Resonance Chemistry DPP

DPPs BOOKLET-1 VIJAY (JR01) | MATHEMATICS
MATHEMATICS
TARGET : JEE (Main + Advanced)

EST I NFORM AT IO
DPP DAILY PRACTICE PROBLEMS
NO. 01 TO 02
DPP No. # A1 (JEE–ADVANCED)

Total Marks : 33 Max. Time:
30 min.
Single choice Objective ('–1' negative marking) Q.2, 3, 4, 7, 8, 9 (3 marks 3 min.) [18, 18]
Multiple choice objective ('–1' negative marking) Q.5, 6, 10 (4 marks, 3 min.) [12, 09]
Subjective Questions ('–1' negative marking) Q.1 (3 marks 3 min.) [03, 03]
Question No. 1 2 3 4 5 6 7 8 9 10 Total

Marks Obtained
ANSWERKEY
y y
4
1. (i) (ii)
O x O x
–2 1 –1 –8 1
–23 –12
y y
(iii) –1
(iv) 1
O O 2
x x
–1 1 –3
2. (A) 3. (C) 4. (A) 5. (ABCD) 6. (BCD) 7. (C) 8. (A)

9. (B) 10. (A)

3 
1. (D) 2. (AC) 3. (CD) 4. (ABCD) 5. (C) 6. x∈  , ∞ 
2 
7. x ∈ (–∞, 1] ∪ [3, ∞) 8. (BCD) 9.. (B)
10. (i) (–∞, –5/2) ∪ (–2, 8) (ii) (–∞, –2) ∪ (–1, 0) ∪ (1/2, +∞) (iii) (–2, ∞) (iv) x = 1
1. Draw the graph of the following functions :
(i) y = 2x3 + 3x2 – 12x – 16

y
4
Ans. O x
–2 1
–23
(ii) y = –x3 + 3x – 10
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PAGE NO.-1
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Ans. O x
–1 –8 1
–12
(iii) y = x4 – 2x2 + 2
y
Ans. –1
O x
–1 1
(iv) y = x4 – 32x + 1
Ans. 1
O 2
x
–3
x− 2
2. Exhaustive solution set of the inequation < 0 is
x2 − 9
(A*) x ∈ (–∞, –3) ∪ (2, 3) (B) x ∈ (–∞, –3] ∪ (2, 3)

(C) x ∈ (–∞, –3) ∪ (2, 3] (D) x ∈ (–∞, 2) ∪ (3, 4)
x− 2
Sol. < 0
(x − 3)(x + 3)
– + – +
–3 2 3
x ∈ (–∞, –3) ∪ (2, 3)
x2 − x − 6
3. Least natural number statisfiying the inequation ≥ 0 is
x 2 + 6x
(A) 1 (B) 2 (C*) 3 (D) 4
(x − 3)(x + 2)
Sol. ≥ 0
x(x + 6)
+ – + – +
–6 –2 0 3
x ∈ (–∞, –6) ∪ [–2, 0) ∪ [3, ∞)
PAGE NO.-2
x+ 2
4. Number of prime numbers less then 19 satisfying the inequation –1 < ≤ 2 are :
x− 1
(A*) 5 (B) 6 (C) 7 (D) 8

Sol. do yourself
3x 2 − 7x + 8
5. Solution set of the inequation 1 < ≤ 2 contains :
x2 + 1
(A*) 6 natural numbers (B*) 3 even numbers
(C*) 3 odd numbers (D*) 2 composite numbers
3x 2 − 7x + 8 3x 2 − 7x + 8
Sol. >1 and ≤2
x2 + 1 x2 + 1
⇒ 2x2 –7x + 7 > 0 and x2 – 7x + 6 ≤ 0
x∈R and (x –1) (x –6) ≤ 0
x ∈ [1, 6]
Hence % x ∈ [1, 6]
6. If the solution of x4 – 5x2 + 4 < 0 is (a, b) ∪ (c, d) then :

