Cas$ng:: Advantages Disadvantages
Cas$ng:: Advantages Disadvantages
Cas$ng:: Advantages Disadvantages
molten
metal
is
poured
into
a
mold
cavity,
where
solidifica7on
takes
Cas$ng:
place
and
the
solid
metal
takes
the
form
of
the
mold.
The
important
factors
in
the
cas7ng
opera7ons
are:
(a)
solidifica7on
–
nuclea7on
and
growth;
(b)
Metal
Flow;
(c)
Heat
Transfer
and
(d)
Mold
Material
Advantages
Disadvantages
Complex
geometries
can
be
cast
Limita7ons
in
mechanical
proper7es
Can
produce
very
large
parts
Presence
of
porosity
Can
be
mass
produced
Low
dimensional
accuracy
Any
metal
can
be
cast
Some
metals
are
a
safety
hazard
when
liquid.
Solidifica)on
of
Pure
Metals
and
Eutec)cs
The
transforma7on
from
a
solid
to
a
liquid
and
vice
versa
occurs
at
a
constant
temperature.
Undercooling:
The
temperature
to
which
the
liquid
metal
must
cool
below
the
equilibrium
freezing
temperature
before
nuclea7on
occurs.
Recalescence:
The
increase
in
temperature
of
an
undercooled
liquid
metal
as
a
result
of
the
libera7on
of
heat
during
nuclea7on.
Thermal
arrest:
A
plateau
on
the
cooling
curve
during
the
solidifica7on
of
a
material
caused
by
the
evolu7on
of
the
latent
heat
of
fusion
during
solidifica7on.
Total
solidifica)on
)me:
The
7me
required
for
the
cas7ng
to
solidify
completely
aMer
the
cas7ng
has
been
poured.
Local
solidifica)on
)me:
The
7me
required
for
a
par7cular
loca7on
in
a
cas7ng
to
solidify
once
nuclea7on
has
begun.
In
pure
metals,
the
viscosity
of
the
liquid
is
approximately
uniform
during
the
solidifica7on
process
and
the
liquid
is
capable
of
moving
to
all
the
spaces
generated
by
the
shrinkage
(contrac7on)
during
the
liquid-‐solid
transforma7on.
The
rela7onship
between
temperature,
chemical
composi7on
and
phases
present
is
illustrated
in
the
Phase
Diagrams,
also
known
as
Equilibrium
Diagrams
or
Cons7tu7onal
Diagrams.
These
diagrams
can
establish
the
rela7onship
between
two,
three
or
four
different
materials
(atoms,
stochiometric
oxides,
nitrides,
etc).
Binary
Phase
Diagrams
are
for
example
between
two
different
type
of
materials
such
as
Cu-‐Ni.
Cu-‐Ni
Diagram:
The
Cu-‐Ni
diagram
is
an
isomorphous
system
i.e.
there
is
100%
solubility
of
one
to
the
other.
It
shows
two
single
phase
regions
and
one
two
phase
regions.
In
the
two
phase
region
coexists
liquid
and
solid,
their
chemical
composi7on
and
percentages
are
given
by
the
7e
line.
Two-‐phase
region:
Tie
line:
across
the
two-‐phase
region
at
the
temperature
of
the
alloy
Point
B:
T=1250oC
Composi7on
of
Liquid
phase:
CL=31.5wt%Ni
–
68.5%Cu
Composi7on
of
a
phase:
Ca=42.5wt%Ni-‐
57.5wt%Cu
S R
WL = Wα =
Two-‐phase
region:
Example:
Point
B
R+S R+S
LEVER
RULE
(Inverse
Lever
Rule)
C − Co C − CL
WL = α Wα = o
Cα − CL Cα − CL
Deriva$on
of
the
lever
rule
Wα + WL = 1
1) All
material
must
be
in
one
phase
or
the
other:
2)
Mass
of
a
component
that
is
present
in
both
phases
equal
to
the
mass
of
the
component
in
one
phase
+
mass
of
the
component
in
the
second
phase:
Wα cα + WLc L = co
3)
Solu7on
of
these
equa7ons
gives
us
the
Lever
rule.
