308 - B.Sc. (Part-I) Chemistry PDF
308 - B.Sc. (Part-I) Chemistry PDF
308 - B.Sc. (Part-I) Chemistry PDF
AND
SYLLABUS
(for Academic Session 2017-2018)
Faculty of Science
UNIVERSITY OF KOTA
MBS Marg, KOTA (Rajasthan)-324 005
INDIA
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Bachelor of Science
CHEMISTRY
(Three Year Course)
SCHEME OF EXAMINATION
Page 2 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Bachelor of Science
CHEMISTRY
(Three Year Course)
Syllabus
B.Sc. (Part-I) Chemistry
Page 3 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Page 4 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Page 5 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Page 6 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Page 7 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Distribution of Marks:
• Inorganic Chemistry Experiments - 20
• Organic Chemistry Experiments - 20
• Physical Chemistry Experiments - 20
• Practical Record (for regular students only) - 05
• Viva-voce (for regular students) - 10
• Viva-voce (for non-collegiate students) - 15
Inorganic Chemistry:
Semi-micro / macro Analysis:
Anion analysis (3 radicals).
Cation analysis: Separation and identification of ions from groups I, II, III, IV, V and
VI (3 radicals). (Total 6 radicals).
Page 8 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Organic Chemistry:
Laboratory Techniques:
Section-A
• Determination of melting point
o Naphthalene 80-82oC, Benzoic acid 121.5-122 oC, Urea 132.5-
133oC,Succinic Acid 184.5-185oC, Cinnamic acid 132.5-133oC ,
Salicylic acid 157.5-158oC, Acetanilide 113.5-114 oC, m-Dinitrobenzene
90oC, p-Dichlorobenzene 52oC , Aspirin 135oC.
• Determination of boiling points
o Ethanol 78oC, Cyclohexane 81.4oC, Toluene 110.6oC, Benzene 80oC
• Determination of mixed melting point
o Urea-Cinnamic acid mixture of various compositions (1:4,1:1, 4:1)
• Distillation
o Simple distillation of ethanol-water, using water condenser
o Distillation of nitrobenzene and aniline using air condenser
• Crystallization
o Concept of induction of crystallization
o Phthalic acid from hot water (using fluted filter paper and stemless
funnel)
o Acetanilide from boiling water.
o Napthelene from Ethanol.
o Benzoic acid from water.
• Decolorisation and crystallization using charcoal
o Decolorisation of brown sugar (sucrose) with animal charcoal using
gravity filtration.
o Crystallization and decolorisation of impure naphthalene (100g of
naphthalene mixed with 0.3g. of Congo Red using l.0g decolorising
carbon) from ethanol.
• Sublimation (Simple and vacuum)
o Camphor, Naphthalene, Phthalic acid and Succinic acid.
Section-B
• Qualitative Analysis:
Detection of extra elements (N, S and halogens) and functional groups
(phenolic, caboxylic, carbonyl, ester, carbohydrates, amine, amide, nitro
and anilide) in simple organic compounds.
Physical Chemistry:
Chemical Kinetics
• To determine the specific reaction rate of the hydrolysis of methyl acetate / ethyl
acetate catalyzed by hydrogen ions at room temperature.
• To study the effect of acid strength on the hydrolysis of an ester.
• To compare the strengths of HCl and H2SO4 by studying the kinetics of
hydrolysis of ethyl-acetate.
• To study kinetically the reaction of decomposition of iodide by H2O2
Distribution Law
• To study the distribution of iodine between water and CCl4
• To study the distribution of benzoic acid between benzene and water.
Page 9 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
Colloids
• To prepare arsenious sulphide sol and compare the precipitating power of
mono-, bi- and trivalent anions.
Viscosity, Surface Tension
• To determine the percentage composition of a given, mixture (non interacting
systems) by viscosity method.
• To determine the viscosity of Amyl alcohol in water at different concentrations
and calculate the viscosity of these solutions.
• To determine the percentage composition of a given binary mixture by surface
tension method (acetone & ethyl-ketone).
