ArcticMeltdown PDF
ArcticMeltdown PDF
1979 2007
Contributing authors:
Kassie Siegel
Brendan Cummings
Anna “Mickey” Moritz
Brian Nowicki
Front Cover:
Polar bear image by Thomas D. Mangelsen/[Link]
1979 and 2007 Arctic sea ice images courtesy of NASA/Goddard Space Flight Center
Scientific Visualization Studio
I. The Polar Bear, Global Warming, and the Endangered Species Act ...............................................2
II. Reducing Greenhouse Pollutants Rapidly Enough to Address Arctic Melting .........................6
A. Carbon Dioxide ...................................................................................................................................7
B. Methane .................................................................................................................................................9
C. Black Carbon or Soot .............................................................................................................................9
D. Other Non-CO2 Pollutants .................................................................................................................10
E. Reduced CO2 and Non-CO2 Pollutants and the Future Arctic ..............................................11
I
n early 2008, the polar bear will likely be formally declared “threatened” or “endangered”
under the Endangered Species Act. But listing of the polar bear under the Endangered Species
Act, while hugely significant both legally and politically, will not in and of itself save the polar
bear or its Arctic sea-ice habitat. In September 2007, the same month that Arctic sea ice reached a
new record minimum extent, government scientists predicted the polar bear would be extinct in
Alaska by 2050 if current greenhouse gas emission trends continue.
The rapid melting of the Arctic should be seen as an early warning of the broader climate crises
to come if the United States and the world do not respond to global warming with the necessary
urgency. Instead, like beachgoers chasing receding ocean waters to gather exposed shellfish just
before a tsunami, nations and industry are racing to the newly ice-free areas to stake claims for
fossil fuels and shipping routes that would lead us further down the path to climate catastrophe.
The situation in the Arctic has reached a critical threshold. But with immediate action it is still
possible to slow the melting of the Arctic. In addition to broader local, national, and international
efforts to reduce U.S. and global carbon dioxide (CO2) emissions, saving the Arctic requires
prompt reductions of other greenhouse gases, along with specific efforts to address direct threats
to the region from industrial activities such as oil development and shipping. Reducing emissions
of methane and black carbon, which both have short atmospheric lifetimes and a large warming
impact on the Arctic, is a critical component of any effective action plan. Immediate methane
and black carbon emissions reductions can buy the world a li�le more time to achieve the deep
reductions in CO2 emissions that are necessary to protect the Far North. But the window of
opportunity to act, like the ice, is shrinking rapidly.
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P
olar bears are completely dependent
upon Arctic sea-ice habitat for survival.
Polar bears need sea ice as a platform
from which to hunt ringed seals and other
prey, to make seasonal migrations between the
sea ice and their terrestrial denning areas, and
for other essential behaviors such as mating.
Unfortunately, the polar bear’s sea-ice habitat is
literally melting away.
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Critically important for the polar bear proposed listing rule. The proposal to list the
and any other species threatened by global polar bear was greeted by worldwide media
warming, the Endangered Species Act a�ention, resulting in over 250 television
requires that all listing decisions be made stories, more than 1000 print stories and over
“solely” on the basis of the “best scientific… 240 editorials. Over 600,000 comments were
data available.” 16 U.S.C. § 1533(b)(1)(A). submi�ed during the public comment periods
A decision not to list a petitioned species on the proposal. The final listing determination
is subject to judicial review. It is this “best is due on January 9, 2008.
available science” standard that provides a
vehicle through the petitioning process to Once the polar bear is listed, the
force federal agencies to squarely address the Endangered Species Act requires the Fish
science of global warming. Moreover, once and Wildlife Service to identify and designate
the Endangered Species Act listing process is critical habitat, convene a recovery team and
initiated, strict timelines apply, with an initial develop and implement a recovery plan.
finding due within 90 days of the petition, a Additionally, the requirement for federal
proposed rule within 12 months of the petition agencies to avoid jeopardizing the species,
if the Fish and Wildlife Service finds that the and a prohibition against unpermi�ed take
species meets the criteria for listing, and a (harm and harassment), will take effect.
final listing determination within a year from These regulatory protections should provide
the proposed rule. Species do not receive substantial benefit to the polar bear (Cummings
any regulatory protection under the Act until and Siegel 2007). While the polar bear has yet
they are officially listed as threatened or to receive any actual legal protection as a result
endangered. of the Endangered Species Act listing process,
the process has already played an important
A series of administrative and legal events role by being a catalyst to focus significant new
in the listing process have greatly increased scientific, public, and political a�ention on
public awareness of the polar bear’s plight. In the problem of the melting Arctic and global
December 2005, ten months a�er the petition warming.
was filed, the Center for Biological Diversity,
joined by NRDC and Greenpeace, sued the The listing process has prompted research
Department of Interior for failing to issue an and analysis on the future of the polar bear, its
initial finding on the petition. In response, a sea-ice habitat, and the Arctic more generally.
positive initial finding was issued in February Most important among these research
2006, initiating both a public comment period efforts are the recent reports released by the
and full status review for the species. The Department of Interior’s U.S. Geological Survey
deadline for the second required finding on the (USGS). The Fish and Wildlife Service asked
petition, due within 12 months of receipt of the the USGS to do the following in support of
petition, was only one week away at the time the listing process: (1) develop population
the first finding was made. The lawsuit was projections for the Southern Beaufort Sea
ultimately se�led with a court-ordered consent polar bear population and analyze existing
decree se�ing a deadline of December 27, 2006 data on two polar bear populations in Canada;
for the Fish and Wildlife Service to make the (2) evaluate northern hemisphere sea-ice
second determination. projections, as they relate to polar bear sea-
ice habitats and potential future distribution
On December 27, 2006, Secretary of Interior of polar bears; and (3) model future range-
Dirk Kempthorne announced that listing of wide polar bear populations by developing a
the polar bear is warranted and that the Fish synthesis of the range of likely numerical and
and Wildlife Service would be publishing a spatial responses to sea-ice projections. The
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T
he essential first component of an reductions on the table, including many
action plan to save the polar bear is a that could be undertaken at a net economic
mandatory reduction in CO2 pollution. benefit (Tables 1-4, Figure 5). According to
Beginning CO2 reductions immediately and conservative projections by the U.S. EPA, about
eventually reducing them to a small fraction 500 MtCO2eq of global methane emissions
of current levels so that atmospheric CO2 reductions could be achieved globally by
concentrations never rise above about 450 2020 at a cost benefit or no cost (EPA 2006;
ppm is essential to saving polar bears. But the Table 4, Figure 7). Nearly 70 MtCO2eq of
Arctic has reached such a critical threshold these available reductions are in the United
that CO2 reductions alone, even if undertaken States (EPA 2006; Table 2, Figure 6). The EPA
immediately and with determination, will estimates total technically feasible methane
almost certainly not be enough to slow and reductions for 2020 at over 2400 MtCO2eq
reverse the warming and melting trend. This is globally and nearly 280 MtCO2eq in the United
because CO2, once emi�ed, tends to remain in States, many of which can be achieved at low
the atmosphere for centuries (Archer 2005), and cost (EPA 2006; Tables 2 and 4; Figures 6,7).
therefore the benefits of reductions today will
not be fully felt for some time. Reductions in CO2, methane, and black
carbon will have major public health benefits
Our window of opportunity to save polar as well. Many of the measures necessary to
bears relates to the fact that the warming reduce global warming pollution, including
impact of “non-CO2” pollutants including increasing energy efficiency, increasing the use
methane, tropospheric ozone, and black carbon of renewable energy and phasing out fossil
(soot) is larger in the Arctic than it is globally. fuels, and ultimately changing our land use,
The non-CO2 pollutants are responsible for transportation, and consumption pa�erns,
at least half of the warming in the Arctic will improve our quality of life, improve our
(Hansen et al. 2007), as opposed to about 30% economy, and make the world a healthier, safer,
globally (Forster and Ramaswamy 2007; Figure and more equitable place. Congress should act
4). Black carbon has a disproportionately immediately to explicitly cap and then rapidly
large warming impact in the Arctic, and both reduce not only CO2, but also the non-CO2
black carbon and methane have much shorter pollutants.
