Fiitjee: JEE (Main) - 2018

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1 AITS-FT-VIII-PCM (Sol.)-JEE(Main)/18
FIITJEE JEE(Main)-2018
ANSWERS, HINTS & SOLUTIONS
FULL TEST – VIII
(Main)
Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

ALL INDIA TEST SERIES
1. C 31. C 61. C
2. B 32. B 62. C
3. D 33. B 63. D
4. C 34. C 64. B
5. D 35. B 65. D
6. D 36. C 66. A
7. B 37. B 67. C
8. C 38. B 68. C
9. D 39. B 69. C
10. A 40. A 70. C
11. C 41. A 71. C
12. D 42. A 72. C
13. B 43. B 73. B
14. A 44. A 74. B
15. D 45. B 75. A
16. A 46. A 76. A
17. C 47. B 77. C
18. D 48. B 78. B
19. B 49. A 79. A
20. C 50. B 80. D
21. A 51. C 81. A
22. D 52. A 82. C
23. B 53. B 83. C
24. C 54. C 84. B
25. D 55. C 85. C
26. C 56. C 86. B
27. A 57. D 87. B
28. C 58. C 88. C
29. C 59. A 89. B
30. D 60. C 90. B
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AITS-FT-VIII-PCM (Sol.)-JEE(Main)/18 2
Physics PART – I
SECTION – A
v1 27
1. 
v2 8
m1 8
So,  (from conservation of momentum)
m2 27
r  A1/3
1/3
r1  8  2
  
r2  27  3
D (1   2 )t  D
2. 7 
d d
t = 9.1 m
3. dp = dq (2R cos )
= (3R cos  d) (2R cos ) dq +dq
p  dp  48   104 Coulomb-meter


4. In absorption spectrum electrons jumps from ground state to higher excited state.
1
5. E
n2
r  n2
1
p
n
Ln
1  4  1 1 
6. u = + 15,  1  
f  3 
  10 
1 1 1
 
v u f
1 1 1
 
v 15 30
v = 30 cm
JEEMAIN.GURU
7. path difference = (SS1 + S1O)  SO

d2
 2 D2  d2  2D 
D S1
2
d d
 n
D
S S2 O
d  D (n = 1)
D D
40
8. Current through battery = = 8 amp
5
1
Current in branch CD = amp
2
iCD 1/ 2 1
So,  
iAF 8 16
0Nir 2
9. B1 
2(r 2  h2 )3/2
 Ni
B2  0
2r
10. Let plank is slight displacement a distance x.

32
Fr  kx
3
32k
a x
3m
32k

3m
11. Tmin = mg cos 0 …(i)

Tmin
mv 2 0
Tmax  mg  …(ii)
R Tmax
1
mv 2  mg R  Rcos )  …(iii)
2 mg
v
Tmax
4
Tmin
 1
0 = cos1  
 2
12. Process PQ is isochoric

Process QR is isothermal
For process RP;
1
V
T
VT = constant
JEEMAIN.GURU
 di 
13. 2  L 1   i2R
 dt 
i q
2L 0 e t/ 1  R  0 e  t/ 2
1 2
t

2e t / 1  e 2
n2
t
2R 1

L RC
14. q = 6e2t
iC = 12 e2t
iL = i1 + i2 + iC
iL = 4  2e2t
V
15. i
Z
200 2
4
(50)2  R2
R = 50 
VR = i  R = 200 V
 I 
16. 20  10log10  12 
 10 
I  10 10 W/m2 …(i)
B
v  200 m/s …(ii)

 Pmax 2  2Iv
Pmax  2  10 4 N/m2 …(iii)
 5 1
K  m ….(iv)
v 2
Pmax = BAK
A = 2  109 m ….(v)
 eq 1  2
17.  
Req R1 R2
 eq  4
 
800 / 3 400 800
 eq  2
 qin
18.  E  ds   0
0
Hence, qin = 0
So, charge inside the surface must be zero.
JEEMAIN.GURU
3
19. from 0 to 4 sec, e1   Volt
2
from 4 to 6 sec, e2 = +4 Volt
eav 
 edt
 dt
3
|   4  42 |
2 1
| eav |  Volt
6 3
20. v = LT1
G = M1L3T2
h = ML2T1
v 1
So, 
h ML
G 1
and 2  3
h ML
Hence, L = G1/2, h1/2, v3/2
21. Displacement of point where force is applied

