1.

IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 Product identifier
Product name ACETYLENE
Synonym(s) PRODUCT CODE: SG040

1.2 Uses and uses advised against

Use(s) FUEL • INDUSTRIAL APPLICATIONS

1.3 Details of the supplier of the product

Supplier name ELGAS LTD
Address 10 Julius Avenue, North Ryde, NSW, 2113, AUSTRALIA
Telephone (02) 8094 3200, 1800 STARGAS
Fax (02) 9018 0146
Website www.stargas.com.au

1.4 Emergency telephone number(s)

Emergency 1800 819 783 (24 hours)

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
GHS classification(s) Flammable Gases: Category 1
Gases Under Pressure: Dissolved gas

2.2 Label elements

Signal word DANGER

Pictogram(s)

Hazard statement(s)
H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
Prevention statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Response statement(s)
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
Storage statement(s)
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
Disposal statement(s)
None allocated.

2.3 Other hazards

Asphyxiant. Effects are proportional to oxygen displacement.

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3. COMPOSITION/ INFORMATION ON INGREDIENTS

3.1 Substances / Mixtures
Ingredient CAS Number EC Number Content
ACETYLENE 74-86-2 200-816-9 >98%

4. FIRST AID MEASURES

4.1 Description of first aid measures
Eye Adverse effects not expected from this product.
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator or Self Contained
Breathing Apparatus (SCBA). Be aware of possible explosive atmospheres. Apply artificial respiration if not
breathing. Give oxygen if available. For advice, contact a Poison Information Centre on 13 11 26 (Australia
Wide) or a doctor.
Skin Adverse effects not expected from this product.
Ingestion Ingestion is not considered a potential route of exposure.
First aid facilities No information provided.

4.2 Most important symptoms and effects, both acute and delayed
In high concentrations may cause asphyxiation. Symptoms may include loss of mobility / consciousness. Victim may not be aware of
asphyxiation. In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache, nausea and loss of
co-ordination.

4.3 Immediate medical attention and special treatment needed

Treat for asphyxia.

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
Stop flow of gas if safe to do so, such as by slowly closing the cylinder valve. If the gas source cannot be isolated, do not extinguish
the flame, since re-ignition and explosion could occur. Await arrival of emergency services or manufacturer's advisor. Drench and cool
cylinders with water spray from protected area at a safe distance. If it is absolutely necessary to extinguish the flame, use only a dry
chemical powder extinguisher. Do not move cylinders for at least 24 hours. Avoid shock and bumps to cylinders.

5.2 Special hazards arising from the substance or mixture

Extremely flammable. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters, naked
lights, pilot lights, mobile phones etc. when handling.

5.3 Advice for firefighters

Temperatures in a fire may cause cylinders to rupture and internal pressure relief devices to be activated. Cool cylinders or containers
exposed to fire by applying water from a protected location. Do not approach cylinders or containers suspected of being hot. This
material is capable of forming explosive mixtures in air.

5.4 Hazchem code

2SE
2 Fine Water Spray.
S Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Dilute spill and run-off.
E Evacuation of people in and around the immediate vicinity of the incident should be considered.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
If the cylinder is leaking, evacuate area of personnel. Inform manufacturer/supplier of leak. Wear self-contained breathing apparatus
when entering area unless atmosphere is proved to be safe. Ensure adequate air ventilation. Eliminate all sources of ignition.
Consider the risk of potentially explosive atmospheres.

6.2 Environmental precautions

Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.

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6.3 Methods of cleaning up

Carefully move material to a well ventilated remote area, then allow to discharge if safe to do so. Do not attempt to repair leaking valve
or cylinder safety devices.

