Eamcet '13 PDF

EAMCET
Engineering Entrance Exam

Solved Paper 2013
Physics
1. If E, M, J and G respectively denote energy,
mass, angular momentum and universal
gravitational constant, the quantity, which m
P
has the same dimensions as the dimensions M
EJ 2
of 5 2
M G β
(a) time (b) angle
(c) mass (d) length
(a) (M + m) g tan β (b) g tan β
2. The work done in moving an object from (c) mg cos β (d) (M + m) g cosec β
origin to a point whose position vector is 5. A ball at rest is dropped from a height of 12.
$ by a force F = 2i$ − $j − k
r = 3 i$ + 2$j − 5k $ is It losses 25% of its kinetic energy on striking
the ground and bounces back to a height ‘h’.
(a) 1 unit (b) 9 units
Then value of ‘h’ is
(c) 13 units (d) 60 units
(a) 3 m (b) 6 m (c) 9 m (d) 12 m
3. A particle is projected from the ground with
an initial speed of v at an angle of projection
6. Two bodies of mass 4 kg and 5 kg are moving
along east and north directions with
θ. The average velocity of the particle
velocities 5 m/s and 3 m/s respectively.
between its time of projection and time it
Magnitude of the velocity of centre of mass
reaches highest point of trajectory is of the system is
v v
(a) 1 + 2 cos 2 θ (b) 1 + 2 sin2 θ (a)
25
m/s (b)
9
m/s
2 2 9 25
v 41 16
(c) 1 + 3 cos 2 θ (d) v cos θ (c) m/s (d) m/s
2 9 9
4. Two wooden blocks of masses M and m are 7. A mass of 2.9 kg is suspended from a string
placed on a smooth horizontal surface as of length 50 cm and is at rest. Another body
shown in figure. If a force P is applied to the of mass 100 g, which is moving horizontally
system as shown in figure such that the with a velocity of 150 m/s strikes and sticks
mass m remains stationary with respect to to it. Subsequently when the string makes
block of mass M, then the magnitude of the an angle of 60° with the vertical, the tension
force P is in the string is ( g = 10 m /s2 )
(a) 140 N (b) 135 N (c) 125 N (d) 90 N
2 | EAMCET (Engineering) l Solved Paper 2013
8. The upper half of an inclined plane with an 12. Two particles A and B of masses ‘m’ and ‘2m’
angle of inclination φ, is smooth while the are suspended from massless springs of
lower half is rough. A body starting from force constants K 1 and K 2 . During their
rest at the top of the inclined plane comes to oscillation, if their maximum velocities are
rest at the bottom of the inclined plane. equal, then the ratio of amplitudes of A and
Then the coefficient of friction for the lower B is
half is K1 K2
(a) (b)
(a) 2 tan φ (b) tan φ K2 2 K1
(c) 2 sin φ (d) 2 cos φ K2 2 K1
(c) (d)
9. Moment of inertia of a body about an axis is K1 K2
4 kg-m 2 . The body is initially at rest and a
torque of 8 N-m starts acting on it along the 13. A tension of 20 N is applied to a copper wire
same axis. Work done by the torque in 20 s, of cross sectional area 0.01 cm 2 , Young’s
in joules, is modulus of copper is 1.1 × 1011 N/m 2 and
Poisson's ratio is 0.32. The decrease in cross
(a) 40 (b) 640
sectional area of the wire is
(c) 2560 (d) 3200
(a) 1.16 × 10−6 cm2 (b) 1.16 × 10−5 m2
10. A uniform circular disc of radius R, lying on (c) 1.16 × 10−4 m2 (d) 1.16 × 10−3 cm2
a frictionless horizontal plane is rotating
with an angular velocity ‘ω’ about is its own 14. A capillary tube of radius ‘r’ is immersed in
axis. Another identical circular disc is gently water and water rises to a height of ‘h’. Mass
placed on the top of the first disc coaxially. of water in the capillary tube is 5 × 10−3 kg.
The loss in rotational kinetic energy due to The same capillary tube is now immersed in
friction between the two discs, as they a liquid whose surface tension is 2 times
acquire common angular velocity is (I is the surface tension of water. The angle of
moment of inertia of the disc) contact between the capillary tube and this
1 2 1 2 liquid is 45°. The mass of liquid which rises
(a) Iω (b) Iω
8 4 into the capillary tube now is, (in kg)
1
(c) Iω2 (d) Iω2 (a) 5 × 10−3 (b) 2.5 × 10−3
2 −3
(c) 5 2 × 10 (d) 3.5 × 10−3
11. The gravitational force acting on a particle,
due to a solid sphere of uniform density and 15. The terminal velocity of a liquid drop of
radius R, at a distance of 3R from the centre radius ‘r’ falling through air is v. If two such
of the sphere is F1. A spherical hole of radius drops are combined to form a bigger drop,
(R/2) is now made in the sphere as shown in the terminal velocity with which the bigger
the figure. The sphere with hole now exerts drop falls through air is (ignore any buoyant
a force F2 on the same particle. Ratio of F1 force due to air)
and F2 is (a) 2 v (b) 2 v
(c) ³ 4 v (d) ³ 2 v
16. A glass flask of volume one litre is filled

R/2 completely with mercury at 0°C. The flask is
R now heated to 100°C. Coefficient of volume
expansion of mercury is 1.82 × 10−4 /°C and
coefficient of linear expansion of glass is
3R
0.1 × 10−4 /°C. During this process, amount of
50 41 41 25 mercury which overflows is
(a) (b) (c) (d)
41 50 42 41 (a) 21.2 cc (b) 15.2 cc
(c) 2.12 cc (d) 18.2 cc
EAMCET (Engineering) l Solved Paper 2013 | 3
17. On a temperature scale Y, water freezes at another tuning fork. When these two tuning
−160° Y and boils at −50° Y. On this Y scale, forks are sounded together, they produce
a temperature of 340 K is 8 beats per second. Then the frequencies of
(a) −160.3° Y (b) −96.3° Y the two tuning forks are, (Consider
(c) −86.3° Y (d) −76.3° Y fundamental frequencies only)
(a) 250 Hz, 258 Hz (b) 240 Hz, 248 Hz
18. Three moles of an ideal monoatomic gas
(c) 264 Hz, 256 Hz (d) 280 Hz, 272 Hz
undergoes a cyclic process as shown in the
figure. The temperature of the gas in 22. A source of sound of frequency 640 Hz is
different states marked as 1, 2, 3 and 4 are 100
moving at a velocity of m/s along a road,
400 K, 700 K, 2500 K and 1100 K 3
respectively. The work done by the gas and is at an instant 30 m away from a point
during the process 1-2-3-4-1 is (universal A on the road (as shown in figure). A person
gas constant is R) standing at O, 40 m away from the road
hears sound of apparent frequency ν′. The
value of ν′ is (velocity of sound = 340 m/s)
2
3
30 m Source
P 1
4 90° θ
v 40 m
(a) 1650 R (b) 550 R

(c) 1100 R (d) 2200 R
19. Efficiency of a heat engine whose sink is at O

temperature of 300 K is 40%. To increase the Person
efficiency to 60%, keeping the sink (a) 620 Hz (b) 680 Hz
temperature constant, the source (c) 720 Hz (d) 840 Hz
temperature must be increased by
(a) 750 K (b) 500 K 23. The two surfaces of a concave lens, made of
(c) 250 K (d) 1000 K
glass of refractive index 1.5 have the same
radii of curvature R. It is now immersed in a
20. Two bodies A and B of equal surface area medium of refractive index 1.75, then the
have thermal emissivities of 0.01 and 0.81 lens
respectively. The two bodies are radiating (a) becomes a convergent lens of focal length 3.5 R
energy at the same rate. Maximum energy is (b) becomes a convergent lens of focal length 3.0 R
radiated from the two bodies A and B at (c) changes as a divergent lens of focal length 3.5 R
wavelengths λ A and λ B respectively. (d) changes as a divergent lens of focal length 3.0 R
Difference in these two wavelengths is 1 µm.
If the temperature of the body A is 5802 K, 24. A microscope consists of an objective of focal
then value of λ B is length 1.9 cm and eye piece of focal length
1 5 cm. The two lenses are kept at a distance of
(a) µm (b) 1 µm
2 10.5 cm. If the image is to be formed at the
3 least distance of distinct vision, the distance
(c) 2 µm (d) µm
2 at which the object is to be placed before the
objective is (least distance of distinct vision
21. An air column in a tube 32 cm long, closed at is 25 cm)
one end, is in resonance with a tuning fork.
(a) 6.2 cm (b) 2.7 cm
The air column in another tube, open at both
(c) 21.0 cm (d) 4.17 cm
ends, of length 66 cm is in resonance with
25. Fresnel diffraction is produced due to light T02

(a) T 2 = T02 cos θ (b) T 2 =
rays falling on a small obstacle. The cos θ
intensity of light at a point on a screen T0
beyond an obstacle depends on (c) T = T0 cos θ (d) T =
cos θ
(a) the focal length of lens used for observation
(b) the number of half-period zones that superpose 29. Two metal plates each of area ‘A’ form a
at the point parallel plate capacitor with air in between
(c) the square of the sum of the number of half the plates. The distance between the plates
period zones d
(d) the thickness of the obstacle
is ‘d’. A metal plate of thickness and of
2
26. A short bar magnet having magnetic same area A is inserted between the plates
moment 4 Am2 , placed in a vibrating to form two capacitors of capacitances C1 and
magnetometer, vibrates with a time period C2 as shown in the figure. If the effective
of 8 s. Another short bar magnet having a capacitance of the two capacitors is C′ and
magnetic moment 8 Am2 vibrates with a the capacitance of the capacitor initially is
time period of 6 s. If the moment of inertia of C′
C, then is
the second magnet is 9 × 10−2 kg-m2 , the C
moment of inertia of the first magnet is
(assume that both magnets are kept in the
C1
same uniform magnetic induction field.)
(a) 9 × 10−2 kg-m 2 (b) 8 × 10−2 kg-m 2
d d/2
−2
(c) 5.33 × 10 kg-m 2
(d) 12.2 × 10−2 kg-m 2
C2
27. Two short bar magnets have their magnetic
2 2
moments 1.2 Am and 1.0 Am . They are
placed on a horizontal table parallel to each (a) 4 (b) 2
other at a distance of 20 cm between their (c) 6 (d) 1
centres, such that their north poles pointing
towards geographic south. They have
30. In the circuit shown in the figure, the
current ‘I’ is
common magnetic equatorial line.
Horizontal component of earth’s field is C
10 V
3.6 × 10−5 T. Then, the resultant horizontal
magnetic induction at mid point of the line A P 2Ω
µ
joining their centers is  0 = 10−7 N / m  24 V B
 4π  1 3Ω
(a) 3.6 × 10−5 T (b) 1.84 × 10−4 T 1Ω D
(c) 2.56 × 10−4 T (d) 5.8 × 10−5 T 9V
(a) 6 A (b) 2 A
28. A deflection magnetometer is adjusted and a
(c) 4 A (d) 7 A
magnet of magnetic moment M is placed on
it in the usual manner and the observed 31. In the meter bridge experiment, the length
deflection is θ. The period of oscillation of the AB of the wire is 1 m. The resistors X and Y
needle before settling of the deflection is T. have values 5 Ω and 2 Ω respectively. When
When the magnet is removed, the period of a shunt resistance S is connected to X, the
oscillation of the needle is T0 before settling balancing point is found to be 0.625 m from
to 0° − 0°. If the earth’s induced magnetic A. Then, the resistance of the shunt is
field is BH , the relation between T and T0 is
(E1 + E2 )λ1λ 2
S (a) hc =
λ 2 − λ1
Y E1 − E2
(b) hc = ⋅ (λ1λ 2 )
λ 2 − λ1
X
G (E − E2 )(λ 2 − λ1 )
(c) hc = 1
A B λ1λ 2
J
λ 2 − λ1
(d) hc = ⋅ E1
λ1λ 2 E2
(a) 5 Ω (b) 10 Ω 36. The work function of a metal is 2 eV. If a
(c) 7.5 Ω (d) 12.5 Ω radiation of wavelength 3000 Å is incident
32. The ends of an element of zinc wire are kept on it, the maximum kinetic energy of the
at a small temperature difference ∆T and a emitted photoelectrons is (Planck’s constant
small current (I) is passed through the wire. h = 6.6 × 10−34 Js; velocity of light
Then, the heat developed per unit time c = 3 × 108 m /s; 1 eV = 1.6 × 10−19 J)
(a) is proportional to ∆T and I (a) 4.4 × 10−19 J (b) 5.6 × 10−19 J
(b) is proportional to I 3 and ∆T (c) 3.4 × 10 −19
J (d) 2.5 × 10−19 J
(c) is proportional to Thomson coefficient of the
metal 37. The radius of 72 Te125 nucleus is 6 fermi. The
(d) is proportional to ∆T only radius of 13 Al27 nucleus in meters is
33. A series LCR circuit is connected across a (a) 3.6 × 10−12 m (b) 3.6 × 10−15 m
source of alternating emf of changing (c) 7.2 × 10 −8
m (d) 7.2 × 10−15 m
frequency and resonates at frequency f0 .
Keeping capacitance constant, if the 38. A U235 nuclear reactor generates energy at a
inductance (L) is increased by 3 times and rate of 3.70 × 107 J/s. Each fission liberates
resistance is increased ( R) by 1.4 times, the 185 MeV useful energy. If the reactor has to
resonant frequency now is operate for 144 × 104 s, then, the mass of the
(a) 31/ 4 f0 (b) 3 f0 fuel needed is (Assume Avogadro’s number
1
1/ 4
= 6 × 1023 mol −1, 1 eV = 1.6 × 10−19 J)
(c) ( 3 − 1)1/ 4 f0 (d)   f0
 3 (a) 70.5 kg (b) 0.705 kg
(c) 13.1 kg (d) 1.31 kg
34. The sensitivity of a galvanometer that
1 39. The base current in a transistor circuit
measures current is decreased by times
40 changes from 45 µA to 140 µA. Accordingly,
by using shunt resistance of 10 Ω. Then, the the collector current changes from 0.2 mA to
value of the resistance of the galvanometer 0.400 mA. The gain in current is
is (a) 9.5 (b) 1 (c) 40 (d) 20
(a) 400 Ω
(b) 410 Ω 40. Of the following, NAND gate is
(c) 30 Ω
(a)
(d) 390 Ω
35. Initially a photon of wavelength λ 1 falls on
photocathode and emits an electron of (b)
maximum energy E1. If the wavelength of
the incident photon is changed to λ 2 , the
(c)
maximum energy of the electron emitted
becomes E2 . Then value of hc (h = Planck’s
(d)
constant, c = velocity of light) is
Chemistry
1. The number of radial nodes of 3s and 8. Which one of the following is an isotonic pair
2 p orbitals respectively are of solutions?
(a) 0, 2 (b) 2, 0 (a) 0.15 M NaCl and 0.1 M Na 2SO 4
(c) 1, 2 (d) 2, 1 (b) 0.2 M Urea and 0.1 M Sugar
(c) 0.1 M BaCl 2 and 0.2 M Urea
2. The basis of quantum mechanical model of
(d) 0.4 M MgSO 4 and 0.1 M NH4Cl
an atom is
(a) angular momentum of electron 9. The vapour pressure in mm of Hg, of an
(b) quantum numbers aqueous solution obtained by adding 18 g of
(c) dual nature of electron
glucose(C6H12O6 ) to 180 g of water at 100°C is
(d) black body radiation (a) 7.60 (b) 76.0
(c) 759 (d) 752.4
3. The number of elements present in the
fourth period is 10. During the electrolysis of copper sulphate
aqueous solution using copper electrode, the
(a) 32 (b) 8
reaction takine place at the cathode is
(c) 18 (d) 2
(a) Cu → Cu2 + (aq ) + 2e −
4. Identify the correct set. (b) Cu2 + (aq ) + 2e − → Cu (s )
1
Molecule
Hybridisation
Shape (c) H+ (aq ) + e − → H2 ( g )
of central atom 2
1
(a) PCl 5 dsp3 square pyramidal (d) SO 24 − (aq ) → SO 3 (g ) + O 2 (g ) + 2e −
2– 3
2
(b) [Ni(CN)4 ] sp tetrahedral
11. The extent of charge of lead accumulator is
(c) SF6 sp3d 2 octahedral
determined by
(d) IF3 dsp3 pyramidal (a) amount of PbSO 4 in the battery
(b) amount of PbO 2 in the battery
5. Which one of the following statements is
(c) specific gravity of H2SO 4 of the battery
correct?
(d) amount of Pb in the battery
(a) Hybrid orbitals do not form σ bonds
(b) Lateral overlap of p-orbitals or p- and d-orbitals 12. The number of octahedral and tetrahedral
produces π-bonds holes respectively present in a hexagonal
(c) The strength of bonds follows the order close packed (hcp) crystal of ‘ X ’ atoms are
σ p − p < σ s− s < π p − p (a) X, 2 X (b) X, X
(c) 2 X, X (d) 2 X, 2 X
(d) s-orbitals do not form σ bonds
13. Which one of the following plots is correct for
6. Which one of the following is an example of a first order reaction?
disproportionation reaction?
(a) 3Cl 2 (g ) + 6OH− (aq ) → ClO 3− (aq ) + 5Cl − (aq )
log (a – x)
log (a – x)
+ 3H2O(l ) (a) (b)