atmospheric lifetimes than CO2. This means
that immediately reducing these pollutants Below we review necessary reductions in
can buy some desperately needed time and greenhouse gas pollutants and opportunities
presents our best opportunity for slowing and for targeted actions to protect the Arctic.
reversing the Arctic melting before it is too Further detail on mitigation strategies for
late.2 methane, black carbon, nitrous oxide, and the
high global warming potential gases is found in
Fortunately, there are many feasible Appendix A.
reduction measures available today for
these pollutants, with literally hundreds of
millions of metric tons of CO2eq “no-cost”
2 For ease of comparison, the volume of each pollutant is expressed as its “carbon dioxide equivalent” in millions of metric tons. Thus, 1 million
metric tons of methane is equivalent to 21 million metric tons of CO2 equivalent (MtCO2eq).
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Figure 6: Methane Emissions and Potential Reductions for the United States in 2020
Data from EPA 2006 and Table 2
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and biomass (Quinn et al. 2007). Black carbon sources that are transported by air currents
warms the atmosphere, but it is a solid, not a most efficiently to the Arctic. Black carbon
gas. Unlike greenhouse gases, which warm the reductions will also provide air quality and
atmosphere by absorbing longwave infra-red human health benefits. Conversely, allowing
radiation, soot has a warming impact because black carbon emissions to increase in the Arctic
it absorbs shortwave radiation, or visible light as the result of increased shipping or industrial
(Chameides and Bergin 2002). Black carbon is activity will accelerate loss of the seasonal sea
an extremely powerful greenhouse pollutant. ice and extinction of the polar bear.
Scientists have described the average global
warming potential of black carbon as about 500 Despite its significance to global climate
times that of carbon dioxide over a 100-year change and to the Arctic in particular, black
period (Hansen et al. 2007; see also Reddy and carbon has not been addressed by the major
Boucher 2007). This powerful warming impact reports on non-CO2 gas mitigation, nor is it
is remarkable given that black carbon remains addressed in current global warming bills in
in the atmosphere for only about four to seven the 110th Congress. Black carbon reductions
days, with a mean residence time of 5.3 days are an essential part of saving the Arctic sea ice
(Reddy and Boucher 2007). and the polar bear, and should be addressed
by Congress in this session. Abatement
Black carbon contributes to Arctic warming opportunities are discussed further in
through the formation of “Arctic haze” and Appendix A.
through deposition on snow and ice, which
increases heat absorption (Quinn et al. 2007; D. Other Non-CO2 Pollutants
Reddy and Boucher 2007). Arctic haze results
from a number of aerosols in addition to black Nitrous oxide and the high global
carbon, including sulfate and nitrate (Quinn warming potential gases do not have the same
et al. 2007). The effects of Arctic haze may be heightened impacts in the Arctic as methane
to either increase or decrease warming, but and black carbon. Nevertheless, because these
when the haze contains high amounts of soot, gases have high global warming potentials and
it absorbs incoming solar radiation and leads to long atmospheric lifetimes, and because there
heating (Quinn et al. 2007). are many readily available mitigation measures
to reduce them, they present important
Soot also contributes to heating when opportunities for reducing global warming
it is deposited on snow because it reduces overall and are therefore an important part of
reflectivity of the white snow and instead tends saving the Arctic and the polar bear.
to absorb radiation. A recent study indicates
that the direct warming effect of black carbon Nitrous oxide has a global warming
on snow can be three times as strong as that potential 310 times that of carbon dioxide
due to carbon dioxide during springtime in the and an atmospheric lifetime of approximately
Arctic (Flanner 2007). Black carbon emissions 114 years (Forster and Ramaswamy 2007). It
that occur in or near the Arctic contribute the constitutes the second-largest proportion of
most to the melting of the far north (Reddy and anthropogenic non-CO2 gases at 7%. The
Boucher 2007; Quinn et al. 2007). main sources of nitrous oxide emissions are
agriculture, wastewater, fossil fuel combustion,
Reductions in black carbon therefore and industrial adipic and nitric acid
provide an extremely important opportunity production.
to slow Arctic warming in the short term, and
mitigation strategies should focus on within- High global warming potential (High-
Arctic sources and northern hemisphere GWP) gases fall into three broad categories:
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While the ongoing changes in the Arctic of a seasonally ice-free Arctic carries with it the
are now readily apparent, for the most part, likelihood of greatly increased shipping in the
U.S. federal agencies have u�erly failed to region.
incorporate this new reality into their decision-
making affecting the Arctic. With the possible Many of these elements of a changing
exception of the Department of Defense (see, Arctic carry a double threat to the polar bear.
e.g. ONR 2001), federal agencies are making Increased oil and gas development in the Arctic
planning decisions and issuing permits, threatens not just to degrade important polar
authorizations, and leases in and affecting bear habitat, but will also lead to further fossil
the Arctic with a near-total disregard for the fuel commitments, making emissions reduction
rapidly changing conditions in the region. This targets all the more difficult to reach. Increased
is leading to uninformed and unwise decision- shipping in the Arctic carries increased risks
making negatively affecting the polar bear and of oil spills and further disruptions of the
the entire Arctic ecosystem. polar bear’s habitat, but also, perhaps more
importantly, it would lead to a substantial
If U.S. agencies have been slow to recognize injection of additional black carbon directly
and respond to new conditions as the sea ice where it would do the most damage to the
Congressional action and new laws The Marine Mammal Protection Act
explicitly capping and reducing CO2 and non- (MMPA) requires regularly updated stock
CO2 pollutants are clearly necessary if we are assessment reports that summarize the current
to slow and ultimately reverse global warming status of all marine mammals subject to U.S.
and save the Arctic and the polar bear. jurisdiction. 16 U.S.C. § 1361 et seq. Updated
Nevertheless, existing law allows, and in some stock assessments for polar bears and walrus
cases requires, the executive branch to take are two years overdue. Stock assessments
significant action to address the current and for ice-dependant seals relied upon by polar
future impacts of global warming on vulnerable bears for food, while regularly updated, do
human landscapes, natural ecosystems, not incorporate recent information on global
plants, and wildlife. Use of this authority warming and sea-ice declines.
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Analysis of greenhouse gas emissions from federal of the best available science. Nevertheless,
actions: few if any agency decisions directly affecting
the polar bear’s Arctic habitat have properly
The Outer Continental Shelf Lands Act taken into account the changing status of the
(OCSLA) governs the leasing of tracts for species in a melting Arctic. For example, in
offshore oil development in federal waters, August 2006, the Fish and Wildlife Service
including those areas of the Beaufort and issued regulations under the MMPA allowing
Chukchi seas utilized by polar bears. In unlimited take of polar bears from all oil-
approving the 2007-2012 Program covering and gas-related activities in the Beaufort Sea
all offshore leasing in the United States, the region for a period of five years. Despite a
Secretary of Interior refused to quantify the request from the Marine Mammal Commission
greenhouse gas emissions from the oil and gas to consider the impacts of global warming
expected to be produced under the program in making the required determination of
and failed to monetize CO2 and non-CO2 “negligible impact” under the statute, the
pollutants in calculating the economic costs and Service issued the authorization, assuming that
benefits of the program. impacts would be similar to those documented
when similar authorizations were issued more
The National Environmental Policy than a decade previously and prior to the
Act (NEPA) requires the preparation of an substantial changes of sea ice and polar bear
environmental impact statement analyzing population size and distribution evidenced by
all significant impacts of proposed federal recent scientific observations. See 71 Fed. Reg.
