Msds en Shell Air Tool s2 A 100

SAFETY DATA SHEET
Prepared according to the regulation on Safety Data Sheets regarding

Hazardous substances and mixtures (R.G. 13/12/2014-29204).
Shell Air Tool Oil S2 A 100
Initial release date: 17.01.2011
Revision Date: 09.09.2015
Version 1.2
MSDS Number: 800001015799
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : Shell Air Tool Oil S2 A 100
Product code : 001D7866
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended restrictions : This product must not be used in applications other than those
on use listed in Section 1 without first seeking the advice of the sup-
plier.
1.3 Details of the supplier of the safety data sheet

Company : Shell & Turcas Petrol A.Ş.
Karamancılar Is Merkezi Gulbahar Mh.
Salih Tozan Sk.No:18bblk Esentepe-Sisli
TR-34394 Istanbul
Telephone : (+90) 2124441502
Telefax : (+90) 2123760600
E-mail address of person : If you have any enquiries about the content of this SDS please
responsible for the SDS email lubricantSDS@shell.com
1.4 Emergency telephone number

Emergency telephone num- : 0212 376 00 00
ber
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification T.R. SEA No 28848

Not a hazardous substance or mixture.
Classification T.R. SAE No 27092
Not a hazardous substance or mixture.
2.2 Label elements
Labelling T.R. SEA No 28848

Hazard pictograms : No Hazard Symbol required
Signal word : No signal word
Hazard statements : PHYSICAL HAZARDS:

Not classified as a physical hazard under
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SAFETY DATA SHEET
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GHS criteria.
HEALTH HAZARDS:
Not classified as a health hazard under
GHS criteria.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard
under GHS criteria.
Precautionary statements : Prevention:

No precautionary phrases.
Response:
Storage:
Disposal:
2.3 Other hazards

Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin result-
ing in disorders such as oil acne/folliculitis.
Used oil may contain harmful impurities.
Not classified as flammable but will burn.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Chemical nature : Highly refined mineral oils and additives.
The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.
Hazardous components
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Not expected to be a health hazard when used under normal
conditions.
Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.
If inhaled : No treatment necessary under normal conditions of use.

If symptoms persist, obtain medical advice.
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SAFETY DATA SHEET
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In case of skin contact : Remove contaminated clothing. Flush exposed area with wa-
ter and follow by washing with soap if available.
If persistent irritation occurs, obtain medical attention.
In case of eye contact : Flush eye with copious quantities of water.

If persistent irritation occurs, obtain medical attention.
If swallowed : In general no treatment is necessary unless large quantities

are swallowed, however, get medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Notes to doctor/physician:
Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon dio-
xide, sand or earth may be used for small fires only.
Unsuitable extinguishing : Do not use water in a jet.

media
5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Hazardous combustion products may include:
fighting A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide may be evolved if incomplete combustion
occurs.
Unidentified organic and inorganic compounds.
5.3 Advice for firefighters

Special protective equipment : Proper protective equipment including chemical resistant
for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).
Specific extinguishing me- : Use extinguishing measures that are appropriate to local cir-
thods cumstances and the surrounding environment.
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SAFETY DATA SHEET
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SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Avoid contact with skin and eyes.
6.2 Environmental precautions

Environmental precautions : Use appropriate containment to avoid environmental contami-
nation. Prevent from spreading or entering drains, ditches or
rivers by using sand, earth, or other appropriate barriers.
Local authorities should be advised if significant spillages

cannot be contained.
6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth
or other containment material.
Reclaim liquid directly or in an absorbent.
Soak up residue with an absorbent such as clay, sand or other
suitable material and dispose of properly.
6.4 Reference to other sections

For guidance on selection of personal protective equipment see Chapter 8 of this Safety Data
Sheet., For guidance on disposal of spilled material see Chapter 13 of this Safety Data Sheet.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Technical measures : Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Use the information in this data sheet as input to a risk as-
sessment of local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.
Advice on safe handling : Avoid prolonged or repeated contact with skin.