(b) Ag 2+ (aq ) + Ag(s ) → 2Ag + (aq )
(c) Zn (s ) + CuSO 4 (aq ) → Cu (s ) + ZnSO 4 (aq )
(d) 2KClO 3 (s ) → 2KCl(s ) + 3O 2 (g ) Time Time
7. At T(K), the ratio of kinetic energies of 4 g of

log (a – x)
(a – x)
H2 ( g) and 8 g of O2 ( g) is (c) (d)

(a) 1 : 4 (b) 4 : 1
(c) 2 : 1 (d) 8 : 1
Time Time
14. The degree of ionization of 0.10 M lactic acid 3. BaCl2 ⋅ 2D2O is an example of
is 4.0% interstitial deuterate.
H The correct statements are

+ (a) 1 and 3 (b) 1 and 2
H 3C —C— COOH º H (aq) (c) 1, 2 and 3 (d) 2 and 3

OH( aq) 19. Solution “X” contains Na2CO3 and NaHCO3.
H 20 mL of X when titrated using methyl
 orange indicator consumed 60 mL of 0.1 M
+ H 3C —C— COO– HCl solution. In another experiment, 20 mL
 of X solution when titrated using
OH( aq) phenolphthalein consumed 20 mL of 0.1 M
The value of K c is HCl solution. The concentrations (in mol L −1)
. × 10−5
(a) 166 (b) 1.66 × 10−4 of Na2CO3 and NaHCO3 in X are
−3 respectively
(c) 1.66 × 10 (d) 1.66 × 10−2
(a) 0.01, 0.02
15. The pH of a buffer solution made by mixing (b) 0.1, 0.1
25 mL of 0.02 M NH4OH and 25 mL of 0.2 M (c) 0.01, 0.01
NH4Cl at 25° is (pK b of NH4OH = 4.8) (d) 0.1, 0.01
(a) 5.8 (b) 8.2 (c) 4.8 (d) 3.8
20. Diborane reacts with HCl in the presence of
16. For which one of the following reactions, the AlCl 3 and liberates
entropy change is positive? (a) H2 (b) Cl 2
1 (c) BCl 3 (d) Cl 2 and BCl 3
(a) H2 (g ) + O 2 (g ) → H2O(l )
2
(b) Na + (g ) + Cl − (g ) → NaCl(s )
21. How many corners of SiO4 units are shared
(c) NaCl(l ) → NaCl(s )
in the formation of three dimensional
(d) H2O(l ) → H2O(g ) silicates?
(a) 3 (b) 2
17. Match the following. (c) 4 (d) 1
List I List II
22. Which one of the following is not correct?
(A) Solid dispersed in liquid (I) Emulsion (a) Pyrophosphoric acid is a tetrabasic acid
(B) Liquid dispersed in liquid (II) Foam (b) Pyrophosphoric acid contains P—O—P linkage
(C) Gas dispersed in liquid (III) Gel (c) Pyrophosphoric acid contains two P—H bonds
(D) Liquid dispersed in solid (IV) Sol (d) Orthophosphoric acid can be prepared by
(V) Aerosol dissolving P4O10 in water
The correct match is 23. Na2S2O3 reacts with moist Cl2 to form
(A) (B) (C) (D) Na2SO4 , HCl and X. Which one of the
(a) (IV) (I) (II) (III) following is X?
(b) (III) (I) (V) (II) (a) H2S (b) SO 2
(c) (III) (I) (II) (IV) (c) SO 3 (d) S
(d) (IV) (I) (V) (III)
24. The role of copper diaphragm in
18. Observe the following statements Whytlaw-Gray’s method is
1. Heavy water is harmful for the growth (a) preventing the corrosion of electrolytic cell
of animals. (b) preventing the mixing of H2 and F2
2. Heavy water reacts with Al4C3 and (c) as anode
forms deuterated acetylene. (d) as cathode
25. Liquid X is used in bubble chamber to detect 32. In which of the following properties, the two
neutral mesons and gamma photons. Then, enantiomers of lactic acid differ from each
X is other?
(a) He (b) Ne (a) Sign of specific rotation
(c) Kr (d) Xe (b) Density
(c) Melting point
26. A compound absorbs light in the wavelength
(d) Refractive index
region 490–500 nm. Its complementary
colour is 33. Heating chloroform with aqueous sodium
(a) red (b) blue hydroxide solution forms
(c) orange (d) blue-green (a) sodium acetate (b) sodium oxalate
(c) sodium formate (d) chloral
27. Which of the following is not added during
the extraction of silver by cyanide process? 34. The products formed in the reaction of
(a) NaCN (b) Air phenol with Br2 dissolved in CS2 at 0°C are
(c) Zn (d) Na 2S2O 3 (a) o-bromo, m-bromo and p-bromophenols
(b) o-bromo and p-bromophenols
28. Cataract and skin cancer are caused by
(c) 2,4,6-tribromo and 2,3,6-tribromophenols
(a) depletion of nitric oxide (d) 2,4-dibromo and 2,6-dibromophenols
(b) depletion of ozone layer
(c) increase in methane 35. The structure of PCC is
⊕
(d) depletion of nitrous oxide (a) C 6H5 NHCrO 2Cls
29. Which one of the following gives Prussian ⊕
(b) C 6H5 NHCrO 3Cls
blue colour? ⊕
(a) Fe 2 [Fe(CN)6 ] (c) C 5H5 NHCrO 2Cls
⊕
(b) Na 4 [Fe(CN)6 ] (d) C 5H5 NHCrO 3Cls
(c) Fe 3 [Fe(CN)6 ]3
(d) Fe 4 [Fe(CN)6 ]3 36. The pK a values of four carboxylic acids are
450 °C given below. Identify the weakest carboxylic
30. C2H 6 → C2H4 + H2 acid.
Above reaction is called as (a) 4.89 (b) 1.28 (c) 4.76 (d) 2.56
(a) combustion (b) rearrangement
37. Identify X and Y in the following reactions
(c) pyrolysis (d) cleavage
NO2
31. Assertion (A) —NH2 group of aniline is
ortho, para directing in electrophilic Zn/NH4Cl Zn + KOH/C2H5OH
substitutions. X Y
Reason (R) —NH2 group stabilises the
arenium ion formed by the ortho, para (a) —NO —N—N—
attack of the electrophile. H H
The correct answer is
(b) —NH2 —N—N—
(a) Both (A) and (R) are correct, (R) is the correct H H
explanation of (A)
(b) Both (A) and (R) are correct, (R) is not the correct (c) —NHOH —N—N—
explanation of (A) H H
(c) (A) is correct, but (R) is not correct
(d) (A) is not correct, but (R) is correct (d) —N—N— —NHOH
H H
38. Example of a biodegradable polymer pair is 40. Identify phenacetin from the following.
(a) nylon-6,6 and terylene NHCOCH3 NHCOCH3
(b) PHBV and dextron
(c) bakelite and PVC
(a) (b)
(d) PET and polyethylene
OC2H5
39. The number of hydrogen bonds between
guanine and cytosine; and between adenine OCH3
and thymine in DNA is NHCOCH3 NHCOCH3
(a) 1, 2
(b) 3, 2
(c) (d)
(c) 3, 1
(d) 2, 1 OCH3
OC2H5
Mathematics
1. If f ( x) = ( p − x n )1/ n , p > 0 and n is a positive 6. If tn denotes the number of triangles formed
integer, then f [ f ( x)] is equal to with n points in a plane, no three of which
(a) x (b) x n are collinear and if tn + 1 − tn = 36, then n is
(c) p1/ n (d) p − xn equal to
(a) 7 (b) 8 (c) 9 (d) 10
2. The value of
 x ∈ R [log (16 7. The term independent of x ( x > 0, x ≠ 1) in the
. )1 − x − (0.625) 6 (1 + x) ] ∈ R is
2
 
10
   ( x + 1) ( x − 1) 
expansion of  2 / 3 1/ 3
−  is
(a) (−∞, − 1) ∪ (7, ∞ ) (b) (−1, 5) ( x − x + 1) ( x − x ) 
(c) (1, 7 ) (d) (−1, 7 )
(a) 105 (b) 210
3. If I is the identity matrix of order 2 and (c) 315 (d) 420
1 1
A= , then for n ≥ 1, mathematical 8. If x is small, so that x2 and higher powers can
0 1
be neglected, then the approximate value for
induction gives
(1 − 2x) −1 (1 − 3 x) −2
(a) A n = nA − (n − 1) I (b) A n = nA + (n − 1) I is
(1 − 4 x) −3
(c) A = 2 A − (n + 1) I (d) A n = 2 n − 1 A − (n − 1) I
n n
(a) 1 − 2 x (b) 1 − 3 x
4. If n Cr − 1 = 330, n Cr = 462, and n Cr + 1 = 462, (c) 1 − 4 x (d) 1 − 5 x
then r is equal to
1 Ax + B Cx + D
(a) 3 (b) 4 9. If 4 2
= 2 + 2 , then
(c) 5 (d) 6 x + x +1 x + x+1 x − x+1
C + D is equal to
5. 10 men and 6 women are to be seated in a
row so that no two women sit together. The (a) −1 (b) 1 (c) 2 (d) 0
number of ways they can be seated, is 1 1 1 1
10. + + + + K is equal to
11 ! 2⋅3 4 ⋅5 6⋅7 8 ⋅9
(a) 11 ! 10 ! (b)
6!5! 2
(a) log   (b) log  
e
10 ! 9 ! 11 ! 10 ! e 2
(c) (d)
5! 5! (c) log (2 e ) (d) e − 1
11. If the harmonic mean between the roots of 20. If a complex number z satisfies
(5 + 2) x2 − bx + (8 + 2 5) = 0 is 4, then the | z2 − 1|= | z|2 + 1, then z lies on
value of b is (a) the real axis (b) the imaginary axis
(a) 2 (b) 3 (c) y = x (d) a circle
(c) 4 − 5 (d) 4 + 5 (1 + i) x − i (1 + 2i) y + i
21. If + = 1, then ( x, y) is
12. The set of solutions satisfying both 2+ i 2− i
x2 + 5x + 6 ≥ 0 and x2 + 3 x − 4 < 0 is equal to
(a) (−4, 1) (b) (−4, − 3] ∪ [−2, 1) 7 −7  7 7
(a)  ,  (b)  , 
(c) (−4, − 3) ∪ (−2, 1) (d) [−4, − 3] ∪ [−2, 1] 3 15   3 15 
7 −7  7 7
13. If the roots of x 3 − 42 x2 + 336 x − 512 = 0, are (c)  ,  (d)  , 
in increasing geometric progression, then its 5 15   5 15 
common ratio is
22. The period of f ( x) = cos   + sin   is
x x
(a) 2 : 1 (b) 3 : 1 3  2
(c) 4 : 1 (d) 6 : 1
(a) 2 π (b) 4 π (c) 8 π (d) 12 π
14. If α and β are the roots of the equation 23. If sin θ + cos θ = p and sin θ + cos 3 θ = q,
3
x2 − 2 x + 4 = 0, then α 9 + β 9 is equal to then p ( p2 − 3) is equal to
(a) −2 8 (b) 2 9
(a) q (b) 2q
(c) −210 (d) 210 (c) −q (d) −2q
−8 5
15. If A= satisfies the equation 24. If tan ( π cos θ) = cot ( π sin θ), then a value of
 2 4
π
x2 + 4 x − p = 0, then p is equal to cos θ −  among the following is
 4
(a) 64 (b) 42 1 1 1 1
(c) 36 (d) 24 (a) (b) (c) (d)
2 2 2 2 4
x+2 x+3 x+5
16. x + 4 x+6 x + 9 is equal to 25. The set of solutions of the system of
x+8 x + 11 x + 15 equations
2π
(a) 3 x2 + 4 x + 5 (b) x3 + 8 x + 2
x+ y=
3
(c) 0 (d) –2 3
and cos x + cos y = ,
17. The system of equations 3 x + 2 y + z = 6, 2
3 x + 4 y + 3 z = 14 and 6x + 10 y + 8 z = a, has where x, y are real, is
infinite number of solutions, if a is equal to x − y 1
(a) ( x, y) : cos   = 
(a) 8 (b) 12 (c) 24 (d) 36   2  2
x − y 1
18. The number of real values of t such that the (b) ( x, y) : sin   = 
system of homogeneous equations   2  2
1
tx + ( t + 1) y + ( t − 1) z = 0 (c) ( x, y) : cos ( x − y) = 
 2
( t + 1) x + ty + ( t + 2) z = 0 (d) Empty set
( t − 1) x + ( t + 2) y + tz = 0 5 3
26. If cos −1   + cos −1   = cos −1 x, then x is
has non-trivial solutions is  13   5
(a) 3 (b) 2 (c) 1 (d) 4 equal to
4 4 3 −36
 1 + i 1 − i (a) (b)
19.   +  is equal to 65 65
 1 − i 1 + i −33
(c) (d) −1
(a) 0 (b) 1 (c) 2 (d) 4 65
1
27. tanh −1   + coth −1 (2) is equal to 34. The shortest distance between the lines
 2 r = 3 i + 5 j + 7 k + λ( i + 2 j + k) and
1 1 r = − i − j − k + µ(7 i − 6 j + k) is
(a) log 3 (b) log 6
2 2 16 26
(a) (b)
1 5 5 5 5
(c) log 12 (d) log 3
2 36 46
(c) (d)
5 5 5 5
28. In any ∆ ABC, r1r2 + r2 r3 + r3r1 is equal to
∆2 ∆ 35. A unit vector coplanar with i + j + 3 k and
(a) (b)
r 2
r i + 3 j + k and perpendicular to i + j + k is
2∆ 1 1
(c) (d) ∆2 (a) (j + k ) (b) (i − j + k )
r 2 3
1 1
1 1 3 (c) (j − k ) (d) (i + j − k )
29. If in a ∆ABC, + = , then 2 3
a+ c b+ c a+ b+ c
∠ C is equal to 36. If a and b are two non-zero perpendicular
(a) 30° (b) 45°
vectors, then a vector y satisfying equations
(c) 60° (d) 90°
a ⋅ y = c (where, c is scalar) and a × y = b is
(a) | a |2 [c a − (a × b)]
30. A person observes the top of a tower from a
(b) | a |2 ⋅ [c a + (a × b)]
point A on the ground. The elevation of the
1
tower from this point is 60°. He moves 60 m (c) [c a − (a × b)]
in the direction perpendicular to the line | a |2
joining A and base of the tower. The angle of 1
(d) [c a + (a × b)]
elevation of the tower from this point is 45°. | a |2
Then, the height of the tower (in metres) is
37. Two numbers are chosen at random from
3
(a) 60 (b) 60 2 {1, 2, 3, 4, 5, 6, 7, 8} at a time. The probability
2 that smaller of the two numbers is less than
2 4 is
(c) 60 3 (d) 60
3 7 8
(a) (b)
31. The points whose position vectors are 14 14
9 10
2i + 3 j + 4 k,3 i + 4 j + 2k and 4 i + 2 j + 3 k are (c) (d)
the vertices of 14 14
(a) an isosceles triangle 38. Two fair dice are rolled. The probability of
(b) right angled triangle the sum of digits on their faces to be greater
(c) equilateral triangle than or equal to 10 is
(d) right angled isosceles triangle 1 1
(a) (b)
5 4
32. P, Q, R and S are four points with the 1 1
position vectors 3 i − 4 j + 5k, − 4 i + 5 j + k (c) (d)
8 6
and −3 i + 4 j + 3 k, respectively. Then, the
line PQ meets the line RS at the point 39. A bag contains 2n + 1 coins. It is known that
(a) 3i + 4 j + 3k (b) −3i + 4j + 3k n of these coins have a head on both sides,
(c) −i + 4j + k (d) i + j + k whereas the remaining n + 1 coins are fair. A
coin is picked up at random from the bag and
33. If a ≠ 0, b ≠ 0, c ≠ 0, a × b = 0 and b × c = 0, tossed. If the probability that the toss
then a × c is equal to 31
results in a head is , then n is equal to
(a) b (b) a 42
(c) 0 (d) i + j + k (a) 10 (b) 11 (c) 12 (d) 13
40. The random variable takes the values 1, 2, 3, 45. If the points (1, 2) and (3, 4) lie on the same
1 side of the straight line 3 x − 5 y + a = 0, then
… , m. If P ( X = n) = to each n, then the
m a lies in the set
variance of X is (a) [7, 11] (b) R − [7, 11] (c) [7, ∞ ) (d) (−∞, 11]
(m + 1)(2 m + 1) m2 − 1 46. The equation of the pair of lines passing
(a) (b)
6 12 through the origin whose sum and product
m+ 1 m2 + 1 of slopes are respectively the arithmetic
(c) (d)
2 12 mean and geometric mean of 4 and 9 is
41. If X is a poisson variate (a) 12 x2 − 13 xy + 2 y2 = 0
P ( X = 1) = 2 P ( X = 2), then P ( X = 3) is equal (b) 12 x2 + 13 xy + 2 y2 = 0
to (c) 12 x2 − 15 xy + 2 y2 = 0
−1 −2
e e (d) 12 x2 + 15 xy − 2 y2 = 0
(a) (b)
6 2
e −1 e −1 47. The equation
(c) (d) x2 − 5xy + py2 + 3 x − 8 y + 2 = 0 represents a
2 3
pair of straight lines. If θ is the angle
42. The origin is translated to (1, 2). The point between them, then sin θ is equal to
(7, 5) in the old system undergoes the 1 1 1 1
(a) (b) (c) (d)
following transformations successively. 50 7 5 10
I. Moves to the new point under the given
48. If the equation
translation of origin.
ax2 + 2hxy + by2 + 2 gx + 2 fy + c = 0
II. Translated through 2 units along the represents a pair of straight lines, then the
negative direction of the new X-axis. square of the distance of their point of
π intersection from the origin is
III. Rotated through an angle about the
4 c(a + b ) − af 2 − bg 2 c(a + b ) + f 2 + g 2
origin of new system in the clockwise (a) 2
(b)
ab − h ab − h2
direction. The final position of the point
(7, 5) is c(a + b ) − f 2 − g 2 c(a + b ) − f 2 − g 2
(c) 2
(d)
 9 −1   7 1  ab − h (ab − h2 )2
(a)  ,  (b)  , 
 2 2  2 2
49. The circle 4 x2 + 4 y2 − 12x − 12 y + 9 = 0
 7 −1   5 −1 
(c)  ,  (d)  ,  (a) touches both the axes
 2 2  2 2
(b) touches the x-axis only
43. If p and q are the perpendicular distances (c) touches the y-axis only
from the origin to the straight lines (d) does not touch the axes
x sec θ − y cosec θ = a and
50. For the circle C with the equation
x cos θ + y sin θ = a cos 2θ, then
2 2 2 2 2 2
x2 + y2 − 16x − 12 y + 64 = 0 match the List I
(a) 4 p + q = a (b) p + q = a with the List II given below.
(c) p2 + 2q 2 = a2 (d) 4 p2 + q 2 = 2 a2
List I List II
44. If 2 x + 3 y = 5 is the perpendicular bisector (i) The equation of the polar of (A) y = 0
of the line segment joining the points ( −5, 1) with respect to C
1 (B) y = 6
A 1,  and B, then B is equal to
(ii) The equation of the tangent
 3 at ( 8, 0) to C
(iii) The equation of the normal at (C) x + y = 7
21 49  17 31
(a)  ,  (b)  ,  (2, 6) to C
 13 39   13 39  (iv) The equation of the diameter (D) 13 x + 5 y = 98
7 49  21 31 of C through ( 8, 12 )
(c)  ,  (d)  , 
 13 39   13 39  (E) x = 8
The correct match is 57. If x = 9 is a chord of contact of the hyperbola

