Version No.

06- Revision Date 27/04/2011

MATERIAL SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION
Product name : UNY MARINE HS , BASE Product No. : 5512
Manufacutrer / Supplier : TOA-Chugoku Paints Co.,Ltd
110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpokong Chachoengsao, 24180
Telephone no. 66 02 2602701-8 , 66 038 570498-9 Fax : 66 02 2602700 , 66 038 570500
In case of emergency : Telephone no. 66 02 2602701-8 , 66 038 570501
Material intended use : Coating: Solvent ( Refer to technical data sheet )
2. HARZARDS IDENTIFICATION

3. COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following hazardous ingredients
Ingredient name CAS No. EINECS No. % by weight Classification
Xylene 1330-20-7 215-535-7 15 - 20 R10
Xn; R20/21
Xi; R38
n-butyl acetate 123-86-4 204-658-1 1-5 R10
R66, R67
solvent naphtha (petroleum), light aromatic 64742-95-6 265-199-0 2 R10
Xn; R20, R65
Xi; R37
R66
N; R51/53
4. FIRST-AID MEASURES

First-aid measures
General : In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation : Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious, place in recovery position and seek medical advice.
Ingestion : If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.

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 Version No.06- Revision Date 27/04/2011

5. FIRE FIGHTING MEASURES

Extinguishing media : Recommended : alcohol-resistant foam, CO2, powders, water spray.
Do not use - water jet.
Recommendation : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Approprirate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove sauces of ignition and ventilation the area, avoid breathing vapour or mist.
Do not turn lights or unprotected electricalequipment on or off.
Spill : Contain and absorb spillage with non-combustible material e.g. sand, earth, vermiculite.
Place in closed container outside building and disposal according to local regulation.
Preferably clean with a detergent. Do not use solvents.
Do not allow spills to enter drains or watercauses.
If drain, lakes, river, or sewers are contimated , inform the appropriateauthorities in
accordance with local regulations.
Note : see section 8 for personal protective equipment and section 13 for waste disposal.

7. HANDLING AND STORAGE

Handling : This coating contains solvents. Solvent vapours are heavier than air and may spread along floors.
vapours may form explosive mixtures with air. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentrations higher than the occupational exposure limits.

In storage : Handle containers carefully to prevent damage and spillage.

Naked flames and smoking should not be permitted in storage areas. It is recommended that
fork lift trucks and electrical equipment are protected to the appropriate standard.

In use : Avoid skin and eye contact. Avoid inhalation of vapours and spray mists.

Observe label precaution. Put on appropriate personal protective equipment.

Smoking, eating and drinking should be prohibited in areas where this material is handled.

Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made
from the same material as the original one.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static and
antistatic footwear; floor should be conductive type.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapour in all case. In such
circumstances they should wear a compressed air-fed respirator during the spraying process
and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
Storage ; Store in accordance with local regulation. Observe label precautions. Store in a cool,
well ventilated area away from incompatible materials and sauce of heat and direct sunlight.

Keep away from ; oxidising agent, strong alkalis, strong acids.

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 Version No.06- Revision Date 27/04/2011

Storage Store on concrete or other impervious floor, preferably with bunding to contain any spillage.
Do not stack more than 3 pallets high.
Keep container tightly closed. Container that have been opened must be carefully resealed and
kept upright to prevent leakage.
Prevent unauthorised access.
This is highly flammable liquid. Refer to the requirements of local regulations for the storage
and handling regulations petaining to this material.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Provide adequate ventilation. Where resonably practicable, this should be achived by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and solvent vapours below the occupational exposure limits (OEL)
suitable respirator must be worn.
Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Material STEL-15 min.ave Long term-TWA-8hr

xylene 150 ppm 100 ppm
solvent naphtha (petroleum), light aromatic - 100 mg/kg
naphtha (petroleum), hydrotreated heavy - 100 mg/kg
n-butyl acetate 200 ppm 150 ppm

Personal protection equipment

Respiratory Protection : Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered
if practical.
Eye Protection : Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of
liquids. Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection : Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection : Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

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 Version No.06- Revision Date 27/04/2011

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : ( ) Solid ( x ) Liquid Odour : Smell of solvent Density : 1.23 g/cm3
( ) Paste ( ) Powder Colour : Various Flash point : 23 °C
Solubility : Insoluble in water Explosion limits : LEL% 0.6 UEL% 12.3

Vapour pressure : 9700 Pa, 20 °C Autoignition temperature : 370 °C

10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see section 8). When exposed to high teemperatures may produce
hazardous decomposition products such as carbon monoxide, carbon dioxide, oxide of nitrogen ans smkoe.