(where a is less then c)
(A) abcd = –4 (B*) a + b + c + d = 0
b
(C*) c & d are coprime (D*) is rational number
c
Sol. (x2 – 4) (x2 – 1) < 0
– –
–2 –1 1 2
⇒ (x –2) (x + 2) (x – 1) (x + 1) < 0
x ∈ (–2, –1) ∪ (1, 2)
7. If a + b + c = 0 and a2 + b2 + c2 = 1, then the value of a4 + b4 + c4 is
1 1
(A) 1 (B) 4 (C*) 2 (D) 4
Sol. (a + b + c)2 = 0
⇒ 1 + 2(ab + bc + ca) = 0
⇒ ab + bc + ca = –1/2
Now (ab + bc + ca)2 = 1/4
1
a2 b2 + b2c2 + c2a2 + 2abc(a + b + c) =
4
1
Now (a2 + b2 + c2)2 = a4 + b4 + c4 + 2 4
 1
Now (a2 + b2 + c2)2 = a4 + b4 + c4 + 2  4 
1
⇒1– = a 4 + b 4 + c4
2
PAGE NO.-3
4x + 19 4x − 17
8. The largest integral value of x which satisfies the inequality < is :
x+ 5 x− 3
(A*) 2 (B) 3
(C) 4 (D) None of these
Sol.
4x + 19
–
4x − 17
<0 ⇒
( 4x 2
) (
+ 19x − 12x − 57 − 4x 2 − 17x + 20x − 85 ) <0
x+ 5 x− 3 (x − 3) (x + 5)
(x + 7)
⇒ <0
(x − 3) (x + 5)
x ∈ (–∞, –7) ∪ (–5, 3) largest integral x = 2.
x 2 (4 − 3x)3 (x − 2)4
9. The number of non negative integral solutions of , ≥ 0 is :
(x − 5)5 .(2x − 7)6
(A) 4 (B*) 5 (C) 6 (D) None of these

x 2 (3x − 4)3 (x − 2)4
Sol. ≤0
(x − 5)5 (2x − 7)6
 4 7 7 
x ∈  ,  ∪  , 5 ∪ {0}
3 2  2 
x 2 − 5x + 6
10. If P and Q are the solution set of the inequations (x – 5) (x + 9) (x – 8) < 0 and <0
x2 + x + 1
respectively then :
(A*) P ∩ Q = φ (B) P ∩ Q = ( − ∞ , − 9) ∪ (5, 8)

(C) P ∪ Q = ( − ∞ , − 9) ∪ (5, 8) (D*)P ∪ Q = ( − ∞ , 2) ∪ (5, ∞ )
Sol. x2 + x + 1 > 0, ∀x∈R
So vr% (x – 2) (x – 3) < 0
⇒ 2<x<3
PAGE NO.-4

Total Marks : 34 Max. Time:
30 min.
Single choice Objective ('–1' negative marking) Q.1,5,9 (3 marks 3 min.) [09, 09]
Multiple choice objective ('–1' negative marking) Q.2,3,4,8 (4 marks, 3 min.) [16, 12]
Subjective Questions ('–1' negative marking) Q.6,7,10 (3 marks 3 min.) [09, 09]
Question No. 1 2 3 4 5 6 7 8 9 10 Total

Marks Obtained
1. Complete solution set of the equation |x+1| – |x| + 3 |x–1| –2 |x–2| = x+2 is :
(A) x ∈ [2, ∞ ) (B) x ∈ (2, ∞ ) (C) x ∈ (2, ∞ ) ∪ {–2} (D*) x ∈ [2, ∞ ) ∪ {–2}
Sol. |x + 1| – |x| + 3 |x – 1| – 2|x – 2| = x + 2
Case-I x≥2
x + 1 – x + 3x – 3 – 2x + 4 = x + 2, holds for all x ≥ 2
Case-II 1≤x<2
x + 1 – x + 3x – 3 + 2x – 4 = x + 2
4x = 8
x = 2 (not possible)
Case-III 0≤x<1
x + 1 – x – 3x + 3 + 2x – 4 = x + 2
2x = – 2 ⇒ x = – 1 (not possible)
Case-IV –1 ≤ x < 0
x + 1 + x – 3x + 3 + 2x – 4 = x + 2
x = x + 2 ; not possible
Case-V x<–1
– x – 1 + x – 3x + 3 + 2x – 4 = x + 2
2x = – 4⇒ x = – 2 (a solution)
Ans. [2, ∞) ∪ {–2}
x 2 (5 − x)(1 − 2x)
2. If S is the set of all real 'x' such that is negative
(5x + 1)(x + 2)
3x + 1
and is positive, then S contains
6x + x 2 − x
3
 3 − 1
(A*) (1, 4) (B) (5, 11) (C*)  − ,  (D) (– 10, – 4)
 2 2 
x 2 (5 − x)(1 − 2x) x 2 (x − 5)(2x − 1)
Sol. < 0, < 0
(5x + 1)(x + 2) (5x + 1)(x + 2)
+ –2 – 1 + 1 – 5
−
5 2
3x + 1
> 0
x(6x 2 + x − 1)
(3x + 1)
> 0
x(2x + 1)(3x − 2)
PAGE NO.-5
+ 1 – 1 + 0 – 2 +
– −
2 3 3
combining both only (A) & (C) satisfy it.
3. Values of x satisfying the equality |x2 + 8x + 7| = |x2 + 4x + 4| + |4x + 3| for x ∈ R are
3   3 
(A) (– 2, ∞) (B)  , ∞  ∪ {– 2} (C*)  − , ∞  ∪ {– 2} (D*) [0, ∞)
4   4 
Sol. | x2 + 4x + 4 + 4x + 3 | = | x2 + 4x + 4 | + | 4x + 3 |
| a + b | = |a| + |b| ⇒ a.b ≥ 0
(x2 + 4x + 4) (4x + 3) ≥ 0
3
x ≥−
4
4. The equation |x + 2| – |x + 1| + |x – 1| = K, x ∈ R has