actions. Few NEPA documents for significant 43926 (Aug. 2, 2006).
greenhouse gas-generating projects prepared
to date analyze the impacts of such emissions. As the above examples demonstrate,
None that we are aware of analyze the impacts management decisions directly affecting the
of greenhouse gas or black carbon emissions on polar bear have not caught up with the science
Arctic warming or the polar bear. demonstrating significant changes in the status
of the species and its Arctic ecosystem. As
The Endangered Species Act (ESA) uninformed decision-making is o�en unwise
requires each federal agency to ensure through decision-making, the polar bear will continue to
consultation with the Fish and Wildlife Service be harmed by federal agency actions until and
that any federal action does not jeopardize the unless all relevant agencies start incorporating
continued existence of any listed species or the most recent information regarding global
destroy or adversely modify its critical habitat. warming and its impacts on the Arctic into their
16 U.S.C. § 1536. To date, despite the fact decision-making. Climate-informed decision-
that existing regulations require consultation making is already the law; now it needs to be
on any action “directly or indirectly causing translated into action.
modifications to the land, water, or air,” 50
C.F.R. § 402.02, no federal agency has ever B. Reduce Other Stressors on Polar Bears and
engaged in consultation regarding the impacts the Arctic
of greenhouse gas emissions flowing from a
given agency action. While a business-as-usual warming scenario
would doom the polar bear to extinction
Analysis of the changing Arctic in federal decision- and render any other conservation efforts
making: irrelevant, saving the polar bear will require
not just dramatically changing greenhouse
Each of the statutes mentioned above gas emission trajectories but also addressing
require informed decision-making and the use other cumulative threats to the species. While
In 2003 the National Research Council noted Polar bears in the Beaufort Sea and
that “[c]limate warming at predicted rates in elsewhere are already undergoing food stress,
the Beaufort Sea region is likely to have serious and as a consequence resorting to cannibalism
consequences for ringed seals and polar bears, or simply starving (Amstrup et al. 2006; Regehr
and those effects will accumulate with the et al. 2006; Aars et al. 2006). Cub survival is
effects of oil and gas activities in the region.” down (Regehr et al. 2006; Aars et al. 2006).
(NRC 2003). Since the NRC report, both the Denning has shi�ed from occurring mostly on
impacts of global warming on the polar bear ice to mostly on land and numerous bears now
and the cumulative impacts of oil and gas congregate on land pending the fall freeze-up
Figure 8: Current and Proposed Oil & Gas Prices on Alaska’s North Slope
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of the sea-ice (Regehr et al. 2006; Aars et al. which brings with it black carbon emissions,
2006). At the same time, the Beaufort Sea coast the risk of oil spills, and direct disruption and
is becoming increasingly industrialized. This disturbance of polar bears and their prey. The
combination is potentially devastating for the United States should work in appropriate
species. Denning bears with reduced fat stores international fora such as the International
from a shorter hunting season are both more Maritime Organization and the Arctic Council
vulnerable to disturbance from oil industry to prevent the establishment of new shipping
activities and increasingly dependant upon routes in the Arctic. Simultaneously, the United
areas subject to such industrial development. States. should require that any vessel transiting
Similarly, hungry bears, trapped on land, are Arctic waters subject to U.S. jurisdiction utilize
more likely to wander into oil camps and fuels and engine technologies that minimize
facilities looking for food, where their odds black carbon emissions (see, e.g. Ballo and
of being directly killed by humans acting in Burt 2007), and apply for take authorizations
self-defense or being exposed to oil and other to ensure operations are consistent with the
chemicals increases dramatically. MMPA and ESA so as to minimize direct
impacts to polar bears and their prey.
In addition to direct impacts on polar
bears, oil industry activity also impacts their Finally, persistent organic pollutants (POPs)
prey, such as ice seals, which may be exposed represent a significant threat to polar bears and
to seismic surveys, icebreakers, and other other Arctic species. As polar bears operate
disturbances that could either harm these in an increasingly food-stressed state, they
animals or render them less available for bears are likely to metabolize body fat containing
to hunt. Oil industry activity also results in unhealthy concentrations of POPs. The impact
methane and black carbon emissions in the of POPs on individual polar bears can have
Arctic from production activities, and of course both lethal and sub-lethal effects. As polar
substantial CO2 emissions from the ultimate bear populations decline and individual
combustion of the recovered oil and gas. bears become more vulnerable, the disruptive
cumulative effects of POPs on the species are
Given the rapidly changing Arctic, the likely to grow. Reduction or elimination of
precarious status of polar bears, and the these compounds, both through application
numerous adverse impacts of oil and gas of U.S. law and international effort, will likely
industry activities on the species, we believe provide substantial benefits to polar bears.
that there should be a moratorium on new
oil and gas leasing and development in the While many of the cumulative threats to the
range of the polar bear. Such a moratorium polar bear are subject to direct regulation by the
should be implemented immediately and United States and can and must be addressed
remain in effect until and unless such activity immediately, the ultimate survival and recovery
can be demonstrated to not have adverse of the polar bear will require international
impacts on the polar bear, and any greenhouse efforts, not just to reduce greenhouse gas
emissions directly or indirectly associated with emissions and stabilize the climate system, but
such activities are shown to be consistent with to protect the fragile Arctic habitat upon which
a comprehensive national plan to reduce CO2 the polar bear depends.
and non-CO2 pollutants to levels determined
necessary to avoid the continued loss of sea ice. C. Towards an International Arctic Protection
Regime
In addition to oil and gas activities, a
growing cumulative threat to the polar bear is Ultimately, the protection of the polar
likely to be increased shipping in the Arctic, bear and its Arctic habitat is the shared
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IV. Conclusion
W
e are commi�ed to
saving the polar
bear from the
ravages of global warming
for its own sake, as well as
ours. Because the Arctic is
the Earth’s early warning
system, what is happening
to the polar bear now is
a harbinger of what will
happen to the rest of the
world if business-as-usual
politics and emissions
continue. We cannot allow
this to happen. It is not too
late to save the Arctic — if we
take action today. Immediate
reductions in both CO2 and Photo (c) Thomas D. Mangelsen/[Link]
non-CO2 pollutants, along with
protection of the Arctic from direct physical incursions, offer a true window of opportunity and
hope. Acting to reduce greenhouse emissions in a timeframe rapid enough to save the polar bear
will also provide us with the necessary urgency to tackle the challenge of global warming before its
impacts drown not only polar bears but entire cities. We must begin immediately.
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Shindell, D., 2007: Local and remote contributions to Arctic warming. Geophys. Res. Le�., 34,
L14704, doi:10.1029/2007GL030221.
West, J., A.M. Fiore, L.W. Horowitz, and D.L. Mauzerall. 2006. Global health benefits of
mitigating ozone pollution with methane emission controls. Proc. Natl. Acad. Sci. 103:3988-3993.
Page 21
Appendix A: Mitigation Strategies for Non‐CO2
Pollutants
The primary non‐CO2 pollutants are methane, black carbon (soot), nitrous oxide, and
the high global warming potential gases (Figure 4). The global warming potential of each of
these pollutants is more powerful than carbon dioxide—21 (methane) to 23,000 (sulfur
hexafluoride) times as powerful over a 100 year period (Forster and Ramaswamy 2007). The
duration over which each of the gases is present in the atmosphere and contributing to the
greenhouse effect varies from 12 years (methane) to centuries (fluorinated gases). For ease of
comparison, the volume of each pollutant is expressed throughout this report as its “carbon
dioxide equivalent” in millions of metric tons. Thus, 1 million metric tons of methane is
equivalent to 21 million metric tons of CO2 equivalent (MtCO2eq).