4 4
 
sin30 sin 45

 4 2  2 meter 

So work done = 80 2  2 Joule 
22. r 2  b2  a2 e2 …(1) A
b 2  a 2 1  e 2  …(2)
b r
From equation (1) & (2)
r=a B D
Now from conservation of energy ae
GMm 1 GMm
  mv 2 
2a 2 a C
GM
v
a
3 2 2
v
23. ucos   v   ucos  
5
ucos
2 2 3 u ucos H
u cos 2   v 2 …(1)
5 5
1  u2 sin2  
v 2  u2 sin2   2g  
3  2g 
2
v 2  u2 sin2  …(2)
3
JEEMAIN.GURU
24. 2 10cos 60    2  2  v 0
5
v0  m/s …(1)
2
5
4   4  16  v
2
1
v  m/s …(2)
2
Now from conservation of energy
2 2
1 5 1  1
 4     4  16     4  10  11  cos  
2 2 2 2
3
cos  
4
3
  cos1  
 4
25. F0cos t  kA cos t = mA2 cos t

F0
 A=
k  m2
26. Heat produced  r2 but change in temperature  r
27. Gravitation potential due to disc is

2Gm
V =  2 ( R2  2  )
R
Gmm
So, Ui   (R<<)

2Gmm
Uf   (  0)
R
 2 1
U  Ui  Uf  Gmm   
R  
1 1  2 1
mv 2  mv 2  Gmm   
2 2 R  
 2 1
v  Gm   
R  
So, relative velocity
 2 1
vR  2v  4Gm   
R 
28. log P = m log V + C …(i)

Where C is constant and m is slope
 5.38  5.10 
m   1.4
 3.10  3.30 
So, from (i) PV1.4 = K (constant)
JEEMAIN.GURU
R
29. H  L 
L
H  L  02
 R  750 
1 1 106
0  L   16.67H
LC 2C 10 4  6
30. Output will be
JEEMAIN.GURU
Chemistry PART – II
SECTION – A
31. The direction of dipole moment in the molecules given in the question is
NH2
H C C Cl
, ,
O
32. Pd belongs to 5th period and 10th group.
33. Highest energy electrons having n = 5 can lie in 5g sub-shell.

 Electronic configuration of element can be
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f 14 5s2 5p6 5d10 5f14 5g18 6s2 6p6 6d10 7s2 7p6 8s2
 Maximum number of electrons can be 138.
34.   iCST
74.4
 2  C  0.0821 298
760
74.4
C
760  2  0.0821 298
74.4
C  2  103 mol L1
37188.016
Ksp (MX) = s2 = (2 × 10-3)2 = 4 × 10-6
35. (A) If x = 3, y = 0, then complex is [Fe(Ox)3]–3 . This complex will show optical isomerism, not
geometrical isomerism.
(B) If x = 1, y = 4, then complex is [Fe(Ox) (H2O)4]+1. This complex neither shows geometrical nor
optical.
(C) If x = 2, y = 2, then the complex is [Fe(Ox)2 (H2O)2]–1. This complex can show geometrical
and optical isomerism both.
(D) If x = 3 and y = 0, then complex will be [Fe(Ox)3]–3.
36. Three nucleotides are required to code each amino acid present in the chain. Therefore, chain
having 21 amino acids will require 63 nucleotides to code the chain.
38. (i) PF3 has greater bond angle due to back bonding.
(ii) LiCl has greater solubility in water due to its higher hydration enthalpy.
(iii) F – F is weaker bond due to lone pair – lone pair repulsion.
(iv)  egH order is : S > Se > O.
39. Xe has highest boiling point among the options given.
40. Correct statements are: a, b, d, f, g
41. Second order rate law for the reaction is

1 1
r  K  A  B 
Since B is in excess, therefore new rate law for pseudo first order reaction becomes
JEEMAIN.GURU
1
r  K1  A  Here K1  K  B1 
 
