shape problems for
active compounds.
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Column Contamination
Column contamination is one of the most common problems encountered in capillary GC. Unfortunately,
it mimics a very wide variety of problems and is often misdiagnosed as another problem. A contaminated
column is usually not damaged, but it may be rendered useless.
There are two basic types of contaminants: nonvolatile and semivolatile. Nonvolatile contaminants or
residues do not elute and accumulate in the column. The column becomes coated with these residues
which interfere with the proper partitioning of solutes in and out of the stationary phase. Also, the residues
may interact with active solutes resulting in peak adsorption problems (evident as peak tailing or loss of
peak size). Active solutes are those containing a hydroxyl (-OH) or amine (-NH) group, and some thiols (-SH)
and aldehydes. Semivolatile contaminants or residues accumulate in the column, but eventually elute. Hours
to days may elapse before they completely leave the column. Like nonvolatile residues, they may cause
peak shape and size problems, and, in addition, are usually responsible for many baseline problems
(instability, wander, drift, ghost peaks, etc.).
Contaminants originate from a number of sources, with injected samples being the most common. Extracted
samples are among the worst types. Biological fluids and tissues, soils, waste and ground water, and similar
types of matrixes contain high amounts of semivolatile and nonvolatile materials. Even with careful and
thorough extraction procedures, small amounts of these materials are present in the injected sample.
Several to hundreds of injections may be necessary before the accumulated residues cause problems.
Injection techniques such as on-column, splitless, and megabore direct place a large amount of sample
into the column, thus column contamination is more common with these injection techniques.
Occasionally, contaminants originate from materials in gas lines and traps, ferrule and septa particles,
or anything coming in contact with the sample (vials, solvents, syringes, pipettes, etc.). These types of
contaminants are probably responsible when a contamination problem suddenly develops and similar
samples in previous months or years did not cause any problems.
Minimizing the amount of semivolatile and nonvolatile sample residues is the best method to reduce
contamination problems. Unfortunately, the presence and identity of potential contaminants are often
unknown. Rigorous and thorough sample cleanup is the best protection against contamination problems.
The use of a guard column or retention gap often reduces the severity or delays the onset of column
Tips & Tools
contamination induced problems. If a column becomes contaminated, it is best to solvent rinse the column Column contamination from sample
to remove the contaminants. matrix components is the number one
cause of column failure. Use Agilent
Maintaining a contaminated column at high temperatures for long periods of time (often called baking-out DuraGuard GC columns with built-in
a column) is not recommended. Baking-out a column may convert some of the contaminating residues into guard if you do not want to use
insoluble materials that cannot be solvent rinsed from the column. If this occurs, the column cannot be column connectors.
salvaged in most cases. Sometimes the column can be cut in half and the back half may still be useable.
Baking-out a column should be limited to 1-2 hours at the isothermal temperature limit of the column.
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Before rinsing a column, cut about 0.5 meter from the front (i.e., injector end) of the column. Insert the
detector end of the column into the rinse kit. Multiple solvents are normally used to rinse columns. Each
successive solvent must be miscible with the previous one. High boiling point solvents should be avoided
especially as the last solvent. The sample matrix solvent(s) is often a good choice.
Methanol, methylene chloride and hexane are recommended and work very well for the majority of cases.
Acetone can be substituted for methylene chloride to avoid using halogenated solvents; however,
methylene chloride is one of the best rinsing solvents. If aqueous based samples (e.g., biological fluids and
tissues) were injected, use water before the methanol. Some residues originating from aqueous based
samples are only soluble in water and not organic solvents. Water and alcohols (e.g., methanol, ethanol,
isopropanol) should be used to rinse bonded polyethylene glycol based stationary phases (e.g., DB-WAX,
DB-WAXetr, DB-FFAP, HP-INNOWax) only as a last resort.
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Table 8 lists the suggested solvent volumes for different diameter columns. Using larger solvent volumes is
not harmful, but rarely better and merely wasteful. After adding the first solvent, pressurize the rinse kit, but Table 8:
stay below 20 psi. Use the highest pressure that keeps the solvent flow rate below 1 mL/min. Except for
most 0.53 mm id columns, the rinse kit pressure will reach 20 psi before the flow rate reaches 1 mL/min.
solvent Volumes
Longer rinse times are required when using heavy or viscous solvents, and for longer or smaller diameter
for Rinsing Columns
columns. When all or most of the first solvent has entered the column, add the next solvent. The previous Column iD solvent Volume
solvent does not have to vacate the column before the next solvent is started through the column. (mm) (ml)
0.18-0.2 3-4
After the last solvent has left the column, allow the pressurizing gas to flow through the column for 0.25 4-5
5-10 min. Install the column in the injector and turn on the carrier gas. Allow the carrier gas to flow through 0.32 6-7
the column for 5-10 min. Attach the column to the detector (or leave it unattached if preferred). Using a
0.45 7-8
temperature program starting at 40-50 °C, heat the column at 2-3 °/min until the upper temperature limit
0.53 10-12
is reached. Maintain this temperature for 1-4 hours until the column is fully conditioned.
Using larger volumes will not damage
the column
Column storage
Capillary columns should be stored in their original box when removed from the GC. Place a GC septa over
the ends to prevent debris from entering the tubing. Upon reinstallation of the column, the column ends
need to be trimmed by 2-4 cm to ensure that a small piece of septa is not lodged in the column.
If a column is left in a heated GC, there should always be carrier gas flow. The carrier gas flow can be
turned off only if the oven, injector, detector and transfer lines are turned off (i.e., not heated). Without
carrier gas flow, damage to the heated portion of the column occurs.
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• Gases: pressures, carrier gas average linear velocity, and flow rates (detector, split vent, septum purge)
• Temperatures: column, injector, detector, and transfer lines
• System parameters: purge activation times, detector attenuation and range, mass ranges, etc.
• Gas lines and traps: cleanliness, leaks, and expiration
• Injector consumables: septa, liners, O-rings, and ferrules
• Sample integrity: concentration, degradation, solvent, and storage
• Syringes: handling technique, leaks, needle sharpness, and cleanliness
• Data system: settings and connections
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Increasing the final temperature or time in the temperature program is one method to minimize or eliminate
a ghost peak problem. Alternatively, a short bake out after each run or series of runs may remove the highly
retained compounds from the column before they cause a problem.
Condensation Test
Use this test whenever injector or carrier gas contamination problems are suspected (e.g., ghost peaks
or erratic baseline).