A. Methane
Methane is the most important of the non‐CO2 pollutants, with a global warming
potential 21 times greater than carbon dioxide, and an atmospheric lifetime of 12 years (Forster
and Ramaswamy 2007). Methane constitutes approximately 20% of the anthropogenic
greenhouse gas effect globally, the largest contribution of the non‐CO2 gases. However,
methane emissions anywhere in the world will have a disproportionate warming impact in the
Arctic, due to the fact that methane is also an ozone precursor. Tropospheric ozone, unlike
other greenhouse gases, absorbs both infrared radiation and shortwave radiation (visible
light). Thus, tropospheric ozone is a particularly powerful greenhouse gas over highly
reflective surfaces like the Arctic, because it traps shortwave radiation both as it enters the
Earth’s atmosphere from the sun and when it is reflected back out again by snow and ice.
Reducing global methane emissions will reduce ozone concentrations in the Arctic, providing
a double benefit to the region.
According to conservative projections by the U.S. EPA, about 500 MtCO2eq of global
methane emissions reductions could be achieved globally by 2020 at a cost benefit or no cost
(EPA 2006; Table 4, Figure 7). Nearly 70 MtCO2eq of these available reductions are in the
United States (EPA 2006; Table 2, Figure 6). The EPA estimates total technically feasible
methane reductions for 2020 at over 2400 MtCO2eq globally and nearly 280 MtCO2eq in the
US, many of which can be achieved at low cost (EPA 2006; Tables 2 and 4; Figures 6,7).
The EPA’s cost projections are conservative for a number of reasons, including the use
of a 10% discount rate. Using a lower discount rate would result in additional cost benefit or
no‐cost reductions. Moreover, the EPA analysis does not account for the value of significant
air quality and health benefits that would accompany methane reductions. West et al. (2006)
found that reducing global methane emissions by 20% would save 370,000 lives between 2010
Appendix A - 1
and 2030, due to the reduction in ozone related cardiovascular, respiratory, and other health
impacts. Methane reductions would also decrease ozone‐related damage to ecosystems and
agricultural crops (West et al. 2006). Methane is the primary component of natural gas, and
many abatement options include the use of captured methane to generate energy. The benefits
of displacing other fossil fuel energy sources with captured methane are also not captured in
the EPA (2006) analysis.
While EPA (2006) may underestimate available no‐cost and low cost methane (and
other non‐CO2 gas) mitigation options, even this conservative analysis shows the enormous
opportunities available to us today (Tables 1‐4; Figures 6‐7). These reductions can be achieved
with technology available today. Moreover, mandatory greenhouse gas regulation will speed
the development and deployment of new technology and mitigation options, making much
deeper reductions feasible in the very near future.
1. The Waste Sector
Methane produced in the waste sector comes from two main sources: landfills and
wastewater. Landfills produced approximately 12% of all global methane emissions in 2000.
Landfills provide one of the largest single sources of available emissions reductions, as the
EPA (2006) estimates that 88% of landfill methane emissions could be abated with existing
technology. Methane is produced in managed (sanitary) landfills due to the anaerobic
decomposition of organic waste. Approximately 50% of landfill gas is methane and the other
50% is largely made up of carbon dioxide. Sanitary landfills are found predominately in
developed countries. Open dumps that do not promote anaerobic conditions are more
common in developing nations, but these countries are rapidly adopting landfill management
techniques because of the many advantages of sanitary waste disposal. In the US, large
landfills with capacity exceeding 2.5 megagrams (2.8 million short tons) are regulated under
the Clean Air Act.1 Despite the current programs in place, the US is the largest source of
landfill methane in the world, producing in 2000 nearly 3 times as much landfill emissions as
the next largest producer, China (EPA 2006: III‐5).
1
In March of 1996, EPA promulgated guidelines (61 Fed. Reg. 9905) for controlling the emissions from existing Municipal
Solid Waste landfills and the New Source Performance Standards for new or modified Municipal Solid Waste landfills under
authority of Section 111 of the Clean Air Act. Although there are some differences in requirements for landfills constructed
or expanded under different stages of the development of the regulations, in general the guidelines required the following:
1) Installation of gas collection and control systems for new and modified landfills designed to hold 2.755 million tons or
more of waste over their lifetime, and that could be expected to emit more than 50 megagrams per year of non-methane
organic compounds (NMOC).
2) When any landfill reaches the above thresholds, it must within 30 months install a gas collection and control system that
covers all portions of the landfill. The collected landfill gas must be combusted at a high enough temperature to destroy 98
percent of the toxics.
3) Three conditions be met prior to capping or removal of the collection and control system: (1) The landfill must be
permanently closed; (2) the collection and control system must have been in continuous operation a minimum of 15 years;
and (3) the annual NMOC emission rate routed to the control device must be less than 50 megagrams per year.
Appendix A - 2
Landfill methane can be abated either through capture and flaring or use for energy
generation, or by diverting organic material from landfills and into composting and recycling‐
reuse programs. Landfill gases are already captured and flared at a number of U.S. landfills.
A preferable option is to use the methane directly for electricity or heat generation, or to sell it
to industrial users for energy use (EPA 2006). Using methane for energy generation, as
opposed to simply flaring it, has the additional benefit of displacing the emissions that would
have resulted from otherwise supplying the energy created.
The second source of waste emissions is wastewater. Wastewater contributes
approximately nine percent of global methane emissions (EPA 2006). Domestic wastewater
processing involves removing organic matter, solids, pathogens, and chemicals. These
produce a biomass “sludge” that is digested either anaerobically to produce methane, or
aerobically to produce carbon dioxide. Approximately 45% of the sludge is usually digested,
and the remainder is sent to landfills. The amount of methane produced is proportional to the
organic content of the sludge.
Industrial sources with especially high organic content include meat and poultry
processing, pulp and paper processing, and produce processing industries. The EPA estimates
that 77% of meat and poultry wastewater degrades anaerobically due to use of lagoons.
Similarly, lagoons are used for pulp and paper processing.
The abatement options for wastewater include: (1) reduced anaerobic digestion and (2)
collection and subsequent flaring or utilization. Reductions in anaerobic digestion can be
accomplished through aeration and reduced usage of settling lagoons. Collection is used in
series with an anaerobic digester. The collected methane can be flared, or preferably used for
energy generation. EPA (2006) states that because most centralized wastewater treatment
facilities already either flare or use captured methane for safety reasons, the “add‐on”
abatement options to existing systems are limited. Large abatement opportunities depend
primarily on the creation of managed wastewater treatment systems in developing countries,
which will require large‐scale structural changes in wastewater management practices (EPA
2006). Because the primary motivation for the installation of improved wastewater treatment
has historically been the direct public health benefits from disease prevention, EPA (2006) did
not calculate cost estimates. The increasing use of centralized wastewater treatment facilities
worldwide is clearly necessary and will bring enormous benefits both for public health and
climate change mitigation.
2. The Energy Sector
Enormous methane mitigation potential exists in the energy sector. The three main
sources globally are natural gas systems (16 % of total methane emissions), coal mining (6 %)
and oil (0.95%). Abatement opportunities from natural gas systems are particularly promising
as natural gas is a rational transition fuel as the global economy is decarbonized. Oil is more
Appendix A - 3
carbon‐intensive than natural gas, and coal the most carbon‐intensive of all. Coal‐fired power
plants, and therefore coal mining, must be reduced and then eliminated. Nevertheless,
methane abatement opportunities currently exist and should be implemented wherever
mining continues. Mitigation opportunities are also available for abandoned coal mines.
The United States is the top consumer of natural gas and is second only to the Russian
Federation in methane emissions from natural gas systems. Methane emissions occur during
production, processing, transmission and storage, and distribution of natural gas. There are a
variety of mitigation options that address each of these stages.