co − cL cα − c o
Wα = WL =
cα − c L cα − c L
Equilibrium Cooling - Example:
Non-Equilibrium Cooling - Fast
Development of Microstructure Cooling
35wt%Cu-‐65wt%Ni
system
–
Slow
cooling
from
point
a
to
point
e
a:
1300oC:
complete
liquid
with
35wt%Cu-‐65wt%Ni
b:
~1260oC:
first
solid
begin
to
form
(a-‐46wt%Ni)
c:
~1250oC:
a-‐43wt%Ni,
L-‐32wt
%Ni
d:~1220oC:
last
liquid
to
solidify
e:
35wt%Cu
–
65wt%Ni
solid
phase
Development
of
microstructure
in
eutec$c
Development
of
microstructure
in
alloys
(III)
-‐Solidifica$on
at
the
eutec$c
non-‐eutec$c
composi$on
(V)
composi$on
(I)
Primary
α
phase
is
formed
in
the
α
+
L
region,
and
the
eutec$c
structure
that
No
changes
above
eutec$c
temperature,
TE.
includes
layers
of
α
and
β
phases
(called
At
TE
liquid
transforms
to
α
and
β
phases
eutec$c
α
and
eutec$c
β
phases)
is
(eutec$c
reac$on).
formed
upon
crossing
the
eutec$c
L
→
α
+
β
isotherm.
L α+L
α+β
The
Iron-‐Carbon
Diagram
Eutectoid
steel
0.8 − 0.4
α% = ×100 = 50%
0.8 − 0.022
(e)
Cons7tuents:
0.4 − 0.022
Perlite-‐eutec7c
(γ-‐0.8%C)
and
perlite% = 0.8 − 0.022 ×100 = 50%
ferrite
(α-‐0.022%C)
are
present
0.8 − 0.4
α% = ×100 = 50%
0.8 − 0.022
(e)
Phases:
0.4 − 0.022
Ferrite
(α-‐0.022%C)
and
Fe3C% =
6.67 − 0.022
×100 = 6%
Cemen7te
(Fe3C-‐6.67%C)
are
6.67 − 0.4
present
α% = ×100 = 94%
6.67 − 0.022
Cast
Structures
• Solidifica7on
starts
on
the
wall
of
the
mold,
because
they
are
usually
cold.
This
is
called
the
Chill
Zone
–
a
solidified
shell
of
fine
equiaxed
grains.
•
The
grains
grow
in
the
opposite
direc7on
of
the
heat
extrac7on.
Some
direc7ons
are
more
favourable
for
dendri$c
growth.
Favourable
grains
that
grow
fast
form
a
Columnar
Zone.
• The
central
region
is
known
as
the
equiaxed
zone.
Beder
proper7es
are
obtained
with
equiaxed
grains.
• Adding
impuri7es
on
purpose
is
called
inocula$on
ß
Heat
extrac7on
Mushy
Zone
forma)on
in
Alloys
Steel
cas7ng
have
narrow
mushy
zones,
whereas
Al
and
Mg
have
wide
mushy
zones,
that
is,
these
alloys
are
in
a
semisolid
state
throughout
most
of
the
solidifica7on
process.
The
lader
behavior
is
used
to
in
a
new
form
of
cas7ng
when
the
semisolid
metal
(mushy
state)
is
injected
into
a
die,
resul7ng
in
lower
solidifica7on
7mes,
porosity
and
precise
cas7ng
(thixocas7ng).
Secondary arms
Macro-Scale:
Engine Block
~1m
Performance criteria:
• Power generated
• Efficiency
• Durability
• Cost Mesostructure:
grains
1-10 mm
Properties affected:
• High cycle fatigue
• Ductility
Microstructure:
dendrites & phases:
50-500 um
Properties affected:
• Yield strength
• Tensile strength Nano-structure:
• High/low cycle fatigue Precipitates
• Thermal growth 3-100 nm
• Ductility Properties affected:
• Yield strength Atomic Structure:
• Tensile strength 1-100 A
• Low cycle fatigue Properties affected:
Mass
Transport
in
Microstructure
• Ductility • Young’s Modulus
Forma7on
• Thermal Growth
Effect
of
Cooling
Rate
Slower
cooling
rates
(102K/s)
results
in
coarse
dendrites
and
longer
distances
between
dendrite
arms.
Higher
cooling
rates
(104K/s)
results
in
short
solidifica7on
7mes
and
finer
structures.
The
resul7ng
structures
are
not
in
equilibrium
and
the
phase
diagram
can
not
be
used
to
predict
the
composi7on
or
percentages
of
phases.
Even
higher
cooling
rates
(106-‐108K/s)
could
result
in
the
development
of
amorphous
structures
(loss
of
crystallinity).
[J.W. Callister: “Introduction to Materials Science and Engineering” 6th Ed, Jon Wiley and Sons (2004)]
Structure-‐
Property
Rela)onships
The
dendri7c
arm
spacing
depends
on
the
solidifica7on
7me,
as
the
solidifica7on
7me
increases
the
secondary
arm
spacing
increases.