(A*) One solution if K ∈ {1}
(B*) Two solutions if K ∈ (1, 2) ∪ (3, ∞)
(C*) Three solutions if K ∈ {2, 3}
(D*) Four solutions if K ∈ (2, 3)
Sol. Graph of y = |x + 2| – |x + 1| + |x – 1|
for two solutions K ∈ (1, 2) ∪ (3, ∞)

5. The sides of a triangle ABC are as shown in the given figure. Let D be any internal point of this triangle
and let e, f, and g denote the distance between the point D and the sides of the triangle. The sum (5e +
12f + 13g) is equal to
(A) 120 (B) 90 (C*) 60 (D) 30
PAGE NO.-6
1
Sol. Area of ∆ADC = 2 × 5e
1
∆CDB = × 12 × f
2
1
∆ADB = × g × 13
2
(5e + 12f + 13g) 1
= × 5 × 12
2 2
Solve the following inequations (Q.6 to Q.7) :
6. |x| – |x – 2| ≥ 1
3 
Ans. x ∈  , ∞ 
 2 
Sol. |x| – |x – 2| ≥ 1
case-I : x ≥ 2
x+2≥1
2≥1
∴ x ∈ [2, ∞) is a solution ...(i)
case-II : 0 ≤ x < 2
x+x–2≥1
3
x≥
2
3 
∴ x ∈  , 2 ...(ii)
 2 
case-III : x < 0
–x+x–2≥1
x∈φ ...(iii)
x ∈ (i) ∪ (ii) ⇒ x ∈ [3/2, ∞)
7. x2 – 4x + 4 ≥1
Ans. x ∈ (–∞, 1] ∪ [3, ∞)

Sol. |x2 – 4x + 4| ≥ 1
∴ |x – 2| ≥ 1
x–2≥1⇒x≥3
or
x–2≤–1⇒x≤1
x ∈ (–∞, 1) ∪ [3, ∞)
8. Solution set of the inequality 7 – x > 2x – 3 , is contained by the set
 11 + 89   11 + 89 
(A)  ,∞  (B*) (– ∞ ,7) (C*)  – ∞ ,  (D*) (– ∞ ,3)
8  8
   
PAGE NO.-7
Sol. 7–x≥0 x≤7 ........(i)

3
case -1 2x–3 > 0 ⇒ x> 2
7 – x > 4x2 + 9 – 12x

4x2 – 11 x + 2 < 0
 11– 89 11 + 89 
x∈  , 
 8 8 
 3 11 + 89 
⇒ x ∈  ,  ....(ii)
2 8 
3
case -2 2x – 3 ≤ 0 x≤ 2
positive > negative
 3
⇒ x∈  –∞ , 2  ....(iii)
 
 3
(i) ∩ (iii)⇒  – ∞ ,  ....(iv)
 2
(ii) ∪ (iv)
 11 + 89 
x∈  – ∞ , 
 8 
9.. The number of solution of the equation, log( − 2x) = 2 log (x + 1) is :

(A) zero (B*) 1 (C) 2 (D) None of these
Sol. log(–2x) = 2log(x + 1)

–2x = x2 + 2x + 1 ⇒ x2 + 4x + 1 = 0
− 4 ± 16 − 4 −4± 2 3
x= = ⇒ –2 ± 3
2 2
x = –2 – 3 and x = –2 + 3
Now –2x > 0 and x + 1 > 0
so x ∈ (–1, 0)
so solution is x = –2 + 3
10. Solve the following inequations
x2 − 1
(i) <3
2x + 5
Ans. (–∞, –5/2) ∪ (–2, 8)
x2 − 1
Sol. − 3 <0
2x + 5
x 2 − 1 − 6x − 15 x 2 − 6x − 16
<0 ⇒
2x + 5 2x + 5
PAGE NO.-8
(x − 8)(x + 2)
<0
2x + 5
 5
x ∈  − ∞ , −  ∪ (–2, 8)
 2
3 2
(ii) 2+ >
x+ 1 x
Ans. (–∞, –2) ∪ (–1, 0) ∪ (1/2, +∞)
3 2
Sol. 2+ – >0
x+ 1 x
2x 2 + 2x + 3x − 2x − 2
>0
x(x + 1)
2x 2 + 3x − 2 (2x − 1)(x + 2) 1 
⇒ >0 ⇒ x ∈ (–∞, –2) ∪ (–1, 0) ∪  , ∞ 
x(x + 1) x(x + 1) 2 
x2 − 1
(iii) <1
x2 + x + 1
Ans. (–2, ∞)
Sol. x2 + x + 1 > 0, ∀x∈R
⇒ x – 1 < x2 + x + 1
2
⇒ x > –2
(iv) (x – 1)2 ≤ 0
Ans. x = 1
Sol. (x – 1)2 = 0 possible
⇒ x=1
PAGE NO.-9
DPPs BOOKLET-1 VIJAY (JR) | CHEMISTRY
O-CHEMISTRY

