SAFETY DATA SHEET

THE DOW CHEMICAL COMPANY

Product name: SULLUBE Issue Date: 05/22/2015

Print Date: 04/12/2016

THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. IDENTIFICATION
Product name: SULLUBE

Recommended use of the chemical and restrictions on use

Identified uses: Selection of the appropriate polyglycol product for a specific application requires
knowledge of the fluid requirements of the application, awareness of the most important of these
requirements, and a match-up with the properties of the various polyglycol materials. Polyglycol
products can be formulated for use in numerous industry applications such as hydraulic fluids,
quenchants, compressor and refrigeration lubricants, heat transfer fluids, machinery lubricants, solder
assist fluids, metalworking lubricants, textile finishing, etc. We recommend that you use this product in
a manner consistent with the listed use. If your intended use is not consistent with the stated use,
please contact your sales or technical service representative.

COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES

Customer Information Number: 800-258-2436

SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: CHEMTREC +1 703-527-3887
Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION
Hazard classification
This material is not hazardous under the criteria of the Federal OSHA Hazard Communication
Standard 29CFR 1910.1200.

Other hazards
no data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 10

company of Dow
Product name: SULLUBE Issue Date: 05/22/2015

Chemical nature: Polyglycol

This product is a mixture.
Component CASRN Concentration

Polypropylene glycol Trade secret > 65.0 - < 75.0 %

Pentaerythritol ester Trade secret > 22.0 - < 27.0 %

Alkylated diphenylamine 68411-46-1 > 4.0 - < 6.0 %

Barium dinonyl-naphthalene sulfonate 25619-56-1 < 0.3 %

4. FIRST AID MEASURES

Description of first aid measures
General advice: If potential for exposure exists refer to Section 8 for specific personal protective
equipment.

Inhalation: Move person to fresh air; if effects occur, consult a physician.

Skin contact: Wash off with plenty of water. Suitable emergency safety shower facility should be
available in work area.

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.

Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.

Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed

Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable extinguishing media: Do not use direct water stream. May spread fire.

Special hazards arising from the substance or mixture

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Product name: SULLUBE Issue Date: 05/22/2015

Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Carbon monoxide. Carbon dioxide.

Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.

Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage.

Special protective equipment for firefighters: Wear positive-pressure self-contained breathing

apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Refer to section 7, Handling, for additional precautionary measures.

Environmental precautions: Material will float on water. Prevent from entering into soil, ditches,
sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Methods and materials for containment and cleaning up: Contain spilled material if possible.
Collect in suitable and properly labeled containers. See Section 13, Disposal Considerations, for
additional information.

7. HANDLING AND STORAGE

Precautions for safe handling: No special precautions required. Do not use sodium nitrite or other
nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines
could be formed. Spills of these organic materials on hot fibrous insulations may lead to lowering of
the autoignition temperatures possibly resulting in spontaneous combustion. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.

Conditions for safe storage: Store in the following material(s): 316 stainless steel. Carbon steel.
Glass-lined container. Polypropylene. Polyethylene-lined container. Stainless steel. Teflon. This
material may soften and lift certain paint and surface coatings. Use product promptly after opening.
Store in original unopened container. Unopened containers of material stored beyond the
recommended shelf life should be retested against the sales specifications before use. Additional
storage and handling information on this product may be obtained by calling your sales or customer
service contact.

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Product name: SULLUBE Issue Date: 05/22/2015

Storage stability
Shelf life: Use within
24 Month

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
Barium dinonyl-naphthalene OSHA Z-1 TWA 0.5 mg/m3 , Barium
sulfonate
ACGIH TWA 0.5 mg/m3 , Barium

None established

Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures

Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of
preferred glove barrier materials include: Butyl rubber. Ethyl vinyl alcohol laminate
("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber
("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride
("PVC" or "vinyl"). Viton. NOTICE: The selection of a specific glove for a particular
application and duration of use in a workplace should also take into account all
relevant workplace factors such as, but not limited to: Other chemicals which may be
handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications
provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, wear respiratory protection when adverse effects, such as
respiratory irritation or discomfort have been experienced, or where indicated by your risk
assessment process. For most conditions, no respiratory protection should be needed;
however, if material is heated or sprayed, use an approved air-purifying respirator.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state Liquid.
Color Green

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Product name: SULLUBE Issue Date: 05/22/2015