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Troubleshooting Guides
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Tailing peaks
possible Cause solution Comments
Column contamination Trim the column Remove 0.5-1 m from the front of the column
Solvent rinse the column Only for bonded and cross-linked phases
Check for inlet contamination
Column activity Irreversible; replace the column Only affects active compounds
Solvent-phase polarity mismatch Change sample solvent More tailing for the early eluting peaks or those closest
to a single solvent to the solvent front
Use a retention gap 3-5 m retention gap is sufficient
Solvent effect violation for splitless Decrease the initial column Peak tailing decreases with retention
or on-column injections temperature
Too low of a split ratio Increase the split ratio Flow from split vent should be 20 mL/min or higher
Poor column installation Reinstall the column More tailing for early eluting peaks
Some active compounds always tail None Most common for amines and carboxylic acids
split peaks
possible Cause solution Comments
Injection technique Change technique Usually related to erratic plunger depression or having sample
in the syringe needle; Use an auto injector
Mixed sample solvent Change sample solvent Worse for solvents with large differences in polarity or boiling points
to a single solvent
Poor column installation Reinstall the column Usually a large error in the insertion distance
Sample degradation in the injector Reduce the injector temperature Peak broadening or tailing may occur if the temperature is too low
Change to an Requires an on-column injector
on-column injection
Poor sample focusing Use a retention gap For splitless and on-column injection
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loss of Resolution
possible Cause solution Comments
Decrease in separation
Different column temperature Check the column temperature Differences in other peaks will be visible
Different column dimensions or phase Verify column identity Differences in other peaks will be visible
Coelution with another peak Change column temperature Decrease column temperature and check for the appearance of a peak
shoulder or tail
increase in peak width
Change in carrier gas velocity Check the carrier gas velocity A change in the retention time also occurs
Column contamination Trim the column Remove 0.5-1 m from the front of the column
Solvent rinse the column Only for bonded and cross-linked phases
Change in the injector Check the injector settings Typical areas: split ratio, liner, temperature, injection volume
Change in sample concentration Try a different sample concentration Peak widths increase at higher concentrations
Improper solvent effect, lack of focusing Lower oven temperature, better solvent, For splitless injection
sample phase polarity match, use a
retention gap
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PART NUMBER INDEX
652
PART NUMBER INDEX
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PART NUMBER INDEX
654
PART NUMBER INDEX
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PART NUMBER INDEX
656
PART NUMBER INDEX
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PART NUMBER INDEX
658
PART NUMBER INDEX
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PART NUMBER INDEX
660
PART NUMBER INDEX
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PART NUMBER INDEX
662
PART NUMBER INDEX
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PART NUMBER INDEX
664
PART NUMBER INDEX
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PART NUMBER INDEX
666
PART NUMBER INDEX
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PRODUCT INDEX
Product Index
Agilent J&W GC Columns CP-Sil PONA CB.........................................................368 DX-1...............................................................................443
CP-Sil PONA for ASTM D5134 ...............................368 DX-4...............................................................................443
Application and Method Guides CP-SilicaPLOT .............................................................435 GS-Alumina..................................................................433
ASTM Methods ....................................................278-285 CP-SimDist...........................................................371-372 GS-Alumina KCl ..........................................................429
Application Cross Reference Guide.................262-264 CP-TAP CB for Triglycerides ....................................409 GS-CarbonPLOT..........................................................437
EPA Methods CP-TCEP for Alcohols in Gasoline..........................373 GS-GasPro....................................................................434
Drinking Water....................................................265-268 CP-Volamine ................................................................381 GS-OxyPLOT................................................................366
Solid Waste .........................................................272-276 CP-Wax 52 CB.....................................................356-357 GS-Q ..............................................................................426
Waste Water.......................................................269-271 CP-Wax 57 CB.............................................................408 HP-1.......................................................................322-323
United States Pharmacopoeia (USP) CP-Wax 57 CB for Glycols and Alcohols..............409 HP-1 Aluminum Clad.................................................369
GC Phases......................................................................277 CP-Wax 58 FFAP CB..................................................360 HP-101 ..........................................................................441
Capillary Columns CP-Wax for Volatile Amines and Diamines .........382 HP-17.............................................................................441
By Group CycloSil-B.....................................................................410 HP-1ms .........................................................................296
Foods, Flavors and Fragrances ...............................405 Cyclodex-B...................................................................411 HP-1ms Ultra Inert.....................................................289
High Temperature.......................................................362 DB-1 ......................................................................318-321 HP-20M.........................................................................361
Life Sciences...............................................................414 DB-1301........................................................................347 HP-35.............................................................................338
Low-bleed GC/MS.....................................................294 DB-17 ............................................................................339 HP-5.......................................................................332-333
Non-Bonded................................................................441 DB-1701........................................................................349 HP-50+..........................................................................340
PAH................................................................................390 DB-1701P .....................................................................386 HP-5ms .........................................................................301
PLOT..............................................................................420 DB-17ht ........................................................................364 HP-5ms Semivolatile .................................................395
Pesticides.....................................................................384 DB-17ms.......................................................................308 HP-5ms Ultra Inert.....................................................290
Petroleum.....................................................................366 DB-1ht...........................................................................362 HP-88.............................................................................405
Polyethylene Glycol (PEG) ...............................351-413 DB-1ms.........................................................................295 HP-Chiral b ..................................................................411
Premium Polysiloxane ..............................................318 DB-1ms Ultra Inert.....................................................289 HP-FFAP .......................................................................359
Semivolatiles...............................................................392 DB-200..........................................................................343 HP-Fast Residual Solvent.........................................416
Ultra Inert.....................................................................286 DB-210..........................................................................344 HP-INNOWax ..............................................................355
Volatiles........................................................................397 DB-225..........................................................................345 HP-PAS5 .......................................................................388
By Stationary Phase DB-225ms ....................................................................312 HP-PLOT Al2O3 KCl...................................................428
Biodiesel...............................................................377-378 DB-23 ............................................................................342 HP-PLOT Al2O3 M .....................................................434
CAM ..............................................................................442 DB-2887........................................................................370 HP-PLOT Al2O3 S.......................................................432
CarboBOND.................................................................436 DB-35 ............................................................................337 HP-PLOT Molesieve ..................................................438
