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    Material Safety Data Sheet: 1. Chemical Product and Company Identification

    Uploaded by

    Kun Adi Reksatama
    MSDS ASF5

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Material Safety Data Sheet: 1. Chemical Product and Company Identification

    Uploaded by

    Kun Adi Reksatama
    88 views7 pages
    MSDS ASF5

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    ASF5

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    © © All Rights Reserved

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    MSDS ASF5

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    88 views7 pages

    Material Safety Data Sheet: 1. Chemical Product and Company Identification

    Uploaded by

    Kun Adi Reksatama
    MSDS ASF5

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 7

    Page 1 of 7

    MATERIAL SAFETY DATA SHEET

    1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

    MATHESON TRI-GAS, INC. Emergency Contact:


    150 Allen Road Suite 302 CHEMTREC 1-800-424-9300
    Basking Ridge, New Jersey 07920 Calls Originating Outside the US:
    Information: 1-800-416-2505 703-527-3887 (Collect Calls Accepted)

    SUBSTANCE: SDS® 2 ARSENIC PENTAFLUORIDE

    TRADE NAMES/SYNONYMS:
    ARSORANE, PENTAFLUORO-; ARSENIC FLUORIDE (ASF5); ARSENIC FLUORIDE; ASF5;
    00223860

    CREATION DATE: Sep 21 1999


    REVISION DATE: Dec 11 2008

    2. COMPOSITION, INFORMATION ON INGREDIENTS

    COMPONENT: ARSENIC PENTAFLUORIDE


    CAS NUMBER: 7784-36-3
    PERCENTAGE: 15

    COMPONENT: PROPRIETARY SORBENT (PROPRIETARY CARBON MEDIA)


    CAS NUMBER: Not assigned.
    PERCENTAGE: 85

    3. HAZARDS IDENTIFICATION

    NFPA RATINGS (SCALE 0-4): HEALTH=3 FIRE=0 REACTIVITY=1

    EMERGENCY OVERVIEW:
    COLOR: colorless
    PHYSICAL FORM: Solid proprietary carbon beads and toxic gas contained within a sealed
    stainless steel cylinder.
    MAJOR HEALTH HAZARDS: TOXIC GAS. If the stainless steel cylinder is opened, heated or otherwise
    tampered with, release of gas may occur. Gas reacts with water vapor in air to form other corrosive, toxic
    substances (hydrofluoric acid gas)., cancer hazard (in humans)

    POTENTIAL HEALTH EFFECTS:


    Page 2 of 7
    INHALATION:
    SHORT TERM EXPOSURE: burns, vomiting, digestive disorders, chest pain, difficulty breathing,
    headache, bluish skin color, lung congestion
    LONG TERM EXPOSURE: burns, nerve damage, cancer
    SKIN CONTACT:
    SHORT TERM EXPOSURE: burns, blisters, frostbite
    LONG TERM EXPOSURE: same as effects reported in short term exposure
    EYE CONTACT:
    SHORT TERM EXPOSURE: burns, frostbite, itching, tearing, blurred vision
    LONG TERM EXPOSURE: same as effects reported in short term exposure
    INGESTION:
    SHORT TERM EXPOSURE: ingestion of harmful amounts is unlikely
    LONG TERM EXPOSURE: ingestion of harmful amounts is unlikely

    4. FIRST AID MEASURES

    INHALATION: If gas is inhaled, move victim to fresh air. If breathing has stopped, give artificial
    respiration. If breathing is weak, give oxygen. Get medical attention without delay.

    SKIN CONTACT: If this chemical contacts the skin, immediately flush the contaminated skin with soap
    and water. If clothing is contaminated, immediately remove and flush the skin with soap and water. Get
    medical attention promptly. Assume victim has also been exposed by inhalation. Treat as HF exposure.
    Consider the use of calcium gluconate.

    EYE CONTACT: In case of eye contact, immediately flush eyes with plenty of water for at least 30 minutes,
    occasionally lifting the lower and upper lids. Get medical attention immediately.

    INGESTION: Ingestion is not a route of exposure.