Odor Mild
Odor Threshold No test data available
pH 8 - 10 DOWM 101495 (16% in water/methanol, 1:10)
Melting point/range Not applicable to liquids
Freezing point See Pour Point
Boiling point (760 mmHg) Decomposes before boiling
Flash point closed cup 210 °C ( 410 °F) ASTM D 93
Evaporation Rate (Butyl Acetate No test data available
= 1)
Flammability (solid, gas) No
Lower explosion limit No test data available
Upper explosion limit No test data available
Vapor Pressure < 0.01 mmHg at 20 °C (68 °F) ASTM E1719
Relative Vapor Density (air = 1) No test data available
Relative Density (water = 1) 0.9827 at 25 °C (77 °F) / 25 °C ASTM D941
Water solubility < 0.1 % at 20 °C (68 °F) Measured
Partition coefficient: n- no data available
octanol/water
Auto-ignition temperature 385 °C (725 °F) ASTM E659
Decomposition temperature No test data available
Kinematic Viscosity 33.9 - 42.1 mm2/s at 40 °C (104 °F) ASTM D 445
Explosive properties No
Oxidizing properties No
Liquid Density 0.9826 g/cm3 at 25 °C (77 °F) ASTM D941
Molecular weight Not determined
pour point -50 °C ( -58 °F) ASTM D97

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY

Reactivity: no data available

Chemical stability: Thermally stable at typical use temperatures.

Possibility of hazardous reactions: Polymerization will not occur.

Conditions to avoid: Exposure to elevated temperatures can cause product to decompose.

Generation of gas during decomposition can cause pressure in closed systems.

Incompatible materials: Avoid contact with: Strong acids. Strong bases. Strong oxidizers.

Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Aldehydes. Alcohols. Ethers. Hydrocarbons. Ketones. Organic acids. Polymer fragments.

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Product name: SULLUBE Issue Date: 05/22/2015

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury.

LD50, Rat, female, > 2,000 mg/kg No deaths occurred at this concentration.

Acute dermal toxicity

Prolonged skin contact is unlikely to result in absorption of harmful amounts.

LD50, Rabbit, male, > 2,000 mg/kg No deaths occurred at this concentration.

Acute inhalation toxicity

At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not
likely to be hazardous. If material is heated or aerosol/mist is produced, concentrations may
be attained that are sufficient to cause respiratory irritation and other effects.
As product: The LC50 has not been determined.

Skin corrosion/irritation
Brief contact may cause slight skin irritation with local redness.
Prolonged contact may cause slight skin irritation with local redness.

Serious eye damage/eye irritation

Essentially nonirritating to eyes.

Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:

No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)

Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Based on available data, repeated exposures to small amounts are not anticipated to cause significant
adverse effects.

Carcinogenicity
No relevant data found.

Teratogenicity
No relevant data found.

Reproductive toxicity
No relevant data found.

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Product name: SULLUBE Issue Date: 05/22/2015

Mutagenicity
No relevant data found.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

COMPONENTS INFLUENCING TOXICOLOGY:

Polypropylene glycol
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not
likely to be hazardous. Vapor from heated material or mist may cause respiratory irritation.

The LC50 has not been determined.

Pentaerythritol ester
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility. Vapor from heated
material or mist may cause respiratory irritation.

The LC50 has not been determined.

Alkylated diphenylamine
Acute inhalation toxicity
As product: The LC50 has not been determined.

Barium dinonyl-naphthalene sulfonate

Acute inhalation toxicity
LC50, Rat, 1 Hour, dust/mist, > 21 mg/l No deaths occurred at this concentration.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

LL50, Oncorhynchus mykiss (rainbow trout), static test, 96 Hour, > 100 mg/l, OECD Test
Guideline 203 or Equivalent

Acute toxicity to aquatic invertebrates

EL50, Daphnia magna (Water flea), static test, 48 Hour, > 100 mg/l, OECD Test Guideline 202
or Equivalent

Persistence and degradability

Biodegradability: Based on information for a similar material: Material is inherently
biodegradable (reaches > 20% biodegradation in OECD test(s) for inherent biodegradability).
Based on stringent OECD test guidelines, this material cannot be considered as readily

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Product name: SULLUBE Issue Date: 05/22/2015

biodegradable; however, these results do not necessarily mean that the material is not
biodegradable under environmental conditions.
10-day Window: Fail
Biodegradation: < 41 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
10-day Window: Not applicable
Biodegradation: 86 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent

Theoretical Oxygen Demand: 2.37 mg/mg

Biological oxygen demand (BOD)

Incubation BOD
Time
5d 5%
10 d 8%
20 d 20 %
28 d 33 %

Bioaccumulative potential
Bioaccumulation: No data available.

Mobility in soil
No data available.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device.

14. TRANSPORT INFORMATION

DOT
Not regulated for transport

Classification for SEA transport (IMO-IMDG):

Not regulated for transport

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Transport in bulk Consult IMO regulations before transporting ocean bulk

according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

Not regulated for transport

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

OSHA Hazard Communication Standard
This product is not a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
This product is not a hazardous chemical under 29CFR 1910.1200, and therefore is not covered by
Title III of SARA.

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Pennsylvania Worker and Community Right-To-Know Act:

To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.

California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.

United States TSCA Inventory (TSCA)

All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

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16. OTHER INFORMATION

Hazard Rating System

NFPA
Health Fire Reactivity
1 1 0

Revision
Identification Number: 101199094 / A001 / Issue Date: 05/22/2015 / Version: 9.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
TWA 8-hour, time-weighted average

Information Source and References

This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.

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