CarboPLOT P7.............................................................436 DB-35ms.......................................................................306 HP-PLOT Q...................................................................425
Carbowax 20M and HP-20M...................................361 DB-35ms Ultra Inert ..................................................291 HP-PLOT U...................................................................428
CP-1301.........................................................................348 DB-5 ......................................................................329-331 HP-PONA .....................................................................367
CP-Al2O3/KCl......................................................430-431 DB-5.625.......................................................................394 HP-VOC .........................................................................401
CP-Al2O3/Na2SO4 ............................................430-431 DB-502.2.......................................................................402 Lowox............................................................................366
CP-Carbowax 400 for Volatiles in Alcohol ...........408 DB-5ht...........................................................................363 PoraBOND Q ...............................................................422
CP-Chirasil Val.............................................................412 DB-5ms.................................................................299-300 PoraBOND U ...............................................................423
CP-Chirasil-Dex CB ....................................................412 DB-5ms EVDX.............................................................415 PoraPLOT Amines......................................................383
CP-Cyclodextrin-b-2,3,6-M-19 .................................413 DB-5ms Ultra Inert.....................................................290 PoraPLOT Q.................................................................424
CP-FFAP CB for Free Fatty Acids DB-608..........................................................................388 PoraPLOT Q-HT ..........................................................424
in Dairy Products........................................................410 DB-624..........................................................................398 PoraPLOT S .................................................................427
CP-Molsieve 5Å..........................................................439 DB-624 Ultra Inert.............................................291, 397 PoraPLOT U.................................................................427
CP-Select 624 CB.......................................................399 DB-ALC1.......................................................................414 Rapid-MS .....................................................................389
CP-Select CB for MTBE............................................403 DB-ALC2.......................................................................414 SE-30 .............................................................................444
CP-Sil 13 CB ................................................................336 DB-CLP1.......................................................................384 SE-54 .............................................................................444
CP-Sil 19 CB ................................................................350 DB-CLP2.......................................................................384 Select Al2O3 MAPD..................................................376
CP-Sil 19 CB for Pesticides .....................................387 DB-Dioxin.....................................................................396 Select Biodiesel..........................................................379
CP-Sil 2 CB ..................................................................373 DB-EUPAH ...................................................................390 Select FAME................................................................407
CP-Sil 24 CB ................................................................341 DB-FFAP.......................................................................358 Select Low Sulfur.......................................................375
CP-Sil 43 CB ................................................................346 DB-HT SimDis.............................................................370 Select Mineral Oil ......................................................404
CP-Sil 5 CB ..........................................................324-326 DB-MTBE.....................................................................402 Select PAH...................................................................390
CP-Sil 5 CB for Formaldehyde.................................367 DB-Petro.......................................................................369 Select Silanes .............................................................380
CP-Sil 5 CB for Sulfur................................................375 DB-Select 624 UI for <467>...........................292, 416 Select for Permanent Gases ...................................376
CP-Sil 5/C18 CB for PCB .........................................395 DB-Sulfur SCD ............................................................374 Ultra 1 ...........................................................................327
CP-Sil 8 CB ..........................................................334-335 DB-TPH .........................................................................403 Ultra 2 ...........................................................................328
CP-Sil 8 CB for Amines.............................................382 DB-UI 8270D Ultra Inert ...........................................292 VF-1301ms ...........................................................315-316
CP-Sil 8 CB for PCB...................................................393 DB-UI 8270D for Semivolatiles ...............................392 VF-1701 Pesticides ....................................................386
CP-Sil 8 CB for Pesticides........................................387 DB-VRX.........................................................................400 VF-1701ms ...................................................................317
CP-Sil 88.......................................................................406 DB-WAX...............................................................351-353 VF-17ms........................................................................309
CP-Sil 88 for Dioxins..................................................396 DB-WAX FF..........................................................351-353 VF-1ms..................................................................297-298
CP-Sil 88 for FAME ....................................................407 DB-WAXetr..................................................................354 VF-200ms .....................................................................311
CP-Sil PAH CB UltiMetal..........................................391 DB-XLB .........................................................................304 VF-23ms........................................................................310
668
PRODUCT INDEX
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PRODUCT INDEX
670
APPLICATION TITLE INDEX
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APPLICATION TITLE INDEX
672
COMPOUND INDEX
Compound Index
A tert-Amyl mercaptan.................................................592 Benzothiophene..............................................................593
tert-Amyl methyl ether (TAME)...515, 546, 581, 595, Benzphetamine ......................................................636, 641
Acenaphthalene ........................................................540 599, 600, 619 Benz[a]pyrene .................................................................505
Acenaphthalene-d10.................................................519 n-Amyl salicylate ...............................................558-560 Benzyl acetate...............................558-560, 566, 617-618
Acenaphthene .................................503, 532, 538, 540 5α-Androstan-17α-ol-3-one (stanolone) ..............648 Benzyl alcohol ............538, 558-559, 561, 563, 602, 605
Acenaphthene-d10 ..................................518, 538, 542 Androsterone .............................................................648 Benzylamine ............................................................609-610
Acenaphthylene...............................503, 518, 532, 538 5-b-Androsterone......................................................648 Benzyl benzoate..................539, 558-561, 563, 566, 569
Acephate............................................................531, 562 Aniline ...............................................538, 542, 610, 629 Benzyl butyl phthalate...................................................518
Acetal (acetaldehyde diethyl acetal).....................619 Anisic alcohol ............................................................561 Benzyl chloride..............................................515, 544, 553
Acetaldehyde .........................550, 553, 568, 581, 600, Anisyl alcohol ............................................................563 Benzyl cinnamate..................................................561, 563
612, 625, 638, 649-650 Antazoline...................................................................644 Benzyl ether.....................................................................619
Acetaminophen.................................................641, 647 Anthracene ..............................503, 518, 532, 538, 540 n-Benzylmethylamine....................................................610
Acetic acid...............................509, 568, 570, 607, 611 Anthracene-d10 .........................................................519 Benzyl salicylate ..........................558, 560-561, 563, 566
Acetone...........515, 517, 548, 550, 553-554, 558-559, Aprobarbital .......................................................637, 641 α-Bergamotene...............................................................556
568, 570, 581-582, 600, 612, 624-626, Arabinitol ....................................................................568 trans-α-Bergamotene....................................................564
632, 638-639, 649-650 Arabitol........................................................................569 α-BHC..506, 508, 511, 513-514, 518, 520-525, 529-530