Avoid inhaling vapour and/or mists.
When handling product in drums, safety footwear should be
worn and proper handling equipment should be used.
Properly dispose of any contaminated rags or cleaning mate-
rials in order to prevent fires.
7.2 Conditions for safe storage, including any incompatibilities

Other data : Keep container tightly closed and in a cool, well-ventilated
place. Use properly labeled and closable containers.
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SAFETY DATA SHEET
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Store at ambient temperature.
Refer to section 15 for any additional specific legislation cov-

ering the packaging and storage of this product.
Packaging material : Suitable material: For containers or container linings, use mild
steel or high density polyethylene.
Unsuitable material: PVC.
7.3 Specific end use(s)

Specific use(s) : Not applicable
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure Limits

Components CAS-No. Value type (Form Control parameters Basis
of exposure)
Oil mist, mineral TWA 5 mg/m3 US. ACGIH
Threshold
Limit Values
Biological occupational exposure limits
No biological limit allocated.
8.2 Exposure controls
Engineering measures
The level of protection and types of controls necessary will vary depending upon potential expo-
sure conditions. Select controls based on a risk assessment of local circumstances. Appropriate
measures include:
Adequate ventilation to control airborne concentrations.
Where material is heated, sprayed or mist formed, there is greater potential for airborne concen-
trations to be generated.
General Information:
Define procedures for safe handling and maintenance of controls.
Educate and train workers in the hazards and control measures relevant to normal activities as-
sociated with this product.
Ensure appropriate selection, testing and maintenance of equipment used to control exposure,
e.g. personal protective equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or maintenance.
Retain drain downs in sealed storage pending disposal or subsequent recycle.
Always observe good personal hygiene measures, such as washing hands after handling the ma-
terial and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be
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SAFETY DATA SHEET
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cleaned. Practice good housekeeping.

Personal protective equipment
Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.
Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical resis-
tance of glove material, dexterity. Always seek advice from
glove suppliers. Contaminated gloves should be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of
a non-perfumed moisturizer is recommended.
For continuous contact we recommend gloves with break-

through time of more than 240 minutes with preference for >
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is de-
pendent on the exact composition of the glove material. Glove
thickness should be typically greater than 0.35 mm depending
on the glove make and model.
Skin and body protection : Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.
Respiratory protection : No respiratory protection is ordinarily required under normal

conditions of use.
In accordance with good industrial hygiene practices, precau-
tions should be taken to avoid breathing of material.
If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the specif-
ic conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are suitable, select an appropri-
ate combination of mask and filter.
Select a filter suitable for the combination of organic gases
and vapours [Type A/Type P boiling point >65°C (149°F)].
Protective measures : Personal protective equipment (PPE) should meet recom-

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SAFETY DATA SHEET
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mended national standards. Check with PPE suppliers.
Environmental exposure controls

General advice : Take appropriate measures to fulfill the requirements of rele-
vant environmental protection legislation. Avoid contamination
of the environment by following advice given in Chapter 6. If
necessary, prevent undissolved material from being dis-
charged to waste water. Waste water should be treated in a
municipal or industrial waste water treatment plant before
discharge to surface water.
Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : Liquid at room temperature.
Colour : amber
Odour : Slight hydrocarbon
Odour Threshold : Data not available
pH : Not applicable
pour point : -24 °C

Method: ISO 3016
Initial boiling point and boiling : > 280 °C

range estimated value(s)
Flash point : 241 °C

Method: ISO 2592
Evaporation rate : Data not available
Flammability (solid, gas) : Data not available
Upper explosion limit : Typical 10 %(V)
Lower explosion limit : Typical 1 %(V)
Vapour pressure : < 0,5 Pa (20 °C)

estimated value(s)
Relative vapour density : >1

estimated value(s)
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SAFETY DATA SHEET
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Relative density : 0,884 (15 °C)
Density : 884 kg/m3 (15,0 °C)