Now applying integrated equation for pseudo first order reaction
K1 
2.303 A 
log10 0
t A
2.303 0.1
5  103  6  log10
100 A 
3  102  100 0.1
 log10
2.303 A 
0.1
1.302  log10
A
Taking antilogarithm
0.1
20 
A 
0.1
A   5  10 3 M
20
43. B is correct option.

dz2 will be the highest energy orbital followed by dxy = dyz.
44. B2H6  6H2 O  2H3BO3  3H2

1
1g B 2H6  mole  0.0357 mole B2H6
28
 Moles of H3BO3 produced = 0.0714 moles.
H3BO3 is a weak monobasic acid.
7.3  1010  0.0714
H   K a1  C 
0.1
 0.521 10 9  5.21 10 10
= 2.28 × 10-5
Now pH = - log10 228 × 10-7
= 7 – log10 228
= 7 – 2.357
= 4.64
45. MnO 4 , Ce 4 ,Cr2 O72 ,CrO 42 ,HNO3 ,F2 are very good oxidizing agents.
46. Pseudo chiral C
H3C CH CH CH CH CH CH3
OH
JEEMAIN.GURU
Z, Z E, E Z, E
d 
Thus, four stereoisomers are possible in total.
47. (I) is least reactive as C – Br bond acquires partial double bond character due to resonance. (II) is
most reactive as it is allylic halide.
48. H O
HO
3
HO S S 1 H
4 H 2 OH
Both the chiral carbon have S, S-configuration. Therefore, correct option is B in which both the
chiral carbon also have S, S-configuration.
49.
HO
H 

Et migrate
H
H


JEEMAIN.GURU
50. (A)
CH CH2 Br2
  Ph CH CH2
Br Br
NaNH2  2 mole 
Ph C CH
H2 O, H2 SO 4 / HgSO4
Ph C CH3
O
(B)
i B2H6
CH CH2 
ii H2O2 /OH
 Ph CH2 CH2 OH
PCC / CH2 Cl2
Ph  CH2  CHO
(C) H O/H SO
2 2 4
CH CH2   CH CrO3 /H2 SO4
CH3   C CH3
OH
O
(D) OH
3 CH COOOH
Ph  CH  CH2  Ph HC CH2 
H2O/NaOH
 Ph CH CH2
O
OH
51. HCOOH, HCHO, CH3  CH2  C  CH2 OH , H3PO2 give silver mirror test.
||
O
CH3  C  CH reacts with Ammonical silver nitrate but does not give metallic silver.
52. (i) Decolourize bromine in CCl4]  Evidence of presence of multiple bond.

(ii) Absorbed hydrogen catalytically]  Evidence of presence of multiple bond.
(iii) Gives precipitate with ammonical cuprous chloride]  Evidence of terminal alkyne.
(iv) 448 mL = 1. 49 g
1.49
22400 mL =  22400  74.5 g (molar mass)
448
 Option (A) is correct.
53. (II), (V), (VI), (VIII), (IX) and (X) are antiseptic.
54. Nylon-6 is a condensation homopolymer.

Nylon-6,6 is a condensation heteropolymer.
Bakelite is a condensation heteropolymer.
PMMA is an addition polymer.
55. Diborane shows unsymmetrical Cleavage with NH3.
56. Ce+3 is more stable than Ce+4.
57. Ni(NO3)2 solution is electrolysed by using Ni electrode. Therefore, no change in molarity of

solution after electrolysis.
JEEMAIN.GURU
58. Order of acidic strength of conjugate acid of species given in question


HI > H2S > NH4 > R  NH3
 Proton accepting tendency of conjugate bases will be

R  NH2  NH3  SH  I
59. - I effect of – OMe group at m-position decreases stability of diazonium ion and hence increases
its reactivity.
60. Propanone gives iodoform test, propanal does not.