Acetone-d6 .................................................................550 Arachidic acid (eicosanoic acid) ............................570 b-BHC..506, 508, 511, 513-514, 518, 520-525, 529-530
Acetonitrile...............515, 624-627, 635, 639, 649-651 Arachidic acid methyl ester............................572, 573 δ-BHC ..506, 508, 511, 513-514, 518, 520-525, 529-530
Acetyl aldehyde .........................................................554 Arachidonic acid methyl ester .......................572, 573 γ-BHC...506, 508, 511, 513-514, 518, 520-525, 529-530
Acetylcedrene............................................................560 Argon ..................................................................552, 582 BHEB .................................................................................633
6-Acetylcodeine ................................................637, 647 Arsine .........................................................................633 BHT ..................................................................561, 567, 633
Acetylene ...................................................580, 584-590 Atraton ................................................................525-526 Bifenthrin..........................................................................519
Acetylsalicylic acid (aspirin) ...................................647 Atrazine .............................511, 518-520, 525-527, 542 Bioallethrin.......................................................................519
Acifluorofen................................................................512 Azinphos-ethyl ...........................................................562 Biphenyl............................................................................540
Acrolein..............................................515, 612, 626-627 Azinphos methyl ...............................................531, 562 b-Bisabolene..................................................559, 564, 566
Acrylamide..................................................................610 Azobenzene................................................................538 α-Bisabolol.......................................................................556
Acrylic acid.................................................................509 Azulene .......................................................................540 Borneol....................................................556, 558-560, 567
Acrylonitrile ..............................515, 517, 548, 626-627 Borneol acetate ..............................................................556
Air/CO........................................................577, 583, 601 Bornyl acetate.........................................................557-558
Alachlor............508, 511, 518, 520, 524-526, 529-530 B α-Bourbonene.................................................................555
Aldrin ...............................506, 508, 511, 513-514, 518, b-Bourbonene ........................................................555, 565
520-525, 529-530, 542 Balan..................................................................................527
Barbital..............................................................................637 BPE (PB)...........................................................................536
Alfentanyl ...................................................................645 Bromacil...................................................518-519, 525-527
Allobarbital ........................................................637, 641 BDE ...........................................................................505, 519
Behenic acid methyl ester ..................................572, 573 Bromazepam...........................................................636, 640
Allyl acrylate ..............................................................628 Bromoacetic acid............................................................543
Allyl alcohol.......................................................515, 581 Benactyzine......................................................................641
Bentazone ........................................................................512 Bromoacetone.................................................................515
Allyl butyrate ......................................................558-559 4-Bromoaniline.......................................................610, 629
Allyl chloride ....................................515, 517, 544, 548 Benthiocarb......................................................................519
Benz[a]anthracene.......................................505, 518, 532 Bromobenzene ............515, 517, 544-546, 548, 614-615
Allyl ether ...................................................................619 2-Bromobiphenyl ...................................................529-530
Allyl ethyl ether .........................................................619 Benz[a]anthracene-7,12-dione ....................................540
Benzaldehyde ........................................558-559, 563, 612 Bromochloroacetic acid................................................543
Alpha isomethyl ionone ...........................................563 Bromochloroacetonitrile ......................................509, 547
Alphenal......................................................................637 Benzaldehyde, 3 methoxy ............................................554
1,2-Benzanthracene.......................................................540 Bromochlorodifluoromethane......................................527
Alprazolam.........................................194, 636, 639-640 Bromochloromethane.........................515, 517, 544-546,
Ametryn ......................................................518, 525-526 Benzene.......................501, 515, 517, 544-546, 548-549,
553, 576-577, 586-589, 593, 596-597, 548- 550, 553, 622
2-Aminoazotoluene ...................................................629 Bromodichloroacetic acid.............................................543
2-Amino-1-butanol ....................................................606 599, 601, 604, 614-616, 623-626,
632, 635, 649-651 Bromodichloromethane ....................507, 509, 515, 517,
2-Amino-ethanol........................................................606 544-548, 553, 622
Aminoethylethanolamine.........................................611 Benzene-d6 .....................................................................597
Benzene ethanol.....................................................558-560 2-Bromo-4,6-dinitroaniline............................................629
n-(2-Aminoethyl) piperazine....................................611 Bromoethane (ethyl bromide) ............................553, 622
2-Aminonaphthalene ................................................629 Benzidine.................................................................538, 629
Benzo[a]anthracene..............................................503, 538 Bromofluorobenzene .....................................................545
1-Amino-4-nitronaphthalene ...................................540 4-Bromofluorobenzene......515, 517, 550, 548-549, 553
5-Amino-1-pentanol ..................................................606 Benzocaine.......................................................................643
Benzo[b]fluoranthene.......503, 505, 518, 532, 538, 542 Bromoform .........507, 509, 515, 517, 544-548, 553, 622
1-Amino-2-propaol ....................................................606 Bromofos ..........................................................................575
Amitriptyline...............................................................642 Benzo[j]fluoranthene.....................................................505
Benzo[k]fluoranthene .......503, 505, 518, 532, 538, 540 Bromomethane ...........515, 517, 544-546, 548-549, 553
Amobarbital .......................................................637, 641 1-Bromo-2-nitrobenzene..............................508, 529-530
Amphetamine ...........................................636, 639, 642 Benzo[b]fluoroanthene .................................................540
Benzo[c]fluorene ............................................................505 Bromopheniramine................................................641, 644
Amyl acetate.....................................554, 569, 617-618 4-Bromophenyl-phenylether ........................................538
Amyl alcohol ..............................................................554 2,3-Benzofluorene ..........................................................540
Benzo[g,h,i]perylene .........503, 505, 518, 532, 538, 540 3-Bromopyridine .............................................................610
n-Amyl alcohol...........................................................568 Bromotrifluoromethane.................................................527
Amyl butyrate ............................................................569 Benzo[a]pyrene ...........................503, 518, 532, 538, 540
Benzo[e]pyrene...............................................................540 Buclizine ...........................................................................644
Amyl cinnamic alcohol.............................................561 Bufotenine........................................................................646
Amyl cinnamyl alcohol.............................................563 Benzoic acid ....................................................................538
Benzonitrile.....................................................610, 626-627 Butabarbital.............................................................637, 641
Amyl cinnamyl aldehyde..........................................561 Butacaine .........................................................................643
n-Amyl mercaptan.....................................................592 Benzophenone ........................................................558-559
5,6-Benzoquinoline.........................................................540 Butachlor ................................................518, 520, 525-526
WWW.AGILENT.COM/CHEM/GC 673
COMPOUND INDEX
1,2-Butadiene .................................................586-587, 634 Butyl ethyl ether .............................................................619 Cetearyl octanoate .................................................558-559