EST INFORM ATIO
DPP
DAILY PRACTICE PROBLEMS
NO. A1
1. Course of the week as per plan : Naming of unsaturated hydrocarbons & cyclic hydrocarbon and
chain terminating functional group.
2. DPP Syllabus : IUPAC Nomenclature.
DPP No. # A1 (JEE-ADVANCED)

Total Marks : 76 Max. Time : 44 min.
Multiple choice objective ('–1' negative marking) Q.1 to Q.8 (4 marks, 2 min.) [32, 16]
Integer type Questions ('–1' negative marking) Q.9 to Q.12 (4 marks 3 min.) [16, 12]
Match the Following (no negative marking) Q.13 (8 marks, 6 min.) [08, 06]
ChemINFO : 5 Questions ('–1' negative marking) Q.14 to Q.18 (4 marks, 2 min.) [20, 10]
ANSWER KEY
1. (BCD) 2. (AD) 3. (ACD) 4. (AC) 5. (ABCD) 6. (ABCD) 7. (ACD)
8. (ABCD) 9. 3 10. 8 11. 2 12. 5
13. (A)→p,r,s; (B)→p,s; (C) → q; (D) → p,s 14. (C) 15. (B) 16. (C) 17. (D)
18. (C)
1. The alicyclic compound/s is / are
(A) (B*) (C*) (D*)

O
2. Which of the following is/are aromatic compounds :
..
(A*) (B) N (C) . . (D*)
O
..
N |
H
3. Which of the following have general formula C nH2n–4 ?
(A*) (B) (C*) (D*)
4. In the given compounds how many are unsaturated hydrocarbon?
NH2
(A*) (B) (C*) (D)

N
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Page No. - 1
5. Which of the following IUPAC names of alkyl radicals is/are correct :
(A*) is 2, 3-dimethylbutyl.
(B*) is 1-methylpropyl
(C*) is 1, 2-dimethylpropyl
(D*) is 1-methylethyl
6._ Which of the following IUPAC name is/are correct :
(A*) 1- Ethyl-2-methylcyclopropane
(B*) 4-Ethyl-2-methyl-1-propylcyclohexane
(C*) 1,1,2-Trimethylcyclopentane 1,
(D*) 1,1-Dimethyl-4-propylcyclohexane 1,
7. In which of the following cyclic ring is a parent chain:
(A*) (B) (C*) (D*)
8. Which of the following has/have correct IUPAC name :
(A*) 1,2,3-Tricyclopropylcyclopropane
Cl
(B*) (2-Chloro-1-methylpropyl) cyclopentane
(C*) 4,6-Bis(1-methylethyl) nonane
Page No. - 2
(D*) 3,4,6-Triethyl-5-methyloctane
9. How many sp2–sp σ bonds are present in the given compound.
Ans. 3
10. How many compounds are hydrocarbon in the following?
OH
OH
Ans. 8
11.
How many isopropyl group/s is/are present on the carbon parent chain as substituent in given
compound ?
Ans. 2
12. The position of locant methyl group in the given cyclic ring is :
Cl CH3
Cl
Ans. 5
3
2 4
Sol. 1 5
Cl CH3
6
Cl
Page No. - 3
13. Match the compounds of Column I with the appropriate compound of Column II.
Column I Column II
O
(A) Aliphatic (p)
NH 2
(B) Hetrocyclic (q)
O
(C) Unsaturated compound (r)
N
(D) Alicyclic (s)
Ans. (A) → p, r, s ; (B) → p, s ; (C) → q ; (D) → p, s
14. What is the general formula of alkyl group ?

(A) CnH2n+2 (B) CnH2n (C*) CnH2n+1 – (D) CnH2n–2
15. What is the name of following group ?