During extraction, the gas is passed through dehydrators to remove water and other
liquids. It is then transported through lines to a processing facility for further refinement. The
processed gas, which is 95% methane, is then compressed and transmitted to storage and
distribution facilities. Finally, the gas is decompressed to be distributed for home or
commercial use.
Leakage from lines and equipment is the main source of methane emissions. These
emissions can be abated through a variety of methods, which can be broadly categorized as
changes in operational practice, equipment upgrade and replacement, and though direct
inspection and maintenance. A number of these measures will actually save the operator
money, on the order of 20‐25$/tCO2eq (EPA 2006:II‐27).
The second largest source of energy sector methane emissions is coal mining. Methane
is produced as organic matter turns to coal. It accumulates in pockets near a coal seam, and is
eventually released during the mining process. More methane is produced by deeper seams.
Because methane is dangerous, it is extracted and usually vented to the atmosphere. Some
methane is also produced during coal processing and from abandoned mines.
Abatement of mining‐related emissions may be through one of three broad methods: (1)
degasification, where methane is captured but not vented prior to operations; (2) enhanced
degasification, which involves special drilling techniques and capture and use of methane; and
(3) oxidation of ventilation air methane (VAM) to produce energy (EPA 2006). Approximately
57% of the methane obtained through degasification—the drilling of wells or boreholes prior
to mining—can be piped out and sold for energy. If additional enrichment techniques are
used to further refine the methane obtained during degasification, called enhanced
degasification, approximately 77% of the methane may be sold for energy. Finally,
approximately 97% of ventilation air methane, which is a much lower concentration, can be
mitigated through oxidation and use for local energy. Due to its low concentration of
methane, this gas is not suitable for distribution.
Because the captured methane can be used or sold for energy, approximately 17% of
emissions can be abated at no cost or positive economic benefit. At a cost of less than 15$ per
Appendix A - 4
tCO2eq, approximately 80% of emissions from coal mining could be eliminated. Profitable
options have been addressed in EPA’s Coalbed Methane Outreach Program started in 2001 to
reduce and use coal mine methane ([Link]
The third major energy‐sector source of methane is oil production. Fugitive emissions
are released during crude oil production, transportation, and refining (EPA 2006). Oil
production accounts for approximately 97% of these methane emissions. Methane emissions
from onshore oil production are more easily captured and transported than those from
offshore production.
The major sources of production emissions are: volatilization of high pressure crude oil
as it enters the holding tank, equipment leaks and vessel blowdowns (removal of liquids
through pressurization), and fugitive leaks and combustion during flares (EPA 2006).
There are three abatement options: (1) flaring instead of venting; (2) direct use for
energy; and (3) reinjection of the methane to the oilfield to enhance later oil recovery. Safety
considerations make flaring more feasible at onshore facilities. This measure has the potential
to reduce methane emissions by 98% over 15 years. Flaring is the least preferred mitigation
option as it does not produce energy, thereby displacing other emissions, yet results in
additional CO2 emissions. The second option is the direct use of the methane for energy at
offshore platforms, and has the potential to reduce 90% of methane emissions. The third
option is to re‐inject the methane into the oilfield. This can reduce methane emissions by 95%
over 15 years.
3. The Agricultural Sector
Agriculture accounts for approximately 52% of global methane emissions, and these are
expected to increase by 30% in 2020 (over 2000 levels). The main agricultural sources of
methane are rice fields and livestock. Methane emissions from rice fields occur due to
anaerobic decomposition of organic matter in flooded rice fields. The majority (90% of
emissions) of rice production occurs in Asia. Management practices that include variation in
the timing of field flooding, tilling practices, and fertilization can reduce the amount of
methane production.2
The second major source of agricultural methane is livestock. This includes both
methane gas emitted by ruminants as a result of digestion (enteric fermentation) and methane
emitted by manure. While all ruminants produce some methane, the majority of global
methane emitted due to enteric fermentation comes from cows used for beef and dairy
production. Switching to higher quality feed and lower volumes of feed can reduce methane
2
Some agricultural practices which reduce methane emissions lead to an increase in nitrous oxide production, and thus
mitigation options must be carefully tailored so that only measures resulting in a net decrease in greenhouse gas emissions
are implemented.
Appendix A - 5
from enteric fermentation because high quality feed increases the proportion of energy that is
available for use by the animal and consequently reduces the amount that is wasted as
methane.3 As a result, these mitigation options actually have a net economic benefit for the
producer.
Methane is also produced by manure during anaerobic decomposition. These
conditions occur when liquid manure is stored in lagoons, ponds, tanks, and pits. The trend in
the U.S. is to increasingly store manure under these conditions. Furthermore, duration of time
stored in this manner and temperature affect the amount of methane that is produced.
The mitigation options for manure methane involve different types of methane
digesters that can capture the methane and produce energy. A manure digester is a system of
containers to collect and biologically treat manure with naturally occurring microorganisms.
The anaerobic environment facilitates the generation and capture of methane. The methane
can then be burned to convert to CO2, and to produce heat and/or electricity. Digesters may
also include systems to collect and separate solids. Large‐scale digesters can be used for
capture and off‐site energy use while temperature digesters can be used at smaller facilities
where the energy is used on‐site.
C. Black Carbon or Soot
Black carbon, or soot, consists of particles or aerosols released through the burning of
fossil fuels, biofuels, and biomass (Quinn et al. 2007). Black carbon warms the atmosphere, but
it is a solid, not a gas. Unlike most greenhouse gases that warm the atmosphere by absorbing
longwave infra‐red radiation, soot warms the atmosphere by absorbing visible light
(Chameides and Bergin 2002). Black carbon is an extremely powerful greenhouse pollutant.
Scientists have described the average global warming potential of black carbon as about 500
times that of carbon dioxide over a 100 year period (Hansen et al. 2007; see also Reddy and
Boucher 2007; Bond and Sun 2005). This powerful warming impact is remarkable given that
black carbon remains in the atmosphere for only about four to seven days, with a mean
residence time of 5.3 days (Reddy and Boucher 2007).
Black carbon contributes to Arctic warming through the formation of “Arctic haze” and
through deposition on snow and ice, which increases heat absorption (Quinn et al. 2007;
Reddy and Boucher 2007). Arctic haze results from a number of aerosols in addition to black
carbon, including sulfate and nitrate (Quinn et al. 2007). Arctic haze may either increase or
decrease warming, but when the haze contains high amounts of soot, it absorbs incoming solar
radiation and leads to heating. In addition, aerosols may interact with clouds changing
droplet number and size, which in turn can alter albedo, or reflectivity.
3
High-energy feed, such as grain, can also increase the methane produced by the manure. However, the need for a trade-off
between lower enteric fermentation emissions and manure emissions will be eliminated if manure emissions are mitigated
through the use of digesters.
Appendix A - 6
Soot also contributes to heating when it is deposited on snow because it reduces
reflectivity of the white snow and instead tends to absorb radiation. A recent study indicates
that the direct warming effect of black carbon on snow can be three times as strong as that due
to carbon dioxide during springtime in the Arctic (Flanner 2007). Black carbon emissions that
occur in or near the Arctic contribute the most to the melting of the far north (Reddy and
Boucher 2007; Quinn et al. 2007).
Reductions in black carbon therefore provide an extremely important opportunity to
slow Arctic warming in the short term, and mitigation strategies should focus on within‐Arctic
sources and northern hemisphere sources that are transported by air currents most efficiently
to the Arctic.. Conversely, allowing black carbon emissions to increase in the Arctic as the
result of increased shipping or industrial activity, will accelerate loss of the seasonal sea ice
and extinction of the polar bear. Black carbon reductions will also provide air quality and
human health benefits.