Keep away from oxidising agents, strongly alkaline and strong acid materials in order to avoid possible exothermic reactions.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.

Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
Aquatic ecotoxicity
Material name Test Result Species Exposure
xylene Mortality Actute LC50 3300 to 4093 u/L Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
trout,donaldson-trout-
Oncorhynchus mykiss
solvent naphtha - Acute EC50 < 10 mg/L Daphnia 48 hours
(petroleum), light aromatic - Acute IC50 < 10 mg/L Algae 72 hours
- Acute LC50 < 10 mg/L Fish 96 hours.
n-butyl acetate Mortality Actute LC50 18000 to 19000 u/L Fish-Fathead minnow 96 hours
Fresh water Pimephales promelas

13. DISPOSAL CONSIDERATION

Method of disposal : Do not allow into drain or water courses. Wastes and empty containers should be disposal
of in accordance with regulations made under the Control of Pollution Act and the
Environmental Protection Act.

Using information provided in this data sheet advice should be obtained from the Waste
Regulation Authority, whether the special waste regulations apply.

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 Version No.06- Revision Date 27/04/2011

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint
UN number : 1263
Class : 3
Packing group : III
Label :

Additional information
ADR / RID : Hazardous identification no. : 30
: Special provision : 640E
IMDG : Class : 3
Proper shipping name : Paint
Emergency schedules (EmS) : F-E, S-E
Marine pollutant : No

15. REGULATORY INFORMATION

The product complies with these local regulations.

EU regulations : The product is classified and labelled for supply in accordance with the Directive 1999/45/EC
as follows:
hazard symbol :

Harmful

Risk phrases : R10 Flammable

R20/21 Harmful by inhalation and in contact with skin
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Safety pharses : S23 Don not breathe vapour / spray.

S36/37 Wear suitable protective clothing and gloves.
S51 Use only in well-ventilated areas.

Contains : Xylene

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 Version No.06- Revision Date 27/04/2011

16. OTHER INFORMATION

CEPE Classification : 1
Full text of R-pharses : R10 Flammable
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R37 irritataing to respiratory system and skin.
R38 Irritaing to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours mau cause drowsiness and dizziness.

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Material Safety Data Sheet is required according to legislation.

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 Version No.06- Revision Date 27/04/2011

MATERIAL SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : UNY MARINE HS , HARDENER Product No. : 5512

Manufacutrer / Supplier : TOA-Chugoku Paints Co.,Ltd
110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpokong Chachoengsao, 24180
Telephone no. 66 02 2602701-8 , 66 038 570498-9 Fax : 66 02 2602700 , 66 038 570500
In case of emergency : Telephone no. 66 02 2602701-8 , 66 038 570501
Material intended use : Coating: Solvent ( Refer to technical data sheet )
2. HARZARDS IDENTIFICATION

3. COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following hazardous ingredients

Ingredient name CAS No. EINECS No. % by weight Classification

Xylene 1330-20-7 215-535-7 42- 45 R10
Xn; R20/21
Xi; R38
n-butyl acetate 123-86-4 204-658-1 3-7 R10
R66, R67
1,6-Diisocyanatohexane 822-06-0 212-484-8 50 T;R23
Xi; R36/37/38
R42/43
Hexamethylene Diisocyanate 28182-81-2 500-060-2 2 R42/43
4. FIRST-AID MEASURES

First-aid measures
General : In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation : Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious, place in recovery position and seek medical advice.
Ingestion : If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.

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 Version No.06- Revision Date 27/04/2011

5. FIRE FIGHTING MEASURES

Extinguishing media : Recommended : alcohol-resistant foam, CO2, powders, water spray.
Do not use - water jet.
Recommendation : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Approprirate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove sauces of ignition and ventilation the area, avoid breathing vapour or mist.
Do not turn lights or unprotected electricalequipment on or off.
Spill : Contain and absorb spillage with non-combustible material e.g. sand, earth, vermiculite.
Place in closed container outside building and disposal according to local regulation.
Preferably clean with a detergent. Do not use solvents.
Do not allow spills to enter drains or watercauses.
If drain, lakes, river, or sewers are contimated , inform the appropriateauthorities in
accordance with local regulations.
Note : see section 8 for personal protective equipment and section 13 for waste disposal.

7. HANDLING AND STORAGE

Handling : This coating contains solvents. Solvent vapours are heavier than air and may spread along floors.
vapours may form explosive mixtures with air. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentrations higher than the occupational exposure limits.

In storage : Handle containers carefully to prevent damage and spillage.