Books suggested :
1. Practical Chemistry: Giri Bajpai and Pandey, S. Chand & Co. Ltd., New Delhi
Page 10 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
ijh{kk&;kstuk
,oa
ikB~;Øe
¼vdknfed&l= 2017&2018½
foKku ladk;
d¨Vk fo'ofo|ky;
,e-ch-,l- ekxZ] d¨Vk ¼jktLFkku½&324005
Page 11 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
foKku Lukrd
jlk;u'kkL=
¼f=o"khZ; ikB~;Øe½
ijh{kk&;kstuk
Page 12 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
foKku Lukrd
jlk;u'kkL=
¼f=o"khZ; ikB~;Øe½
ikB~;Øe
ch-,llh- ¼Hkkx&izFke½ jlk;u'kkL=
iz'ui=&I ¼CH-101½% vdkcZfud jlk;u
vkofrZrk xq.k%
ijek.kq ,oa vk;fud f=T;k,a] vk;uu ÅtkZ] bysDVªkWu ca/kqrk ,oa fo|qr
_.kkRedrk&ifjHkk"kk ekiu vFkok Kkr djus dh fof/k;k¡] vkorhZ lkj.kh esa jklk;fud
xq.k/keZ ,oa jklk;fud O;ogkj dh ifjdYiuk o O;k[;kv¨a esa mi;¨fxrkA
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Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
p-[k.M ds rRo%
13&17 lewg rRoksa (fod.kZ lEcU/k lfgr½ dk rqyukRed v/;;u] 13&16 lewg ds
gkbMªkbMks]a vkWDlkbMksa vEyksa ,oa gSykbM~l ds ;kSfxdksa dk Hkh v/;;uA
Page 14 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
[k.M v % bl [k.M esa ,d vfuok;Z iz'u ftlesa izR;sd bdkbZ ls 02 y?kq iz'u ysrs gq,
dqy 10 y?kq iz'u gksxa As izR;sd y?kq iz'u dk mÙkj yxHkx 20 'kCnksa esa gksA
dqy vad % 05
[k.M c % bl [k.M esa izR;sd bdkbZ ls 02 iz'u ysrs gq, dqy 10 iz'u gksxsa As izR;sd
bdkbZ ls ,d iz'u dk p;u djrs gq, dqy 05 iz'uksa ds mÙkj nsus gksxa As izR;sd
iz'u dk mÙkj yxHkx 250 'kCnksa esa gksA
dqy vad % 25
[k.M l % bl [k.M esa 04 iz'u o.kZukREkd gksxa s ¼iz'u esa Hkkx Hkh gks ldrs gS½ tks lHkh
bdkbZ;ksa esa ls fn, tkosxa ]s fdUrq ,d bdkbZ ls ,d ls vf/kd iz'u ugha gksxkA
nks iz'uksa ds mÙkj fn;s tkus gSAa izR;sd iz'u dk mÙkj yxHkx 500 'kCnksa esa gksA
dqy vad % 20
bdkbZ&I lajpuk ,oa vkca/ku%
ladj.k] cU/k yEckbZ ,oa ca/k dks.k] ca/k ÅtkZ] LFkkuhd`r ,oa foLFkkuhd`r jlk;fud ca/k]
okUMj oky vU;ksU; fØ;k] lefo"V ;kSfxd] DySFkzsV ;kSfxd] vkos'k LFkkukUrj.k ladqy]
vuqukn] vfrla;qXeu] izsjf.kd ,oa {ks= izHkko] gkbMªkstu ca/kuA
vfHkfØ;k e/;orhZ%
dkcZ/kuk;u] dkcZ_.kk;u] eqDr ewyd] dkchZu] ,jhu ,oa ukbVªhu (mnkgj.k lfgr½A
e/;orhZ o vU; vk;fud Lih'kht ij fu;efu"B ¼vkSipkfjd½ vkos'k dk fu;ruA
fØ;kfof/k fu/kkZj.k dh fof/k;k¡ ¼mRikn fo'ys"k.k] e/;orhZ] leLFkkfud izHkko] cyxfrdh
,oa f=foeh; jklk;fud v/;;u½A
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Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
pØh; ,YdsUl%
ukedj.k] cukus dh fof/k;k¡] jklk;fud vfHkfØ;k,a] cs;j dk fod`frokn fl)kUr ,oa
mldh lhek;sAa NksVh oy;ksa esa oy; fod`fr ¼pØh; izksisu ,oa pØh; C;wVsu½] fod`fr
jfgr oy;ksa dk fl)kUrA pØh;izksisu dk fooj.k¢ dnyh ca/kA
Page 17 of 21
Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
lax.kd (Computers):
lax.kdksa dk lkekU; ifjp;] lax.kd ds vyx&vyx Hkkx] gkMZos;j ,oa lkW¶Vos;jA
vkjksfir&fuxZfer ;qfDr;k¡] f}&la[;k,a ,oa vadxf.kr] lax.kdksa dh Hkk"kkvksa dk ifjp;A
izkØeu] izpkyu ra=A
bdkbZ&III æo voLFkk%
varjk&v.kqd cy] æoksa dh lajpuk,sa ¼xq.kkRed o.kZu½A Bkslks]a æoksa o xSlksa ds e/;
lajpukRed varjA
æo fØLVy% æo fØLVy] Bksl ,oa æo esa varjA lqf=y ,oa dksfyfLVªd voLFkkv¨a dh
lajpuk ,oa oxhZdj.kA Å"ekys[ku ,oa lIr&[k.M lsyA
dksykWbMh voLFkk%