(i) (ii) (iii) (iv) x2 − y2 = 9, then the equation of the tangent
(a) (D) (B) (A) (E) at one of the points of contact is
(b) (D) (A) (B) (E) (a) x + 3 y + 2 = 0 (b) 3 x + 2 2 y − 3 = 0
(c) (C) (D) (A) (B) (c) 3 x − 2 y + 6 = 0 (d) x − 3 y + 2 = 0
(d) (C) (E) (B) (A) 58. The perpendicular distance from the point
π
51. If the length of the tangent from ( h, k) to the (1, π) to the line joining (1, 0° ) and 1, ,
2 2
circle x + y = 16 is twice the length of the  2
tangent from the same point to the circle (in polar coordinates) is
x2 + y2 + 2 x + 2 y = 0, then (a) 2 (b) 3 (c) 1 (d) 2
(a) h2 + k 2 + 4h + 4k + 16 = 0
59. If D(2, 1, 0), E (2, 0, 0) and F(0, 1, 0) are
(b) h2 + k 2 + 3h + 3k = 0 mid-points of the sides BC, CA and AB of
(c) 3h2 + 3k 2 + 8h + 8k + 16 = 0 ∆ABC, respectively. Then, the centroid of
(d) 3h2 + 3k 2 + 4h + 4k + 16 = 0 ∆ABC is
1 1 1 4 2
(a)  , ,  (b)  , , 0
52. ( a, 0) and ( b, 0) are centres of two circles  3 3 3 3 3 
belonging to a coaxial system of which y-axis 1 1 1 2 1 1
is the radical axis. If radius of one of the (c)  − , ,  (d)  , , 
 3 3 3  3 3 3
circles is ‘ r’ , then the radius of the other
circle is 60. The direction ratios of the two lines AB and
(a) (r 2 + b 2 + a2 )1/ 2 (b) (r 2 + b 2 − a2 )1/ 2 AC are 1, − 1, − 1 and 2, − 1, 1. The direction
2 2 2 1/ 3 2 2 2 1/ 3 ratios of the normal to the plane ABC are
(c) (r + b − a ) (d) (r + b + a )
(a) 2, 3, –1 (b) 2, 2, 1
53. If the circle x2 + y2 + 4 x − 6 y + c = 0 bisects (c) 3, 2, –1 (d) –1, 2, 3
the circumference of the circle
x2 + y2 − 6x + 4 y − 12 = 0, then c is equal to
61. A plane passing through ( −1, 2, 3) and whose
normal makes equal angles with the
(a) 16 (b) 24 coordinate axes is
(c) –42 (d) –62
(a) x + y + z + 4 = 0 (b) x − y + z + 4 = 0
54. A circle of radius 4, drawn on a chord of the (c) x + y + z − 4 = 0 (d) x + y + z = 0
parabola y2 = 8 x as diameter, touches the
axis of the parabola. Then, the slope of the
62. A variable plane passes through a fixed
point (1, 2, 3). Then, the foot of the
chord is
perpendicular from the origin to the plane
1 3
(a) (b) lies on
2 4
(c) 1 (d) 2 (a) a circle (b) a sphere
(c) an ellipse (d) a parabola
55. The mid-point of a chord of the ellipse
x2 + 4 y2 − 2x + 20 y = 0 is (2, − 4). The 63. Let f be a non-zero real valued continuous
equation of the chord is function satisfying f ( x + y) = f ( x) ⋅ f ( y) for
all x, y ∈ R. If f (2) = 9, then f (6) is equal to
(a) x − 6 y = 26 (b) x + 6 y = 26
(c) 6 x − y = 26 (d) 6 x + y = 26 (a) 32 (b) 36 (c) 34 (d) 33
3 3
x2 y2 tan x − sin x
56. If the focii of the ellipse + = 1 and the 64. lim is equal to
25 16 x→ 0 x5
x2 y2 5 3
hyperbola − 2 = 1 coincide, then b2 is (a) (b)
4 b 2 2
equal to 3 2
(c) (d)
5 5
(a) 4 (b) 5 (c) 8 (d) 9
1 1 p  1 1 1 1
65. If f ( x) = and g( x) = , then g′ (2) (a)  +  (b) p  + 
1 1 2 u v  u v 
1+ 1+
x f ( x) p  1 1 1 1
(d) p  − 
(c)  − 
is equal to 2 u v  u v 
1 1 72. If u = log ( x 3 + y 3 + z3 − 3 xyz), then
(a) (b)
5 25 ( x + y + z)(ux + u y + u z ) is equal to
1
(c) 5 (d) (a) 0 (b) x − y + z
16
(c) 2 (d) 3
y x dy  2 + sin 2x 
66. If + = 2, then is equal to
∫e  dx is equal to
x
x y dx 73. 
 1 + cos 2x 
x 2 + y2 x 2 − y2
(a) (b) (a) e x cot x + C (b) 2e x sec 2 x + C
x+ y x+ y
(c) e x cos 2 x + C (d) e x tan x + C
(c) 1 (d) 2
74. If
d x − sin x  x   x 
67. If
dx
[( x + 1)( x2 + 1)( x4 + 1)( x 8 + 1)] ∫ 1 + cos x dx = x tan  2  + p log  sec  2  +C,
= (15x p − 16x q + 1)( x − 1) −2 , then ( p, q) is then p is equal to
equal to (a) –4 (b) 4 (c) 2 (d) –2
(a) (12, 11) (b) (15, 14) dx
(c) (16, 14) (d) (16, 15) 75. If ∫ = I + C, then I is
x (log x − 2)(log x − 3)
68. If cos −1   = 2 log   , where x > 0, then
y x equal to
 b  2
2 1 log x − 3
d y dy (a) log
x2 +x is equal to x log x − 2
dx2 dx
log x − 3
(a) 4y (b) − 4y (b) log
log x − 2
(c) 0 (d) − 8y
log x − 2
69. The relation between pressure p and volume (c) log
log x − 3
V is given by pV 1/ 4 = constant. If the
1 (d) log| (log x − 3)(log x − 2 )|
percentage decrease in volume is , then the b dx ∞ dx
2 76. If ∫
percentage increase in pressure is 0 1 + x2
= ∫b 1 + x2
, then b is equal to
1 1 1 3
(a) −
8
(b)
16 (a) tan−1   (b)
 3 2
1 1
(c) (d) (c) 2 (d) 1
8 2
77. The area (in sq units) bounded by the curves
70. If the curves x2 + py2 = 1 and qx2 + y2 = 1 x = − 2 y2 and x = 1 − 3 y2 is
are orthogonal to each other, then 2 4 5
1 1 (a) (b) 1 (c) (d)
(a) p − q = 2 (b) − =2 3 3 3
p q 3 dx
(c)
1 1
+ = −2 (d)
1
+
1
=2
78. The approximate value of ∫1 2 + 3 x using
p q p q
Simpson’s rule and dividing the interval
71. The focal length of a mirror is given by [1, 3 ] into two equal parts is
2 1 1 1 11 107
= − . In finding the values of u and v, (a) log   (b)
f v u 3  5 110
the errors are equal to ‘ p’ . Then, the relative 29 119
(c) (d)
error in f is 110 440
79. An integrating factor of the equation 80. The solution of the differential equation
(1 + y + x2 y) dx + ( x + x 3) dy = 0 is dy
− 2 y tan 2x = ex sec 2x is
(a) e x
(b) x 2 dx
1 (a) y sin 2 x = e x + C (b) y cos 2 x = e x + C
(c) (d) x
x (c) y = e x cos 2 x + C (d) y cos 2 x + e x = C
Answers
Physics
1. (b) 2. (b) 3. (c) 4. (a) 5. (c) 6. (a) 7. (b) 8. (a) 9. (d) 10. (b)
11. (a) 12. (b) 13. (a) 14. (a) 15. (c) 16. (b) 17. (c) 18. (a) 19. (c) 20. (d)
21. (c) 22. (b) 23. (a) 24. (b) 25. (b) 26. (b) 27. (c) 28. (a) 29. (b) 30. (a)
31. (b) 32. (a) 33. (d) 34. (d) 35. (b) 36. (c) 37. (b) 38. (b) 39. (c) 40. (d)
Chemistry
1. (b) 2. (c) 3. (c) 4. (c) 5. (b) 6. (a) 7. (d) 8. (a) 9. (d) 10. (b)
11. (c) 12. (a) 13. (c) 14. (b) 15. (b) 16. (d) 17. (a) 18. (a) 19. (b) 20. (a)
21. (c) 22. (c) 23. (d) 24. (b) 25. (d) 26. (a) 27. (d) 28. (b) 29. (d) 30. (c)
31. (a) 32. (a) 33. (c) 34. (b) 35. (d) 36. (a) 37. (c) 38. (b) 39. (b) 40. (d)
Mathematics
1. (a) 2. (a) 3. (a) 4. (c) 5. (d) 6. (c) 7. (b) 8. (c) 9. (d) 10. (b)
11. (d) 12. (b) 13. (c) 14. (c) 15. (b) 16. (d) 17. (d) 18. (*) 19. (c) 20. (b)
21. (a) 22. (d) 23. (d) 24. (a) 25. (d) 26. (c) 27. (d) 28. (a) 29. (c) 30. (a)
31. (c) 32. (b) 33. (c) 34. (d) 35. (c) 36. (c) 37. (c) 38. (d) 39. (a) 40. (b)
41. (a) 42. (c) 43. (a) 44. (a) 45. (a) 46. (a) 47. (a) 48. (c) 49. (a) 50. (b)
51. (c) 52. (b) 53. (d) 54. (c) 55. (a) 56. (b) 57. (b) 58. (d) 59. (b) 60. (a)
61. (c) 62. (b) 63. (b) 64. (b) 65. (b) 66. (c) 67. (d) 68. (b) 69. (d) 70. (d)
71. (b) 72. (d) 73. (d) 74. (a) 75. (b) 76. (d) 77. (c) 78. (c) 79. (c) 80. (b)
(*) None of the correct option.
Hints & Solutions

Physics
EJ 2 Now, on putting these dimensions in Eq. (i), we
1. Given quantity is …(i)
have
M 5G 2
where dimensions of the various given quantities are [ML2 T –2 ][ML2 T –1 ]2
=
Dimensions of E = [ML2 T –2 ] [M5 ][M–1L3 T –2 ]2
Dimensions of J = [ML2 T –1 ] [M3L6 T –2 ]

= = dimensionless
[M3L6 T –2 ]
Dimension of M = [M]
Dimension of G = [M–1L3 T –2 ] Since, angle is a dimensionless quantity
2. We know, work done W = F ⋅ d 5. Energy of balls at rest, K1 = mgh1 and K 2 = mgh2

Given, force, F = 2 $i − $j − k$ , K1 − K 2
percentage loss in KE = × 100
K1
and position vector, d = 3$i + 2 $j − 5 k$
25  12 − h 2 
Using vector identify $i ⋅ $i = $j ⋅ $j = k$ ⋅ k$ = 1 = 
100  12 
Hence, W = F ⋅ d = (2 $i − $j − k$ )⋅ (3$i + 2 $j − 5 k$ )
25 × 12
⇒ = 12 − h2
= 6 − 2 + 5 = 9 units 100
displacement ⇒ h2 = 12 − 3 = 9 m
3. We know, average velocity =
time
6. Velocity of centre of mass is
µ 2 + R2 / 4 m1v1 + m2 v 2
vav = …(i) vCM =
T /2 m1 + m2
y Given, m1 = 4 kg, m2 = 5 kg, v1 = 5$j m /s
v2 = 3$i m /s
4 × 5$j + 5 × 3$i
∴ vCM =
5+ 4
H
x 20 i 15 $
$
= + j
R/2 9 9
2 2
v 2 sin 2 θ  20   15
where, H = maximum height = …(ii) Hence, magnitude| vCM | =   +  
2g  9  9
v 2 sin 2θ 25
Range R = …(iii) = m /s
g 9
2 v sin θ 7. From law of conservation of momentum, we
Time of flight T =
g known,
Putting the values of Eqs. (ii), (iii) and (iv) in Eq. (i)
we have
v
vav = 1 + 3 cos 2 θ
2 60° T T cos θ
4. The free body diagram of the given situation is
T sin θ
ma
co
sβ N
β m mg
P ma
M mg m1u1 + m2u 2 = m1v1 + m2 v2

sin
mg
β u1 = 0,u 2 = 150 m /s, m1 = 2.9 kg and m2 = 0.1kg
β
So, 2.9 × 150 = (2.9 + 0.1) v
(given)
2.9 × 150
Force = Mass × Acceleration ⇒ =v
∴ P = ( M + m) a 3
ma cos β = mg sin β ⇒ v = 145 m/s
sin β mv 2
⇒ a=g Also, T sin θ =
cos β r
= g tan β Putting the values and solving, we get T = 135 N.
∴ P = (M + m) g tan β
8. For upper half where, M and m are mass of solid sphere and
particle respectively. Gravitational force on
A
particle due to sphere with cavity
l/2  M
th G  m
oo GMm  8
sm F2 = 2
−
9R (5R / 2 )2
l/2 ug
h
ro GMm  1 4 
= −
φ 2 
R  9 8 × 25 
B
C
GMm  41 
=
From equation, R 2  50 × 9 
v 2 = u 2 + 2 as F1 50
∴ =
we have, u = 0 (from rest), s = l/2 F2 41
l
v 2 = 0 + 2 (g sin φ ) ⋅ …(i) K
2 12. We knows, maximum velocity Vmax = Aω = A
m
For lower half,
Given, K1, m1 = m, K 2 , m2 = 2 m
v = 0 and a = g (sin φ − µ cos φ ),
(Vmax )A = (Vmax )B
l
⇒ 0 = u 2 + 2 g (sin φ − µ cos φ ) ⋅
2 K1 K2
AA = AB
⇒ − gl sin φ = gl (sin φ − µ cos φ ) M 2m
⇒ µ cos φ = 2 sin φ ⇒ µ = 2 tan φ AA K2
⇒ =
9. Given, I = 4 kg -m 2 , τ = 8 N -m and t = 20 s AB 2 K1
τ = Iα 13. Given, σ = 0.32, F = 20 N
τ 8
⇒ α = = =2 A = 0.01cm 2 = 0.01 × 10 –3 m
I 4
1 and Y = 1 − 1 × 1011 N/m 2
θ = αt 2
2 We know that
1 ∆l 20
⇒ θ= × 2 × 20 × 20 = 400 =
F
= = 18.1 × 10 −7
2 l AY 0.01 × 10 −3 × 1.1 × 1011
ω = τθ = 8 × 400 = 3200 J
and we also known
10. We know the KE of a rotational circular disc
− ∆r / r
1 2 1 σ=
KE = Iω and I = MR 2 ∆l / l
2 2
∆r
Hence, the resultant loss rotational KE will be the − = 0.32 × 18.1 × 10 −7 = 5.79 × 10 −7
1 r
addition of both energy loss is = Iω 2
4 Hence, decrease in cross reactional area of wire is
∆r
11. Gravitational force due to solid sphere is ∆A = 2 × A = 2 × 5.79 × 10 −7 × 0.01 × 10 −3
GMm GMm r
F1 = = = 0.158 × 10 −10 m 2
(3R )2 9R 2
= 1.26 × 10 −6 cm 2
M 14. We knows height of water rise in a capillary tube
R/2 2T cos θ
m h=
R rdg
2T1 cos θ1 2T cos θ 2
h1 = , h2 = 2
rdg rdg
3R
Given, h1 = h,T1 = T ,θ1 = 0 18. We knows