1,3-Butadiene ........................................553, 584-591, 634 Butyl heptanoate ............................................................618 Chloral hydrate.......................................................509, 547
Butalbital ..........................................................................637 1-Butyl mercaptan..........................................................592 Chloramben......................................................................512
Butanal..............................................................................611 n-Butyl mercaptan..........................................................592 Chlorcyclizine..........................................................641, 644
1,3-Butandiol...........................................................619, 622 tert-Butyl mercaptan.............................................581, 592 α-Chlordane........................506, 508, 511, 513-514, 518,
1,4-Butandiol....................................................................619 sec-Butyl methacrylate .................................................628 520-524, 529-530
2,3-Butandiol....................................................................619 Butyl methyl ether..........................................................619 γ-Chlordane..................................506, 508, 511, 513-514,
Butane......................................................................599, 601 tert-Butyl methyl ether (MTBE) ..................................553 518, 520-524, 529-530
iso-Butane.......................................................583, 590-591 Butyl propionate ............................................618, 627-628 Chlordiazepoxide.............................................................636
n-Butane ...............................577, 580, 583-590, 596, 634 4-tert-Butyltoluene .................................................614-615 Chloroacetic acid............................................................543
n-Butane/cis-2-butene ................................................ 591 Butyl valerate ..................................................................618 Chloroacetonitrile .........................................515, 517, 548
1,3-Butanediol .................................................................620 2-Butyne (dimethylacetylene) .............................586-587 2-Chloroaniline .......................................................610, 629
1,4-Butanediol .................................................................620 1-Butyne (ethylacetylene) ....................................586-587 3-Chloroaniline .......................................................610, 629
2,3-Butanediol .................................................................620 2-sec-Butyl-4,6-dinitrophenol (dionseb)...........542, 543 4-Chloroaniline ..............................................538, 610, 629
2,3 Butanedione (VDK)..................................................554 Butyraldehyde ........................................................600, 612 Chlorobenzene ....................515, 517, 544-546, 548-549,
2,3-Butanedione (diacetyl) ...................................558-559 Butyric acid ............................................570, 607-608, 611 553, 604, 614-615, 623, 625, 651
1-Butanethiol.........................................578-579, 581, 591 iso-Butyric acid ...............................................................611 Chlorobenzene-d5.........................................550, 553, 549
Butanol......................................................................626-628 n-Butyric acid ..................................................................509 Chlorobenzilate...508, 511, 518, 520-521, 524, 529-530
1-Butanol .....................................515, 554, 595, 600, 602, Butyric acid methyl ester ...................................572, 573 4-Chlorobenzonitrile.......................................................610
605-606, 625, 649-650 2-Chlorobiphenyl.............................................................518
2-Butanol ........................................................554, 635, 639 1-Chlorobutane...........515, 517, 548, 603, 622, 649-650
iso-Butanol.......................................................................606 C 2-Chlorobutane........................................................649-650
n-Butanol........................................................568, 624, 650 Cadinene...........................................................................564 Chlorodibromoacetic acid.............................................543
sec-Butanol.........................568, 595, 602, 605, 624, 650 δ-Cadinene ......................................................557-559, 566 1-Chloro-1,1-difluoroethane .........................................527
tert-Butanol..................................595, 602, 605, 624, 650 γ-Cadinene................................................................556-557 Chlorodifluoromethane..................................................527
2-Butanone (MEK)..............................515, 517, 548, 550, Caffeine...................................................636, 640-641, 647 2-Chloro-4,6-dinitroaniline ............................................629
553, 600, 612, 626, 639 Camphene.............................556, 558-559, 560, 564, 567 Chloroethane ......515, 517, 527, 544-546, 548-549, 553
2-Butanthiol .....................................................................581 Camphor..................................................556, 558-559, 597 2-Chloroethanol......................................................515, 631
Butene...............................................................................617 Capric acid methyl ester .............................561, 572, 573 bis(2-Chloroethoxy) methane ......................................538
Butene-1 ..........................................................584, 586-587 Caproic acid methyl ester.........561, 572, 570, 573, 607 bis(2-Chloroethyl) ether ................................................538
1-Butene ................................584-585, 588-591, 617, 634 Caprylic acid methyl ester..........................561, 572, 573 2-Chloroethyl vinyl ether...............................................544
cis-2-Butene ............................................................584-590 Captafol............................................................508, 529-530 1-Chloro-3-fluorobenzene ..........................517, 544, 548
trans-2-Butene ........................................................584-591 Captan ..............................................................524, 529-530 Chloroform...........................507, 509, 515, 517, 544-549,
1-Butene/methyl acetylene.........................................590 d-Carane............................................................................557 553, 603, 622, 624, 635, 649-650
3-Buten-1-ol ............................................................602, 605 Carbamazepine.......................................................640, 643 1-Chlorohexane .............................................515, 603, 622
2-Buten-1-ol (crotyl alcohol)...............................602, 605 Carbazole .................................................................538, 540 1-Chloro isooctane .........................................................623
Butethal ............................................................................637 Carbepoxide 10/11.........................................................644 3-Chloro isooctane .........................................................623
Butlypentyltin ..................................................................537 Carbinoxamine.................................................................644 4-Chloro isooctane .........................................................623
2-Butoxyethanol.....................................................602, 605 Carbon dioxide....................549, 552, 577, 583, 601, 605 bis(2-Chloroisopropyl) ether................................538, 544
bis(2-n-Butoxyethyl) phthalate....................................539 CO/air.......................................................................552, 601 Chloromethane............................515, 517, 527, 544-546,
Butyl acetate ..........................................617-618, 627-628 Carbon disulfide ..................................517, 546, 548, 550, 548-549, 553
n-Butyl acetate................................................................625 553, 578, 579, 591 4-Chloro-2-methylaniline...............................................629
sec-Butyl acetate....................................................617-618 Carbon monoxide............................................................582 4-Chloromethyl 2,2'-dimethyl pentane ......................623
n-Butylbenzene ..........................517, 544, 546, 548, 576, Carbon tetrachloride .........507, 509, 515, 517, 544-549, 2-Chloro-5-methylphenol ..............................................541
593, 597, 604, 632 553, 603, 622, 635, 649-651 4-Chloro-2-methylphenol ..............................................541
tert-Butyl acetate....................................................617-618 Carbonyl sulfide (COS) .......................550, 577-579, 581, 4-Chloro-3-methylphenol ...........528, 538, 541-543, 604
Butyl acrylate...........................................................627-628 591, 605, 634 2-Chloronaphthalene .....................................................538
n-Butyl acrylate...............................................................628 Carbophenothion ...................................................524, 562 Chloroneb .....................................508, 511, 518, 520-521,
n-Butyl alcohol .......................................................581, 625 Carboxin...........................................................518, 525-526 524, 529-530
s-Butyl alcohol ................................................................581 tau-Cardinol......................................................................556 2-Chloro-4-nitroaniline...................................................629
sec-Butyl alcohol...................................624-625, 649-650 3-Carene............................................................................556 4-Chloro-2-nitroaniline...................................................629
tert-Butyl alcohol ..........................515, 581,625, 649-650 Carfentanyl.......................................................................645 1-Chloro-4-nitrobenzene .......................................614-615
