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COATINGS FILTRATION FEEDING SYSTEMS MELT SHOP REFRACTORIES METAL TREATMENT BINDERS CRUCIBLES

DYCOTE*
MA N UAL

+ Equal filling of the die

+ Controlled heat transfer

+ Good surfaces of the castings

+ Long life time


Introduction
Although various aspects of the permanent Where a special coating is only available in
mould casting process have been studied some countries it has not been included in
and developed, such as alloy selection, the table. Also not every mentioned coating
machine automation, etc., little attention has is available in every country. For more details,
been given to the products and methods for please contact your local Foseco company.
preparing the surfaces of the die.
The manual is completed with appendices on
It is often the operator that selects and cryogenic sandblasting, coating application
prepares the coating material, and the defects and defects in die-cast parts.
final choice is based almost exclusively on
practical experience rather than technical Die casting and the role of coatings
and theoretical considerations. This manual Die casting is a process that uses permanent
aims to provide foundry engineers and moulds made of metal (dies) enabling large
operators involved in die preparation with batches of identical castings to be produced.
the information required for the correct use Contrary to sand moulds, in which the
of coating materials, in order to optimise permeability of the compacted sand allows
efficiency and so improve foundry production. the air to escape freely during casting, metal
moulds are impermeable and therefore must
This latest revised and illustrated edition of be designed with suitable air vents. The
the Foseco DYCOTE Manual comprises: An advantages of the die process over sand are:
analysis of the functions of coating materials,
preparation and application methods, and + 
superior structural characteristics
examples of die preparation for the most
common castings. + better appearance of the casting

+ greater dimensional accuracy


The tables with the characteristics of
DYCOTE products have been extended, + 
reduced feed demand
rationalised and now include a new
family of DYCOTE’s, the DURA group. + 
higher production rates
This offers extended coating life, to improve
+ 
lower cost (for larger batches)
productivity.

1
Function of DYCOTE
The principal functions required of a coating
for die casting are:

+ 
Control of the metal flow to ensure that it
reaches all parts of the die at a sufficient
temperature to prevent the formation of
seams, cold laps, etc.

+ 
Control of heat transfer to obtain better
solidification and ensure that the castings
are properly fed.
Compared to sand moulds, the use of a
permanent metal mould requires completely + 
Easy release: since castings are
different conditions for filling the metal alloy extracted at just below the solidification
and for its solidification; the function of the die temperature, easy release ensures that
coating – a semi-permanent layer deposited on castings do not come out deformed.
the walls – is to control these processes and
+ 
Good surfaces, and therefore a reduction
to facilitate release of the casting, prolong die
in finishing costs.
life, etc. In die casting, coating selection and its
method of application are at least as important + 
Longer die life, therefore increased
as other factors, such as the design of the productivity and reduced maintenance.
die, type of alloy, temperature of the metal These results are directly in line with the
and so on. Foseco produces a vast range of characteristics of DYCOTE.
die coating products under its DYCOTE brand
as well as other products and systems which
have long been used in all areas of the modern
metal foundry. In addition, Foseco is constantly
seeking new products and systems to make
casting production safer, more environmentally
friendly and more economic.

2
Heat transfer control Bonding agents: in the majority of cases
The control of heat dispersal through the sodium silicate with an appropriate SiO2/Na20
various sections of the die is undoubtedly ratio, although sometimes other materials are
the most important characteristic of DYCOTE, used, such as certain types of clays, starch,
because it permits control of both directional etc. The DYCOTE DURA family is based on a
solidification and die filling (which will be new binder system, which offers improved
discussed in the section „Metal flow control“). bond toughness

The degree of insulation depends on: Water: with controlled hardness.