2T dQ = du + dw
∴ h= …(i)
rdg and we also known du = 0 for cyclio process so
1 that
Given, T2 = 2T ,θ = 45° ,cos 45° =
2 dQ = dw
1 Here, in given condition the work done during is
2 2T ×
2 a basic process
∴ h2 = …(ii)
rdg w2 − 3 = P2 (v3 − v2 )
From Eqs. (i) and (ii), we observe w4 − 1 = p1(v1 − v4 )
h2 = h. Total work done = p2 (v3 − v2 ) + p1(v1 − v4 )
3×T
Hence, same mass of liquid rises into the From gas equation pV = nRT =
capillary as before 5 × 10 −3 kg. 2
Hence, total work done
2 r 2 (ρ − σ ) g
15. Terminal velocity v = 3R
9 η = (400 + 2500 − 700 − 1100 )
2
When, the two drops of same radius r coalesce 3
then radius of new drop is R. = R (2900 − 1800 )
2
4 4 4 3 3300 R
∴ πR 3 = πr 3 + πr 3 = R(1100 ) =
3 3 3 2 2
⇒ R = 21/ 3 ⋅ r = 1650R
Critical velocity ∝ r 2 T 40 3
19. 2 = 1 − η = 1 − =
T1 100 5
v r2
∴ = 2/ 3 2 5
v1 2 ⋅ r ⇒ T1 = T2
3
⇒ v1 = 3 4 ⋅ v 5
⇒ T1 = × 300 = 500 K
16. Due to volume expansion of both mercury and 3
flask, the change in volume of mercury relative to New efficiency η′ = 60%
flask is given by T2 60 2
= 1 − η′ = 1 − =
∆V = V0 [γ L − γ g ] ∆θ T1′ 100 5
= V [γ m − 3α g ] ∆θ 5
⇒ T1′ = × 300 = 750 K
Given, γ m = 182 × 10 −6 / ° C, α g = 10 × 10 −6 / ° C 2
∆θ = 100 ° C, V = 1L Increase in temperature = 750 − 500 = 250 K
∴ ∆V = 1 [(182 × 10 −6 − 3 × 10 × 10 −6 )] × 100 20. We knows from Stefan’s law,
∆V = 15.2 CC E = eAσT 4
17. In given condition Here, E1 = e1 AσT14
Y + 160 340 − 273 E2 = e 2 AσT24
=
−50 + 160 373 − 273 so, E1 = E2
Y + 160 67 ∴ e1T14 = e 2T24
=
110 100 1/ 4 1/ 4
e   1 
67 × 110 ⇒ T2 =  1 T14  =  × (5802 )4 
Y + 160 =  e2   81 
100
⇒ TB = 1934 K
Y = 73.7 − 160
From Wein’s law, λ ATA = λ BTB
Y = − 86.3° Y
λ A TB 23. From lens maker’s formula

⇒ =
λ B TA 1 m  1 1
= (g µ − 1)  − 
λ B − λ A TB − TB f  R1 R2 
⇒ =
λB TA
gµ 1.5
Now, gµ = =
m
1 5802 − 1934 3968
⇒ = = mµ 1.75
λB 5802 5802
3 For concave lens as shown in the figure, in this
⇒ λ B = µm case
2
R1 = − R and R2 = + R
21. We knows frequency of a closed end an column
v mµ
n1 = gµ
4l1
We knows frequency of a open end an column R1 R2
v
n2 = medium
2l2 mµ
Given, l1 = 32 cm, l 2 = 66 cm
and n1 − n2 = 8 heat/s 1  1.5   1 1 0.25 × 2
= − 1  − −  = +
v v f  1.75   R R 1.75R
So, n1 = =
4 × 32 128 ⇒ f = + 3.5R
and n2 =
v
=
v The positive sign shows that the lens behaves as
2 × 66 132 a convergent lens.
In given condition, 24. For eye piece
v
−
v
=8 Ve = − 25 cm, fe = 5 cm
128 132 1 1 1
⇒ − =
v = 8448 × 4 −25 ue 5
v = 33792 25
⇒ ue = − cm
33792 6
Hence, n1 =
128 25 38
v0 = L − | ue | = 10.5 − = cm
n1 = 264 Hz 6 6
33792 For objective
and n2 =
132 1 1 1
− =
n2 = 256 Hz v0 u 0 f0
22. We know that, 1 1 1
− =
 v  38/ 6 u 0 1.9
n′ = n  
 v − v s cos θ  ⇒
1
=
6
−
1
  u 0 38 1.9
 340  ⇒ u 0 = 2.7 cm
Hence, n′ = 640 
100 3 
 340 − ×  25. In Fresnel diffraction, no lenses are required for
 3 5 rendering light rays parallel and also the
  diffraction pattern may be dark or bright
 340  depending upon the number of half-period zones
n′ = 640 
100  that superpose at the point. Hence, the intensity
 340 − 
 5  of light at a point a screen beyond or obstacle
340 depends on the number of half-periods zones
n′ = 640 × = 2 × 340 that superpose at the point.
320
= 680 Hz
26. We know that the time period of a vibrating bar T BH

=
magnet T0 F + BH2
2
I
T = 2π BH BH
MBH = =
BH2 2
+ tan θ + BH2 BH sec 2 θ
Given, T1 = 8 s, I1 = I, M = 4 Am 2
I = cos θ
8 = 2π …(i)
4 × BH ⇒ T = T02 cos θ
2
Given, T2 = 6 s, I2 = 9 × 10 −2 kg -m 2 , M = 8 Am 2 ε0 A
29. We knows capacitance C =
d
9 × 10 −2
6 = 2π …(ii) When plate is inserted
8 × BH ε A 2ε A
C′ = 0 = 0
Dividing Eqs. (i) and (ii) d d
d −
8 2I 2
=
6 9 × 10 −2 C′ 2
=
C 1
Squaring both sides and solving, we have
30. Applying junction law
I = 8 × 10 −2 kg -m 2
We have
µ0 M
27. We knows, B = I = I1 + I2
4π r 3 24 − V 10 − V 9 − V
= +
Hence the resultant horizontal magnetic 3 2 1
induction point of the line joining their conters is 24 − V 28 − 3 V
⇒ =
B = B1 + B2 + BH 3 2
10 −7 × 1.2 10 −7 × 1 ⇒ 2(24 − V ) = 3(28 − 3 V )
= + + 3.6 × 10 −5
−2 3
(10 × 10 ) (10 × 10 −2 )3 ⇒ 48 − 2V = 84 − 9 V
⇒ 7V = 36
= 1.2 × 10 −4 + 1 × 10 −4 + 0.36 × 10 −4
⇒ V = 5.14 V
= 2.56 × 10 −4 T From Ohm’s law
28. In deflection magnetometer, field due to magnet ∆V = IR
F and horizontal component BH of earth’s field are ∆V = 24 − 5.14 = 18.86, R = 3 Ω
perpendicular to each other. 18.86
∴ I= ≈ 6A
∴ Net field is F 2 + BH2 3
So the time period 31. Here in given condition, we have
I bx
T = 2π …(i) b + x 0.625
2 =
M F + BH
2 0.375
When magnet is removed bx 25
=
I (b + x )2 15
T0 = 2 π …(ii)
MBH 5b 5
=
F (b + 5)2 3
Also, = tan θ
BH b 1
=
Dividing Eqs. (i) by (ii), we get 2 b + 10 3
⇒ 3b − 2 b = 10
b = 10 Ω
32. The heat developed per unit time in given hc

36. Maximum KE = − φ0
condition is proportional to ∆T and I. λ
33. We knows in LCR circuits Given, λ = 3000 Å = 3000 × 10 −10 m,
1 h = 6.6 × 10 −34 J -s, c = 3 × 10 8 m /s, φ = 2 eV
f =
2π LC Maximum KE
1 6.6 × 10 −34 × 3 × 10 8 1
and f ∝ = × −2
−10
L 3000 × 10 1.6 × 10 −12
Here, in given condition
= 4.13 − 2 = 2.13 eV
f1 L L
= 1 = In Joules : 2.13 × 1.6 × 10 −19 = 3.41 × 10 −19 J
f2 L2 3L
1/ 4
37. The relation between radius (R) and atomic
 1 number (A) is
⇒ f1 =   f2
 3 1/ 3
R1  A1 
= 
34. ig =
S
i R2  A2 
S +G
Given, R1 = 6 fermi, A1 = 125, A2 = 27
1 10 1/ 3
= 6  125 5
40 10 + x =  =
R2  27  3
⇒ 10 + x = 400
6 × 3 18
⇒ x = 390 Ω ⇒ R2 = = = 3.6 fermi
5 5
35. From equation of photoelectric effect, we have = 3.6 × 10 −15 m
hc
E1 = −W …(i) 38. In 1 s, energy generated is 3.7 × 10 7 J
λ1
In 144 × 10 4 s, energy generated is
hc
E2 = −W …(ii) = 3.7 × 10 7 × 144 × 10 4 J
λ2
Also energy released in one fission is
where, W is work function.
= 185 meV
hc = 185 × 10 6 × 1.6 × 10 −19 J
E1 + W = …(iii)
λ1
3.7 × 10 7 × 144 × 10 4
hc Number of fission =
E2 + W = …(iv) 185 × 10 6 × 1.6 × 10 −19
λ2
= 1.8 × 10 24 of U 235 atoms.
From Eq. (iv)
Mass contained in 1.8 × 10 24 atoms of U 235 is
hc
W= − E2 ,
λ2 235 × 1.8 × 10 24
= = 702.3 g = 0.70 kg
∴ Putting this value in Eq. (iii), we have 6.023 × 10 23
∆ic
E1 +
hc
− E2 −
hc 39. Current gain β =
λ1 λ1 ∆i b
∆ic = (4 − 0.2) mA = 3.8 × 10 −3 A
 1 1
⇒ E1 − E2 = hc  −  ∆i b = (140 − 45) µA = 95 × 10 −6 A
 λ1 λ 2 
3.8 × 10 −3
 λ − λ1 ∴ β= = 40
⇒ E1 − E2 = hc  2  95 × 10 −5
 λ 1λ 2 
40. The logic symbol of NAND gate is
(E1 − E2 )λ 1λ 2
⇒ hc =
(λ 2 − λ 1 )
Chemistry
1. Number of spherical/radial nodes in any orbital 3
7. KE = RT for 1 mole of the gas.
= n − l −1 2
For s = orbitals, l = 0. Q 4 g of H 2 gas has 2 moles of H 2
∴ Number of radial nodes in 3s-orbital ∴ It has 2 times KE as compared to 1 mole of gas
= 3 − 0 − 1= 2 But 8 g of O 2 gas has 1/4 moles of O 2 ;
For p - orbitals, l = 1 ∴ It has one fourth part of the KE as compared to
∴ Number of radial nodes in 2 p-orbitals 1 mole of gas.
= 2 − 1− 1= 0
Hence, ratio of KE of H 2 and O 2
2. The quantum or wave mechanical model of atom 1
is based upon the dual nature of electron, i.e., the KEH2 : KEO 2 = 2 : = 8 : 1
electron is not only a particle but has a wave 4
character. The wave character of electron has 8. Two solutions are isotonic if they have same
partical significance since its wavelength is easily molar concentrations of the particles.
observed in electromagnetic spectrum. (a) 0.15 M NaCl and 0.1 M Na 2SO 4
3. For 4th period, n = 4. NaCl is an electrolyte which dissociates to give
Orbitals being filled = 4s, 3 d , 4 p 2 ions, thus concentration of ions in the solution
Number of elements in the period = 2, 10, 6 = 18 0.30 M.
4. Molecule Hybridisation Shape Similarly for Na 2SO 4 (3 ions), the concentration of
ions in the solution = 0.30 M. Hence, both are
PCl 5 sp3d Trigonal
isotonic.
bipyramidal
dsp2 Square planar 9. According to Raoult’s law
[Ni(CN)4 ] 2− p° − p s n2
=
IF3 dsp 3
Trigonal p° n1 + n2
bipyramidal where, p° = vapour pressure of pure water at 100°C
(bent T shaped)
= 760 mmHg.
5. (a) Hybridised orbitals show only head on p s = vapour pressure of solution at 100°C
overlapping and thus form only σ bonds. w 18
They never form π bonds. n2 = moles of solute = 2 = = 0.1mol
M2 180
(c) Head on overlapping is stronger than lateral
or sideways overlapping. Therefore, the w1 180
n1 = moles of solvent = = = 10 mol
strength of bonds follows the order M1 18
π -p < σ s- s < σ s-p < σ p -p By putting these values in the formula
14p2 43 14442444 3
lateral head on overlapping of same shell p° − p s 0.1
=
overlapping p° 10 + 0.1
(d) s-orbitals are spherically symmetrical and
or 10.1 ( p° − p s ) = 0.1 p°
thus show only head on overlapping and
form only σ bonds. or 10 p° = 10.1 p s
6. A reaction in which the same species is 10 × 760
or ps = = 752.4 mmHg.
simultaneously oxidised as well as reduced is 10.1
called a disproportionation reaction.
10. During the electrolysis of an aqueous solution of
Reduced copper sulphate using copper electrodes, both
0 ∆ –1 +5 Cu 2+ and H + ions move towards cathode, but the
3Cl 2(g ) + 6OH − (aq ) → 5Cl (aq ) + Cl O 3− (aq )
−
discharge potential of Cu 2+ ions is lower than that
Oxidised + 3H 2O of H + ions, therefore Cu 2+ ions are discharged in
preference to H + ions and copper is deposited on Cα ⋅ Cα Cα 2

∴ Kc = =
the cathode. C(1 − α ) (1 − α )
Cu 2 + (aq ) + 2e − → Cu(s) (at cathode) 0.1 × 0.04 × 0.04
=
(1 − 0.04)
11. In a fully charged lead accumulator or lead
storage battery, sulphuric acid has a specific 1.6 × 10 −4
= = 1.66 × 10 −4
gravity (i.e., density that varies from 1.260 to 0.96
1.285. But during discharge (i.e., when the battery 15. As a mixture of NH 4OH and NH 4Cl acts as a basic
is in use). H 2SO 4 is used up. buffer, so its pH must be basic, (i.e., greater than
Pb(s) + PbO 2 (s) + 4H + (aq ) + 2SO 24 − (aq ) → 7), hence the answer must be 2nd. It can also be
2PbSO 4 (l ) + 2H 2O find by calculations :
[salt]
As a result, the specific gravity of H 2SO 4 falls pOH = pK b + log
[base]
when it falls below 1.230 the battery needs
0.2 M
recharging. = 4.8 + log
0.02 M
12. In a close packed structure (hcp or ccp)
(i) Number of octahedral voids = Number of = 4.8 × log 10
particles present in the close packing pOH = 4.8 + 1 = 5.8
(ii) Number of tetrahedral voids = 2 × Number of ∴ pH = 14 − pOH = 14 − 5.8 = 8.2
octahedral voids. 16. Evaporation of water in an open vessel is a
13. Integrated rate equation for first order reaction process which takes place by itself, by absorption
2.303 a of heat from the surroundings, because the
k= log gaseous water molecules are more random than
t (a − x )
the liquid water molecules.
k a H 2O(l ) → H 2O(g ); ∆H = + 40.8 kJ mol −1
or t = log
2.303 (a − x )
In other words, the process is spontaneous
= log a − log (a − x ) because it is accompanied by increase of
k entropy, which is further a measure of
or log (a − x ) = − t + log a
2.303 randomness or disorder of the system.
Thus, if log (a − x ) values are plotted against time 17. The examples of colloidal systems are sols
‘ t ’ the graph obtained should be a straight line. (solids in liquids), gels (liquids in solids),
emulsions (liquids in liquids) and foams (gases in
liquids) whereas aerosols are the colloidal system
k in which dispersed phase is liquid and dispersion
slope = – medium is gas.
log (a – x) 2.303
log a 18. (a) Heavy water is injurous to human beings,
plants and animals since it slows down the
rates of reactions occuring in them.
t (b) Heavy water reacts with aluminium carbide
forming deuteromethane.
14. % dissociation = 4% Al 4C 3 + 12D 2O → 4Al(OD)3
4 aluminium
degree of dissociation (α ) = = 0.04 carbide + CD 4
100
deuteromethane
For lactic acid
– + (c) In interstitial hydrates or deuterates, water
CH 3CH(OH)COOH º CH CH(OH)COO + H
3 molecules are present in interstitial sites or
Initial concentration voids in the crystal lattice. e.g., BaCl 2 ⋅ 2H 2O
C mol L−1 0 0 and similarly BaCl 2 ⋅ 2D 2O are interstitial
At. equilibrium C(1 − α ) Cα Cα compounds.
19. For titration of a basic solution of Na 2CO 3 and 22. In pyrophosphoric acid (H 4P2O 7 ), the phosphorus
NaHCO 3 against HCl, if phenolphthalein is used is bonded in tetrahedral manner with four sp3
as indicator, the end point is indicated only for half bonds. It has +5 oxidation state and it has four
neutralization of Na 2CO 3 , i.e., (upto NaHCO 3 ). P—OH bonds, two P==O bonds and one
Na 2CO 3 + HCl → NaHCO 3 + NaCl P—O—P linkage.
The remaining solution then contains the O O
unreacted NaHCO 3 from this reaction plus the
unreacted NaHCO 3 originally in the solution. At P P
the phenolphthalein end point, there is no HO O OH
reaction between HCl and NaHCO 3 . OH HO
From the equations pyrophosphoric acid
Mol of HCl consumed = mol of Na 2CO 3 (H4P2O7)
20 mL of 0.1 M = 20 mL of 0.1 M P4O10 + 6H 2O → 4H 3PO 4

