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Chapter One: 1.1 Background

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CHAPTER ONE

INTRODUCTION

1.1 Background

Tubular reactors resemble batch reactors in provision, a tubular reactor is a vessel


through which flow is continuous, usually at steady state, and configured so that
conversion of the chemicals and other dependent variables are functions of position
within the reactor rather than of time. In the ideal tubular reactor, the fluids flow as if
they were solid plugs or pistons, and reaction time is the same for all flowing material at
any given tube cross section. Initially high driving forces, which diminish as the reactions
progress down the tubes. Flow in tubular reactors can be laminar, as with viscous fluids
in small-diameter tubes, and greatly deviate from ideal plug-flow behavior, or turbulent,
as with gases. Turbulent flow generally is preferred to laminar flow, because mixing and
heat transfer are improved. For slow reactions and especially in small laboratory and
pilot-plant reactors, establishing turbulent flow can result in inconveniently long reactors
or may require unacceptably high feed rates. . The majority of the selected chemicals are
exothermic but other endothermic reactions in tubular reactors are present in the
chemical industry, e.g. cracking in fired tubular reactors to produce ethylene and
propylene. Tubular reactors are used in the industry since they are relatively easy to
maintain due to no moving parts and usually have the highest conversion per reactor
volume of other types of reactor. Tubular reactors can be used either for homogenous
or heterogeneous reaction chemistry. Homogenous reactors have only one phase in the
reaction environment and heterogeneous have more than one. The temperature
changes quickly in the beginning of the reactor due to high reaction rate. The reaction
rate is generally affected by concentration of reactants and temperature which means
that the reaction rate is high in the beginning and then lowers trough the reactor and
the change in temperature follows accordingly. To keep the reaction rate high and
therefore increase the reaction conversion of with a given reactor cooling of exothermic
reactors and heating of endothermic reactors is employed.
As a consequence the heat transfer between the reactive stream and utility is strictly
connected with the reaction kinetics which therefore cannot be ignored when designing
the utility system.

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