Butyl aldehyde.........................................................554,581 Carvacrol...........................................................................560 4-Chloro-3-nitrobenzotrifluoride .........................529-530
Butylate....................................................................518, 525 cis-Carveol...............................................................563, 565 Chloropentafluoroethane..............................................527
Butylbenzene................................515, 577, 608, 614-615 trans-Carveol..................................................555, 563, 565 2-Chlorophenol.............................................502, 528, 538,
s-Butylbenzene.......................................................576, 593 Carvone .............................................................................565 541-543, 604, 630
sec-Butylbenzene.......................515, 517, 544-546, 548, l-Carvone...........................................................................555 3-Chlorophenol................................................................502
577, 593, 604, 614-615 Carvone phenylethyl acetate .......................................558 4-Chlorophenol.......................................................502, 541
tert-Butylbenzene.............515, 517, 544-546, 548, 576, cis-Carvyl acetate ..................................................555, 565 4-Chlorophenyl-phenyl ether .......................................538
593, 601, 604, 614-615 Caryophyllene..................................................................556 Chloropicrin.............................................................509, 547
Butyl benzyl phthalate..........................................538, 539 α-Caryophyllene..............................................................566 Chloroprene......................................................................544
Butyl caproate.................................................................618 β-Caryophyllene............................555, 557-559, 564-566 2-Chloropropane ............................................................544
Butyl cellosolve...............................................................625 Caryophyllene oxide.......................................................556 2-Chloropropene .............................................................594
Butyl cellosolve acetate................................................625 Celestolide........................................................................558 3-Chloropropene (allyl chloride)................553, 603, 622
Butylene............................................................................601 Cellosolve acetate ..........................................................625 3-Chloropropionitrile ......................................................515
Butyl ether........................................................................619 Cetearyl decanoate ................................................558-559 Chloropropylate..............................................508, 529-530
674
COMPOUND INDEX
WWW.AGILENT.COM/CHEM/GC 675
COMPOUND INDEX
676
COMPOUND INDEX
Endosulfan I.................................506, 508, 511, 513-514, Ethyl cellosolve ...............................................................625 Farnesyl acetate..............................................................566
518, 520-525, 529-530 Ethyl decanoate ......................................................558-559 Fenamiphos.....................................................518-519, 525
Endosulfan II................................506, 508, 511, 513-514, Ethyl dodecanoate..................................................558-559 Fenarimol.................................................................518, 525
518, 520-525, 529-530 Ethylene ...............577, 580, 584-585, 588-590, 601, 634 Fenchone ..........................................................................563
α-Endosulfan ...................................................................575 Ethylene/acetylene........................................................591 Fenchyl acetate...............................................................558
b−Endosulfan ..................................................................575 Ethylenediamine .............................................................611 Fenitrothion.............................................................562, 575
Endosulfan sulfate .....................506, 508, 511, 513-514, Ethylene ............................................................................595 Fentanyl............................................................640, 645-646
518, 520-525, 529-530, 575 Ethylene glycol .....................602, 605, 619-622, 649-650 Fenthion............................................................................562
Endrin ...................................506, 508, 511, 513-514, 518, Ethylene glycol monoacetate ......................................607 Fenvalerate.......................................................................519
520-525, 529-530, 542 Ethylene glycol monobutyl ether........................619-620 Florazone ..................................................................558-559
Endrin aldehyde ..........................506, 508, 511, 513-514, Ethylene glycol monoethyl ether........................619-620 Flunitrazepam ........................................194, 636, 639-640
518, 520-525, 528-530 Ethylene glycol monoformate......................................607 Fluoranthene.........................................503, 532, 538, 540
Endrin ketone ..............................506, 508, 513-514, 518, Ethylene glycol monomethyl ether ....................619-620 Fluorene ...............................503, 518, 532, 538, 540, 542
521-524, 529-530 Ethylene glycol phenyl ether .......................................622 Fluorobenzene ............515, 517, 544, 545, 548, 614-615
Ephedrine..........................................................................636 Ethylene oxide ......................................594, 605, 607, 631 2-Fluorobiphenyl .............................................................538
Epiandrosterone (trans-androsterone) ......................648 Ethyl ether .....................................515, 619, 624-625, 650 2-Fluorophenol ................................................................538
Epichlorohydrin.......................................................515, 619 Ethyl formate .......568, 607, 617-618, 624-625, 649-650 Flurazepam..............................................................640, 642
EPTC .................................................................518, 525-526 Ethyl heptanoate.....................................................558-559 Fluridone ..........................................................518, 525-526
Eptam ................................................................................527 Ethyl hexadecanoate .............................................558-559 Fonofos .............................................................................526
Erucic acid methyl ester ......................................572, 573 Ethyl hexanoate ......................................................558-559 Formaldehyde ................................................550, 553, 613
Erythritol............................................................................569 2-Ethyl hexanoic acid ....................................................509 Formaldehyde-DNPH .....................................................613
Esfenvalerate...................................................................519 2-Ethyl-1-hexanol...................................................602, 605 Formaldehyde-PFBHA ...................................................614
Estazolam .........................................................................636 Ethyl isovalerate .....................................................558-559 Formic acid.....................................................509, 570, 607
17-α-Estradiol..................................................................648 Ethyl mercaptan....................................579, 581, 591-592 Frambinone (raspberry ketone)...........................558-559
b-Estradiol ........................................................................648 Ethyl methacrylate...............................515, 517, 548, 628 Fucitol................................................................................568
Estriol.................................................................................648 Ethyl methyl sulfide .......................................................578 Furan..................................................................................619
Estrone ..............................................................................648 Ethyl morphine ................................................................637 Furfural.............................................................558-559, 612
Ethane ..................580, 583-585, 588-591, 596, 601, 634 Ethyl nonanoate......................................................558-559 Furfuryl alcohol.......................................................602, 605
Ethane/ethylene.............................................................580 Ethyl octadecanoate ..............................................558-559
Ethanethiol .......................................................................578 Ethyl octanoate .......................................................558-559
Ethanol ...............515, 554, 568, 581, 595-596, 600, 602, Ethyl parathion ................................................................575 G
605, 623-628, 635, 638-639, 649-650 Ethyl pentadecanoate....................................................559 Galactitol...................................................................568-569
Ethanolamine...................................................................608 Ethyl pentadecanoate nonadecane............................558 Geranial............................................................558-559, 564
Ethchlorvynol ...................................................................646 Ethyl pentanoate.....................................................558-559 Geranial acetate..............................................................566