λ2 = k1t m
As
the
grain
size
decreases
or
the
dendri7c
arm
spacing
decreases
and
the
microporosity
decreases,
then
the
strength
and
duc7lity
of
the
cas7ng
increases
and
the
toughness
increases
i.e.
the
tendency
to
fracture
decreases.
Inocula)on:
Use
of
small
par7cles
as
nuclea7on
agents,
to
enhance
the
forma7on
of
a
large
number
of
nuclei
in
the
liquid,
with
low
or
no
undercooling.
The
result
is
a
beder
cast
with
homogeneous
proper7es
and
smaller
grain
size.
Rheocas)ng:
S7rring
of
the
liquid
metal
in
the
mushy
state.
The
small
dendrites
break
and
mix
with
the
remainder
liquid,
causing
a
large
number
of
nuclei
and
finer
grain
structure.
Vibra)on:
Electromagne)c
S)rring:
Shrinkage
Most
of
the
metals
contracts
during
solidifica7on.
The
cast
contrac7on
is
caused
by
(a)
Cooling
of
the
molten
metal;
(b)
phase
change
from
liquid
to
solid
and
(c)
Cooling
of
the
solid
cast
to
room
temperature.
The
contrac7on
causes
dimensional
changes,
cracking
(hot
tears)
and
porosity.
The
volume
of
the
mold
cavity
forming
the
outside
surface
of
a
steel
cas7ng
is
6000
cm3.
An
internal
sand
core
placed
at
the
bodom
of
the
cas7ng
experiences
a
buoyancy
force
of
30kg.
What
is
the
weight
of
the
final
cas7ng?
Ignore
the
shrinkage
effects.
Data:
Sand
Density=1.6g/cm3
;
Steel
Density=7.82g/cm3
Buoyancy 30 ×1000g 3
VSteel = = = 4823.15cm
ρ Steel − ρ Sand ( 7.82 −1.6 ) g / cm 3
3
ΔV = VCavity −VSteel = 6000 − 4823.15 = 1176.85cm
WSteel = ρ Steel × ΔV = 7.82 ×1176.85 = 9.20Kg
Example:
Based
on
experimental
work,
a
mold
constant
in
Chvorinov's
rule
of
4.25
min/cm2,
for
the
cas7ng
of
steel
under
certain
mold
condi7ons.
The
cas7ng
is
a
flat
plate
whose
length
=
50
cm,
width
=
8
cm,
and
thickness
=
1.5
cm.
Determine
how
long
it
will
take
for
the
cas7ng
to
solidify.
π 2
V = (35) 8 = 7696.9cm 3
4
Vexcess = 1.08 × 7696.9 = 8312.7cm 3
Heat = ρVexcess #$c p−solid (Tfusion − RT ) + H fusion + c p (Tpouring − Tfusion )%&
Heat = 7.14 × 8312.7 × #$0.388 × ( 420 − 25) +113+ 0.388 × ( 570 − 420 )%& = 19.26MJ
Example
The
desire
volume
flow
rate
of
the
molten
metal
into
a
mold
is
0.01m3/min.
The
top
of
the
sprue
has
a
diameter
of
20mm
and
its
length
is
200mm.
What
diameter
should
be
specified
at
the
bodom
of
the
sprue
in
order
to
prevent
aspira7on?
What
is
the
resultant
velocity
and
Reynolds
Number
at
the
bodom
of
the
sprue
if
the
metal
being
cast
is
aluminum
and
it
has
a
viscocity
of
0.004N-‐s/m2?
Plaster/Ceramic Molding
P e r m a n e n t good finish, low porosity, high Costly mold, simpler gears, gear housings
mold production rate shapes only
Die Excellent dimensional accuracy, costly dies, small parts, gears, camera bodies,
high production rate non-ferrous metals car wheels
Centrifugal Large cylindrical parts, good Expensive, few shapes pipes, boilers,
quality flywheels
Tempered
sand
is
packed
into
wood
or
metal
padern
halves,
removed
form
the
padern,
and
Sand
Cas$ng
assembled
with
or
without
cores,
and
metal
is
poured
into
resultant
cavi7es.
Various
core
materials
can
be
used.
Molds
are
broken
to
remove
cas7ngs.
Specialized
binders
now
in
use
can
improve
tolerances
and
surface
finish.
Metals:
Most
castable
metals.
Size
Range:
Limita7on
depends
on
foundry
capabili7es.
Ounces
to
many
tons.
Semiconductor
Cas$ng
Cas$ng
of
a
Turbine
Blade
Melt-‐Spinning
Process