Method: ISO 12185
Solubility(ies)
Water solubility : negligible
Solubility in other solvents : Data not available
Partition coefficient: n- : Pow: > 6

octanol/water (based on information on similar products)
Auto-ignition temperature : > 320 °C
Viscosity
Viscosity, dynamic : Data not available
Viscosity, kinematic : 100 mm2/s (40,0 °C)

Method: ISO 3104
11,5 mm2/s (100 °C)

Method: ISO 3104
9.2 Other information

Conductivity : This material is not expected to be a static accumulator.
Decomposition temperature : Data not available
SECTION 10: Stability and reactivity
10.1 Reactivity
The product does not pose any further reactivity hazards in addition to those listed in the following
sub-paragraph.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : Reacts with strong oxidising agents.
10.4 Conditions to avoid
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SAFETY DATA SHEET
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Conditions to avoid : Extremes of temperature and direct sunlight.
10.5 Incompatible materials

Materials to avoid : Strong oxidising agents.
10.6 Hazardous decomposition products

Hazardous decomposition products are not expected to form during normal storage.
SECTION 11: Toxicological information
11.1 Information on toxicological effects

Information on likely routes of : Skin and eye contact are the primary routes of exposure al-
exposure though exposure may occur following accidental ingestion.
Acute toxicity
Product:
Acute oral toxicity : LD50 (rat): > 5.000 mg/kg
Remarks: Expected to be of low toxicity:
Acute inhalation toxicity : Remarks: Not considered to be an inhalation hazard under

normal conditions of use.
Acute dermal toxicity : LD50 (Rabbit): > 5.000 mg/kg

Remarks: Expected to be of low toxicity:
Skin corrosion/irritation
Product:
Remarks: Expected to be slightly irritating.
Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin result-
ing in disorders such as oil acne/folliculitis.
Serious eye damage/eye irritation
Product:
Remarks: Expected to be slightly irritating.
Respiratory or skin sensitisation
Product:
Remarks: Not expected to be a skin sensitiser.
Germ cell mutagenicity
Product:
Genotoxicity in vivo : Remarks: Not considered a mutagenic hazard.
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Carcinogenicity
Product:
Remarks: Not expected to be carcinogenic.
Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin-
painting studies.
Highly refined mineral oils are not classified as carcinogenic by the International Agency for Re-
search on Cancer (IARC).
Material GHS/CLP Carcinogenicity Classification

Highly refined mineral oil No carcinogenicity classification.
Reproductive toxicity
Product:
Effects on fertility :
Remarks: Not expected to impair fertility.
Not expected to be a developmental toxicant.
STOT - single exposure
Product:
Remarks: Not expected to be a hazard.
STOT - repeated exposure
Product:
Remarks: Not expected to be a hazard.
Aspiration toxicity
Product:
Not considered an aspiration hazard.
Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumulated during use. The con-
centration of such impurities will depend on use and they may present risks to health and the
environment on disposal.
ALL used oil should be handled with caution and skin contact avoided as far as possible.
Remarks: Slightly irritating to respiratory system.
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SECTION 12: Ecological information
12.1 Toxicity
Product:
Toxicity to fish (Acute toxic- : Remarks: Expected to be practically non toxic:
ity) LL/EL/IL50 > 100 mg/l
Toxicity to daphnia and other : Remarks: Expected to be practically non toxic:

aquatic invertebrates (Acute LL/EL/IL50 > 100 mg/l
toxicity)
Toxicity to algae (Acute toxic- : Remarks: Expected to be practically non toxic:

ity) LL/EL/IL50 > 100 mg/l
Toxicity to fish (Chronic toxic- : Remarks: Data not available

ity)
Toxicity to daphnia and other : Remarks: Data not available

aquatic invertebrates (Chron-
ic toxicity)
Toxicity to bacteria (Acute :