Ethinamate .......................................................................646 α-Ethylphenethyl alcohol.....................................602, 605 Geraniol........................558-559, 560, 561, 563, 566, 569
Ethoprop...........................................................518, 525-526 b-Ethylphenethyl alcohol.....................................602, 605 cis-Geraniol ......................................................................556
Ethosuximide ...................................................................643 2-Ethylphenol...................................................................630 trans-Geraniol..................................................................563
Ethotoin.............................................................................644 4-Ethylphenol...................................................................630 Geranyl acetate............................556, 558-559, 564, 566
2-Ethoxyethanol ..........................602, 605, 607, 635, 639 Ethyl-3-phenyl oxiran carboxylate ..............................569 Geranyl butyrate .............................................................559
bis(2-Ethoxyethyl) phthalate........................................539 Ethyl propanoate.............................................................554 Geranyl formate ......................................................558-559
2-Ethoxyethyl acetate...................................607, 617-618 Ethyl propionate....................558-559, 617-618, 627-628 Geranyl-2-methyl valerate ............................................558
2-Ethyl-1-hexanol............................................................567 Ethyl tetradecanoate..............................................558-559 Geranyl tiglate .........................................................558-559
bis(2-Ethylhexyl) adipate...............................................518 4-Ethyltoluene .................................................................553 Germacrene-d.......................................555, 556, 565, 566
bis(2-Ethylhexyl) phthalate..........................518, 538-539 m-Ethyltoluene .......................................................576, 593 Gesatamine (atraton).....................................................518
Ethyl acetate.................................515, 553-554, 558-559, p-Ethyltoluene ........................................................576, 593 Glucitol ..............................................................................568
568-569, 617-618, 624-628, Ethyl undecanoate..................................................558-559 Glucuronic acid ...............................................................569
635, 639, 649-650 Ethyl valerate...................................................................618 Glucuronic acid-1,5-lactone .........................................569
Ethyl acetylene................................................................634 Ethyl vinyl ether ..............................................................619 Glutethimide ...........................................................640, 646
Ethyl acrylate ..........................................617-618, 626-628 Etridiazole ......................................508, 511, 520-521, 524 Glycidol.....................................................................602, 605
Ethyl alcohol ....................................................................607 Eucalyptol.................................................................556-557 Glyme.................................................................................620
2-(Ethylamino)-ethanol..................................................606 Eugenol ....................................................................561, 563 Glyme (propylene glycol dimethyl ether).........619, 620
Ethyl and dimethyl thiophenes....................................593 iso-Eugenol ......................................................................561 GOAL .................................................................................527
Ethylbenzene ..............501, 515, 517, 544-546, 548-549, Evernyl...............................................................................558 3,7-Guaiadiene.................................................................558
553, 576-577, 588-589, 593-594, Eugenyl acetate ......................................................558-559 α-Gurjunene.....................................................................566
596-597, 599, 601, 604, 614-616, Eugenyl methyl ether.....................................................559
623, 625, 632, 639, 649-651
Ethylbenzene-d10 ..........................................................597 H
Ethyl benzoate................................................569, 617-618 F
Halazepam...............................................................636, 640
Ethyl butanoate...............................................................554 Farnescene.......................................................................566 Haloperidol .......................................................................646
2-Ethyl-1-butanol.............................................................606 b-Farnesene.....................................................................556 Halothane .........................................................................632
Ethyl t-butyl ether (ETBE)515, 546, 581, 595, 600, t-b-Farnesene ..................................................................557 Helium ...............................................................................552
625, trans-b-Farnesene .................................................555, 565 Heneicosane....................................................................558
Ethyl butyrate ........................................558-559, 569, 618 Farnesol ............................................................................563 Heneicosanoic acid methyl ester ......................572, 573
Ethyl caprate....................................................................554 Farnesol 1.........................................................................563 1,7-Hepatanediol.............................................................620
Ethyl caproate..................................................................618 Farnesol acetate .............................................................566 Heptachlor....................................506, 508, 511, 513-514,
Ethyl caprylate.................................................................554 Farnesol isomer ..............................................................561 518, 520-525, 529-530
WWW.AGILENT.COM/CHEM/GC 677
COMPOUND INDEX
Heptachlor epoxide ....................506, 508, 511, 513-514, Hexobarbital............................................................637, 641 Isophorone .....................................................518, 538, 542
518, 520-525, 529-530, 542 Hexyl acetate...........................................................558-559 Isoprene ....................................................................586-589
2,2',3,3',4,4',6-Heptachlorobiphenyl ...........................518 Hexyl butyrate .................................................................556 Isopropanol ..........................................554, 581, 602, 605,
Heptadec-1-ene .............................................................558 Hexyl cinnamaldehyde ..................................................563 624-625, 638, 650
Heptadecane....................................................................536 Hexyl cinnamic aldehyde..............................................561 Isopropyl acetate ..................................617-618, 624, 639
n-Heptadecane................................................................597 Hexylene glycol.......................................................558-559 Isopropyl acrylate ...................................................627-628
Heptadecanoic acid methyl ester......................572, 573 Hexyl 2-ethylhexyl phthalate .......................................539 Isopropyl alcohol..................515, 553, 624-625, 649-650
cis-10-Heptadecenoic acid methyl ester .........572, 573 1-Hexyl mercaptan .........................................................592 Isopropyl amine .....................................................649-650
Heptanal...........................................................554, 611-612 n-Hexyl mercaptan .........................................................592 Isopropyl benzene ......................515, 517, 544-546, 548,
1,7-Heptandiol ........................................................619, 620 Hexyl methacrylate ........................................................628 577, 588, 589, 593, 604, 614-616
Heptane........................................576, 593, 601, 616, 623, α-Humulene.....................................................................564 Isopropyl ether ................................................................619
625, 639, 649-650 Hydrocarbon.....................................................................616 Isopropyl mercaptan ......................................................592
n-Heptane..............................................553, 577, 588-589, Hydrocodone...........................................................639, 641 Isopropyl myristate.................................................558-559
596-597, 624, 635, 650 Hydrogen oxide ...............................................................577 2-Isopropylphenol ...........................................................630
Heptanoic acid ..............................................570, 607, 611 Hydrogen sulfide.........................550, 577-579, 581, 583, Isopropyltoluene .............................................................515
n-Heptanoic acid.............................................................509 591, 592, 601, 605, 634 4-Isopropyltoluene..................................................545-546
1-Heptanol..............................................532, 602, 605-606 Hydroxy acetate ..............................................................607 p-Isopropyltoluene........................................517, 544, 548
2-Heptanol...............................................................602, 605 Hydroxy citronellal................................558-559, 561, 563 Isovaleraldehyde....................................................581, 600