CH 3–CH 2–CH–CH3
(A) Iso-Butyl (B*) Sec-Butyl (C) t-Butyl (D) n-Butyl

16. Which of the following groups is attached to the cyclohexane ring in the following compound.
(A) Methyl (B) n-Propyl (C*) Iso-propyl (D) Neo-pentyl

17. Which of the following alkyl group can possible from Iso-butane ?
(A) Iso-Butyl & n-butyl (B) Sec. butyl & Ter. butyl
(C) n-butyl & Ter. butyl (D*) Iso-butyl & Ter. butyl
18. How many 1° hydrogen are present in Iso-octane :

(A) 5 (B) 10 (C*) 15 (D) 20
Page No. - 4
PHYSICS

O
DPPDAILY PRACTICE PROBLEMS
NO. A1 TO A2
DPP No. : A1 (JEE-Main)

Single choice Objective ('–1' negative marking) Q.1 to Q.19 (3 marks, 2 min.) [57, 38]
Match the Following (no negative marking) Q.20 (8 marks, 6 min.) [08, 06]
ANSWER KEY OF DPP No. : A1 (JEE-MAIN)

1. (C) 2. (C) 3. (C) 4. (A) 5. (C) 6. (A) 7. (B)
8. (D) 9. (A) 10. (D) 11. (C) 12. (C) 13. (A) 14. (B)
15. (A) 16. (A) 17. (C) 18. (B) 19. (B)
20. (a) → Q, (b) → P, (c) → R, (d) → Q, (e) → Q.
1. sin 300º is equal to

3 3
(A) 1/2 (B) –1/2 (C*) – (D)
2 2
3
Sol. sin 300º = sin (360 – 60) = – sin 60º = –
2
2. Value of tan225º is :
1
(A) 3 (B) (C*) 1 (D) –1
3
Sol. tan 225º = tan (180 + 45) = tan 45º = 1
3. Value of sin15º. cos15º is :

3
(A) 1 (B) 1/2 (C*) 1/4 (D)
2
sin30° 1
Sol. sin 15º cos 15º = =
2 4
4. Value of sin (37°) cos (53°) is -

9 12 16 3
(A*) (B) (C) (D)
25 25 25 5
3 3 9
Sol. sin 37° × cos 53° = × =
5 5 25
1
5. If sin θ = , then cos θ will be -
3
8 4 2 2 3
(A) ± (B) ± (C*) ± (D) ±
9 3 3 4
1 2 2
Sol. cos θ = 1 − sin2 θ = 1− = ±
9 3
6. Convert 18 degree into radians.
PAGE NO.-1
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π π π 18
(A*) rad (B) rad (C) rad (D)
10 180 18 π
π π
Sol. = 18 × = rad.
180 10
7. sin (90º + θ) is -
(A) sin θ (B*) cos θ (C) – cos θ (D) – sin θ

Sol. sin (90º + θ) = cos θ
8. sec (π + θ) =
(A) cosθ (B) tanθ (C) sec θ (D*) – sec θ
9. sin (750°) =
1 1 3
(A*) (B) – (C) 0 (D)
2 2 2
 11π 
10. cos   =
 6 
1 3 3
(A) (B) − (C) 0 (D*)
2 2 2
11. Equation of straight line is 2x + 3y = 5. Slope of the straight line is :
(A) 3/2 (B) 2/3 (C*) –2/3 (D) –3/2

dy
Sol. y = – 2/3 x + 5/3 ⇒ = – 2/3
dx
Alter : y = mx + c
(slope) m = –2/3
dy
12. If y = ex . cot x then will be
dx
(A) excot x – cosec2x (B) ex cosec2x (C*) ex[cot x – cosec2x] (D) excot x
dy
Sol. y = ex . cot x
dx
dy dy
= ex (cot x) + cot x (ex)
dx dx
= ex (–cosec2x) + cotx ex
= ex [cotx – cosec2x]
13. Double differentiation of displacement w.r.t. time is :
(A*) acceleration (B) velocity (C) force (D) none of these
dx d2 x
Sol. =v ⇒ = acceleration
dt dt 2
∫ x dx is equal to :
3
14.
x4 x4
(A) 3x2 (B*) + C (C) (D) 4x3
4 4
x4
∫ x dx
3
Sol. = + C
4
15. ∫ 2 sin(x)dx
is equal to :
(A*) –2cos x + C (B) 2 cosx + C (C) –2 cos x (D) 2 cosx
PAGE NO.-2
2π
16. Evaluate ∫ 2sin(x)dx