toxicity) Remarks: Data not available
12.2 Persistence and degradability
Product:
Biodegradability : Remarks: Expected to be not readily biodegradable.
Major constituents are expected to be inherently biodegrada-
ble, but contains components that may persist in the environ-
ment.
12.3 Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Contains components with the potential to bioac-
cumulate.
12.4 Mobility in soil
Product:
Mobility : Remarks: Liquid under most environmental conditions., If it
enters soil, it will adsorb to soil particles and will not be mo-
bile.
Remarks: Floats on water.
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12.5 Results of PBT and vPvB assessment
Product:
Assessment : This mixture does not contain any REACH registered sub-
stances that are assessed to be a PBT or a vPvB..
12.6 Other adverse effects
Product:
Additional ecological informa- : Remarks: Product is a mixture of non-volatile components,
tion which are not expected to be released to air in any significant
quantities.
Not expected to have ozone depletion potential, photochemi-
cal ozone creation potential or global warming potential.
Remarks: Poorly soluble mixture.

May cause physical fouling of aquatic organisms.
Remarks: Mineral oil is not expected to cause any chronic

effects to aquatic organisms at concentrations less than 1
mg/l.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Waste product should not be allowed to contaminate soil or
ground water, or be disposed of into the environment.
Waste, spills or used product is dangerous waste.
Disposal should be in accordance with applicable regional,

national, and local laws and regulations.
Local regulations may be more stringent than regional or na-
tional requirements and must be complied with.
Contaminated packaging : Dispose in accordance with prevailing regulations, preferably

to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.
Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
SECTION 14: Transport information
14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
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14.3 Transport hazard class(es)

14.4 Packing group
14.5 Environmental hazards
14.6 Special precautions for user
Remarks : Special Precautions: Refer to Chapter 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category : Not applicable
Ship type : Not applicable
Product name : Not applicable
Special precautions : Not applicable
Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Other regulations : Regulations on the health and safety precautions for chemi-
cals in the workplace. Regulations on the fire protection of
buildings. Regulations on the prevention of industrial acci-
dents and the reduction of their effects.
The components of this product are reported in the following inventories:

EINECS : All components listed or polymer exempt.
TSCA : All components listed.
SECTION 16: Other information
SDS Author
Name, Surname : Eda Demirer
Address : Shell & Turcas Petrol A.Ş. Derince Tesisleri

Deniz Mah. P.O Cad.
41900 Derince-Kocaeli
Certified Qualification date : 25 May 2015

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Certificate number : GBF-1921
Further information
Other information : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
Revision changes: Revised according to regulation on Safety

Data Sheets (SDSs) regarding hazardous substances and
mixtures (R.G. 13/12/2014-29204)
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with
any other materials or in any process, unless specified in the text.
TR / EN
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SAFETY DATA SHEET

Prepared according to the regulation on Safety Data Sheets regarding

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product code : 001D7866

1.3 Details of the supplier of the safety data sheet

Telefax : (+90) 2123760600

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification T.R. SEA No 28848

Labelling T.R. SEA No 28848

Signal word : No signal word

Hazard statements : PHYSICAL HAZARDS:

Precautionary statements : Prevention:

2.3 Other hazards

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : No treatment necessary under normal conditions of use.

In case of eye contact : Flush eye with copious quantities of water.

If swallowed : In general no treatment is necessary unless large quantities

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : Do not use water in a jet.

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

Local authorities should be advised if significant spillages

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Avoid prolonged or repeated contact with skin.

7.2 Conditions for safe storage, including any incompatibilities

Store at ambient temperature.

Refer to section 15 for any additional specific legislation cov-

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

8.2 Exposure controls

cleaned. Practice good housekeeping.

For continuous contact we recommend gloves with break-

Respiratory protection : No respiratory protection is ordinarily required under normal

Protective measures : Personal protective equipment (PPE) should meet recom-

mended national standards. Check with PPE suppliers.

Environmental exposure controls

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Odour : Slight hydrocarbon

Odour Threshold : Data not available

pour point : -24 °C

Initial boiling point and boiling : > 280 °C

Flash point : 241 °C

Evaporation rate : Data not available