Despite its significance to global climate change and to the Arctic in particular, black
carbon has not been addressed by the major reports on non‐CO2 gas mitigation, nor is it
explicitly addressed in current global warming bills in the 110th Congress. Black carbon
reductions are an essential part of saving the Arctic sea ice and the polar bear, and should be
addressed by Congress in this session.
The highest priority sources for regulation include the following: diesel generators and
residential stoves within the Arctic, ships operating in or near Arctic waters, diesel truck and
automobile engines, and biomass burning.
Specific measures that should be implemented include replacing diesel generators with
alternative energy sources, improving the efficiency and/or particulate matter traps on
residential stoves, or fuel switching in residential stoves.
Ships operating in or near Arctic waters can introduce black carbon directly into the
region and should therefore be stringently regulated. One of the simplest ways to reduce
black carbon emissions from ships is simply to slow them down (Ballo and Burt 2007:26). A
ten percent reduction in speed can result in a 23.3 percent reduction in emissions (Ballo and
Burt 2007:27). Requiring ships to switch to cleaner, lower sulphur content fuels will also
reduce black carbon emissions (Ballo and Burt 2007:29). There are a variety of design changes
available to increase the efficiency of ships and therefore decrease their emissions (Kleiner
2007). Finally, shipping should be stringently limited in the Arctic, as discussed above.
All diesel engines are a significant contributor to black carbon emissions. Emissions
from diesel cars and trucks should be more stringently regulated (Jacobson 2002). Abatement
options include upgrading vehicles, installing end of the pipe filters, better vehicle
maintenance, and buy out/buy back programs for super emitters.
Appendix A - 7
Emissions reductions from biomass burning and other sources are most important
when the Arctic ice extent is relatively large (Quinn et al. 2007), and therefore regulating both
the amount and timing of anthropogenic biomass burning can also reduce black carbon levels
in the Arctic.
Much more attention needs to be focused on identifying and implementing black
carbon emissions from all sources.
D. Nitrous Oxide
Unlike methane and black carbon, nitrous oxide and the high global warming potential
gases discussed below do not have a disproportionate impact on the Arctic. Nevertheless,
because these gases have high global warming potential, long atmospheric lifetimes, and
because there are many readily available mitigation measures to reduce them, they present
important opportunities for reducing global warming overall and are therefore an important
part of saving the Arctic and the polar bear.
Nitrous oxide has a global warming potential 310 times that of carbon dioxide and an
atmospheric lifetime of approximately 120 years. It constitutes the second largest proportion
of anthropogenic non‐CO2 gases at 7%. The main sources of nitrous oxide emissions are:
agriculture, fossil fuel combustion, and industrial adipic and nitric acid production.
1. Agriculture
Agriculture is the largest source of anthropogenic nitrous oxide (84%) (EPA 2006).
These emissions are projected to increase by 37% in 2020 (over 2000 levels). Agricultural
nitrous oxide is produced primarily (1) through the processes of nitrification and
denitrification of soil, (2) by livestock manure, and (3) from rice farming.
Nitrous oxide emissions occur as a result of addition of nitrogen to the soil through
fertilization, nitrogen‐fixing crops, retention of crop residues, and cultivation of high organic
content soil (peat or histosol) (EPA 2006). Nitrous oxide emissions can also result from
volatilization of applied nitrogen and runoff.
In 2000, the United States’ soil nitrous oxide emissions were second only to the former
Soviet Union, and are predicted to surpass the FSU by 2010. Practices such as irrigation,
drainage, tillage, and fallowing all influence nitrous oxide emissions.
An important consideration when selecting abatement options is that a number of
practices may reduce nitrous oxide emissions while increasing carbon dioxide emissions,
resulting in a net increase in greenhouse gases. The abatement options presented below are
those that do not result in increased carbon dioxide emissions.
Appendix A - 8
The options include reduced fertilization or more efficient fertilization, and no‐till
management to maintain at least 30% of the ground covered by crop residue after planting.
The most effective fertilization option is the use of a fertilizer that includes a nitrification
inhibitor. No‐till, or conservation tillage, is effective primarily because it reduces carbon loss.
The net reductions potential for croplands is approximately 24%, with 15% possible at zero net
cost.
Rice fields produce both methane and nitrous oxide. The cycle, however, is different for
each of the gases so that some methods that reduce one gas may increase the other. Thus,
management practices must be considered carefully to balance the effects. Shallow flooding,
off‐season straw, and ammonium sulfate are the management practices that can reduce nitrous
oxide emissions as well as methane emissions. The practice of mid‐season drainage reduces
methane substantially while increasing nitrous oxide. Yet, due to the magnitude of methane
reduction, this practice results in a net reduction of equivalent greenhouse gases.
The final major agricultural source of nitrous oxide is livestock manure. The practices
outlined above for reductions in methane emissions from livestock manure also apply to
reductions in nitrous oxide.
2. Industrial production
The production of nitric and adipic acid account for approximately 5% of nitrous oxide
emissions. Nitric acid accounts for approximately 67% and adipic acid accounts for
approximately 33% of emissions. Nitric acid is used in fertilizers as well as explosives, metal
processing, and etching. Adipic acid is a component of nylon, synthetic lubricants and
plastics, polyurethane resins, and plasticizers. It is also used in some artificial foods to impart
a “tangy” flavor.
Plants that produce nitric acid and do not employ nonselective catalytic reduction may
generate up to 19 kilograms of nitrous oxide per ton of nitric acid. The majority of plants in
the US do not use this technology, and approximately 80% of plants worldwide do not use it.
Nitric acid plants can reduce their emissions by 90 to 95% through high‐temperature or low‐
temperature catalytic reduction. The costs are minor: approximately $2‐$6/tCO2eq. The high‐
temperature option is less expensive and reduces nitrous oxide by 90%. The low‐temperature
option costs slightly more and reduces emissions by 95%.
The abatement option for adipic acid plants is thermal destruction. This option costs
only $0.50/tCO2eq and can reduce nitrous oxide emissions by 98 to 99%.
Appendix A - 9
E. High Global Warming Potential Gases
High global warming potential (High‐GWP) gases fall into three broad categories:
hydrofluorocarbons (HFCs), perfluorcarbons (PFCs), and sulfur hexafluoride.
Hydrofluorocarbons were developed to replace ozone‐depleting substances used in
refrigeration and air conditioning systems, solvents, aerosols, foam production, and fire
extinguishing. HFCs have global warming potentials between 140 and 11,700 times that of
carbon dioxide, and their atmospheric lifetimes range from one year to 260 years, respectively.
Perfluorocarbons are emitted during aluminum production and semiconductor
manufacture (EPA 2006). Their global warming potential ranges from 6,500 to 9,200 times that
of carbon dioxide. In addition, they have extremely long atmospheric lifetimes, e.g. 10,000 and
50,000 years for two common PFCs.
The highest global warming potential exists in sulfur hexafluoride at 23,900 times that
of carbon dioxide. Sulfur hexafluoride remains in the atmosphere for 3,200 years. Sulfur
hexafluoride is used: (1) for insulation and current interruption in electrical power
transmission and distribution; (2) during semiconductor manufacture; (3) to protect against
burning in the magnesium industry.
1. Hydrofluorcarbons
a. Refrigeration and Air Conditioning
Hydrofluorocarbons are used for refrigeration and air conditioning, solvents, foam
manufacture, aerosols, and in fire extinguishers. The emission of hydrofluorocarbons related
to refrigeration occurs during manufacturing and servicing, leaks during operation, and
disposal. An indirect effect of using these systems is the use of energy and resulting emission
of carbon dioxide. Thus, mitigation measures should be evaluated both for direct HFC
emissions as well as carbon dioxide emissions.