orthophosphoric acid
∴ The concentration of Na 2CO 3 in solution
X = 0.1M. 23. Sodium thiosulphate is oxidised by moist Cl 2 or
Note that for a quantity of Na 2CO 3, exactly half chlorine water and precipitates sulphur,
volume of the HCl is used at the phenolphthalein Na 2S 2O 3 + Cl 2 + H 2O → Na 2SO 4 + 2HCl
end point and the second half volume of the HCl sodium
thiosulphate
is required for complete neutralization of Na 2CO 3
at methyl orange end point. + S
sulphur
NaHCO 3 + HCl → NaCl + CO 2 + H 2O 24. In Whytlaw-Gray’s method for preparation of
∴ Volume of HCl required to neutralize fluorine, the copper diaphragm is used to prevent
Na 2CO 3 in original sample = 2 × 20 mL the mixing of H 2 and F2 liberated at cathode and
anode respectively.
= 40 mL
Reactions in the electrolytic cell
If methyl orange is used, the end point is KHF2 → KF + HF
indicated when all the alkali is neutralized. ⇓
NaHCO 3 + HCl → NaCl + CO 2 + H 2O K + + F−
As 40 mL of 0.1 M HCl is consumed in complete
neutralization of Na 2CO 3 at methyl orange end At cathode At anode
point, so the volume of HCl used to neutralized
K + + e − → K F− → F + e −
NaHCO 3 from the original sample would be
K + HF → KF + H 2F → F2
Remaining HCl = 60 − 40 = 20 mL of 0.1 M
2H → H 2
As per equation = 1mol of NaHCO 3 = 1 mol of HCl
∴ 0.1 mol of NaHCO 3 = 0.1 mol of HCl,
25. Liquid xenon is used in bubble chamber for the
detection of γ-photon and neutral mesons.
20. Diborane reacts with HCl in the presence of AlCl 3 26. When a compound absorbs a certain wavelength
catalyst and liberates H 2 gas. (i.e., 490 nm - 500 nm) from the visible light which
AlCl 3 corresponds to the blue-green light in the visible
B2H 6 + HCl → B2H 5Cl + H 2 ↑ spectrum, the colour or light transmitted by it
diborane does not contain the colour of absorbed radiation
21. If all the four corners, i.e., all the four oxygen and thus shows the complementary colour, i.e.,
atoms of each tetrahedra (SiO 4 ) are shared with red.
other tetrahedra, three-dimensional network 27. In the extraction of silver from cyanide process
structure is obtained. i.e., different forms of silica (also Mac-Arthur Forrest process), the siliver
such as quartz, tridymite and crystobalite. compound dissolve in NaCN solution forming a
soluble complex salt, in presence of air, then o-bromination

silver is precipitated from this complex salt by the
addition of Zn, because Zn being more reactive NH2 NH2 NH2
displaces the Ag.
+ Br Br Br
Ag 2S + 4NaCN 2Na[Ag(CN)2 ]+ Na 2S ↓ H H H
º
Na 2S + 2O 2 → Na 2SO 4 + +
2Na[Ag(CN)2 ]+ Zn → Na 2 [Zn(CN)4 ] + 2Ag ↓

28. The most serious effect of the delpetion of ozone +
NH2
layer is that the UV rays coming from the sun can
pass through the stratosphere and reach the Br
surface of the earth. IT has been found that with H
increase in the exposure to UV rays, the chance
for occurance of skin cancer, increases, also
exposure of eye to UV rays damages the cornea p-bromination
and lens of the eye and may cause cataract and +
even blindness. NH2 NH2 NH2
29. Ferric salts (such as FeCl 3 ) form Prussian blue +
(blue ppt or colouration) with potassium

+
ferrocyanide.
H Br H Br H Br
4FeCl 3 + 3K 4 [Fe(CN)6 ] → Fe 4 [Fe(CN)6 ]3
Prussian blue
In addition to the usual resonating structures, that
(ferric ferrocyanide)
stabilizes the intermediate carbonium ion, the
+ 12KCl resonating strucutres formed by the interaction of
30. Decomposition of a compound by application of lone pair electrons of nitrogen with the positively
heat is called pyrolysis and pyrolysis of higher charged carbon of the ring also increase the
alkanes into a mixture of lower alkanes, alkenes, stability of the carbonium ion formed during the
etc. is also called cracking. atttack of Br + ion (electrophile) on o- and
p-positions.
31. The —NH 2 group of aniline is a very strong
electron donor (+ M effect), hence it activates the 32. The compound which is non-superimposable on
benzene ring thoroughly and the electrophilic its mirror image, is called optically active or chiral
aromatic substitutions on the benzene ring are and its two non-superimposable mirror images
very easy to take place at ortho and are called enantiomers which have all physical
para-positions. and chemical properties same and also rotate the
plane polarised light upto same extent but in
+ +
NH2 NH2 NH2 opposite direction.
s CH3 H 3C
C
C
H COOH HOOC H
s OH HO
enantiomers of lactic acid
+
NH2 NH2
33. On heating chloroform with concentrated
s aqueous or alcoholic NaOH, we get sodium
formate,
Cl NaOH NO2 NO NHOH

OH
H—C—Cl + NaOH H—C—OH
–NaCl Zn-NH4Cl 2[H]
Cl NaOH OH
unstable
–H2O
phenyl
O O hydroxylamine
NaOH (ii) While in alkaline medium, using Zn-NaOH,

H—C—ONa H—C—OH
sodium formate mononuclear intermediate products
(nitrobenzene and phenylhydroxyl amine)
34. Phenol when treated with Br2 in the presence of interact to each other to give dinuclear
non-polar solvent CS 2 , it gives only o- and product. Final product using Zn-NaOH is
p-bromophenols instead the trisubstituted hydrazobenzene, which in a formed viz the
products. Reason for the above observation is formation of azoxybenzene and azobenzene.
supression of phenoxide ion in non-polar solvent. NO2 NO NHOH
Thus, we get only mono substituted products.
Zn/NaOH 2[H]
OH OH OH
Br
Br2/CS2 nitrobenzene phenyl
+
hydroxylamine
o-bromophenol
Br
—N N—
35. Pyridinium chlorochromate (PCC) can be
prepared by the dissolution of chromium trioxide O
azoxybenzene
in aqueous HCl. Addition of pyridine gives
pridinium chlorochromate as orange cryotol. –H2O 2[H]
O O N
HCl 2[H]
Cr Cl—Cr—OH —N N—
O O
O azobenzene
chlorochromic acid
s —NH—NH—
O
⊕ hydrazobenzene
Cl—Cr—O H—N
38. The polymers which disintegrate by themselves
O during a certain period of time by enzymatic
pyridinium chlorochromate (PCC) hydrolysis and to some extent by oxidation, are
PCC offers the advantage of the selective known as biodegradable polymers. Example →
oxidation of alcohols to aldehydes, whereas Poly-β-hydroxy-butyrate-co-β-hydroxyvalerate
many other reagents are less selective. (PHBV), which is used in orthopaedic devices
36. The more the value of pK a , compound will be less and in controlled drug release, and poly (glycollic
acidic indicating the less value of K a and smaller acid) poly (lactic acid) or commonly known as
the value of pK a , the compound will be more dextron, which is used for stitching of wounds
acidic, i.e., there will be more the value of K a . after operation.
37. (i) On reduction in neutral media, using Zn dust 39. The only possible pairing in DNA are between
and NH 4Cl solution nitrobenzene gives G (guanine) and C (cytosine) through three
phenyl hydroxylamine. H-bonds i.e., (C ≡ G) and between A (adenine)
and T (thymine) through two H-bonds (i.e., A = T) 40. Phenacetin is a derivative of p-aminophenol and
as shown in figure. used as analgesic (pain killer). The main limitation
of this drug is that it may act on red blood cells
5′ 3′ and thus may be harmful even in moderate dose.
O
—G ≡ C—
NH—C—CH3
—A = T—
—T = A—
—C ≡ G—
3′ OC2H5
5′
phenacetin
The double α-helix structure of DNA.
Mathematics
1. Given, f ( x ) = ( p − x n )1/ n , p > 0 1 n
An =
n 1/ n 0 1
Now, f [f ( x )] = f [( p − x ) ]
n 1/ n × n 1/ n We have, nA − (n − 1) I
= { p − (p − x ) }
n n  n − 1 0 
= ( x n )1/ n = x = −
0 n   0 n − 1
2
2. x ∈ R |log [(1.6)1 − x − (0.625)6(1 + x ) ] ∈ R} =
1 n
= An
0 1
1 − x2 6( 1 + x )
Now, (1.6) > (0.625)
2
An = nA − (n − 1) I is true
1− x 6( 1 + x )
⇒ (1.6) > (0.625)
4. Given,
1 − x2 −6 ( 1 + x )
 8  8
n
Cr − 1 = 330, n Cr = 462
=  > 
 5  5
and n
Cr + 1 = 462
2
∴ 1 − x > − 6 (1 + x ) n
Cr + 1
⇒ x 2 − 6x − 7 < 0 Now, n
=1
Cr
⇒ ( x − 7 )( x + 1) < 0 n!
⇒ x ∈ (−∞, − 1) ∪ (7, ∞ ) (r + 1) ! (n − r − 1) !
⇒ =1
Hence, n!
2
x ∈ R |log [(1.6)1 − x − (0.625)6(1 + x ) ]| ∈ R} r ! (n − r ) !
= (−∞, − 1) ∪ (7, ∞ ) r ! (n − r )(n − r − 1) !
⇒ =1
 1 1 (r + 1) r ! (n − r − 1) !
3. Given A= n−r
0 1 ⇒ = 1 ⇒ n − 2r = 1 …(i)
r +1
 1 1  1 1
Now, A2 =
0 1 0 1
n
Cr 462 77
Again, = =
1 + 0 1 + 1  1 2
n
Cr − 1 330 55
= =
0 + 0 0 + 1 0 1 n!
Similarly, r ! (n − r ) ! 77
⇒ =
1 3 n! 55
A3 =
0 1 (r − 1)! (n − r + 1) !
(r − 1) ! (n − r + 1)(n − r ) ! 77 The general term is

⇒ =
r (r − 1) ! (n − r ) ! 55 Tr + 1 = 10Cr ( x1/ 3 )10 − r (− x −1/ 2 )r
⇒ 55 n − 132 r + 55 = 0 …(ii) 10 − r r
−
From Eqs. (i) and (ii), we get = 10Cr (−1)r ⋅ x 3 2
22 r = 110 For the term independent of x, put

∴ r =5 10 − r r
− =0
5. M M M M M M M M M M 3 2
W W W W W W W W W W W ⇒ 20 − 2 r − 3 r = 0
First, we arrange 10 men in a row at alternate ⇒ 20 = 5 r ⇒ r = 4
position. 10 × 9 × 8 × 7
∴ T5 = 10C4 = = 210
So, number of ways formula = 10 ! 4× 3×2 ×1
Now, 6 women can arrange in 11 positions 8. Given expression is
So, number of ways for women = 11P6 (1 − 2 x )−1(1 − 3 x )−2
E=
Required number of ways = 10 ! × P6 11
(1 − 4 x )−3
10 ! 11 ! (1 + 2 x + 2 x 2 + ... )(1 + 6 x + ... )
= =
5! (1 + 12 x + ... )
6. t n = The number of triangles formed with n points (1 + 2 x + 6 x + ... )
=
in a plane, no three of which are collinear. (1 + 12 x )
i.e., t n = nC3 = (1 + 8 x )(1 + 12 x )−1
n+1
⇒ tn + 1 = C3 (neglect higher powers)
Now, t n + 1 − t n = 36 = (1 + 8 x )(1 − 12 x ... )
n+1
⇒ C3 − nC3 = 36 = (1 + 8 x − 12 x ... )
(n + 1) ! n! = (1 − 4x )
⇒ − = 36
(n − 2 ) ! 3 ! (n − 3) ! 3 ! (Q neglecting the higher term)
(n + 1) n(n − 1) n(n − 1)(n − 2 ) 9. Given,
⇒ − = 36
6 6 1 Ax + B Cx + D
=− 2 +
⇒ n(n − 1)(n + 1 − n + 2 ) = 36 × 6 x4 + x2 + 1 x + x + 1 x2 − x + 1
⇒ 3n(n − 1) = 36 × 6 ⇒ 1 = ( Ax + B)( x 2 − x + 1) + (Cx + D )( x 2 + x + 1)
⇒ n 2 − n − 72 = 0
⇒ 1 = ( Ax 3 + Ax 2 + Ax + Bx 2 − Bx + B)
⇒ n 2 − 9 n + 8 n − 72 = 0
+ (Cx 3 + Cx 2 + Cx + Dx 2 + Dx + D )
⇒ n(n − 9) + 8 (n − 9) = 0
⇒ 1 = ( A + C )x 3 + (− A + B + C + D )x 2
⇒ (n − 9)(n + 8) = 0
∴ n=9 (Q n ≠ − 3) + ( A − B + C + D )x + (B + D )
10 On comparing, the coefficient of like powers on
 ( x + 1) ( x − 1) 
7.  2 / 3 − both sides, we get
( x − x1/ 3 + 1) ( x − x )
A+C=0 …(i)
10
 ( x1/ 3 )3 + 13 {( x )2 − 1}  −A + B + C + D = 0 …(ii)
=  2/ 3 −
( x − x1/ 3 + 1) x ( x − 1)  A−B+C+ D=0 …(iii)
10 and B + D =1 …(iv)
( x1/ 3 + 1)( x 2 / 3 − x1/ 3 + 1) {( x )2 − 1} 
= − On adding Eqs. (ii) and (iii), we get
 ( x 2 / 3 − x1/ 3 + 1) x ( x − 1) 
10
2(C + D ) = 0
 ( x + 1) ⇒ C+D=0
= ( x1/ 3 + 1) − = ( x1/ 3 − x −1/ 2 )10
 x 
1 1 1 1 ⇒ ( x − 2 ){ x 2 − 32 x − 8 x + 256} = 0
10. + + + +K∞
2 ⋅ 3 4⋅ 5 6⋅ 7 8⋅ 9 ⇒ ( x − 2 ){ x( x − 32 ) − 8 ( x − 32 )} = 0
1 1 1 1 1 1 1 1
=  −  +  −  +  −  +  −  +K∞ ⇒ ( x − 2 )( x − 32 )( x − 8) = 0
 2 3  4 5  6 7   8 9
⇒ ( x − 2 )( x − 8)( x − 32 ) = 0
= 1 − loge 2 ⇒ x = 2, 8, 32
= loge e − loge 2
Which represents a geometric progression in
= log  
e increasing order.
 2 8
Common ratio = = 4 : 1
11. Given equation is 2
(5 + 2 )x 2 − bx + (8 + 2 5 ) = 0 14. Given quadratic equation is
Let α and β be the roots of this equation. x2 − 2 x + 4 = 0
∴ α+β=
b whose roots are α and β.
5+ 2 ∴ α + β = 2 and αβ = 4 …(i)
8+ 2 3 Now,
and αβ =
5+ 2 α 9 + β 9 = (α 3 )3 + (β 3 )3
Given that harmonic mean between the roots of = (α 3 + β 3 )(α 6 + β 6 − α 3β 3 )
the given equation is 4. = (α + β )(α 2 − αβ + β 2 )[(α 2 )3 + (β 2 )3 − α 3β 3 ]
2αβ
∴ =4 = (α + β )[(α + β )2 − 3αβ ]
α+β
[(α 2 + β 2 )(α 4 + β 4 − α 2β 2 ) − α 3β 3 ]
8+ 2 5 5+ 2
⇒ × =2 = (α + β )[(α + β )2 − 3αβ ][{(α + β )2 − 2αβ}
5+ 2 b
{(α 2 + β 2 )2 − 3α 2β 2 } − α 3β 3 ]
8+ 2 5
∴ b= = (α + β )[(α + β ) − 3αβ ][{(α + β )2 − 2αβ}
2
2
= 4+ 5 [{(α + β )2 − (2αβ )]2 − 3α 2β 2 } − α 3β 3 ]
= 2[4 − 12 ][{ 4 − 8}{(4 − 8)2 − 48} − 64]
12. Given, x 2 + 5 x + 6 ≥ 0 and x 2 + 3 x − 4 < 0
[from Eq. (i)]
⇒ x 2 + 2 x + 3x + 6 ≥ 0
= 2(−8) {(−4)(−32 )(−64)}
and x 2 + 4x − x − 4 < 0
= 2(−8)(128 − 64)
⇒ x( x + 2 ) + 3 ( x + 2 ) ≥ 0 = 2(−8)(64) = − 210
and x( x + 4) − 1 ( x + 4) < 0
−8 5
⇒ ( x + 2 )( x + 3) ≥ 0 15. Given, A = 
 2 4
and ( x + 4)( x − 1) < 0 −8 5 −8 5
A2 = 
+ – + + – +  2 4  2 4
–∞ –3 –2 +∞ –∞ –4 1 +∞ 64 + 10 −40 + 20 
=
⇒ x ∈ (−∞, − 3] ∪ [−2, ∞ ) and x ∈ (−4, 1) −16 + 8 10 + 16
74 −20 
Common condition is =
x ∈ (−4, − 3] ∪ [−2, 1)  −8 26
−32 20 
13. Given, cubic equation is 4A = 
x 3 − 42 x 2 + 336 x − 512 = 0  8 16
−p 0 
⇒ x 2 ( x − 2 ) − 40 x( x − 2 ) + 256 ( x − 2 ) = 0 − pI = 
 0 − p
⇒ ( x − 2 )( x 2 − 40 x + 256) = 0
Since, the matrix A satisfies the equation C13  ′  2 −6 6 ′