H3C C O  H2 CH C CH H2  O C CH3 
HCl

CH3 O CH3
H3 C C CH C CH C CH3  2,6  dim ethyl  2,5  heptadien  4  one 

CH3 O CH3
JEEMAIN.GURU
Mathematics PART – III
SECTION – A
61. yn – 1 = (y – 1)(y – 1)(y – 2) ..... (y – n – 1)

yn  1
   y  1  y   2  .....  y   n1 
y 1
 1 + y + y2 + ..... + yn – 1 = (y – 1)(y – 2) ..... (y – n – 1)
Putting y = 1
 (1 – 1)(1 – 2) ..... (1 – n – 1) = n
z3  z1
62.  i
z3  z2
|z3 – z1| = |z3 – z2|
 z  z1  
Also arg  3 
 z3  z 2  2
 Angle at vertex z3 is 90º
63. If exactly one negative then the value of expression is 1

If exactly two negative then value of expression is –1
If all three negative then value of expression is –3
If all three positive then value of expression is 3
64. |P| |Q| |R| = 3

3
|Q| =
4
65. cos2  + p + sin2  + p = –4

5
p
2
61
(cos2  + p)(sin2  + p) =
16
1
sin2  cos2  
16
x2 – (tan2  + cot2 )x + tan2  cot2  = 0
Required equation x2 – 14x + 1 = 0
66.  +  = –p,  = +q
 ,  are the roots of the equation x 2n + pnxn + qn = 0
 n, n are the roots of the quadratic equation y2 + pny + qn = 0
n + n = –pn, nn = qn
n
 
1  

f   


    n   p n  1
 n  n  n pn
1 n

JEEMAIN.GURU
8 A
67. tan  
x
18
tan  90º    cot   C 90º – 
x P
26 feet x 
x 18

8 x 8 feet
x = 12

B Q
x
1
68. sin2  
2
i.e.,  = 105º, 165º, 285º, 345º
69. Let a and b be roots of x 2 – 7x + 8 = 0 then a + b = 7 and ab = 8 and C = 60º

a2 + b2 = (a + b)2 – 2ab = 49 – 16 = 33
a2  b2  c 2
cosC 
2ab
2
1 33  c

2 16
c2 = 33 – 8 = 25  c = 5
abc 85 5
r.R   
2  a  b  c  2  12 3
70. AM  G.M.
 8  8  1  1  1  1  1  1 1/8
8
 88 
 8  8  6  8
Which is possible only if 8 = 8 = 1
  = 1 and  = 1
4000
1 1  1 1   1 1  1 1 
71.  pp          .....  
d  p1 p2   p2 p3 
    10
i 1 i i 1  p4000 p4001  
p4001  p1 4000 d
 10   10  p1 p4001 = 400 and p1 + p4001 = 50
d  p1  p4001  d  p1  p4001 
|p1 – p4001| = 30
72. R  b  c   a bc  2R sin A bc
bc
sin A 
2 bc
bc
Now sin A  1  1
2 bc
2
 b c  0 b=c

sin A = 1  A = and b = c
2
Hence, triangle is right angled isosceles triangle
JEEMAIN.GURU
73. 21 + 22 + 33 – 1 = 0

21 + 22 + 33 = 1
 21  2 2  33  4  4  9 12   22   32
1
12   22  32 
17
74. Any point on the first line is P(3r1 + 1, r1 + 2, 2r1 + 3) and on second line is
Q  r2  3, 2r2  1, 3r2  2  P and Q represent the same point if r1 = r2 = 1 and the point of
intersection of the given lines is P(4, 3, 5), the planes given is (A), (B), (C) and (D) all passes
through P the plane at greatest distance is one which is at a distance equal to OP from the origin
is 42  32  52  50 which is satisfies by the plane (B)
75. By the change of origin there is no change in the variance but by the change of scale. New
variance ||2 2 here || = 2
7
76. C4(2)4(–1)3
77. Equation of director circle of x 2 + y2 = 25 is x2 + y2 = 50


k  5 2,  5  5, 5 2   
78. Given below
q ~q p ~p ~q  p p  ~p (~q  p)  (p  ~p)
T F T F F T T
T F F T F T T
F T T F T T T
F T F T F T T
79. Let the number of elements in set P, Q, R, S be p, q, r, s respectively now to find positive integral
solutions of p + q + r + s = 12, p, q, r, s > 0 and p < q
 Total ways = 70
80. Equation of tangent to y2 = 4x at (4, 4) is x – 2y + 4 = 0