0
1 2
(A*) 0 (B) (C) (D) 2
3 3
dx
17. Find ∫ ax + b
1 1
(A) loge(ax + b) + C (B) a loge(ax + b) + C (C*) C + loge(ax + b) (D) loge(ax + b) + C
a b
dx 1
Sol. ∫ ax + b = a
loge (ax + b) + C.
18. If y = x2sin(x3) , then ∫ ydx will be : [

 cos x 3   cos x 3 
(A) –cos(x3) + C (B*)  −  +C (C) cos(x3) + C (D)   +C
 3   3 
Sol. y = x2 sinx3
∫ x sin x dx
2 3
let u = x3 ⇒ du = 3x2 dx
sin xdx 1 1
∫ 3
= (–cosx) + C = – cosx3 + C
3 3
π /2
19. Value of ∫
0
cos3t is
2 1 2 1
(A) (B*) − (C) − (D)
3 3 3 3
π /2 π /2
 sin3t 
Sol. ∫0 cos3t dt =  3 
0
1 −1
= [–1 – 0] =
3 3
20. Match the following columns :
−3
(a) sin 37º (P)
5
3
(b) cos 127º (Q)
5
4
(c) tan 307º (R) −
3
4
(d) cos 307º (S)
3
3
(e) cos (–53º) (T)
4
Ans. (a) → Q, (b) → P, (c) → R, (d) → Q, (e) → Q.
3
Sol. (a) sin37º =
5
3
(b) cos127º = cos(180º – 53º) = – cos53º = −
5
Since, cos(180º – θ) = – cosθ
4
(c) tan307º = tan(360º – 53º) = – tan53º = −
3
3 3
(d) cos307º = cos(360º – 53º) = cos53º = (e) cos(–53º) = cos53º = .
5 5
PAGE NO.-3
PAGE NO.-4
P-CHEMISTRY

EST INFORM ATIO
DPP
DAILY PRACTICE PROBLEMS
NO. A1
DPP No.# A1 (JEE-MAIN)

Single choice Objective ('–1' negative marking) Q.1 to Q.17 (3 marks, 2 min.) [51, 34]
ChemINFO : 3 Questions ('–1' negative marking) Q.18 to Q.20 (4 marks, 2 min.) [12, 06]
ANSWER KEY
1. (D) 2. (B) 3. (D) 4. (D) 5. (B) 6. (A) 7. (A)
8. (C) 9. (C) 10. (A) 11. (C) 12. (B) 13. (C) 14. (C)
15. (B) 16. (D) 17. (C) 18. (A) 19. (B) 20. (D)
1. 1 amu is equal to :
1 16
(A) 1.66 × 10–24 kg (B) times the mass of one 8O –atom
8
1 1 12
(C) times the mass of one 11H -atom (D*) times the mass of one 6 C –atom
2 12
Sol. It is a fact to be remembered.
2. The mass of half mole of electrons is about : (Given : Mass of electron = 9.1 × 10 –28 g)
(A) 0.546 mg (B*) 0.273 mg (C) 1.092 mg (D) 4.55 mg
3. In which of the following options, the molecules are correctly matched with their atomicity :
(1) P4 (p) 7
(2) HNO3 (q) 6
(3) C2H4 (r) 5
(4) H2SO4 (s) 4
(A) (1 – s), (2 – r), (3 – p), (4 – q) (B) (1 – q), (2 – s), (3 – p), (4 – r)
(C) (1 – q), (2 – s), (3 – r), (4 – p) (D*) (1 – s), (2 – r), (3 – q), (4 – p)
4. 39.4 kg of gold was recovered from a smuggler. The number of atoms of gold recovered are :
(A) 200 (B) 1.2044 × 1025 (C) 6.022 × 1025 (D*) 1.2044 × 1026
 39.4 × 103 
Sol. No. of atoms of gold recovered = Moles of gold × NA =   × NA = 1.2044 × 10
26
 197 
PAGE NO.-1
5. 124 g of P4 will contain which of the following :

(1) 4 atoms of Phosphorus (2) 4NA atoms of Phosphorus
(3) NA molecules of Phosphorus (4) 1 molecule of Phosphorus
(A) (1) and (4) (B*) (2) and 3 (C) (1) and (3) (D) (2) and (4)
Sol. Molecular mass of P4 = 4 × 31 = 124 amu

∴ 124 g of P4 contains 1 mole of P4 = NA molecules of Phosphorus.
1 mole of P4 contains 4NA atoms of P.
6. 1.5 × 1022 atoms of an element weigh about 0.9 g. The atomic mass of the element (in amu) is :
,d rRo ds 1.5 × 1022 ijek.kqvksa dk nzO;eku yxHkx 0.9 g gSA rRo dk ijek.kq nzO;eku (amu
esa) D;k gksxk %

(A*) 36 (B) 18 (C) 54 (D) 72
Sol. Mole of element × Gram Atomic Mass of element = Mass of element
 1.5 × 1022 
 NA  × Gram Atomic Mass of element = 0.9
 
∴ Gram Atomic Mass of element = 36 g, Atomic mass = 36 u
7. Sulphur exist in different allotropic forms like S 2, S6 and S8 etc. If equal moles of these three forms are
taken in separate containers, then the ratio of number of atoms present in them respectively is :
(A*) 1 : 3 : 4 (B) 1 : 1 : 1 (C) 12 : 4 : 3 (D) 4 : 3 : 1