Naked flames and smoking should not be permitted in storage areas. It is recommended that
fork lift trucks and electrical equipment are protected to the appropriate standard.

In use : Avoid skin and eye contact. Avoid inhalation of vapours and spray mists.

Observe label precaution. Put on appropriate personal protective equipment.

Smoking, eating and drinking should be prohibited in areas where this material is handled.

Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made
from the same material as the original one.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static and
antistatic footwear; floor should be conductive type.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapour in all case. In such
circumstances they should wear a compressed air-fed respirator during the spraying process
and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
Storage ; Store in accordance with local regulation. Observe label precautions. Store in a cool,
well ventilated area away from incompatible materials and sauce of heat and direct sunlight.

Keep away from ; oxidising agent, strong alkalis, strong acids.

Page 2 / 6
 Version No.06- Revision Date 27/04/2011

Storage Store on concrete or other impervious floor, preferably with bunding to contain any spillage.
Do not stack more than 3 pallets high.
Keep container tightly closed. Container that have been opened must be carefully resealed and
kept upright to prevent leakage.
Prevent unauthorised access.
This is highly flammable liquid. Refer to the requirements of local regulations for the storage
and handling regulations petaining to this material.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Provide adequate ventilation. Where resonably practicable, this should be achived by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and solvent vapours below the occupational exposure limits (OEL)
suitable respirator must be worn.
Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Material STEL-15 min.ave Long term-TWA-8hr

xylene 150 ppm 100 ppm
n-butyl acetate 200 ppm 150 ppm
1,6-Diisocyanatohexane - 0.005 ppm
3
Hexamethylene Diisocyanate 1.0 mg/m 0.5 mg/m3

Personal protection equipment

Respiratory Protection : Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered
if practical.
Eye Protection : Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of
liquids. Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection : Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection : Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

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 Version No.06- Revision Date 27/04/2011

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : ( ) Solid ( x ) Liquid Odour : Smell of solvent Density : 1.00 g/cm3
( ) Paste ( ) Powder Colour : Clear Flash point : 29 °C
Solubility : Insoluble in water Explosion limits : LEL% 1 UEL% 24

Vapour pressure : 9700 Pa, 20 °C Autoignition temperature : 370 °C

10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see section 8). When exposed to high teemperatures may produce
hazardous decomposition products such as carbon monoxide, carbon dioxide, oxide of nitrogen ans smkoe.

Keep away from oxidising agents, strongly alkaline and strong acid materials in order to avoid possible exothermic reactions.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.

Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
Aquatic ecotoxicity
Material name Test Result Species Exposure
xylene Mortality Actute LC50 3300 to 4093 u/L Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
trout,donaldson-trout-
Oncorhynchus mykiss
n-butyl acetate Mortality Actute LC50 18000 to 19000 u/L Fish-Fathead minnow 96 hours
Fresh water Pimephales promelas
Biodegradability
Ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily

13. DISPOSAL CONSIDERATION

Method of disposal : Do not allow into drain or water courses. Wastes and empty containers should be disposal
of in accordance with regulations made under the Control of Pollution Act and the
Environmental Protection Act.

Using information provided in this data sheet advice should be obtained from the Waste
Regulation Authority, whether the special waste regulations apply.

Page 4 / 6
 Version No.06- Revision Date 27/04/2011

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint
UN number : 1263
Class : 3
Packing group : III
Label :

Additional information
ADR / RID : Hazardous identification no. : 30
: Special provision : 640E
IMDG : Class : 3
Proper shipping name : Paint
Emergency schedules (EmS) : F-E, S-E
Marine pollutant : No

15. REGULATORY INFORMATION

The product complies with these local regulations.

EU regulations : The product is classified and labelled for supply in accordance with the Directive 1999/45/EC
as follows:
hazard symbol :

Harmful

Risk phrases : R10 Flammable

R20/21 Harmful by inhalation and in contact with skin
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Safety pharses : S23 Do not breathe vapour / spray

S24 Avoid contact with skin
S37 Wear suitable gloves.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible)
S51 Use only in well-ventilated areas.

Contains : Xylene

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 Version No.06- Revision Date 27/04/2011

16. OTHER INFORMATION

CEPE Classification : 1
Full text of R-pharses : R10 Flammable
R11 Highly flammable.
R14 Reacts violently with water.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R23 Toxicity inhalation.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R38 Irritaing to skin.
R42 May cause sensitisation by inhalation.
R42/43 May cause sensitisation by inhalation and skin contact.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours mau cause drowsiness and dizziness.
The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Material Safety Data Sheet is required according to legislation.

Page 6 / 6