    5. FIRE FIGHTING MEASURES

    FIRE AND EXPLOSION HAZARDS: Heating of cylinder beyond pressure relief.

    FIRE FIGHTING: Wear self-contained breathing apparatus with full face shield and protective clothing.
    Apply cooling water to sides of container exposed to flame until well after fire is out. Isolate area until gas
    has dispersed.

    FLASH POINT: nonflammable gas

    6. ACCIDENTAL RELEASE MEASURES

    WATER RELEASE:
    Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of
    Page 3 of 7
    water supplies and sewers.

    OCCUPATIONAL RELEASE:
    Isolate area until gas has dispersed. Use appropriate protective equipment including self-contained breathing
    apparatus. Be certain to flush lines and enclosures with inert gas before repairing.

    7. HANDLING AND STORAGE

    STORAGE: Store and handle in accordance with all current regulations and standards. Protect from
    physical damage. Store in a cool, dry, well ventilated area of non-combustible construction. Protect cylinders
    from direct sunlight, mechanical damage and temperatures above 55 C. Keep away from cylinders of oxygen
    or other highly oxidizing or flammable materials. Ship and store cylinders with outlet plug and valve
    protective cap in place.

    HANDLING: Handle this material only in a sealed, purged system. Do not heat cylinder by any means to
    increase discharge rate of product from the cylinder. In order to maintain the subatmospheric (<760 Torr)
    package, SDS cylinder temperature should not exceed 24 C. If subject to temperature greater than 24 C
    container may become pressurized which increases the risk of leakage and possible exposure to toxic gas.

    8. EXPOSURE CONTROLS, PERSONAL PROTECTION

    EXPOSURE LIMITS:
    SDS® 2 ARSENIC PENTAFLUORIDE:
    INORGANIC FLUORIDES (as F):
    2.5 mg/m3 OSHA TWA
    2.5 mg/m3 ACGIH TWA
    2.5 mg/m3 NIOSH recommended TWA 10 hour(s) (solid fluorides)

    ARSENIC PENTAFLUORIDE:
    ARSENIC AND INORGANIC COMPOUNDS EXCEPT ARSINE:
    10 ug(As)/m3 OSHA TWA
    5 ug/m3 OSHA action level
    0.01 mg(As)/m3 ACGIH TWA
    0.002 mg(As)/m3 NIOSH recommended ceiling 15 minute(s)

    VENTILATION: Exhausted process enclosure recommended to meet published exposure limits. Use only
    in a well ventilated area.

    EYE PROTECTION: Wear safety glasses.

    CLOTHING: Wear appropriate chemical resistant clothing.

    GLOVES: Wear appropriate chemical resistant gloves.


    Page 4 of 7
    RESPIRATOR: Respirators depend on exposure level. SCBA with full face piece recommended during
    change outs and available in case of emergency.

    9. PHYSICAL AND CHEMICAL PROPERTIES

    PHYSICAL STATE: gas


    COLOR: colorless
    PHYSICAL FORM: Solid proprietary carbon beads and toxic gas contained within a sealed stainless steel
    cylinder.
    ODOR: Not available
    MOLECULAR WEIGHT: 169.91
    MOLECULAR FORMULA: AS-F5
    BOILING POINT: -63 F (-53 C)
    FREEZING POINT: -112 F (-80.0 C)
    VAPOR PRESSURE: 11790 mmHg @ 20 C
    VAPOR DENSITY: Not available
    SPECIFIC GRAVITY: Not applicable
    DENSITY: 7.71 g/L
    WATER SOLUBILITY: reacts
    PH: Not applicable
    VOLATILITY: Not applicable
    ODOR THRESHOLD: Not available
    EVAPORATION RATE: Not applicable
    COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
    SOLVENT SOLUBILITY:
    Soluble: alcohol, ether, benzene

    10. STABILITY AND REACTIVITY

    REACTIVITY: Avoid contact with water or moisture. May react with evolution of heat on contact with
    water.

    CONDITIONS TO AVOID: Exposure to air.

    INCOMPATIBILITIES: Exposure to air.

    HAZARDOUS DECOMPOSITION:
    Thermal decomposition products: hydrogen fluoride, oxides of arsenic

    POLYMERIZATION: Will not polymerize.

