SDS for Product: Emmy's Best Premium Anti-Chew Bitter Spray, Rev.

Date: 16 January 2018

Sheet No. 2134 Revision Date: 16 January 2018

SAFETY DATA SHEET

HMIS: NFPA:
Health- 1 Flammability- 3 Reactivity- 0 Pers. Health- 1 Flammability- 3 Reactivity- 0 Special Hazard-
Protection- A N
WHMIS: B 2, D 2 B

Section 1: Product and Company Identification

Product: Emmy's Best Premium Anti-Chew
Synonyms:
Bitter Spray
Emmy's Best LLC
825 Market Street, Building M Suite 250
Allen TX 75013
Non-Emergency: 24 hr Emergency Spill Information:
US 972-861-2240
International
Section 2. Hazards Identification
EMERGENCY OVERVIEW
Appearance/Odor: Colorless liquid, mildly unpleasant aroma

WARNING
Flammability : R 10: Flammable Liquid
Health Hazards Listed : May be a mild irritant
Ecological Hazards Listed : None known
Potential Health Effects: See section 11 for more information.

R10 - Flammable
Risk Phrases:
R36 - Irritating to eyes
R37 - Irritating to respiratory system

S2 - Keep out of the reach of children

Safety Phrases: S7 - Keep container tightly closed
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice

Hazard Phrases: H303 - May be harmful if swallowed

Precautionary P211 - Do not spray on an open flame or other ignition source.

Phrases: P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 - Keep container tightly closed.

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 SDS for Product: Emmy's Best Premium Anti-Chew Bitter Spray, Rev. Date: 16 January 2018

Likely Routes of Exposure: Mouth, eyes

Eye: Direct exposure can irritate
Skin: Prolonged or repeated exposure can irritate
Ingestion: Can irritate digestive tract
Inhalation: Can irritate respiratory tract or cause dizziness or headache
Medical Conditions Aggravated By Exposure:
Allergies
Target Organs: None known
This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
Potential Environmental Effects: (See section 12 for more information.)
None known
Section 3. Composition/Information on Ingredients
WHMIS
Component CAS# % by Weight Controlled
2-Propanol 67-63-0 10 - 30 Y Y
Polysorbate-20 9005-64-5 1-5 N
Water 7732-18-5 60 - 80 N
Propylene Glycol 57-55-6 0.1 - 1.0 Y
Tea Tree Oil 85085-48-9 0.1 - 1.0 N
Denatonium Benzoate 3734-33-6 < 0.1 N
Section 4. First Aid Measures
Flush eyes with copious amounts of clean water, holding lids open. If irritation
Eye Contact:
persists, consult a physician.
Skin Contact: Wash with soap and water.
Inhalation: Remove to fresh air.
Ingestion: If conscious, give water or milk to drink.
Product is very bitter. Spontaneous vomiting may occur in case of ingestion. Contains
Note to Physicians:
2-Propanol (Isopropyl Alcohol)
Section 5. Fire Fighting Measures
Suitable Extinguishing Media: Water, foam, carbon dioxide, dry chemical
Unsuitable Extinguishing Media: None known
Products of Combustion: Oxides of carbon and nitrogen
Protection of Firefighters: As for surrounding fire
Section 6. Accidental Release Measures
Personal Precautions: Keep away from skin, eyes and mouth
Environmental Precautions: Keep out of surface waters
Methods for Containment: Dike area with sand, clay or other suitable material.
Methods for Clean-Up: Absorb on sand, clay or other suitable material or mop up with water.
Other Information:
Section 7. Handling and Storage
HANDLING

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 SDS for Product: Emmy's Best Premium Anti-Chew Bitter Spray, Rev. Date: 16 January 2018

Keep cool. Do not open until ready to use.

