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  • Spectrum

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    Bashir Dar
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    This document contains 24 multiple choice questions about UV-visible spectroscopy and infrared spectroscopy. UV-vis spectroscopy can be used to measure conjugation, differentiate between conjugate and non-conjugate bonds, and identify unknown compounds. The Beer-Lambert law relates absorption and concentration. IR spectroscopy is used to determine molecular structure through vibrational transitions and provides a fingerprint region for compound identification. Both techniques have applications in quantitative analysis and determining structural features.

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    This document contains 24 multiple choice questions about UV-visible spectroscopy and infrared spectroscopy. UV-vis spectroscopy can be used to measure conjugation, differentiate between conjugate and non-conjugate bonds, and identify unknown compounds. The Beer-Lambert law relates absorption and concentration. IR spectroscopy is used to determine molecular structure through vibrational transitions and provides a fingerprint region for compound identification. Both techniques have applications in quantitative analysis and determining structural features.

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    © All Rights Reserved
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    223 views4 pages

    Spectrum

    Uploaded by

    Bashir Dar
    This document contains 24 multiple choice questions about UV-visible spectroscopy and infrared spectroscopy. UV-vis spectroscopy can be used to measure conjugation, differentiate between conjugate and non-conjugate bonds, and identify unknown compounds. The Beer-Lambert law relates absorption and concentration. IR spectroscopy is used to determine molecular structure through vibrational transitions and provides a fingerprint region for compound identification. Both techniques have applications in quantitative analysis and determining structural features.

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    © All Rights Reserved
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    of 4

    Q no 1: UV spectroscopy is used to measure the

    a) No of conjugate bonds b) Diffrentiate between conjugate & non conjugate bonds

    c) Aromatic conjugation with molecules d) All

    Ans: All

    Q no 2: Units of absorbance are

    a) dm³ mol⁻¹ cm⁻¹ b) Dimensionless c)mol dm⁻³ d)cm

    Ans: Dimensionless

    Q no 3: Beer‒Lambert law gives the relation between which of the following

    a) Reflected radiation & concentration b) Scattered radiation & concentration

    c) Energy absorption & concentration d) Energy absorption & reflected radiation

    Ans: Energy absorption & concentration

    Q no 4: Lambert’s law states that the intensity of light decreases with respect to

    a) Concentration b) Volume c) Distance d) Composition

    Ans: Distance

    Q no 5: Which of the following is not true about absorption spectroscopy

    a) It involves transmission b) Scattering is kept minimum

    c) Reflection is kept maximum d) Intensity of radiation leaving the substance is an indication of


    concentration

    Ans: Reflection is kept maximum

    Q no 6: Ordinary spectrometers cover a range of

    a) 200‒400 nm b) 220‒800 nm c) 400‒800 nm d) 350‒700 nm

    Ans: 220‒800 nm

    Q no 7: Red shift is also called as

    a) Bathochromic shift b) hypsochromic shift c) hypochromic shift d) Hyperchromic shift


    Ans Bathochromic shift

    Q no 8: R‒ Bands arise due to

    a) n‒π* b) π‒π* c)σ ‒π* d) σ‒σ*

    Ans: n‒π*

    Q no 9: Which of the following is application of UV spectroscopy

    a) Extent of conjugation b) determination of geometrical isomerism

    c) Identification of unknown compound d) All

    Ans: All

    Q no 10: Quantitative analysis is based on

    a) Beer’s law b) Lambert’s law c) Beer‒ lambert law d) None

    Ans: Beer‒ lambert law

    Q no 11: Spectroscopy used for the determination of structure of a compound using vibrational
    transistions

    a)IR b) UV c) Visible d) Microwave

    Ans: IR

    Qno 12: The IR region of electromagnetic radiation spectrum extends from

    a) 0.3‒200μ b) 0.8 ‒200μ c) 0.4‒300μ d) 0.1‒100μ

    Ans: 0.8‒200μ

    Q no13: The order of energies for various transistions is

    a) n‒σ* >π‒σ*>σ‒σ*>π‒π* b)σ‒σ*>n‒σ*>π‒π*>n‒π* c) σ‒σ*<n‒σ*<π‒π*<n‒π* d)


    n‒π*<π‒π*<σ‒π*<n‒σ*

    Ans: σ‒σ*>n‒σ*>π‒π*>n‒π*

    No 14: Allowed transistions with values of extinction coefficient є max more than generally arise due
    to

    a) π‒π* transistions b)σ‒σ* transistions c) n‒π* transistions d) n‒σ* transistions


    Ans: π‒π* transistions

    Q no 15: Which of the following shows both types of transistions both allowed & forbidden

    a) Benzophenone b) cyclopentonone cHexene d) None

    Ans: benzophenone

    Q no 16 : Groups which distort the geometry of molecules cause

    a) bathochromic shift b)Hypsochromic shift c) Hypochrmic shift d) Hyperchromic shift

    Ans: Bathochromic shift

    Q no 17: molecular vibrations are detected & measured in

    a) 2.5μ to 15μ b) 2.4μ to 20μ c) 4.2μ to 80μ d) 5.2 μ to 40μ

    Ans: 2.5μ to 15μ

    Q no 18: Which of the following provides finger print region

    a) UV b) IR c) Microwave d) ALL

    Ans: IR

    Qno 19: In which of the following bond angle changes

    a) Strecthing b) Bending c) twisting d) None

    Ans: Twisting

    QNo 20: Which of the following is IR inactive

    a) H₂ b) N₂ c) O₂ d)All

    Ans: All

    Q no 21: Absorbed band of hexane comes in

    a) 1713 cm⁻¹ b) 1709 cm⁻¹ c)1726 cm⁻¹ d) 1728 cm⁻¹

    Ans: 1726 cm⁻¹

    Q no 22: Prism used to obtain monochromatic light is made of

    a) Glass b) NaCl c) CaCl ₂ d) None


    Ans: Nacl

    Q no 23: Solvents used for IR are

    a) Chlorofom b) Carbontetrachloride c) Carbondisulphide d) All

    Ans: All

    Q no24: Position of IR bands of chelate compounds is

    a) 2300‒3200 cm⁻¹ b) 2500‒3000 cm⁻¹ c) 2500‒ 3200 cm⁻¹ d) 2200‒3000 cm⁻¹

    Ans: 2500‒3200 cm⁻¹

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