+ 
the properties of the raw material The degree of compaction of the layer, which
used depends on the application method, affects
the property of thermal insulation: if the layer
+ 
the method used to apply DYCOTE to the is not very compact, contact between particles
surface of the die is slight, and therefore the permeability and
insulation properties are greater.DYCOTE
+ 
the thickness of the layer.
products are usually supplied in the form of
The basic ingredients of DYCOTE are: a paste for dilution with water depending
on the type of application (and therefore the
Fillers: composed generally of refractory degree of insulation) desired, i.e. with brush
powders such as TiO2, talc, mica, silica or spray application; the dilution ratio is
flour, iron oxide, AI2O3, etc. At the normal relatively unimportant from this point of view,
casting temperature of aluminium alloys since excess water is removed by heat from
in the die-casting process (650-800 °C), the warm die surface (120-140 °C with brush
the refractoriness of the fillers is such as to application and around 180-250 °C for spray
ensure that no chemical reaction takes place. application).
Their function therefore remains exclusively
physical, i.e. only thermal conductivity and
particle form and dimensions are involved
(the importance of the latter factors will
be discussed when dealing with metal flow
control).

3
Brush application leaves the die with a very thin section of the casting a thick layer of a
rough surface full of air pockets. This gives a coarse insulating DYCOTE, the solidification
high degree of insulation, ideal for the surfaces rate will be reduced. On a thick section of the
not requiring special finishes (such as runners casting, a thin layer of a fine DYCOTE can be
and risers). applied, thereby accelerating solidification,
the cooling characteristics of the metal can be
In spray application, DYCOTE products are rendered sufficiently uniform to give a sound
applied in several thin layers until the desired casting. The larger the difference between
thickness is obtained. In this case the layer the sections of a casting, the greater should
also comprises air pockets but they are smaller be the insulating properties of the DYCOTE
than in the previous case, and are due to applied. In extreme cases, the desired effect
the accumulation of particles rather than the can be obtained by removing or rubbing down
formation of bubbles in the bonding agent. the coating from thick sections. Runners and
risers, where metal has to remain molten
Air pressure and distance of the pistol from for a certain time to feed the casting during
the surface of the die must be sufficient to solidification, normally require a thick layer of
overcome the phenomenon of evaporation an highly insulating DYCOTE.
and permit the DYCOTE to adhere completely
to the die surface. Air pressure of 0,4-0,5 MPa
and a distance of 25-30 cm from the die is
recommended (see figure 6).

Good quality castings with no, or at least only


a controlled level of, solidification shrinkage
are obtained if the concept of directional
solidification is observed, i.e. if solidification
proceeds steadily towards the risers from the
parts of the casting farthest from them.

An appropriate coating, with the thickness


varying with those of the casting, allows the
control of heat transfer, favouring directional
solidification. For example, by applying on a

4
Controlling metal flow transmission of heat and rapidly reduces
Since the coating is thin (50-150 microns) fluidity; this can result in incomplete
and the temperature differential between the filling, cold laps, etc., especially when the
molten alloy and the die varies between 400 metallostatic pressure is low, as for example in
and 500 °C, the thermal conductivity stays the case of castings with thin sections.
relatively high and the transmission of heat
from the metal to the die is instantaneous
and intense. The physical characteristics
of DYCOTE (coarseness, filler size), have
a marked effect not only on the surface
quality of the casting, but also on the
flow of metal and degree of insulation.
For example, a thin layer with ample
contact with the metal increases the
Figure 1: Directional Solidification

Figure 2:

Metal flow
starting from
the centre
Metal path favo-
urs the rougher
surface
Smooth
DYCOTE 32

Rough
DYCOTE 34

Source: Daniel Whitrow, University Birmingham

5
Figure 3: Formation of Cold Lap

Conversely, with a layer of DYCOTE with a The roughness of the refractory particles
coarse surface, the contact between molten also influences the flow of metal. Given that
metal and DYCOTE is significantly reduced, the surface tension of aluminium is high, its
because the metal, due to its surface tension, flow characteristics and wettability are low;
is first in contact with only the „peaks“ of as a consequence of this, if a refractory filler
the layer, and only after a time, though this with sharp edges is used, the aluminium
is extremely short, does it penetrate into the oxide skin will be continuously broken down
„valleys“, after which the air escapes through during pouring, and the metal will run much
the channels in the permeable coating. The more easily over the surfaces. Unfortunately
result of this phenomenon is to reduce heat coarse coating layers with sharp-edged
loss to a minimum in the molten metal, particles tend to become smoother with each
which thus maintains its fluidity at the critical casting. Indeed, the sharp projections of the
moment to fill the die completely. layer bind to the surface of the casting during
solidification and break off during extraction:
it may therefore be necessary to touch up
regularly to obtain better results consistently.