C11 C12
x 2 + 4 x − p = 0, then adj A = C21 C22 C23  = −6 18 −18
A2 + 4 A − pI = 0 C31 C32 C33   2 −6 6
74 −20  −32 20  − p 0   2 − 6 2 
⇒  + + =  −6 18 −6
 −8 26  8 16  0 − p
 6 −18 6
0 0
=  2 − 6 2   6
0 0
So, (adj A) B = −6 18 −6 14
74 − 32 − p −20 + 20 + 0  0 0 
⇒  =  6 −18 6  a
 −8 + 8 + 0 26 + 16 − p  0 0 
 12 − 84 + 2 a   −72 + 2 a
42 − p 0  0 0 
⇒  = = −36 + 252 − 6 a =  216 − 6 a
 0 42 − p 0 0   36 − 252 + 6 a  −216 + 6 a
On comparing, we get 3 2 1
42 − p = 0 ⇒ p = 42 and | A| = 3 4 3
x+2 x+3 x+5 6 10 8
16. Let ∆ = x + 4 x + 6 x + 9 = 3 (32 − 30 ) − 2 (24 − 18) + 1 (30 − 24)
x + 8 x + 11 x + 15
= 3 (2 ) − 2 (6) + 6 = 6 − 12 + 6 = 0
Apply operations R2 → R2 − R1, R3 → R3 − R1, we We know that, if | A| = 0 and (adj A)⋅ B = 0, then
get the system of equations is consistent and has an
x+2 x+3 x+5 infinite number of solutions.
∆= 2 3 4 (adj A)⋅ B = 0
6 8 10
 72 + 2 a 0 
−
Again, apply operation C2 → C2 − C1, ⇒  216 + 6 a = 0 
C3 → C3 − C1, we get −216 + 6 a 0 
x+2 1 3 On comparing, we get
∆= 2 1 2
6 2 4 2 a − 72 = 0
∴ a = 36
Expand along R1, we get
18. Given,
∆ = ( x + 2 )(4 − 4) − 1 (8 − 12 ) + 3 (4 − 6)
t x + ( t + 1 )y + ( t − 1)z = 0
= 0 + 4 + 3 (−2 ) = 4 − 6 = − 2
( t + 1) x + ty + ( t + 2 ) z = 0
17. Given system of equation is
3x + 2 y + z = 6 ( t − 1) x + ( t + 2 ) y + t z = 0
3 x + 4 y + 3 z = 14 Here,
 t t +1 t − 1
6 x + 10 y + 8 z = a
Coefficient matrix, A = t + 1 t t + 2
3 2 1  6 t − 1 t +2 t 
Here, A = 3 4 3 , B = 14
6 10 8  a If| A| = 0, then system of equations has non-trivial
solution and it has infinite solutions.
C11 = (32 − 30 ) = 2, C12 = − (24 − 18) = − 6,
C13 = (30 − 24) = 6 t t + 1 t −1
| A| = t + 1 t t +2 =0
C21 = − (16 − 10 ) = − 6, C22 = (24 − 6) = 18, t −1 t + 2 t
C23 = − (30 − 12 ) = − 18
C31 = (6 − 4) = 2,C32 = − (9 − 3) = − 6, Apply operation R2 → R2 − R1,R3 → R3 − R1,we get
C33 = (12 − 6) = 6 t t + 1 t −1
= 1 −1 3 =0
−1 1 1
Apply C2 → C2 − C1,C3 → C3 − C1, we get (1 + i )x − i (1 + 2 i )y + i

21. + =1
t 1 −1 2+i 2−i
1 −2 2 =0 [(1 + i )x − i ](2 − i ) [(1 + 2 i )y + i ](2 + i )
⇒ + =1
−1 2 2 (4 − i 2 ) (4 − i 2 )
Expanding along R1, we get 2(1 + i )x − 2 i − i (1 + i )x + i 2
⇒
t (−4 − 4) − 1(2 + 2 ) − 1(2 − 2 ) = 0 4+ 1
⇒ −8 t − 4 = 0 2(1 + 2 i )y + 2 i + i (1 + 2 i )y + i 2
+ =1
−1 (4 + 1)
∴ t =
2 (2 + 2 i − i − i 2 )x − 2 i + i 2
⇒
So, no option is correct. 5
1+ i
4
1− i
4 (4i + 2 + i + 2 i 2 )y + 2 i + i 2
+ =1
19.   +  5
 1 − i  1+ i
(2 + i + 1)x − 2 i − 1 (5 i + 2 − 2 )y + 2 i − 1
4 4 ⇒ + =1
(1 + i )(1 + i )  (1 − i )(1 − i )  5 5
=  + 
 (1 − i )(1 + i )  (1 + i )(1 − i ) ⇒ (3 + i )x − 2 i − 1 + (5 i )y + 2 i − 1 = 5
4 4
(1 + i )2  (1 − i )2  ⇒ (3 + i )x + 5 iy = 7
= 2 
+ 2  ⇒ 3 x + ix + 5 iy − 7 = 0
 1− i   1− i 
4 4 ⇒ (3 x − 7 ) + ( x + 5 y ) i = 0 + i 0
1 + i 2 + 2 i  1 + i 2 − 2 i 
=  +  On comparing, we get
 1+ 1   1+ 1  3x − 7 = 0
4 4
1 − 1 + 2i  1 − 1 − 2 i  7
=   +  ⇒ x= and x + 5 y = 0
 2   2  3
= (i )4 + (− i )4 −7
⇒ y=
15
= i 4 + i 4 = 2 i 4 = 2(1) = 2
7 −7
20. Given, | z 2 − 1| = | z |2 + 1 Hence, ( x, y ) =  , 
 3 15 
Let z = x + iy
22. Given, f ( x ) = cos   + sin  
x x
⇒ |( x + iy ) − 1| = | x + iy |2 + 1
2
 3  2
⇒ | x 2 − y 2 + 2 ixy − 1| = ( x 2 + y 2 ) + 1 Period of cos x and sin x are 2π.
⇒ |( x 2 − y 2 − 1) + 2 ixy | = ( x 2 + y 2 + 1) ∴ Period of f ( x ) = Period of cos + sin 
x x
 3 2 
⇒ ( x 2 − y 2 − 1)2 + 4 x 2 y 2 = x 2 + y 2 + 1
x x
= Period of cos + Period of sin
⇒ ( x 2 − y 2 )2 + 1 − 2( x 2 − y 2 ) + 4 x 2 y 2 3 2
2π 2π 6π 4π
= ( x 2 + y 2 + 1)2 = + = +
1
  1
  1 1
= x4 + y4 + 2 x2 y2 + 1 + 2 x2 + 2 y2  3  2
⇒ −2 x 2 y 2 − 2 x 2 + 4 x 2 y 2 = 2 x 2 y 2 + 2 x 2 LCM of (6π , 4π ) 12 π
= = = 12π
⇒ −2 x 2 = 2 x 2 LCM of (1, 1) 1
⇒ 4x 2 = 0 ⇒ x=0 23. Given, sin θ + cos θ = p …(i)

3 3
∴ z = x + iy = 0 + iy and sin θ + cos θ = q …(ii)
⇒ z = iy ⇒ ( x, y ) = (0, y ) ⇒ (sin θ + cos θ )
Hence, z lies on the imaginary axis. (sin 2 θ − sin θ ⋅ cos θ + cos 2 θ ) = q
⇒ p(1 − sin θ ⋅ cos θ ) = q Now, we have

[From Eq. (i) and sin 2 θ + cos 2 θ = 1] x − y
cos ( x − y ) = 2 cos 2   −1
q  2 
⇒ 1 − sin θ ⋅ cos θ =
p 9 9 7
= 2 × − 1= − 1= [from Eq. (ii)]
q 4 2 2
⇒ sin θ ⋅ cos θ = 1 − …(iii)
p 2 x − y
and cos ( x − y ) = 1 − 2 sin  
 2 
On squaring both sides of Eq. (i), we get
x − y
sin 2 θ + cos 2 θ + 2 sin θ ⋅ cos θ = p2 ⇒ sin   <0
 2 
1 + 2 1 −  = p2
q
⇒ [from Eq. (iii)] So, system of equation have empty set of
 p
3
solution.
⇒ p + 2 (p − q) = p
5 3
⇒ 3 p − 2q = p3 26. cos −1   + cos −1   = cos −1 x
 13  5
⇒ p3 − 3 p = − 2q 5 3 25 9
= cos −1  ⋅ − 1 − ⋅ 1 −  = cos −1 x
⇒ p( p2 − 3) = − 2q
13 5 169 25 
24. Given, tan (π cos θ ) = cot (π sin θ ) 3 12 4 
⇒ cos −1  − ⋅ = cos −1 x
π 13 13 5 
⇒ tan (π cos θ ) = tan  − π sin θ 
2  15 − 48 
π ⇒ cos −1  = cos −1 x
⇒ π cos θ = − π sin θ  65 
2 −33
1 ∴ x=
⇒ sin θ + cos θ = 65
2
1
⇒
1
sin θ +
1
cos θ =
1 27. tanh −1   + coth −1 (2 )
 2
2 2 2 2
π π 1 1 1
⇒ cos θ ⋅ cos + sin θ ⋅ sin = ⇒ tanh −1   + tanh −1  
4 4 2 2  2  2
π 1 [coth −1 x = tanh −1 (1/ x )]
⇒ cos θ −  =
 4  2 2 1
⇒ 2 tanh −1  
25. Given system of equation is  2
2π
x+ y= …(i)  1 + 1
3 1  2  tanh −1 x = 1 log  1 + x  
⇒ 2 ⋅ log   
and cos x + cos y =
3
, where x, y are real. 2 1  2  1 − x  
1−  
2  2
x + y x − y 3
⇒ 2 cos   ⋅ cos   =  3
 2   2  2  
= log  2  = log 3
1 2π x − y 3 1
⇒ cos  ⋅  ⋅ cos   =  
2 3   2  4  2
[from Eq. (i)] 28. In ∆ABC,
 π  x − y 3 r1r2 + r2 r3 + r3 r1
⇒ cos   ⋅ cos   =
 3  2  4
∆ ∆ ∆ ∆ ∆ ∆
1 x − y 3 = ⋅ + ⋅ + ⋅
⇒ cos   = s − a s − b s − b s −c s −c s − a
2  2  4
∆2
x − y 3 = [s − c + s − a + s − b]
⇒ cos   = …(ii) (s − a)(s − b)(s − c )
 2  2
∆2 3 s − (a + b + c ) ⇒ h=x 3 …(i)
= (Q 2s = a + b + c )
(s − a)(s − b)(s − c ) In ∆BAC,
∆2 (3 s − 2 s) ∆2 ⋅ s BC 2 = AB 2 + AC 2
= = 2
(s − a)(s − b)(s − c )  ∆  ⇒ BC = x 2 + (60 )2
 
 s = x 2 + 3600
2
 ∆  h
Q s = (s − a)(s − b)(s − c ) In ∆CBD, tan 45° =
  3600 + x 2
s2 ⋅ ∆2 ∆2 ∆2 Q r = ∆  ⇒ h = 3600 + x 2
= = = 2
∆ 2
 ∆ 
2
r  s 
⇒ h 2 − x 2 = 3600 …(ii)
 s
From Eqs. (i) and (ii), we get
29. In ∆ABC, 3 x 2 − x 2 = 3600
1 1 3 ⇒ 2 x 2 = 3600 ⇒ x 2 = 1800
+ =
a+c b+c a+ b+c From Eqs. (i) and (ii), we get
Let ∠ C = 60 °, then h 2 − 1800 = 3600
π ⇒ h 2 = 5400
cos C =
3 ⇒ h = 30 6 = 30 2 ⋅ 3
2 2 2
⇒ a + b − c = ab 2⋅ 3 3
2 2 2
= 30 × = 60
⇒ b + bc + a + ac = ab + ac + bc + c 2 2
⇒ b(b + c ) + a(a + c ) = (a + c )(b + c ) 31. Let a = 2 i + 3 j + 4 k = OA
Divide by (a + c )(b + c ) and add 2 on both sides, b = 3 i + 4 j + 2 k = OB
we get and c = 4 i + 2 j + 3 k = OC
b a
1+ + 1+ =3 AB = OB − OA = i + j − 2 k
a+c b+c
BC = OC − OB = i − 2 j + k
1 1 3
⇒ + = and CA = OA − OC = − 2 i + j + k
a+c b+c a+ b+c
Now, AB = 1 + 1 + 4 = 6
So, ∠ C should be 60°.
BC = 1 + 4 + 1 = 6
30. In ∆ABD,
and CA = 4 + 1 + 1 = 6
D
Since, the length of all three sides are equal.
So, the triangle is an equilateral triangle.
32. Let the coordinates of four points P, Q, R and S be
(3, − 4, 5), (0, 0, 4), (−4, 5, 1) and (−3, 4, 3)
respectively.
C h
45° Now, equation of line PQ is
x−3 y+4 z−5
√3
= =
6 00
60 m 0 − 3 0 + 4 4− 5
+
x
2
90° x−3 y+4 z−5

60° 90° ⇒ = = = r1 (say) …(i)
−3 4 −1
A B
x Equation of line RS is
h x+4 y − 5 z −1
tan 60 ° = = 3 = =
x −3 + 4 4 − 5 3 − 1
x + 4 y − 5 z −1 Given, [r, a b ] = 0, i.e., coplanar.

⇒ = = = r2 (say) …(ii)
1 −1 2 x y z
Let (−3 r1 + 3, 4r1 − 4, − r1 + 5) and (r2 − 4, − r2 + 5, ⇒ 1 1 3 =0
2 r2 + 1) be the points on line (i) and (ii), 1 3 1
respectively. Since, both lines intersect at a ⇒ x(1 − 9) − y(1 − 3) + z(3 − 1) = 0
common point, then
⇒ −8 x + 2 y + 2 x = 0
−3 r1 + 3 = r2 − 4
⇒ −4 x + y + z = 0 …(i)
⇒ 3 r1 + r2 = 7 …(iii)
and r ⋅ c = 0, i.e., perpendicular
and − r2 + 5 = 4 r1 − 4
⇒ ( x i + y j + z k )⋅ ( i + j + k ) = 0
⇒ 4r1 + r2 = 9 …(iv)
⇒ x+ y+ z=0 …(ii)
On subtracting Eq. (iv) from Eq. (iii), we get
On solving Eqs. (i) and (ii), we get
r1 = 2
5y + 5z = 0
On putting the value of r1 in Eq. (iii), we get
⇒ y=−z …(iii)
3 (2 ) + r2 = 7 ⇒ r2 = 1
Q r is a unit vector.
So, required point of intersection is (−3, 4, 3)
∴ | r| = 1 = x 2 + y2 + z2
i.e., − 3i + 4 j + 3k
33. Given, ⇒ x 2 + y2 + z2 = 1
a ≠ 0,b ≠ 0,c ≠ 0 and a × b = 0,b × c = 0 ⇒ x 2 + 2 y 2 = 1 [from Eq. (iii)] …(iv)
a × b = 0 ⇒ Vector a and b are parallel. Put y = − z in Eq. (i), we get
⇒ a and c are also parallel. −4 x = 0 ⇒ x = 0
⇒ a ×c =0 From Eq. (iv), we get
34. The given lines are r = a1 + λb1, r = a 2 + µb 2 1
2 y2 = 1 ⇒ y = ±
where, 2
a 1 = 3 i + 5 j + 7 k,b1 = i + 2 j + k Required vector is
a 2 = − i − j − k,b 2 = 7 i − 6 j + k r = xi + y j + zk
i j k 1 1
= 0i + j± k
| b1 × b 2 | = 1 2 1 2 2
7 −6 1 j−k −j+ k
= or
⇒ | i (2 + 6) − j (1 − 7 ) + k (−6 − 14)| 2 2
⇒ | 8 i + 6 j − 20 k | 36. Since, a, b and a × b are non-coplanar, hence
⇒ 64 + 36 + 400 = 500 = 10 5 y = a x + tb x + (a × b ) z
Now, [(a 2 − a 1 )b1b 2 ] = (a 2 − a 1 )⋅ (b1 × b 2 ) For some scalars x, t and z,
= (−4 i − 6 j − 8 k )⋅ (8 i + 6 j − 20 k ) Now,
= − 32 − 36 + 160 b =a × y
= 160 − 68 = 92 ⇒ b = (a × a ) x + (a × b ) t + a × (a × b ) z
Shortest distance = 0 x + (a × b ) t + [(a ⋅ b )a − (a ⋅ a )b ] z
[(a 2 − a 1 )⋅ (b1 × b 2 )]
= [Q a × a = 0, a ⋅ b = 0 ]
| b1 × b 2 |
⇒ b = (a × b ) t − (a ⋅ a ) b ⋅ z
92 46 −1
= = ⇒ t = 0 and z =
10 5 5 5 | a |2
35. Let the unit vector be Also, c = a ⋅ y = a ⋅ a x + a ⋅ b t + a ⋅ (a × b ) z
r = xi + y j + zk = | a |2 x + 0 t + 0 z
and a = i + j + 3 k,b = i + 3 j + k
=| a |2 x [Q a ⋅ b = 0, (a a b ) = 0 ]
and c = i + j + k
c ∞
⇒ x= 40. var ( X ) = Σ Pi( Xi − X )2
| a |2 i=2
∴ y = a x + bt + (a × b )z 1 + 2 + K + m m(m + 1) m + 1
X= = =
m 2⋅m 2
ac  −1 
y= + b 0 + (a × b )  2  var ( X ) = { P( X = 1) + P( X = 2 ) + K + P( X = m)}
| a |2 | a |  2 2
1 m + 1 1  m + 1 1
⇒ y=
1
[ac − (a × b )] =  1 −  + 2 −  +K+
m  2  m  2  m
| a |2
2
37. Case I When smaller of the two numbers is 1.  m − m + 1 