Sol. S2 S6 S8
mole n n n
molecule n × NA n × NA n × NA
atoms n × NA × 2 n × NA × 6 n × NA × 8
∴ Ratio of atoms of S = 2 : 6 : 8 = 1 : 3 : 4.
4
8. A sample of oxygen containing mol of oxygen is represented on a Y-map where its volume at NTP,
NA
mass of the sample and number of particles are shown. Study the map & choose the correct option.
(A) Y-map is correct (B) mass of sample is wrong

PAGE NO.-2
(C*) Number of ‘O’ atoms is wrong (D) Volume of oxygen is wrong
4 4
Sol. (Moderate) mole of O2 = × 22.4 Ltr O2
NA NA
4
= × NA molecule of O2 = 4 molecule of O2 = 8 atoms of O = 8 × 16 = 128 amu
NA
9. The charge on 1 gram of Al3+ ions is : (NA = 6.02 × 1023, e = electronic charge)
1 1 1
(A) NAe coulomb (B) NAe coulomb (C*) NAe coulomb (D) 3 NAe coulomb
27 3 9
1 1
Sol. Moles of Al3+ ions = so no. of Al3+ ions = NA
27 27
1 1
so charge on these ions = NA × 3e coulomb = NAe coulomb
27 9
10. Total number of neutrons present in 4g of heavy water (D 2O) is : (Where NA represents Avogadro's
number)
(A*) 2NA (B) 4NA (C) 1.2NA (D) 2.4NA

4 1
Sol. Moles of D2O = =
20 5
No. of neutrons in D = 1 and in oxygen = 8
So, total no. of neutrons in 1 mole D2O = 10 NA
1 1
Now, in moles D2O, no. of neutrons = 10 NA × = 2 NA
5 5
11. Four identical containers are filled with N 2(g), Ne(g), CO2(g) & NH3(g) at same pressure & temperature
respectively. Ratio of number of atoms in these container is
(A) 1 : 1 : 1 : 1 (B) 2 : 1 : 4 : 3 (C*) 2 : 1 : 3 : 4 (D) none of these
Sol. Ratio of moles N2 Ne CO2 NH3

(or molecules) 1 : 1 : 1 : 1
Ratio of atoms 2 : 1 : 3 : 4
12. 5.6 litres of gas at STP are found to have a mass of 11 g. The gram molecular mass of the gas is :
(A) 22 (B*) 44 (C) 88 (D) 32

5.6 1
Sol. moles of gas = =
22.4 4
1 11
= GMM = 44 g/mol
4 GMM
PAGE NO.-3
13. An element is found in nature in two isotopic forms with mass numbers (A–1) and (A+3). If the average
atomic mass of the element is found to be A, then the relative abundance of the heavier isotope in the
nature will be :
(A) 60% (B) 75% (C*) 25% (D) 40%
Sol. Let relative abundance of heavier isotope be x %. ekuk fd Hkkjh leLFkkfud dh vkisf{kr cgqY;rk
x% gSA
(100 − x) (A − 1) + x(A + 3)
A=
100
100 A = 100 A – xA – 100 + x + 3x + xA
4x = 100
∴ x = 25.
14. A gaseous mixture is composed of equal number of moles of CH 4, C2H6 and C2H2. The average
molecular mass of mixture (in amu) is :
(A) 36 (B) 48 (C*) 24 (D) 60

15. The minimum molar mass of a compound containing 3.2% oxygen by mass is :
(A) 1000 g (B*) 500 g (C) 2000 g (D) Cannot be determined
Min. mass of oxygen

Sol. × 100 = 3.2
Mass of compound
16
× 100 = 3.2
Mol. mass of compound
Minimum molecular mass of compound = 500 g.
16. Find the empirical formula of a compound containing Fe, S and O in mass ratio 7 : 6 : 12 :
(A) FeSO4 (B) Fe2S2O3 (C) Fe2S2O7 (D*) Fe2S3O12
Mass Moles Simplest ratio
7 1
Fe 7 = 1
56 8
Sol. 6 3 3
S 6 =
32 16 2
12 3
O 12 = 6
16 4
Whole number ratio = 2 : 3 : 12
So, Fe2S3O12
17. The density of a liquid is 1.2 g/mL. There are 35 drops in 2 mL. The number of molecules in one drop
(molar mass of liquid = 70 g/mol) is :
2
 1.2  1  1 1.2
(A)  NA (B) NA (C*) NA (D) 1.2 NA
 35  1.2  35  (35)2
PAGE NO.-4
2 2.4
Sol. Mass of one drop = × 1.2 = g
35 35
2.4 1.2
Moles of liquid in one drop = =
35 × 70 35 2
1.2
∴ Molecules = × NA
35 2
18. 3g of a hydrocarbon on combustion in excess of oxygen produces 8.8 g of CO 2 and 5.4 g of H 2O. The
data illustrates the law of :
(A*) conservation of mass (B) multiple proportions
(C) constant proportions (D) none of these
19. CO2 was collected from combustion of lime stone. The mass ratio of carbon and oxygen was found to
be 3:8. Find the mass ratio of oxygen and carbon in the CO 2 obtained by burning coke in excess
oxygen.
(A) 3 : 8 (B*) 8 : 3 (C) 12 : 32 (D) None of these
20. Which of the following is not an attribute of balanced chemical equation ?