Let the other point of intersection is (t2, 2t)
 Equation of ellipse is (2x – y – 4)(2x – (t + 2)y + 4t)) + (x – 2y + 4)(2x – (t – 1)y – 2t) = 0
Since axes parallel to coordinate axes
 Coefficient of xy = 0  t = –3
2 2
81. a 2
 3a  3   a 2
 7a  13 
 20(a2 + 2a – 8)(a – 1) < 0
 (a + 4)(a – 2)(a – 1) < 0
 a  (–, –4)  (1, 2)
1
Probability =
11
82. As 2q = p + r  p and r both are even or both are odd

If p and r both odd then number of ways = 2·5C2
If p and r both even then number of ways = 2·4C2 + 4C1
 Total ways = 36
JEEMAIN.GURU
83. On adding all equation a + b + c = 6.4

Now subtracting one by one all three equation, we get a = 2, b = 1.3, c = 3.1
84. xf(x) + 2f(x) = 3x

1
2  dx
I.F. = e x  x 2
x2f(x) = c + x3
c=0
f(x) = x
f(3) = 3
1
1004
85. Let I1   t1004 1  t  dt
0
1
1004
I2   t1004 1  t 2010  dt
0
1005
Put t = u  1005t1004 dt = du
1
1 1004
= 
1005 0
1  u2  du 
a a
Using property  f  x  dx   f  a  x  dx
0 0
1
1 1004
= u1004  2  u  du
1005 0
Put u = 2v
g x 
86. Let g(x) = ax 2 + bx + c then g(3) = 9, and lim 7
x 2 x2
3 1 3
87. lim f  t   and lim g  t   ; lim f  t   g  t  
t  2 t  2 t  4
n n 1 1 r
Cr r 2 2
 n
n x 
88. lim
n 
 n r  x dx =  x  nlim

 Cr  
n
 dx

r 0 0 0  r 0 
1 n 1
  x  2
= x
2
 lim 1    dx = x ex dx  e  2
 n  n  
0   0
1
89. 2
 
1  sin cos 1 x
1
 sin  cos x   1
2
3
 x
2
90. Let P(5 cos , 4 sin )
PN = 4 sin   AN = 5 – 5 cos 
 AN = 5 + 5 cos 
PN2 16 sin2  16
  
AN  A N 25 1  cos2  25  
JEEMAIN.GURU

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Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

7. path difference = (SS1 + S1O)  SO

10. Let plank is slight displacement a distance x.

11. Tmin = mg cos 0 …(i)

12. Process PQ is isochoric

21. Displacement of point where force is applied

25. F0cos t  kA cos t = mA2 cos t

26. Heat produced  r2 but change in temperature  r

27. Gravitation potential due to disc is

28. log P = m log V + C …(i)

30. Output will be

32. Pd belongs to 5th period and 10th group.

33. Highest energy electrons having n = 5 can lie in 5g sub-shell.

39. Xe has highest boiling point among the options given.

40. Correct statements are: a, b, d, f, g

41. Second order rate law for the reaction is

43. B is correct option.

44. B2H6  6H2 O  2H3BO3  3H2

46. Pseudo chiral C

PCC / CH2 Cl2

52. (i) Decolourize bromine in CCl4]  Evidence of presence of multiple bond.

54. Nylon-6 is a condensation homopolymer.

55. Diborane shows unsymmetrical Cleavage with NH3.

56. Ce+3 is more stable than Ce+4.

57. Ni(NO3)2 solution is electrolysed by using Ni electrode. Therefore, no change in molarity of

58. Order of acidic strength of conjugate acid of species given in question

60. Propanone gives iodoform test, propanal does not.

H3 C C CH C CH C CH3  2,6  dim ethyl  2,5  heptadien  4  one 

Mathematics PART – III

61. yn – 1 = (y – 1)(y – 1)(y – 2) ..... (y – n – 1)

63. If exactly one negative then the value of expression is 1

64. |P| |Q| |R| = 3

65. cos2  + p + sin2  + p = –4

69. Let a and b be roots of x 2 – 7x + 8 = 0 then a + b = 7 and ab = 8 and C = 60º

73. 21 + 22 + 33 – 1 = 0

77. Equation of director circle of x 2 + y2 = 25 is x2 + y2 = 50

80. Equation of tangent to y2 = 4x at (4, 4) is x – 2y + 4 = 0

82. As 2q = p + r  p and r both are even or both are odd

83. On adding all equation a + b + c = 6.4

84. xf(x) + 2f(x) = 3x

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