3-Heptanol...............................................................602, 605 4-Hydroxy-4-methyl-2-pentanone ......................602, 605 Isovaleric acid.........................................................570, 607
2-Heptanone ....................................................................612 Hydroxyphenamate ........................................................641
3-Heptanone ....................................................................612 Hydroxypropionitrile.......................................................515
4-Heptanone ....................................................................612 Hydroxypropyl acrylate..................................................628 J
cis-4-Hepten-1-ol ...................................................602, 605 Hydroxyzine......................................................................644 Jasmolin I.........................................................................536
trans-2-Hepten-1-ol...............................................602, 605 Jasmolin II........................................................................536
Hercolyn D cis-Jasmone............................................................555, 565
(tetrahydro & dihydro methyl abietate).....................558 I
Heroin.............................................194, 637, 639-641, 647 Ibogaine ...................................................................640, 646
Hexabromobenzene (HBB) ..........................................524 Ibuprofen..................................................................641, 647 K
Hexabromobiphenyl .......................................................519 Imipramine .......................................................................642 Kelthane...........................................................508, 529-530
Hexacosane .....................................................................503 Indan..........................................................................596-597 Kepone ..............................................................................519
Hexachlorobenzene....508, 518, 520, 524, 529-530, 538 Indeno[1,2,3-c,d]pyrene.............503, 505, 518, 532, 538 Ketamine..................................................................646, 647
Hexachlorobezene.................................................511, 521 Inositol...............................................................................568 Krypton..............................................................................582
2,2',4,4',5,6'-Hexachlorobiphenyl................................518 Iodobenzene.............................................................614-615
Hexachlorobutadiene.................515, 517, 538, 544-546, Iodoform...................................................................603, 622
548, 553, 603, 622
Hexachloro-1,3-butadiene ............................................549
Iodomethane................................517, 544, 548, 603, 622 L
Irgafos ...............................................................................633
b-Hexacholorcyclohexane............................................575 L-9-Carboxy-11-nor-δ9-THC ..........................................649
Irganox .............................................................................633
δ-Hexacholorcyclohexane ............................................575 L-11-Hydroxy-δ9-THC .....................................................649
Isoamyl acetate.....................................554, 569, 617-618
γ-Hexacholorcyclohexane.............................................575 Lactose..............................................................................569
Isoamyl alcohol .....................................554, 568, 649-650
Hexachlorocyclopentadiene.............508, 511, 518, 538, Lactulose ..........................................................................569
Isoamyl butyrate .............................................................569
542, 603, 622 Lauric acid methyl ester........................................572,573
Isoamyl mercaptan.........................................................592
Hexachloroethane..............515, 517, 538, 548, 603, 622 Lavandulol ........................................................................556
Isoamyl salicylate ..................................................558, 560
Hexachloropentadiene ..........................................529-530 Lavandulyl acetate .........................................................556
Isoborneol........................................................558-560, 567
Hexadecane .....................................................................503 Levulinic acid...................................................................509
Isobutane.........................................................584-589, 599
n-Hexadecane.........................................................249, 597 Lidocaine.........................................................640, 643, 647
Isobutanol...........515, 568, 581, 595, 602, 605, 626-628
Hexadecanoic acid .........................................................570 Lignoceric acid methyl ester .............................572, 573
Iso-butene ........................................................................634
2,4-Hexadienal.................................................................557 Lilial...........................................................................561, 563
Isobutyl acetate .....554, 558-559, 617-618, 624, 627-628
Hexanal ............................................................554, 611-612 Limonene......................555, 558-560, 563-564, 565, 567
Isobutyl acrylate......................................................627-628
1,6-Hexandiol...................................................................619 δ-Limonene .....................................................556-557, 564
Isobutyl alcohol...............................................................554
Hexane ........517, 548, 599, 601, 623-626, 639, 649-650 S-(-)-Limonene.................................................................567
Isobutyl aldehyde...................................................554, 581
n-Hexane ..............................553, 577, 583-585, 588-589, Linalool............................................555, 558-561, 563-567
Isobutylbenzene....................................577, 604, 614-615
596-597, 624, 635, 650 b-Linalool..........................................................................556
Isobutylene...............................................................584-587
1,6-Hexanediol.................................................................620 Linalool acetate...............................................................556
Isobutyl mercaptan ........................................................592
Hexanoic acid..................................................................611 cis-Linalool oxide....................................................558-559
Isobutyl propionate ................................................627-628
Hexanol ...........................................249, 251-252, 558-559 trans-Linalool oxide................................................558-559
Isobutyraldehyde..................................582, 600, 612, 625
1-Hexanol........................................................554, 602, 606 Linalyl acetate .........................................................558-560
Isobutyric acid .......................................509, 570, 607-608
2-Hexanol.................................................................602, 605 Linoleic acid methyl ester ..................................572, 573
Isocaproic acid .......................................................570, 607
3-Hexanol.................................................................602, 605 Linolelaidic acid methyl ester ...........................572, 573
Isodrin......................................................508, 524, 529-530
2-Hexanone...........................................517, 548, 553, 612 Linolenic acid methyl ester ................................572, 573
Isoeugenol........................................................................563
3-Hexanone......................................................................612 γ-Linolenic acid methyl ester ............................572, 573
trans-Isoeugenol.............................................................563
n-Hexatriacontane..........................................................597 Lofentanyl.........................................................................645
Isomenthol .......................................................................557
Hexazinone..............................................518-519, 525-527 Lorazepam.......................................................636, 639-640
Isomenthone...................................................555, 557-559
Hexchlorocyclopentadiene...........................................520 Lormetazepam.................................................................636
d-Isomethone...................................................................565
cis-2-Hexen-1-ol.....................................................602, 605 Lyral ...................................................................................561
Isonox ...............................................................................633
cis-3-Hexen-1-ol.....................................................602, 605 Lyral 1................................................................................563
Isooctane..............577, 588-589, 596-597, 623-624, 635
cis-2-Hexene............................................................588-589 Lyral 2................................................................................563
Isopentane..............................................577, 584-589, 596
trans-2-Hexene........................................................588-589 Lysergic acid diethylamide (LSD) ......................640, 646
Isopentanoic acid ...........................................................509
678
COMPOUND INDEX
WWW.AGILENT.COM/CHEM/GC 679
COMPOUND INDEX
680
COMPOUND INDEX
WWW.AGILENT.COM/CHEM/GC 681
COMPOUND INDEX
682
COMPOUND INDEX
WWW.AGILENT.COM/CHEM/GC 683
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WWW.AGILENT.COM/CHEM/GC 693
NOTES
694
NOTES
WWW.AGILENT.COM/CHEM/GC 695
NOTES
696
NOTES
WWW.AGILENT.COM/CHEM/GC 697
NOTES
698
NOTES
WWW.AGILENT.COM/CHEM/GC 699
NOTES
700
NOTES
WWW.AGILENT.COM/CHEM/GC 701
NOTES
702
NOTES
WWW.AGILENT.COM/CHEM/GC 703
NOTES
704
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