There are a variety of uses for refrigeration systems: household refrigeration, car air‐
conditioning, chillers for large spaces such as shopping malls as well as submarines and
nuclear reactors, retail food refrigeration, cold storage warehouses, refrigerated transport,
industrial refrigeration during manufacture, and residential and commercial air conditioning
and heat pumps. Because a number of these systems currently use ozone‐depleting substances
that are being phased out as equipment ages, the impact of switching systems has been
incorporated into the mitigation analysis (EPA 2006).
The abatement options fall into three categories: practice options, alternative refrigerant
options, and technology options. Practice includes actions such as leak repair, refrigerant
Appendix A - 10
recovery/recycling, and sales restrictions on HFCs. The alternative refrigerants include
ammonia, hydrocarbons such as isobutene, and carbon dioxide.
Many of the abatement options carry a net economic benefit, such that the U.S. alone
could reduce over 20 metric tons CO2eq emissions by the year 2020 at no cost or at a net
economic benefit.
b. Solvents
Solvents used in precision and electronic cleaning, and to a much lesser extent metal
cleaning, have replaced ozone‐depleting substances in a variety of ways, including
substitution of HFCs and PFCs. There are three main mitigation options: (1) improved solvent
containment and use of carbon absorption; (2) use of aqueous or semi‐aqueous cleaning
processes; and (3) conversion to different low‐global warming potential compounds or organic
compounds.
The conversion to alternative compounds is a no‐cost abatement option that could
reduce baseline emissions by approximately 25% by the year 2020. Similarly, conversion to
semi‐aqueous cleaning processes would only cost approximately $0.67/tCO2eq.
c. Foam manufacture
HFCs are used during the blowing process to produce foam. These emissions are
expected to rise dramatically in coming years. Another ozone ‐depleting substance,
hydrochloroflurocarbons (HCFCs), is still in use in developing countries, but will be phased
out with time. The US currently allows the use of HCFC‐22, but not HCFC‐141b.
Emissions occur during the manufacture process, during foam application, while foams
are in use, and when they are discarded. Abatement can be achieved through replacement of
the blowing agent used in the manufacture process and proper disposal of appliance foam at
end‐of‐life. Several of the replacement options would bring a net economic benefit. The total
possible reduction from the predicted 2020 baseline emissions is approximately 31%.
d. Aerosols
Aerosols are used to propel a variety of products. After CFCs were banned in the US,
some products began using HFCs as propellants. Medical applications, such as inhalers,
currently still use CFCs, but these companies are developing HFC alternatives.
Abatement of non‐medical HFC emissions involves replacing current HFCs with other
HFCs that have a lower global warming potential, hydrocarbon propellants, and other
application methods such as hand pumps, roll‐on applicators, and powders. All of these non‐
Appendix A - 11
medical options can be achieved at no cost and would reduce current HFC emissions by at
least 57% in the year 2020.
Transitioning away from CFCs has proven to be a challenge with medical inhalers. One
alternative for some patients, however, is the use of dry powdered inhalers. The use of this
application method has the capability of reducing medical propellant HFC emissions by half.
e. Fire Extinguishing
Halon was traditionally used in fire extinguishing systems—both portable fire
extinguishers and “total flooding” systems that protect large spaces. Due to its ozone
depleting characteristics, halon is being replaced in some instances with HFCs.
Depending on the application, HFC systems can be replaced by inert gas systems, water
mist systems, or fluorinated ketone systems. In addition, abatement can be achieved through
recovery and reuse of HFCs and through improved detection mechanisms to prevent
erroneous release in total flooding systems.
f. HCFC‐22
As mentioned above, HCFC‐22 is an ozone depleting substances that is used in
refrigeration, some solvents, and synthetic polymer production. One of the byproducts is
HFC‐23, which has a global warming potential of 11,700 times that of carbon and an
atmospheric lifetime of 260 years. The US is close behind China as the second largest producer
of HFC‐23 emissions resulting from production of HCFC‐22.
There are several options for mitigating HFC emissions. Manufacturing optimization
can maximize HCFC‐22 production and minimize HFC‐23 production at very lost cost.
Thermal oxidation of HFC‐23 by product can reduce 95% of HFC emissions. Oxidation costs
only about $0.23/tCO2eq and can reduce HFC emissions at existing plants by 88%, even
assuming that current plans to minimize HCFC‐22 are implemented.
At the commemoration meeting of the Montreal Protocol on September 21, 2007, the
U.S. and other developed nations agreed to a schedule of reductions that includes ceasing to
use HCFCs by 2020, which is 10 years sooner than previously agreed. Thus, the assumptions
upon which the EPA 2006 report were based may be inapplicable.
Appendix A - 12
2. Perfluorocarbons
a. Aluminum production
The aluminum industry is the largest source of PFC emissions. PFCs are emitted when
so‐called anode effects occur during the smelting process. The amount of PFCs emitted
depends directly on the number and duration of such events.
Although the aluminum industry has taken voluntary reductions and has pledged
further reductions, there are still mitigation options that should be implemented to further
reduce emissions. The two main methods are: installation of computer control systems and
installation of alumina point‐feed systems. The computer control system is considered a
minor retrofit and the alumina point‐feed system is considered a major retrofit. The efficacy of
these measures depends on the current technology used by the plant. They may reduce PFC
emissions by up to 97% when combined at some facilities. The implementation of these
options can also come at an economic benefit in some facilities.
b. Semiconductor manufacturing
The manufacture of semiconductors releases PFCs, sulfur hexafluoride, and HFC‐23
primarily during plasma etching of thin films and cleaning chemical‐vapor‐deposition (CVD)
chambers. Etching is estimated to account for approximately 20% of emissions, while CVD
chamber cleaning accounts for approximately 80%. PFC emissions also occur as a by‐product
of reactions between other gases. The U.S. is the second largest emitter of PFCs, although it is
a member of the World Semiconductor Council, which has committed to voluntary reductions
in emissions.
The most effective abatement option is nitrogen trifluoride remote cleaning technology.
This system can reduce emissions by approximately 95%. This option has a net economic
benefit and when implemented could reduce baseline emissions by 42%, even assuming the
industry meets its voluntary emissions reduction goal. The second most effective option is
point‐of‐use plasma abatement during the etching process.
3. Sulfur hexafluoride
a. Electrical industry
Sulfur hexafluoride is primarily emitted by the electrical industry. Sulfur hexafluoride
is used as a dielectric insulator in transmission lines, sub‐stations, and transformers. The
United States is the largest emitter of sulfur hexafluoride. The electric industry has recently
begun reducing its sulfur hexafluoride emissions, however much more remains to be done.
Appendix A - 13
Sulfur hexafluoride emissions can be reduced through sulfur hexafluoride recycling,
leak detection and repair, and equipment refurbishment. Recycling presents the greatest
opportunity for mitigation, with a net economic benefit and potential for emissions reduction
of approximately 43% above and beyond currently planned reductions. Many companies
already recycle sulfur hexafluoride. The average efficacy of their systems is 80%, but this
could easily be increased to provide for 95% reductions in sulfur hexafluoride emissions. Leak
detection and repair can reduce emissions that occur during operation. Finally, equipment
refurbishment can also reduce emissions.
b. Magnesium production
Sulfur hexafluoride is currently used as a cover gas during magnesium production to
prevent spontaneous combustion. Essentially all of the sulfur hexafluoride is emitted into the
atmosphere. The International Magnesium Association, representing 80% of the industry, has
pledged to eliminate sulfur hexafluoride by 2011. They will do so by substituting different
cover gases.
Emissions can be abated by replacing sulfur hexafluoride with either sulfur dioxide or
fluorinated gases. New technology has solved the toxicity, corrosion, and odor concerns
associated with sulfur dioxide. Thus, it is can fully eliminate emissions that contribute to
global warming, and is relatively inexpensive. The replacement of sulfur hexafluoride with
fluorinated gases is also possible, although these gases still have global warming effects.