Then, total number of cases  2  
= 1 × 7C1 = 7
1  2 (m + 1)2 m + 1 
Case II When smaller of two numbers is 2. =  1 + − 2 ⋅ 1  
m  4  2 
Then, total number of cases
= 1 × 6C1 = 6  (m + 1)2 m + 1
+ 2 2 + − 2 ⋅2  +K
 4 2 
Case III When smaller of two numbers is 3.
Then, total number of cases  (m + 1)2 (m + 1) 
+  m2 + − m⋅2 
= 1 × 5C1 = 5  4 2 
Total favourable cases = 7 + 6 + 5 = 18
1  2 2 2 (m + 1)2
Total case = 8C2 = 28 = (1 + 2 + K + m ) + (1 + 1 + K
m 4
18 9
∴ Required probability = =
28 14 + m times) − (m + 1)(1 + 2 + 3 + K + m)

38. Total samle points, n(S ) = 6 × 6 = 36
1  m(m + 1)(2 m + 1) m(m + 1)2
Favourable events =  +
m 6 4
= [(6, 4), (6, 5), (6, 6), (5, 5), (5, 6), (4, 6)]
(m + 1)(m + 1) m 
Total favourable events, n(E ) = 6 − 
2 
Required probability
n(E ) 6 1 1
= = = = (m + 1)[2(2 m + 1) + 3 (m + 1) − 6 m + 1]
n(S ) 36 6 12
1
39. The probability that the toss results is a tail = (m + 1)(4 m + 2 + 3 m + 3 − 6 m − 6)
12
(n + 1)
= 1 1
2(2 n + 1) = (m + 1)(m − 1) = (m2 − 1)
12 12
(n + 1)
∴ 1− is the probability that the toss 41. In poission distribution
2(2 n + 1)
λ xe − λ
result is a head. P( X = x ) = …(i)
n+1 31 x!
∴ 1− =
2(2 n + 1) 42 λe − λ
P( X = 1) = = λe − λ
4 n + 2 − n − 1 31 1!
⇒ =
4n + 2 42 λ2e − λ λ2e − λ
P( X = 2 ) = =
3 n + 1 31 2! 2
⇒ =
4 n + 2 42 P( X = 1) = 2 P( x = 2 )
⇒ 126 n + 42 = 124 n + 62 λ2 e − λ
⇒ λe − λ = 2 ×
⇒ 2 n = 20 2
⇒ n = 10 ⇒ λ (λ − 1) = 0
λ≠0 2x + 3 y = 5
∴ λ =1
1, 1 l1
(1)3 e −1 e −1 3
Hence, P( X = 3) = = (Q λ = 1) A
P
B
3! 6
42. Under the translation of origin to (1, 2 ) the point
(7, 5) undergoes to (7 − 1, 5 − 2 ) ≡ (6, 3)
Equation of line AB is
Under the translation through 2 units along the
 y − 1 = 3 ( x − 1)
negative direction of the new x-axis, the point (6, 3)
 3 2
undergoes to (6 − 2, 3) ≡ (4, 3)
π 7
Under the rotation throw an angle about the ⇒ 3x − 2 y = …(i)
4 3
origin of new system in the clockwise direction, Equation of line l1 is
the final position of point (7, 5) 2 x + 3y = 5 …(ii)
π π π π
=  4 cos + 3 sin , − 4 sin + 3 cos  From Eqs. (i) and (ii), we get
 4 4 4 4 13 x = 17
4 3 4 3  7 1 17
=  + ,− +  = ,−  ⇒ x=
 2 2 2 2   2 2 13
43. Given equations of straight lines are From Eq. (i), we get
34 65 − 34 31
x sec θ − y cosec θ = a …(i) 3y = 5 − ⇒ y= =
13 13 × 3 39
x cos θ + y sin θ = a cos 2θ …(ii)
17 31
Also, So, mid-point P →  , 
 13 39
p = Perpendicular distance from the origin to the
line (i) Coordinate of point B
| 0 − 0 − a| a sin θ ⋅ cos θ 17 31 1
P= = =  × 2 − 1, × 2 − 
sec 2 θ + cosec 2 θ 1  13 39 3
34 − 13 62 − 13  21 49
a
= a sin θ ⋅ cos θ = sin 2θ =  ,  = , 
2  13 39   13 39
⇒ 2 p = a sin 2θ 45. Since, the points (1, 2) and (3, 4) lie on the same
and q = perpendicular distance from the origin to side of the line 3 x − 5 y + a = 0
the line (ii) ∴ 3 (1) − 5 (2 ) + a ≥ 0 or ≤ 0
| 0 + 0 − a cos 2θ | a cos 2θ ⇒ a − 7 ≥ 0 or ≤ 0
q= = = a cos 2θ
cos 2 θ + sin 2 θ 1 ⇒ a ≥ 7 or a ≤ 7
Now, and 3 (3) − 5 (4) + a ≥ 0 or ≤ 0
4 p2 + q 2 = a2 sin 2 2θ + a2 cos 2 2θ ⇒ a − 11 ≥ 0 or ≤ 0
⇒ a ≥ 11 or a ≤ 11
= a2 (sin 2 2θ + cos 2 2θ )
So, common condition is [7, 11].
= a2 (1) = a2
46. Let m1 and m2 be the slopes of lines.
44. Let l1 ≡ 2 x + 3 y = 5 …(i) 13
Then, m1 + m2 = arithmetic mean = …(i)
Since, line AB ⊥ l1 2
∴ Slope of l1 is and m1m2 = geometric mean = 36 = 6 …(ii)
−2
m1 say = Now, equation of the pair of lines passing through
3 the origin is
−1 3 ( y − m1 x ) ( y − m2 x ) = 0
∴ Slope of AB = =
(−2 / 3) 2
⇒ y 2 − (m1 + m2 ) xy + m1m2 x 2 = 0 f 2 − bc g 2 − ac
= +
Using Eq. (i) and (ii), we get h 2 − ab h 2 − ab
13 f 2 + g 2 − c ( a + b)
y2 − xy + 6 x 2 = 0 =
2 h 2 − ab
⇒ 12 x 2 − 13 xy + 2 y 2 = 0
c ( a + b) − f 2 − g 2
=
47. Comparing the given equation ab − h 2
x 2 − 5 xy + py 2 + 3 x − 8 y + 2 = 0 …(i)
49. Given circle is
2 2
with ax + 2 hxy + by + 2 gx + 2 fy + c = 0 …(ii) 4 x 2 + 4 y 2 − 12 x − 12 y + 9 = 0
we get 9
−5 3 ⇒ x 2 + y 2 − 3x − 3y + = 0
a = 1, h = , b = p, g = , f = − 4 and c = 2 4
2 2 9
⇒ ( x 2 − 3x ) + ( y 2 − 3y) = −
Eq. (i) represents a pair of straight lines, if 4
abc + 2 fgh − af 2 − bg 2 − ch 2 = 0 y
3, 3
3 −5
⇒ 1 × p × 2 + 2 × (−4) × ×   − 1 × (−4)2
2 2
2 2
2 2 3/2
3 −5
− p ×   − 2 ×   = 0
x′ x
O
 2 2 3/2
⇒ p=6 ∴ p=6
∴ Required angle, y′
2
−5
2   − 1 × 6
2 2
3 3 9
2 h 2 − ab 2 ⇒  x −  +  y −  =
tan θ = =  2  2 4
a+ b 1+ 6 2 2 2
⇒  x − 3 +  y − 3 =  3
A  2  2  2
3 3 3
√50
Hence, centre =  ,  and radius =
1
 2 2 2
So, the given circle touches both the axes.
θ 50. Given equation of circle is
B C
7
C = x 2 + y 2 − 16 x − 12 y + 64 = 0 …(i)
1 1 (i) Equation of polar at (−5, 1) w.r.t. to C is
⇒ tan θ = ⇒ θ = tan −1
7 7
x(−5) + y(1) − 8 ( x − 5) − 6 ( y + 1) + 64 = 0
1
∴ sin θ = ⇒ −5 x + y − 8 x + 40 − 6 y − 6 + 64 = 0
50
⇒ −13 x − 5 y + 98 = 0
48. We know that the point of intersection of the pair ⇒ 13 x + 5 y = 98
of straight line is
(ii) On differentiating Eq. (i) w.r.t. to x, we get
 f 2 − bc g 2 − ac  dy dy
 
 h 2 − ab , h 2 − ab  2x + 2y − 16 − 12 +0=0
  dx dx
dy
Required distance ⇒ (2 y − 12 ) = (16 − 2 x )
2 dx
 2 2
dy  8 − x 
 f 2 − bc   g 2 − ac 
=    
 h 2 − ab − 0 +  h 2 − ab − 0 
 ⇒ = 
 dx  y − 6
   
 
 dy  8− 8 Therefore, putting x = 0 in Eq. (i), we get

At (8, 0 ) = =0
 dx  ( 8, 0 ) 0 − 6 R 2 = r 2 − a2 + b2 − 0 + 0
∴ Equation of tangent at (8, 0 ) is ( y − 0 ) = 0( x − 8) ⇒ R = (r 2 + b2 − a2 )1/ 2
⇒ y=0
53. The common chord of the given circle is
(iii) Slope of normal is
S1 − S 2 = 0
dy 6 − y
= 2 2
⇒ ( x + y + 4x − 6y + c )
dx 8 − x
6− 6 − ( x 2 + y 2 − 6 x + 4 y − 12 ) = 0
 dy  = =0
 dx  ( 2, 6 ) 8 − 2 ⇒ 10 x − 10 y + c + 12 = 0 …(i)
2 2
Since, circle x + y + 4 x + 6 y + c = 0 bisects
Equation of normal is
the circumference of the circle.
( y − 6) = 0( x − 2 )
x 2 + y 2 − 6 x + 4 y − 12 = 0
⇒ y=6
(iv) Equation of the diameter of circle through Therefore, Eq. (i) passes through the centre of
(8, 12 ) is second circle i.e., (3, − 2 )
x=8 ∴ 10(3) − 10(−2 ) + c + 12 = 0
51. Given equations of circle is ⇒ 30 + 20 + c + 12 = 0
x 2 + y 2 = 16 ⇒ c = − 62
and x2 + y2 + 2 x + 2 y = 0 54. Given, equation of parabola is

y 2 = 8x …(i)
According to the questions,
Length of the tangent from (h, k ) to the circle ∴ a=2
x 2 + y 2 = 16 Let (h, 4) be the coordinate of mid-point of chord.
Then, equation of chord is
= 2 × Length of the tangent from (h, k ) to the
circle x 2 + y 2 + 2 x + 2 y = 0 y − 4 = m( x − h ) …(ii)
If line (ii) passes through the point P(2 t12 , 4 t1 ) and
⇒ h 2 + k 2 − 16 = 2 × h 2 + k 2 + 2 h + 2 k Q(2 t 22 , 4 t 2 ) on parabola Eq. (i), then
On squaring both sides, we get y(t1 + t 2 ) − 2 x − 4 t1t 2 = 0 …(iii)
h 2 + k 2 − 16 = 4 × (h 2 + k 2 + 2 h + 2 k ) having slope
2
⇒ 3 h 2 + 3 k 2 + 8 h + 8 k + 16 = 0 m= …(iv)
t1 + t 2
52. Let the equation of circle whose centre (a, 0 ) and Since, (h, 4) is the mid-point of PQ. Therefore,
radius (r ) is 2 × 4 = 4 (t1 + t 2 )
( x − a)2 + ( y − 0 )2 = r 2 ⇒ t1 + t 2 = 2
⇒ S1 ≡ x 2 + a2 − 2 ax + y 2 − r 2 = 0 Hence, slope of chord PQ is
2
and the equation of circle whose centre (b, 0 ) and m= =1 [using Eq. (iv)]
radius R is 2
( x − b)2 + ( y − 0 )2 = R 2 55. Equation of chord at (2, − 4) is
⇒ S 2 ≡ x 2 + b2 − 2 bx + y 2 − R 2 = 0 T = S′
∴ Equation of radical axis is ⇒ 2 x + 4 y (−4) − ( x + 2 ) + 10( y − 4)
S1 − S 2 = 0 = (2 )2 + 4 (−4)2 + 2(2 ) + 20(−4)
⇒ a2 − b2 + 2 bx − 2 ax + R 2 − r 2 = 0 ⇒ 2 x − 16 y − x − 2 + 10 y − 40
⇒ R 2 = r 2 − a2 + b2 − 2 bx + 2 ax …(i) = 4 + 64 − 4 − 80
Since, radical axis is y-axis. ⇒ x − 6 y = 42 − 16 ⇒ 26
56. Given, equation of ellipse is ∴ Equation of tangent at (9, 6 2 ) is

x2 y2 3
+ =1 (y − 6 2 ) = ( x − 9)
25 16 2 2
and equation of hyperbola is ⇒ 2 2 y − 24 = 3 x − 27
x2 y2
− 2 =1 ⇒ 3x − 2 2 y − 3 = 0
4 b
and equation of tangent at (9, − 6 2 ) is
eccentricity of ellipse
−3
b2 = a2 (1 − e 2 ) (y + 6 2 ) = ( x − 9)
2 2
⇒ 16 = 25 (1 − e 2 )
⇒ 2 2 y + 24 = − 3 x + 27
2 16 9
⇒ e = 1− = ⇒ 3x + 2 2 y − 3 = 0
25 25
3 π
⇒ e =± 58. Given points (1, π ), (1, 0° ) and 1,  are in polar
5  2
Focii of the ellipse = (± ae , 0 ) = (± 3, 0 ) which form.
coincide with focii of the hyperbola. Now, change in cartesian form,
Let e1 be the eccentricity of the hyperbola. (1, π ) → (1⋅ cos π , 1 ⋅ sin π ) → (−1, 0 )
∴ ± ae1 = ± 3 (1, 0 ° ) → (1⋅ cos 0 ° , 1⋅ sin 0 ° ) → (1, 0 )
3
⇒ e1 = π π π
2 and 1,  → 1 ⋅ cos , 1 ⋅ sin  → (0, 1)
 2   2 2
Now, b2 = a2 (e12 − 1)
Now, equation of the line passing through (1, 0 )
9 5
⇒ b2 = 4  − 1 = 4 × and (0, 1) is
4  4
1− 0
⇒ b2 = 5 ( y − 0) = ( x − 1)
0 −1
57. Given that, x = 9 is a chord of contact of ⇒ y=−x+1
hyperbola. ⇒ x + y − 1= 0 …(i)
x2 − y2 = 9 …(i) So, the perpendicular distance from the point
put x = 9, 81 − y 2 = 9 (−1, 0 ) to the line (i) is
| − 1 + 0 − 1| 2
⇒ y 2 = 72 = = = 2
1+ 1 2
⇒ y=6 2 or −6 2
59. Let A ≡ ( x1, y1, z1 ), B ≡ ( x 2 , y 2 , z2 ) and
∴ Points are (9, 6 2 ) and (9, − 6 2 )
C ≡ ( x 3 , y 3 , z3 )
Now, differentiating Eq. (i) w.r.t. x, we get A (x1, y1, z1)
dy
2x − 2y =0
dx
dy x
⇒ = (0, 1, 0) F E (2, 0, 0)
dx y
 dy  9 3
at (9, 6 2 ) = =
 dx  ( 9, 6 2) 6 2 2 2 B C
(x2, y2, z2) D (x3, y3, z3)
3
and at (9 − 6 2 )  
dy (2, 1, 0)
=−
 dx  ( 9, − 6 2) 2 2
Since, F is the mid-point of AB. Let < a, b, c > be the direction ratio of the normal
∴ x1 + x2 = 0  to the plane ABC.