    11. TOXICOLOGICAL INFORMATION


    Page 5 of 7
    ARSENIC PENTAFLUORIDE:
    CARCINOGEN STATUS: OSHA: Carcinogen; NTP: Known Human Carcinogen; IARC: Human
    Sufficient Evidence, Animal Limited Evidence, Group 1 (Inorganic arsenic compounds); ACGIH: A1 -
    Confirmed Human Carcinogen (Inorganic arsenic compounds)
    LOCAL EFFECTS:
    Corrosive: inhalation, skin, eye
    TARGET ORGANS: nervous system
    MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: diabetes, heart or cardiovascular disorders,
    immune system disorders or allergies, kidney disorders, liver disorders, nervous system disorders, skin
    disorders and allergies

    12. ECOLOGICAL INFORMATION

    Not available

    13. DISPOSAL CONSIDERATIONS

    Dispose in accordance with all applicable regulations. Hazardous Waste Number(s): D004. Dispose of in
    accordance with U.S. EPA 40 CFR 262 for concentrations at or above the Regulatory level. Regulatory
    level- 5.0 mg/L.

    14. TRANSPORT INFORMATION

    U.S. DOT 49 CFR 172.101:


    PROPER SHIPPING NAME: Compressed gas, toxic, n.o.s. (ARSENIC PENTAFLUORIDE)
    ID NUMBER: UN1955
    HAZARD CLASS OR DIVISION: 2.3
    LABELING REQUIREMENTS: 2.3
    QUANTITY LIMITATIONS:
    PASSENGER AIRCRAFT OR RAILCAR: Forbidden
    CARGO AIRCRAFT ONLY: Forbidden

    CANADIAN TRANSPORTATION OF DANGEROUS GOODS:


    SHIPPING NAME: Compressed gas, toxic, n.o.s. (ARSENIC PENTAFLUORIDE)
    UN NUMBER: UN1955
    CLASS: 2.3

    15. REGULATORY INFORMATION

    U.S. REGULATIONS:
    CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated.
    Page 6 of 7
    SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355 Subpart
    B): Not regulated.

    SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355 Subpart
    C): Not regulated.

    SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370 Subparts B
    and C):
    ACUTE: Yes
    CHRONIC: Yes
    FIRE: No
    REACTIVE: Yes
    SUDDEN RELEASE: Yes

    SARA TITLE III SECTION 313 (40 CFR 372.65):


    ARSENIC AND INORGANIC COMPOUNDS (as As)

    OSHA PROCESS SAFETY (29 CFR 1910.119): Not regulated.

    STATE REGULATIONS:
    California Proposition 65:
    Known to the state of California to cause the following:
    ARSENIC AND INORGANIC COMPOUNDS (as As)
    Cancer (Feb 27, 1987)
    Developmental toxicity (May 01, 1997)

    CANADIAN REGULATIONS:
    WHMIS CLASSIFICATION: Not determined.

    NATIONAL INVENTORY STATUS:


    U.S. INVENTORY (TSCA): Listed on inventory.

    TSCA 12(b) EXPORT NOTIFICATION: Not listed.

    CANADA INVENTORY (DSL/NDSL): Not determined.

    16. OTHER INFORMATION

    ©Copyright 1984-2009 ChemADVISOR, Inc. All rights reserved.

    MATHESON TRI-GAS, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES,


    GUARANTEES OR REPRESENTATIONS REGARDING THE PRODUCT OR THE
    INFORMATION HEREIN, INCLUDING BUT NOT LIMITED TO ANY IMPLIED WARRANTY
    OF MERCHANTABILITY OR FITNESS FOR USE. MATHESON TRI-GAS, INC. SHALL NOT BE
    LIABLE FOR ANY PERSONAL INJURY, PROPERTY OR OTHER DAMAGES OF ANY NATURE,
    WHETHER COMPENSATORY, CONSEQUENTIAL, EXEMPLARY, OR OTHERWISE,
    Page 7 of 7
    RESULTING FROM ANY PUBLICATION, USE OR RELIANCE UPON THE INFORMATION
    HEREIN.

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