STORAGE
Keep out of the reach of children. Store in original container at ambient conditions (0 - 60°C, 32 - 140°F)
Section 8. Exposure Controls/Personal Protection
EXPOSURE GUIDELINES
COMPONENT: TWA: LD-50
2-Propanol TLV 200 ppm 5800 mg/kg
Polysorbate-20 None established > 3850 mg/kg
Water Not applicable Not applicable
Propylene Glycol None established 20 000 mg/kg
Tea Tree Oil None established 2300 mg/kg
Denatonium Benzoate None established 749 mg/kg
Engineering Controls: Not normally necessary.
Eye/Face Protection: Protective goggles recommended if handling large quantities.
Skin Protection: Rubber or other protective gloves recommended if handling large quantities.
Respiratory Protection: Not normally necessary. Organic vapor respirator may be advisable if handling large
quantities.
General Hygiene Considerations: Keep away from face and skin. Keep out of food and beverages.

Section 9. Physical and Chemical Properties

Odor: Mild, moderately irritating. Characteristic of
Color: Colorless to pale yellow.
2-Propanol
Physical State: Liquid Odor Treshhold:
pH: 7 - 8 Freezing Point: Not determined. Less than 0°C/32°F
Boiling Point: Not determined. Greater than
Evaporation Rate: Not determined.
82°C/180°F.
Flash Point: 28°C/83°F PMCC Flammability(solid,gas): Not applicable.
Upper Flammability Limit: Not determined. Lower Flammabilty Limit: Not determined.
Vapor Pressure: Greater than water. Specific Gravity: 0.97
Vapor Density: Not determined. Auto-ignition Temperature: Not determined.
Volatile Organic Compound (VOC),%weight: Solubility (water): Soluble
20% Percent Volatile: 96.5% Including water
Section 10. Stability and Reactivity
Stability: Stable.
Conditions to Avoid: High temperatures, open flames.
Incompatable Materials: None known.
Hazardous Decomposition Products: None known.
Possibility of Hazardous Reactions: Extremely low probability
Section 11. Toxicology Information
ACCUTE EFFECTS
Oral LD50: Not established for mixture. Weighted average more than 20 grams per kilogram.
Dermal LD50: Not established for mixture. Weighted average more than 20 grams per kilogram.
Inhalation: Not established for mixture. Weighted average more than 20 milligrams per Liter.

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 SDS for Product: Emmy's Best Premium Anti-Chew Bitter Spray, Rev. Date: 16 January 2018

Eye Irritation: Direct contact can be severely irritating due to drying effect of 2-propanol
Skin Irritation: Prolonged or repeated contact can dry or irritate skin
Sensitization: Not expected to be a problem in normal use
CHRONIC EFFECTS
Carcinogenicity: None known
Mutagenicity: None known
Reproductive Effects: None known
Developmental Effects: None known
Section 12. Ecological Information
Ecotoxicity: None known
Persistence/Degradability: Biodegradable
Bioaccumulation/Accumulation: None known
Mobility in Enviroment: Not determined.
Section 13. Disposal Considerations
Disposal: Dispose according to all Federal, State or Provincial, and Local regulations.
Section 14. Transportation Information
US DOT (ground)
Proper Shipping Description: Consumer Commodity - ORM-D
CANADA TDG (ground)
Proper Shipping Description: Consumer Commodity - ORM-D
ICAO (air)
Proper Shipping Description: UN1993, Flammable Liquid NOS (Isopropanol) Class 3 Packaging Group III
IMDG (water)
Proper Shipping Description: UN1993, Flammable Liquid NOS (Isopropanol) Class 3 Packaging Group III, EmS
F-E, S-E
Section 15. Regulatory Information
Global Inventories
TSCA: United States Included
DSL: Canada Included
ECL: Korea Not-Known
PICCS: Philippines Not-Known
ENCS: Japan Not-Known
AICS: Australia Included
IECS: China Not-Known
EINECS: European Union Included

SARA 313 Information : Does not contain any SARA 313 Substances

California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65)
Does not contain any Proposition 65 substances
WHMIS: Canadian Workplace Hazardous Material Information System
B 2, D 2 B

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 SDS for Product: Emmy's Best Premium Anti-Chew Bitter Spray, Rev. Date: 16 January 2018

Section 16. Other Information

Legends:
NFPA, HMIS:
0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard

Prepared By: Technical Dept.

While we believe that the data contained herein are factual and the opinions expressed are those of qualified
experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for
which we assume legal responsibility. The information is offered solely for your consideration, investigation
and verification. Any use of these data and information must be determined by the user to be in accordance with
federal, state and local laws.