Figure 4: Fine coating Figure 5: Coarse coating

6
Easy release is repeated. The drawback here, which arises
Regardless of the design of the die, release from having to apply a second coating, is
can be made easier by using graphite in a that this tends to cancel out the advantages
colloidal and semi-colloidal form. Graphite can of particle size in base coats. What happens
be used as a component of the refractory base is that the graphite tends to collect in the
of the DYCOTE, in the coating itself, or applied „valleys“, so that the layer takes on a smoother
separately on top of a standard DYCOTE. appearance, reducing the fluidity of the metal.
When graphite is used in the composition
of refractory DYCOTE, care must be taken Recently, insulating coatings have been
to avoid weakening the coating due to the introduced with a composition that includes
thin layers of graphite flaking off. If a DYCOTE Boron Nitride (BN), which has a hexagonal
flakes it will tend to lose its thermal insulation. graphite-like structure. The presence of Boron
Graphite for application over a layer of DYCOTE Nitride reduces the wettability to molten
base is often used on areas of a die where aluminium while increasing the refractories
release is difficult, or on its moving parts. The of the coating. Boron Nitride allows excellent
composition of the DYCOTE must be accurately release while the white colour prevents the
controlled since, if the bonding agent forms a discolouration of the casting, which is often
hard „shell“ around each graphite particle, its seen with graphite.
lubricating properties will be reduced or even
completely destroyed. When a graphite-based
DYCOTE is applied the lamellae are spread in
a disorderly manner, and therefore numerous
tiny blisters may form in the lining, with the
effect of reducing the thermal conductivity
of the layer. After a few castings, however,
there is a tendency for the graphite film to
become flat and impermeable (this can be
seen from the shiny appearance of the film
after release) as a result of continual friction
against the metal caused by shrinkage during
solidification. Therefore the bonding agent
must be weak, allowing part of the overlaid
film to break off, exposing the underlying
layer over which the application of graphite

7
Good surface Lifetime
As seen from the information above, a good The factors that contribute to the life of a
surface will be linked to the choice of DYCOTE; coating layer are:
for example flat thin surfaces require a coarse
angular layer which favours the flow of metal. + Type of bonding agent
This is because the metallostatic pressure
+ 
Method of application
is low and filling the die is facilitated by
the continual breakdown of the aluminium + 
Type of refractory
oxide film. The surface of the casting will be
relatively rough but sound, while a smooth The bonding agent must not only resist high
layer would cause filling to be incomplete. temperatures but also the high temperature
The parts of the mould corresponding to thick changes that cause tensile stresses in the
sections of the casting can be coated with coating layer.
finer DYCOTE products, since the metallostatic Very often sodium silicate is used with a well
pressure in these areas is higher. Also the type determined Na20/SiO2 ratio, as it not only resists
of application will affect the final result: brush thermal cracking, but over time becomes more
application produces an uneven surface, while resistant to high temperatures and therefore is
spray application produces a smooth even long-lasting. As stated initially, the application
surface. method is important and the die temperature

Figure 6: SPRAY DISTANCE VS. ABRASION


Coating thickness after abrasion test

Die Temperature - around 200 °C


Spraying Pressure - 0,5 MPa
Dillution Ratio Coating:Water - 1:5

Spray distance (cm)

8
is the most critical factor. If the temperature is Copper alloys
too low and consequently water evaporation The major difficulty encountered when die
is retarded, the coating forms an impermeable casting in these materials is the deposit of zinc
film that detaches from the die forming oxide on the die surface. If it is not removed,
blisters, due to steam forming under the layer. it rapidly forms a thickness that renders the
Then the layer can contract and detach when surface of the castings unacceptable. The
it is completely dry, leaving part of the die dies are therefore designed so they can be
exposed. If the temperature is too high and dismantled and immersed in a bath containing
water evaporation too violent, the refractory a suspension of a carbonaceous material that
particles, surrounded by a film of water and inhibits the formation of zinc oxide as well as
sodium silicate, will become separated from coating the die this practice also cools the
each other and also from the surface of the die. The carbonaceous material is deposited
die by tiny explosions which take place when on the surface in a porous structure, giving
the steam is released into the air. it both insulating and lubricating properties.
The result is a weak, coarse, powdery layer that The inhibitor to a certain extent prevents
peels off easily. Although, as has been said, the formation of zinc oxide on the surface.
the ratios of the constituents remain constant Another advantage of this process is the high
despite being diluted with water, the ratio of production derived from the simplicity of the
dilution influences the final appearance of the immersion application method.
coating. As a general rule, insufficient dilution
results in a weaker bond between the coating Aluminium bronze
and the die, but the layer will be rough will In this case DYCOTE products can be used for
have lower thermal conductivity and therefore light alloys, together with a second graphite-
will have better insulating properties. based coat to facilitate release. Use can also
be made of the immersion method described
Magnesium alloys above.
DYCOTE also adapts to magnesium alloys,
where prior to casting, the procedure for
preventing the oxidation of the metal is carried
out by saturating the die cavity with inert gas.
The DYCOTE BN coatings are compatible with
Magnesium alloys.