6.4 Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Use of safe work practices are recommended to avoid inhalation. Do not drag, drop, slide or roll cylinders. The uncontrolled release of
a gas under pressure may cause physical harm. Use a suitable hand truck for cylinder movement. Never open an acetylene cylinder
valve without the regulator attached. Gas regulator of suitable pressure and flow rating fitted to cylinder and manifold with low pressure
gas distribution equipment which controls fuel gas mixture and flame. The regulator and other equipment must be compatible with the
product and suited for the particular use. Never "sniff" acetylene as it may ignite spontaneously. Instead, carefully inspect the outlet
and if there are any signs of dirt, blow it out with a jet of clean compressed air or nitrogen.

7.2 Conditions for safe storage, including any incompatibilities

Do not store near incompatible substances and sources of ignition. Cylinders should be stored: upright, prevented from falling, in a
secure area; below 45°C, in a dry, well ventilated area constructed of non-combustible material with firm level floor (preferably
concrete), away from areas of heavy traffic and emergency exits. Post "No Smoking or Open Flames" signs in the storage areas.
Refer to applicable legislation on flammable storage quantity restrictions. Never transfer acetylene to another cylinder or other
container.

7.3 Specific end use(s)

No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters
Exposure standards
TWA STEL
Ingredient Reference
ppm mg/m³ ppm mg/m³
Acetylene SWA (AUS) Asphyxiant

Biological limits
No biological limit values have been entered for this product.

8.2 Exposure controls

Engineering controls Provide suitable ventilation to minimise or eliminate exposure. Confined areas (e.g. tanks) should be
adequately ventilated or gas tested. Flammable/explosive vapours may accumulate in poorly ventilated
areas.

PPE
Eye / Face Wear safety glasses.
Hands Wear leather or cotton gloves.
Body Wear coveralls and safety boots.
Respiratory If using product in a confined area, wear an Air-line respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance COLOURLESS GAS
Odour GARLIC-LIKE ODOUR
Flammability EXTREMELY FLAMMABLE

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9.1 Information on basic physical and chemical properties

Flash point < 23°C
Boiling point -84°C
Melting point NOT AVAILABLE
Evaporation rate NOT APPLICABLE
pH NOT APPLICABLE
Vapour density 0.906 (Air = 1)
Specific gravity NOT APPLICABLE
Solubility (water) SOLUBLE
Vapour pressure 4700 kPa @ 25°C
Upper explosion limit 80 % to 85 %
Lower explosion limit 2.5 %
Partition coefficient NOT AVAILABLE
Autoignition temperature 305°C
Decomposition temperature NOT AVAILABLE
Viscosity NOT AVAILABLE
Explosive properties NOT AVAILABLE
Oxidising properties NOT AVAILABLE
Odour threshold NOT AVAILABLE
9.2 Other information
Critical temperature 36.3°C (dissolved in acetone and porous medium)
Cylinder pressure (when full) 1550 kPa @ 15°C
% Volatiles 100 %
Critical pressure 6, 242 kPa

10. STABILITY AND REACTIVITY

10.1 Reactivity
Forms explosive acetylides with copper, silver and mercury. Do not use alloys containing more than 65% copper.

10.2 Chemical stability

Stable under recommended conditions of storage. However, sensitive to heat or shock and may become explosive.

10.3 Possibility of hazardous reactions

Polymerizes with evolution of heat. Avoid contact with curing agents, accelerators, and/or initiators.

10.4 Conditions to avoid

Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites), copper, copper alloys (>70% copper), silver and mercury to form explosive
acetylides. May decompose violently at high temperatures and/or pressures or in the presence of a catalyst. Hazardous by-products
may be produced when this gas/gas mixture is used in welding, cutting and associated processes.

10.6 Hazardous decomposition products

May evolve toxic gases if heated to decomposition.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Skin Not classified as a skin irritant.
Eye Not classified as an eye irritant.
Sensitization Not classified as causing skin or respiratory sensitisation.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen.
Reproductive Not classified as a reproductive toxin.
STOT – single Asphyxiant. Effects are proportional to oxygen displacement. Over exposure may result in dizziness,
exposure drowsiness, weakness, fatigue, breathing difficulties and unconsciousness.
STOT – repeated Not classified as causing organ effects from repeated exposure.
exposure

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Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION

12.1 Toxicity
No ecological damage is expected to be caused by this product.

12.2 Persistence and degradability

This product is not readily biodegradable.