(A) It contain equal mass of atoms on both side of equation.
(B) It contains equal number of atoms on both sides of equation.
(C) It contain equal charge on both side of equation.
(D*) None of these
PAGE NO.-5

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DPPs BOOKLET-1 VIJAY (JR01) | MATHEMATICS

TARGET : JEE (Main + Advanced)

DPP No. # A1 (JEE–ADVANCED)

Question No. 1 2 3 4 5 6 7 8 9 10 Total

2. (A) 3. (C) 4. (A) 5. (ABCD) 6. (BCD) 7. (C) 8. (A)

DPP No. # A2 (JEE–ADVANCED)

(i) y = 2x3 + 3x2 – 12x – 16

(A*) x ∈ (–∞, –3) ∪ (2, 3) (B) x ∈ (–∞, –3] ∪ (2, 3)

x ∈ (–∞, –3) ∪ (2, 3)

(A) 1 (B) 2 (C*) 3 (D) 4

(A*) 5 (B) 6 (C) 7 (D) 8

6. If the solution of x4 – 5x2 + 4 < 0 is (a, b) ∪ (c, d) then :

Sol. (x2 – 4) (x2 – 1) < 0

x ∈ (–2, –1) ∪ (1, 2)

7. If a + b + c = 0 and a2 + b2 + c2 = 1, then the value of a4 + b4 + c4 is

(A) 4 (B*) 5 (C) 6 (D) None of these

(A*) P ∩ Q = φ (B) P ∩ Q = ( − ∞ , − 9) ∪ (5, 8)

DPP No. # A2 (JEE–ADVANCED)

Question No. 1 2 3 4 5 6 7 8 9 10 Total

combining both only (A) & (C) satisfy it.

3. Values of x satisfying the equality |x2 + 8x + 7| = |x2 + 4x + 4| + |4x + 3| for x ∈ R are

| a + b | = |a| + |b| ⇒ a.b ≥ 0

4. The equation |x + 2| – |x + 1| + |x – 1| = K, x ∈ R has

for two solutions K ∈ (1, 2) ∪ (3, ∞)

(A) 120 (B) 90 (C*) 60 (D) 30

Ans. x ∈ (–∞, 1] ∪ [3, ∞)

8. Solution set of the inequality 7 – x > 2x – 3 , is contained by the set

Sol. 7–x≥0 x≤7 ........(i)

7 – x > 4x2 + 9 – 12x

positive > negative

9.. The number of solution of the equation, log( − 2x) = 2 log (x + 1) is :

Sol. log(–2x) = 2log(x + 1)

10. Solve the following inequations

TARGET : JEE (Main + Advanced)

DPP No. # A1 (JEE-ADVANCED)

1. The alicyclic compound/s is / are

(A) (B*) (C*) (D*)

2. Which of the following is/are aromatic compounds :

(A*) (B) (C*) (D*)

4. In the given compounds how many are unsaturated hydrocarbon?

(A*) (B) (C*) (D)

5. Which of the following IUPAC names of alkyl radicals is/are correct :

6._ Which of the following IUPAC name is/are correct :

7. In which of the following cyclic ring is a parent chain:

(A*) (B) (C*) (D*)

8. Which of the following has/have correct IUPAC name :

(C*) 4,6-Bis(1-methylethyl) nonane

9. How many sp2–sp σ bonds are present in the given compound.

10. How many compounds are hydrocarbon in the following?

(B) Hetrocyclic (q)

Ans. (A) → p, r, s ; (B) → p, s ; (C) → q ; (D) → p, s

14. What is the general formula of alkyl group ?

15. What is the name of following group ?

(A) Iso-Butyl (B*) Sec-Butyl (C) t-Butyl (D) n-Butyl

(A) Methyl (B) n-Propyl (C*) Iso-propyl (D) Neo-pentyl

18. How many 1° hydrogen are present in Iso-octane :

TARGET : JEE (Main + Advanced)

DPP No. : A1 (JEE-Main)

ANSWER KEY OF DPP No. : A1 (JEE-MAIN)

(A) (B) (C) (D*)

(A) (B) (C) (D*)

(A) (B) (C) (D)

(A) (B) (C) (D*)