dksykWbMksa dh ifjHkk"kk] dksykWbMksa dk oxhZdj.kA Bksl dk æo¨a esa dksykWbMh foy;u
¼lksy½% xfrt] izdk'kdh; ,oa oS|qr xq.k/keZ] dksykWbMksa dk LFkkf;RoA j{kd fØ;k]
gkMhZ&'kqYt fu;e] Lo.kkaZadA æoksa dk æoksa esa dksykWbMh foy;u (ik;l)% ik;lksa ds
izdkj] cukus dh fofèk;k¡] ik;lhdkjdA Bkslksa esa æo dksykWbMh foy;u ¼tSy½% oxhZdj.k]
cukus dh fof/k;k¡ ,oa xq.k/keZA fujksèk] dksykWbMksa ds lkekU; mi;ksxA
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Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
vdkcZfud jlk;u%
lw{e&va'k@LFkwy fo'ys"k.k
_.kk;u fo'ys"k.k ¼a3 ewyd½A
/kuk;u fo'ys"k.k% lewg I, II, III, IV, V ,oa VI lewg ds vk;uksa dk i`FkDdj.k ,oa
fo'ys"k.k ¼a3 ewyd½A dqy 6 ewyd
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Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
dkcZfud jlk;u%
iz;ksx'kkyk fof/k;kWa%
Hkkx&v
• xyukad ekiu%
o uS¶Fkyhu 80&820C] csUtkWbd vEy 121-5&1220C] ;wfj;k 132-5&1330C]
lfDlfud vEy 184-5&1850C] flUusfed vEy 132-5&1330C]
lsfyflfyd vEy 157-5&1580C] ,lhVSfuykbM 113-5&1140C]
0 0 0
m&MkbukbVªkscsUthu 90 C] p&MkbDyksjkscsUthu 52 C] ,sfLifju 132 CA
• DFkukad ekiu%
o ,FksukWy 780C] lkbDyksgSDlsu 81-40C, VkWywbu 110-60C] csUthu 800CA
• feJ xyukad ekiu%
o ;wfj;k&flusfed vEy ds vyx&vyx la?kVd (1:4,1:1, 4:1) ds feJ.kA
• vklou%
o ty la?kfu= ds }kjk ,FksukWy&ty feJ.k dk ljy vklouA
o ok;q la?kfu= ds }kjk ukbVªkscsUthu ,oa ,sfuyhu feJ.k dk vklouA
• fØLVyhdj.k%
o fØLVyhdj.k dh foisjz .kk ladYiuk
o xeZ ty }kjk FkSfyd vEy (rSjrs gq, NUuk i= o ruk jfgr dhi dks
dke esa ysdj)
o mcyrs gq, ty ls ,lhVsfuykbM
o ,FksukWy ls us¶Fkyhu
o ty ls cSUtkWbd vEyA
• pkjdksy ds mi;ksx }kjk fojatu ,oa fØLVyhdj.k%
o xq:Ro Nfu= fof/k }kjk tUrq pkjdksy dh enn ls Hkwjh 'kdZjk dk
fojatuA
o ,FksukWy }kjk v'kq) uS¶Fkyhu (1xzke fojaftr dkcZu ds iz;ksx ls 0-3xzke
dkaxksjsM ;qDr uS¶Fkyhu½ dk fojatu ,oa fØLVyhdj.kA
• m/oZikru ¼ljy ,oa fuokZr½%
o diwj] uS¶Fkyhu] FkSfyd vEy ,oa lDlhfud vEyA
Hkkx&c
xq.kkRed fo'ys"k.k%
ljy dkcZfud ;kSfxdkas esa vfrfjDr rRoksa (N, S o gSykstuks)a fØ;kRed lewgksa
(QhukWfyd] dkcksZfDlfyd] dkcksZfuy] ,LVj] dkcksZgkbMªsV] ,ehUl] ,ekbM] ukbVªks o
,fuykbM½ dh igpkuA
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Syllabus: B.Sc. (Part-I) Chemistry
University of Kota, Kota (Rajasthan)
for the Academic Session 2017-2018
HkkSfrd jlk;u%
jlk;u cyxfrdh%
• d{k rki ij esfFky ,slhVsV@,fFky ,lhVsV dk gkbMªkts u vk;u dh mifLFkfr esa
ty&vi?kVu dh fof'k"V vfHkfØ;k osx dk ekiuA
• ,LVj ds ty&vi?kVu ij vEy lkeF;Z ds izHkko dk v/;;u A
• ,fFky ,lhVsV ds ty vi?kVu dh njksa ij HCl o H2SO4 dh izcyrk dh
rqyukA
• H2O2 }kjk vk;ksMkbM ds fo?kVu dh vfHkfØ;k dh nj dk jlk;fud cyxfrdh
v/;;uA
forj.k dk fu;e%
• ty ,oa CCl4 ds e/; l2 ds forj.k dk v/;;uA
• ty ,oa csUthu ds e/; csUtkbd vEy ds forj.k dk v/;;u A
dksykbM~l%
• vkflZfu;l lYQkbM lkWy dk cukuk ,oa ,dy&] f}&] f=la;ksth _.kk;uksa dh
vo{ksi.k {kerk dh rqyuk djukA
';kurk] i`"B&ruko%
• ';kurk ekiu fof/k }kjk fn, x, feJ.k ¼vfØ;k'khy ra=½ dk izfr'kr la?kVu
dk ekiuA
• fofHkUu lkanzrkvksa ij ,fey ,YdksgkWy dh ty esa ';kurkvksa dk ekiu ,oa bu
foy;uksa dh vf/k&';kurkvksa dh x.kukA
• i`"B&ruko fof/k }kjk fn, x, fnvaxh feJ.k ds izfr'kr la?kVu dk ekiu
¼,lhVksu ,oa ,fFky feFkkby dhVksu½A
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