Capitulo 7 - Fllujo de Gas
Capitulo 7 - Fllujo de Gas
Capitulo 7 - Fllujo de Gas
• assimilation
• respiration
• transpiration
• translocation
• microbial activity
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of surface soil
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- slope of land
- vegetative cover
- albedo
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of subsurface soil
-------------------
- water content
- bulk density
Radiation
See Fig. 5.1, 5.2, 5.3, 5.4, 5.5, 5.6, and 5.7 in the book (Jury et al., 1991)
• Earth radiates energy nearly like a black body (primarily long wave)
SSC 107, Fall 2001 – Chapter 8 Page 8-3
• H2O vapor, CO2, N2O, CH4, synthetic industrial gases, and dust absorb long wave
SSC 107, Fall 2001 – Chapter 8 Page 8-4
1. Radiative
- Stefan's Law
∑ = ε σ T4
cal
∑- - Energy flux, integrated over all wavelengths
cm 2 min
ε = 1 for blackbody
ε < 1 for other bodies
σ = 8x10-11 cal cm min-1 ºK-4
T - ºK
2. Convection
3. Conduction
Within soil, radiative and convection are very small in relation to conduction
SSC 107, Fall 2001 – Chapter 8 Page 8-5
Measurement of Temperature
- Glass thermometers
- response good
- small size
- Radiation Thermometer
- measures infrared
• Peak shifts
SSC 107, Fall 2001 – Chapter 8 Page 8-6
Heat Capacity
∆Q
Heat capacity = (cal / o K)
∆T
∆Q is quantity of heat
∆T is associated T change
Heat capacity is dependent upon size of the system. Heat capacity per unit mass is
∆ Q cal
c=
m∆t g ° K
Soil
Minerals H2O Humus
Csoil = S Xi ρi ci
∆Q cal
Csoil =
V∆T cm3 °K
Csoil = Xm ρm cm + Xo ρo co + Xw ρw cw + Xa ρa ca
- Xm, Xo, Xw, & Xa are volume fractions of mineral matter, organic
matter, water, & air
ρw
ρa = therefore ρa ≈ 0
1000
Csoil = Xm ρm cm + Xo ρo co + Xw ρw cw
ρm = 2.6 g/cm3
ρo = 1.3 g/cm3
ρw = 1.0 g/cm3
= 0.52 Xm + 0.65 Xo + Xw
Heat Flow
Steady State
dT
J H = - λe
dz
cal
J H = heat flux density
cm2 sec
cal
λe - effective thermal conductivity
cm soil sec ° K
T - temperature °K
z - distance (cm)
Transient State
∂T - ∂ J H
C =
∂t ∂z
∂T ∂ ∂T
C =
∂t ∂z λe ∂z
If λ e constant with z
∂T
= λe ∂ 2
2
T
C
∂t ∂z
∂T
= KT ∂ 2
2
T
∂t ∂z
λe
KT =
C
λe C KT
θ θ θ
Also, see Fig. 5.10 and 5.11 in Jury et al., 1991 book.
cal
dry soil 1.5 x 10-3
cm sec ° K
Determining KT in field
12 hrs 24 hrs
A0
T
T
time
T(o,t) = T + Ao sin ωt
2π
ω= τ - period = 86,400 s (=24 hours)
τ
2 π radians
ω=
86,400 s
∂T
= KT ∂ 2
2
T
∂t ∂z
z
T(z, t) = T + A o e-z/d [sin ( ω t - )]
d
d = 2K T ω
Amplitude Equation
amplitude at z=o is Ao
amplitude at z=z1 is A1 = Ao exp (-z1/d)
amplitude at z=z2 is A2 = Ao exp (-z2/d)
A1 exp (-z1/d)
= = exp [(z 2 - z1 )/d]
A 2 exp (-z2 /d)
z2 - z1
ln( A1 / A 2) =
d
z2 - z1
d=
ln( A1 / A2)
z 2 - z1
2 KT ω =
ln( A1 / A2)
2
ω z -z
KT = 2 1
2 ln( A1 / A2)
SSC 107, Fall 2001 – Chapter 8 Page 8-13
Phase Equation
z
T(z, t) = T + A o e- z/d sin ( ω t - )
d
z1 π
∴ ω t1 - =
d 2
and
z π
ω t2 - 2 =
d 2
z1 z
ω t1 - = ωt 2 - 2
d d
- z1 z 2
+ = ω t2 - ω t1
d d
1
(z 2 - z1 ) = ω(t 2 - t 1 )
d
1 z2 - z1
ω t 2 - t 1
d=
SSC 107, Fall 2001 – Chapter 8 Page 8-14
1 z 2 - z1
2 KT ω =
ω t 2 - t 1
2
2 K T 1 z 2 - z1
= 2
ω ω t 2 - t1
2
1 z 2 - z1
2 ω t 2 - t 1
KT =
Thus, KT can be determined by measuring the time at which the maximum temperature is observed at two
depths. KT is the diffusivity of the soil between two depths.
SSC 107, Fall 2001 – Chapter 8 Page 8-15
• Temperature gradients affect soil-water potential which induces both liquid and vapor movement.
• Soil-water potential gradients move water, which consequently carries heat.
• Combined transport generally ignored in very wet systems and in very dry systems. Temp. gradient
effect on water flow small in relation to soil-water potential grad. in wet range. Little water is moved
in very dry range.
• Two approaches
• Mechanistic
• Irreversible thermodynamics
Mechanistic
∂ θv ∂ ∂T ∂ ∂ θ v ∂K
For water = DT + Dw -
∂t ∂z ∂z ∂z ∂z ∂z
For heat
∂T ∂ ∂T ∂ ∂θ
C = λe - L D w,v
∂t ∂z ∂z ∂z ∂z
- Two flow mechanisms are not strictly additive since they interact
SSC 107, Fall 2001 – Chapter 8 Page 8-16
Irreversible thermodynamics
1 dP 1 dT
For water q w = - Lww - Lwh 2
T dz T dz
1 dP 1 dT
For heat q h = - Lhw - Lhh 2
T dz T dz
P - Soil-water potential