y1 + y2 = 2  …(i) Then, a− b−c = 0
z1 + z2 = 0  and 2a − b + c = 0
Since, D is the mid-point of BC. By cross-multiplication method,
∴ x2 + x3 = 4  a b c
 = =
y2 + y3 = 2  …(ii) −1 − 1 −2 − 1 −1 + 2
z2 + z3 = 0 
a b c
and E is the mid-point of AC = =
−2 −3 1
∴ x3 + x1 = 4 
 a b c
y3 + y1 = 0  …(iii) ⇒ = =
z3 + z1 = 0  2 3 −1
x1 + x2 + x3 = 4  So, the direction ratio of the normal to the plane
So, 
y1 + y2 + y3 = 2  …(iv) ABC is < 2, 3, − 1 >.
z1 + z2 + z3 = 0  61. A plane passing through the point (−1, 2, 3), then
∴ x3 = 4, y3 = 0, z3 = 0 its equation is
x1 = 0, y1 = 0, z1 = 0 a( x + 1) + b( y − 2 ) + c ( z − 3) = 0 …(i)
and x2 = 0, y2 = 2, z2 = 0 where < a, b, c > are direction ratios of normal to
the plane ABC.
∴ Centroid of ∆ABC
So, the normal makes equal angles with
x + x2 + x3 y1 + y2 + y3 z1 + z2 + z3 
=  1 , ,  coordinate axes
 3 3 3 
1 1 1
4 2 i.e., (a, b, c ) =  , , 
=  , , 0  3 3 3
3 3 
Now, from Eq. (i),
60. Direction ratios of AB and AC are < 1, − 1, − 1 > and 1 1 1
( x + 1) + ( y − 2) + ( z − 3) = 0
< 2, − 1, 1 >, respectively. 3 3 3
A (x1, y1, z1) ⇒ x + y + z − 4= 0
62. The foot of the propendicular from the origin to
the plane lies on a sphere.
(1, –1, –1) F E (2, –1, 1)
DR’s DR’s 63. Q f ( x + y ) = f ( x ) f ( y ), ∀ x, y ∈ R …(i)
Put x = y = 1, we get
DR’s
C
f (2 ) = f (1)⋅ f (1) = 9 [Q f (2 ) = 9]
B
(x2, y2, z2) D (x3, y3, z3) ⇒ f(1)2 = 9 ⇒ f(1) = 3
(–3, 2, 0)
Now, put x = 2 and y = 1in Eq. (i), we get
∴ x2 − x1 = 1 
 f (3) = f (2 )⋅ f (1) = 32 ⋅ 3 = 33
y2 − y1 = − 1 …(i)
z2 − z1 = − 1 Now, put x = 3 and y = 1in Eq. (i), we get
f (4) = f (3) ⋅ f (1) = 33 ⋅ 3 = 34
x1 − x3 = 2 

and y1 − y3 = − 1 …(ii) Again, put x = 4 and y = 2 in Eq. (i), we get
z1 − z3 = 1  f (6) = f (4)⋅ f (2 ) = 34 ⋅ 32 = 36
From Eqs. (i) and (ii), Alternative Method
x2 − x3 = 3 ⇒ x3 − x2 = − 3 We have,

y2 − y3 = − 2 ⇒ y3 − y2 = 2  …(iii) f ( x + y ) = f ( x ) f ( y ), ∀ x, y ∈ R
z2 − z3 = 0 ⇒ z3 − z2 = 0  and f(2 ) = 9 …(i)
Now, f (1 + 1) = f (1)⋅ f (1) 1

=  + 0 {(1 + 0 + ... )2 + (1 − 0 + ... )2
⇒ f (2 ) = { f (1)} 2 2 
⇒ { f (1)} = { f (2 )} …(ii) + (1 + 0 )(1 − 0 )}

1 3
Now, f (6) = f (1 + 1 + 1 + 1 + 1 + 1) = (1 + 1 + 1) =
2 2
= f (1) ⋅ f (1) ⋅ f (1) ⋅ f (1) ⋅ f (1) ⋅ f (1) 1 x
65. f( x) = =
= { f (1)} 6 [using Eq. (ii)] 1 1+ x
1+
= [ { f (2 )} ]6 = [f (2 )]3 x
1 1 x
= (9)3 [using Eq. (i)] and g( x ) = = =
1 1+ x 2x + 1
1+ 1+
= (3)6 f( x) x
tan 3 x − sin 3 x (2 x + 1)⋅ 1 − x(2 ) 1
64. lim ∴ g′ ( x ) = =
x→ 0 x5 (2 x + 1)2 (2 x + 1)2
 3
 1 1
x3 2 5  Now, g′ (2 ) = =
 x + + x + K   (4 + 1)2 25
 3 15  
  3 5

3 y x
x x 66. We have + =2
 − x − + + K  x y
  3! 5!  
= lim ⇒ y + x =2 x⋅ y
x→ 0 x5
3 On squaring both sides, we get
 x2 2 4  
1 + + x + K  x 2 + y 2 + 2 xy = 4 xy
 2 15  
⇒ x 2 + y 2 − 2 xy = 0
  x2 x4  
3
 − 1 − + + K  ⇒ ( x − y )2 = 0 ⇒ y = x
  3! 5!  
= lim dy
x→ 0 x2 ∴ =1
dx
2 2 4
 x 2 4   x x  d
 1 + + x + K − 1 − + + K  67. [( x + 1)( x 2 + 1)( x 4 + 1)( x 8 + 1)]
 3 15   3 ! 5 !  dx
 2 2
 (15 x p − 16 xq + 1)
x2   x2  = …(i)
 1 + + K + 1 − + K  ( x − 1)2
 3   3!  
 2 2
 d ( x 2 − 1)( x 2 + 1)( x 4 + 1)( x 8 + 1)
     LHS =
+ K 
x x

+ 1 + + K 1 − dx  ( x − 1) 

  3   3!  
= lim
x→ 0 x 2 d ( x 4 − 1)( x 4 + 1)( x 8 + 1)
=
[using (a − b ) = (a − b)(a2 + b2 + ab)]
3 3 dx  ( x − 1) 

 x2 
2
 x2
2
  d ( x 8 − 1)( x 8 + 1)
 1 + + K + 1 − + K  =
x 2 4
 3 3!   dx  ( x − 1) 

+ K    
x
 + 
2 8   x2   x2   d ( x16 − 1)
+ 1+ + K 1 − +K
   
=
= lim  3   3 dx  ( x − 1) 
x→ 0 2
x
( x − 1)(16 x15 ) − ( x16 − 1)
 2 2
 =
x2   x2
 ( x − 1)2
  1 + + K + 1 − + K 
 1 x2   3   3!  
= lim  +    16 x16 − 16 x15 − x16 + 1
x→ 0 2 8   x2   x2   =
 +  1 + 3 + K  1 − + K  ( x − 1)2
    3!  
15 x16 − 16 x15 + 1 70. Given curves are

=
( x − 1)2 x 2 + py 2 = 1 …(i)
2 2
On comparing LHS = RHS, we get and qx + y = 1 …(ii)
p = 16 and q = 15 On differentiating Eq. (i), w.r.t., x we get
∴ ( p, q ) = (16, 15) dy
2x + 2y p =0
68. cos −1   = 2 log   , x > 0
y x dx
 b  2 dy x
⇒ = m1 = −
On differentiating w.r.t. x we get dx py
1 1 dy 1 1 On differentiating Eq. (ii), w.r.t. to x, we get
− ⋅ =2⋅ ⋅
2 b dx  x 2 dy
1− 2
y   2qx + 2 y =0
b  2 dx
dy − qx
1 dy 2 ⇒ = m2 =
⇒ − ⋅ = dx y
2 2
b −y dx x
Since, both the curves are orthogonal to each
dy
⇒ x = − 2 b2 − y 2 …(i) other,
dx
Then, m1m2 = − 1
Again, differentiating w.r.t. x we get, − x − qx
⇒ ⋅ = −1
d 2 y dy 1 dy
x 2 + = − 2 ⋅ (b2 − y 2 )−1/ 2 (−2 y ) py y
dx dx 2 dx ⇒ qx 2 = − py 2 …(iii)
2
d y dy 2y dy 2 2
⇒ x 2 + = ⋅ ⇒ q(1 − py ) = − py [from Eq. (i)]
2 2 dx
dx dx b −y 2 2
⇒ q − pqy = − py
d 2 y dy 2y dy
⇒ x 2 + = ⋅ [from Eq. (i)] ⇒ q = ( pq − p) = y 2
dx dx − x ⋅ dy dx
q
2 dx ∴ y2 =
2 pq − p
2 d y dy
⇒ x + x = − 4y −p
dx 2 dx and x2 =
1/ 4
pq − p
69. Given, pV = a, where a is constant.
On putting x 2 and y 2 in Eq. (ii) we get
a
⇒ p = 1/ 4 pq q
V − + =1
pq − q pq − p
∴ Decreased volume
⇒ − pq + q = pq − p ⇒ p + q = 2 pq
V 1/ 4 199 1/ 4
= V 1/ 4 − = V 1 1
200 200 ⇒ + =2
p q
a 200 a
Increased pressure = = 2 1 1
199 1/ 4 199 V 1/ 4 71. Given, equation is = − …(i)
V f v u
200
∴ Percentage increase in pressure Differentiating the given equation, we have
2 1 1
200 a
−
a − 2 df = − 2 dv +  − 2  du
199 V 1/ 4 V 1/ 4 f v  u 
= × 100 1 1 1 1
= − p  −   +  Q = p
a dv du
=
V 1/ 4  v u  v u  v u 
200  − 2 p  1 1
=  − 1 × 100 =  +  [using Eq. (i)]
 199  f  v u
100 1 1 1
= p  + 
df
= ≈ (approximate) ∴
199 2 f  v u
72. Given, u = log ( x 3 + y 3 + z 3 − 3 xyz ) but given,

x − sin x x  x
ux =
du
= 3
3 x 2 − 3 yz ∫ 1 + cos x dx = x tan 2 + p log  sec 2  + C
dx ( x + y 3 + z 3 − 3 xyz )
On comparing, we get
du 3 y 2 − 3 xz
uy = = 3 p= −4
dy x + y 3 + z 3 − 3 xyz
dx
du 3 z 2 − 3 xy 75. Let I1 = ∫
and u z = = 3 x (log x − 2 )(log x − 3)
dz x + y 3 + z 3 − 3 xyz dx
Let t = log x ⇒ dt =
u x + uy + uz x
3 ( x 2 + y 2 + z 2 − xy − yz − zx ) ∴ I1 = ∫
dt
=
( x + y + z )( x 2 + y 2 + z 2 − xy − yz − zx ) (t − 2 )(t − 3)
⇒ ( x + y + z )(u x + u y + u z ) = 3  1 1 
=∫ − dt
 2 + sin 2 x  (t − 3) (t − 2 )
73. Let I = ∫ e x   dx
 1 + cos 2 x  = log|( t − 3)| − log|( t − 2 )| + C
 2 sin 2 x   log x − 3 

= ∫ex  +  dx = log  +C
1 + cos 2 x 1 + cos 2 x   log x − 2 
dx
 2 2 sin x cos x  ⇒ I1 = ∫
= ∫ex  2
+  dx x (log x − 2 ) (log x − 3)
2 cos x 2 cos 2 x 
 log x − 3 
= ∫ e x (sec 2 x + tan x ) dx = log  + C
 log x − 2 
= ∫ e x sec 2 x dx + ∫e
x
tan x dx dx
But given, ∫ =I+C
= e tan x − ∫ e tan x dx + x(log x − 2 )(log x − 3)
∫e
x x x
tan x dx
On comparing, we get
= e x tan x + C
 log x − 3 
x − sin x I = log  
74. Let I = ∫ dx  log x − 1 
1 + cos x
x sin x 76. We have,
=∫ dx − ∫ dx b dx ∞ dx
1 + cos x 1 + cos x ∫0 1 + x 2
=∫
b 1 + x2
2 sin   cos  
x x
[tan −1 x ] 0 = [tan −1 x ] b∞
b
1 x  2  2 ⇒
= ∫ dx − ∫ dx
2 ⇒ tan −1 (b) − tan −1 (0 ) = tan −1 (∞ ) − tan −1 (b)
cos 2   2  x
x
2 cos  
 2  2 π
⇒ 2 tan −1 (b) − 0 =
1 2
x sec 2   dx − ∫ tan   dx
x x
2∫
=
 2  2 π π
⇒ tan −1 (b) = ⇒ b = tan  
1 4  4
 x  x 
=  x ⋅ 2 tan   − ∫ 2 tan   dx 
2  2  2  ∴ b=1
77. Given curves,
− ∫ tan   dx
x
 2 x = − 2 y2 …(i)
2
= x tan − ∫ tan dx − ∫ tan   + C
x x x and x = 1 − 3y …(ii)
2 2  2
On solving both curves, we get
x x
= x tan − 4 log  sec  + C −2 y 2 = 1 − 3 y 2
2  2
⇒ y = ± 1 and x = −2
So, the intersection points are (−2, 1) and (−2, − 1). dy  1 (1 + x 2 )y 

⇒ =− 2
+ 2 
x = 1 – 3y 2 y
dx  x(1 + x ) x(1 + x )
x = 2y 2 (–2, 1) dy y 1
⇒ − =−
dx x x(1 + x 2 )
1 1
x′ x Here, p = − ,Q = −
(–1, 0) 2 x(1 + x 2 )
Integrating factor ≡ e ∫
p dx
(–2, –1)
 1
y′ ∫  − x 
=e dx
∴ Required area − log x
1
=e
=2 ∫0 {(1 − 3 y 2 ) − (−2 y 2 )} dy  1
log  
 x
1 =e
∫0 (1 − y
2
=2 ) dy
1
1
=
 y3  1 x
= 2  y −  = 2 1 − 
 30  3 80. Given, differential equation is
dy
2 4 − 2 y tan 2 x = e x sec 2 x
=2 × = dx
3 3
Here, P = 2 tan 2 x, Q = e x sec 2 x
3−1
78. Here, h = =1 − 2 tan 2 x dx
2 ∴ IF = e ∫
−2 log sec 2 x
x 1.0 2.0 3.0
=e 2
y 0.2 0.125 0.09
= e − log sec 2x
3 dx 1 1
∴ ∫1 2 + 3 x = 3 (0.2 + 4 × 0.125 + 0.09) =
sec 2 x
1
= (0.2 + 0.500 + 0.09) ∴ Required solution is
3 y 1
1 22 = ∫ex ⋅ ⋅ sec 2 x dx + C
= × 0.79 = 0.263 = sec 2 x sec 2 x
3 110
⇒ y cos 2 x = ∫ e x ⋅ 1 dx + C
79. Given, differential equation is,
dx(1 + y + x 2 y ) + ( x + x 3 ) dy = 0 ⇒ y cos 2 x = e x + C
dy 1 + y + x 2 y  where, C is the constant of integration.
⇒ =− 3 
dx  x+ x 

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EAMCET

Engineering Entrance Exam

16. A glass flask of volume one litre is filled

(a) 1650 R (b) 550 R

19. Efficiency of a heat engine whose sink is at O

25. Fresnel diffraction is produced due to light T02

(a) 3.6 × 10−5 T (b) 1.84 × 10−4 T 1Ω D

(c) 2.56 × 10−4 T (d) 5.8 × 10−5 T 9V

+ 3H2O(l ) (a) (b)

7. At T(K), the ratio of kinetic energies of 4 g of

H2 ( g) and 8 g of O2 ( g) is (c) (d)

The correct match is 57. If x = 9 is a chord of contact of the hyperbola

(*) None of the correct option.

Hints & Solutions

Dimensions of J = [ML2 T –1 ] [M3L6 T –2 ]

2. We know, work done W = F ⋅ d 5. Energy of balls at rest, K1 = mgh1 and K 2 = mgh2

M mg m1u1 + m2u 2 = m1v1 + m2 v2

Given, h1 = h,T1 = T ,θ1 = 0 18. We knows

λ A TB 23. From lens maker’s formula

26. We know that the time period of a vibrating bar T BH

32. The heat developed per unit time in given hc

preference to H + ions and copper is deposited on Cα ⋅ Cα Cα 2

20 mL of 0.1 M = 20 mL of 0.1 M P4O10 + 6H 2O → 4H 3PO 4

soluble complex salt, in presence of air, then o-bromination

2Na[Ag(CN)2 ]+ Zn → Na 2 [Zn(CN)4 ] + 2Ag ↓

29. Ferric salts (such as FeCl 3 ) form Prussian blue +

(blue ppt or colouration) with potassium

Cl NaOH NO2 NO NHOH

NaOH (ii) While in alkaline medium, using Zn-NaOH,

(r − 1) ! (n − r + 1)(n − r ) ! 77 The general term is

22 r = 110 For the term independent of x, put

Since, the matrix A satisfies the equation C13  ′  2 −6 6 ′

Apply C2 → C2 − C1,C3 → C3 − C1, we get (1 + i )x − i (1 + 2 i )y + i

⇒ 4x 2 = 0 ⇒ x=0 23. Given, sin θ + cos θ = p …(i)

⇒ p(1 − sin θ ⋅ cos θ ) = q Now, we have

90° x−3 y+4 z−5

x + 4 y − 5 z −1 Given, [r, a b ] = 0, i.e., coplanar.

 dy  8− 8 Therefore, putting x = 0 in Eq. (i), we get

and x2 + y2 + 2 x + 2 y = 0 54. Given, equation of parabola is

56. Given, equation of ellipse is ∴ Equation of tangent at (9, 6 2 ) is

Now, f (1 + 1) = f (1)⋅ f (1) 1

⇒ { f (1)} = { f (2 )} …(ii) + (1 + 0 )(1 − 0 )}

15 x16 − 16 x15 + 1 70. Given curves are

72. Given, u = log ( x 3 + y 3 + z 3 − 3 xyz ) but given,

So, the intersection points are (−2, 1) and (−2, − 1). dy  1 (1 + x 2 )y 

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