12.3 Bioaccumulative potential

This product is not expected to bioaccumulate.

12.4 Mobility in soil

Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.5 Other adverse effects

No information provided.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Waste disposal Cylinders should be returned to the manufacturer or supplier for disposal of contents.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT

(ADG) (IMDG / IMO) (IATA / ICAO)

14.1 UN Number 1001 1001 1001

14.2 Proper ACETYLENE, DISSOLVED ACETYLENE, DISSOLVED ACETYLENE, DISSOLVED
Shipping Name

14.3 Transport 2.1 2.1 2.1

hazard class
14.4 Packing Group None Allocated None Allocated None Allocated
14.5 Environmental hazards No information provided
14.6 Special precautions for user
Hazchem code 2SE
GTEPG 2A1
EMS F-D, S-U
Other information Ensure cylinder is separated from driver and that outlet of relief device is not obstructed.

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the
Uniform Scheduling of Medicines and Poisons (SUSMP).

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Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
Labelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous
Substances [NOHSC: 1008(2004)].
Hazard codes E Explosive
F+ Extremely flammable
Risk phrases R5 Heating may cause an explosion.
R6 Explosive with or without contact with air.
R12 Extremely Flammable.

Safety phrases S9 Keep container in a well ventilated place.

S16 Keep away from sources of ignition - No smoking.
S33 Take precautionary measures against static discharges.
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances)
All components are listed on AICS, or are exempt.

16. OTHER INFORMATION

Additional information The storage of significant quantities of gas cylinders must comply with AS4332 The storage and
handling of gases in cylinders. When using this gas/gas mixture for welding, cutting and associated
processes, additional hazards may be generated by the process such as radiation, noise and fume.
Risk assessments should be made for each activity to identify and quantify the individual hazards
involved. Please refer to the relevant Safety Data Sheets for the welding consumables being used or,
if available, the materials being welded.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:

The recommendation for protective equipment contained within this report is provided as a guide
only. Factors such as method of application, working environment, quantity used, product
concentration and the availability of engineering controls should be considered before final selection
of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:

It should be noted that the effects from exposure to this product will depend on several factors
including: frequency and duration of use; quantity used; effectiveness of control measures; protective
equipment used and method of application. Given that it is impractical to prepare a ChemAlert report
which would encompass all possible scenarios, it is anticipated that users will assess the risks and
apply control methods where appropriate.

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists

CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
CNS Central Nervous System
EC No. EC No - European Community Number
EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)
GHS Globally Harmonized System
GTEPG Group Text Emergency Procedure Guide
IARC International Agency for Research on Cancer
LC50 Lethal Concentration, 50% / Median Lethal Concentration
LD50 Lethal Dose, 50% / Median Lethal Dose
mg/m³ Milligrams per Cubic Metre
OEL Occupational Exposure Limit
pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).
ppm Parts Per Million
STEL Short-Term Exposure Limit
STOT-RE Specific target organ toxicity (repeated exposure)
STOT-SE Specific target organ toxicity (single exposure)
SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
SWA Safe Work Australia
TLV Threshold Limit Value
TWA Time Weighted Average

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Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
product and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the
manufacturer, importer or supplier or obtained from third party sources and is believed to represent
the current state of knowledge as to the appropriate safety and handling precautions for the product
at the time of issue. Further clarification regarding any aspect of the product should be obtained
directly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
no liability for any loss, injury or damage (including consequential loss) which may be suffered or
incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies

5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: info@rmt.com.au
Web: www.rmt.com.au.

[ End of SDS ]

SDS Date: 20 Mar 2015

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