Appendix A - 14
Table 1: United States Non‐CO2 Emissions and Potential Reductions for 2010
Non-CO2 Sector Baseline No-Cost No-Cost < $15/ < $15/ Techno- Techno-
Gas emissions reduction reduction tCO2eq tCO2eq logically logically
(MtCO2eq) (%) (MtCO2eq) reduction reduction feasible feasible
(%) (MtCO2eq) reduction reduction
(%) (MtCO2eq)
Methane Livestock 173.0 6.4 11.1 9.4 16.3 21.4 37.0
(CH4) Landfill 125.4 10.0 12.5 42.1 52.8 87.3 109.5
Wastewater 36.1 N/A
Coal mining 51.1 49.2 25.2 86.0 43.9 86.0 43.9
Natural gas 138.6 14.5 20.1 19.2 26.7 54.8 75.9
Oil 3.7 0.0 0.0 17.7 0.7 21.8 0.8
CH4 Total 527.9 13.0 68.9 26.6 140.4 50.6 267.1
SF6 Electric power 12.8 35.0 4.5 41.0 5.3 41.0 5.3
Mg production 1.2 0.0 0.0 97.5 1.2 97.5 1.2
SF6 Total 14.0 32.0 4.5 45.9 6.4 45.9 6.4
All Tables: Emissions and potential reduction for global Non‐CO2 gases. All values are taken from EPA report 430‐R‐06‐005,
Global Mitigation of Non‐CO2 Greenhouse Gases (2006). As discussed in the text, EPA (2006) calculations are conservative, and
thus underestimate the no‐cost and low cost mitigation opportunities. The baselines reported here do not account for all
emissions; they only account for emissions that EPA determined should be considered for mitigation measures. Some sectors
emit multiple types of greenhouse gas. In these instances, the emissions for the sector were attributed to the Non‐CO2 gas that
is present in the largest proportion. For industries that have committed to some improvement in technology, the baseline and
reductions are based on assumptions that these technologies will be adopted.
Appendix A - 15
Table 2: United States Non‐CO2 Emissions and Potential Reductions for 2020
Non-CO2 Sector Baseline No-Cost No-Cost < $15/ < $15/ Techno- Techno-
Gas emissions reduction reduction tCO2eq tCO2eq logically logically
(MtCO2eq) (%) (MtCO2eq) reduction reduction feasible feasible
(%) (MtCO2eq) reduction reduction
(%) (MtCO2eq)
Methane Livestock 171.0 6.3 10.8 11.8 20.2 23.0 39.3
(CH4) Landfill 123.5 10.0 12.4 42.1 52.0 87.3 107.8
Wastewater 37.8 N/A
Coal mining 46.4 49.2 22.8 86.0 39.9 86.0 39.9
Natural gas 164.8 14.5 23.9 19.2 31.7 54.8 90.2
Oil 4.5 0.0 0.0 17.7 0.8 21.8 1.0
CH4 Total 548.0 12.8 69.9 26.4 144.6 50.8 278.3
SF6 Electric power 11.8 0.0 0.0 31.3 3.7 31.3 3.7
Mg production 1.0 0.0 0.0 90.0 0.9 90.0 0.9
SF6 Total 12.8 0.0 0.0 35.9 4.6 35.9 4.6
Appendix A - 16
Table 3: World Non‐CO2 Emissions and Potential Reductions for 2010
Non-CO2 Sector Baseline No-Cost No-Cost < $15/ < $15/ Techno- Techno-
Gas emissions reduction reduction tCO2eq tCO2eq logically logically
(MtCO2eq) (%) (MtCO2eq) reduction reduction feasible feasible
(%) (MtCO2eq) reduction reduction
(%) (MtCO2eq)
Methane Rice 708 10.5 74.3 21.9 155.1 24.9 176.3
(CH4) Livestock 2548 3 76.4 4.4 112.1 6.8 173.3
Landfill 760.6 11.7 89.0 40.5 308.0 87.8 667.9
Wastewater 594 N/A
Coal mining 407.6 16.6 67.7 79.8 325.4 79.8 325.4
Natural gas 1271.5 10.1 128.5 25.0 317.6 53.4 678.5
Oil 82.9 0 0 28.1 23.3 34.7 28.8
CH4 Total 6372.6 6.8 436.0 19.5 1241.5 32.2 2050.1
SF6 Electric power 46.8 45.8 21.4 50.2 23.5 50.2 23.5
Mg production 3.6 0 0 94.4 3.4 94.4 3.4
SF6 50.4 42.5 21.44 53.4 26.9 53.4 26.9
Total
Appendix A - 17
Table 4: World Non‐CO2 Emissions and Potential Reductions for 2020
Non-CO2 Sector Baseline No-Cost No-Cost < $15/ < $15/ Techno- Techno-
Gas emissions reduction reduction tCO2eq tCO2eq logically logically
(MtCO2eq) (%) (MtCO2eq) reduction reduction feasible feasible
(%) (MtCO2eq) reduction reduction
(%) (MtCO2eq)
Methane Rice 776.0 10.5 81.5 21.9 169.9 24.9 193.2
(CH4) Livestock 2867.0 2.9 83.1 4.4 126.1 6.7 192.1
Landfill 816.9 11.8 96.6 40.7 332.3 87.8 716.9
Wastewater 665.0 N/A
Coal mining 449.5 14.5 65.2 79.8 358.7 79.8 358.7
Natural gas 1695.8 10.2 172.8 25.3 428.2 53.8 912.5
Oil 131.8 0.0 0.0 29.0 38.2 35.8 47.2
CH4 Total 7402.0 6.7 499.2 19.6 1453.5 32.7 2420.6
SF6 Electric power 57.5 40.9 23.5 50.2 28.9 50.2 28.9
Mg production 4.8 0.0 0.0 96.5 4.6 96.5 4.6
SF6 Total 62.3 37.7 23.5 53.8 33.5 53.8 33.5
Appendix A - 18
Table 5: Global Mean Annual Budget of BC for Different Geographical Regions
Emissions Contribution Contribution to
Tg/yr of Biofuels Global Dry Global Wet Burden x 100 Residence Surface Deposition
(regional (regional Deposition Deposition Tg (regional Time North to 60N,
Region contribution) contribution) (Tg/yr) (Tg/yr) contribution) (days) South to 60S
SAM 0.314 (6%) 5%c (25%) 0.049 0.265 0.452 (6.5)% 5.28 1%
NAM 0.522 (11%) 6% (20%) 0.092 0.430 0.697 4.80 11%
(10.0%)
AFR 0.483 (10%) 21% (72%) 0.088 0.395 0.947 7.16 1%
(13.6%)
EUR 0.602 (12%) 5% (13%) 0.128 0.474 0.823 5.01 63%
(11.8%)
WCA 0.157 (3%) 1% (11%) 0.040 0.117 0.312 (4.5%) 7.29 2%
SAS 0.602 (13%) 25% (68%) 0.120 0.483 1.086 6.59 2%
(15.6%)
EAS 2.038 (43%) 36% (29%) 0.333 1.708 2.565 4.60 17%
(36.8%)
AUP 0.036 (1%) <1% (14%) 0.006 0.030 4.062 (0.7%) 4.62 1%
OCE 0.036 (1%) – (– ) 0.007 0.029 0.042 (0.6%) 4.24 2%
Global 4.791 34% 0.860 3.931 6.970 5.32 –
Table 1 from Reddy, M.S. and Boucher, O (2007), Climate impact of black carbon emitted from energy
consumption in the world’s regions, Geophysical Research Letters, 34: L11802. Regional abbreviations: SAM, South
America; NAM, North America; AFR, Africa; EUR, Europe; WCA, West and Central Asia; SAS, South Asia; EAS,
East Asia; AUP, Australia and Pacific Islands; OCE, Oceanic Regions.
Appendix A - 19