9
Low pressure casting have been developed that allow blasting in
In this process the metal is injected into a situ without having to dismantle the die, with
mould mounted on a sealed furnace. The air clear advantages from the environmental
or nitrogen pressure applied to the surface of point of view but with problems getting into
the metal causes it to rise and pass into the deep parts of the die. Also a big problem is
mould through a tube. The pressure required the loud noise. The disadvantage is, that not
to move the metal is slightly higher than the all coating types can be removed.
metallostatic pressure. Normally the same
DYCOTE products are used as for gravity Die temperature
casting. Dies generally operate at a temperature of
around 300 to 400 °C, but the coating must
Preparing the Die be first appliedin a variable range between
Cleaning 180 and 250 °C, depending on the type of
A fundamental requirement is cleaning the DYCOTE and the degree of adherence desired.
surface to be coated: no residue of previous During operation local areas may require
coatings must remain and also no oil, grease repair, this operation must be done at the
or soot. Cleaning can be performed with wire running temperature and needs a special
brushes or by blasting with sand, alumina steel procedure, which is described in Figure 7.
shot etc. Recently, dry ice cleaning systems

Figure 7: DIE TEMPERATURE VS. ABRASION


Coating thickness after abrasion test

Dillution Ratio Coating:Water - 1:5


Spray Distance - 20 cm
Spraying Pressure - 0,5 MPa

Die Temperature (°C)

10
As the application temperature increases,
the adherence is reduced. Therefore the
temperature of the die should be controlled
accurately during application, using a contact
thermocouple. The temperature to which the
die is heated before coating should preferably
be higher (250-300 °C), after which it is
left to cool, preferably under a cover, to the
correct coating temperature: this improves
the uniformity of the die temperature and Figure 9: Effect of coating thickness on insulation and fluidity
avoids intermediate heating when successive
layers must be applied. After the die has Coating thickness
been coated and before the first casting The coating thickness must be defined and
is poured, it must be heated to working controlled on the basis of the insulation
temperature. To get the best results when required. Thicknesses in the order of 50 µm
retouching the coating, it would be preferable and 150 µm (see figure 8) are sufficient to get
first to bring the die temperature down to the maximum degree of insulation typical for
the recommended coating temperature. the product used.
For castings and risers, brush application
can achieve a thickness of up to 4-5 mm.
The coating thickness is the principal factor
Figure 8: INSULATION in the heat exchange between casting and
die. Coatings applied carelessly over previous
coatings result in thick layers with a number
of negative consequences, such as alteration
Insulation value

of the thickness, poor layer tightness and


hot spot defects on the casting. The effect of
coating thickness on filling ability is illustrated
in figure 9 which shows the effect on fluidity.

Coating thickness (microns)

11
Coating life Preparing the Materials
This is certainly the aspect of greatest interest Adequate storage and appropriate preparation
and it is linked to the quality of the carefull of the coating materials are of vital importance
preparation of the die and the die coatings. for obtaining optimum performance from the
Absolute thorough cleaning and correct products used.
heating are needed to ensure that all types of DYCOTE must be stored and applied in an
DYCOTE adhere properly to the die metal. A enclosed, cool, dry place not exposed to direct
carefully applied coating could last at least sunlight.
one day, potentially one week depending on
DYCOTE coatings are sensitive to frost.
the casting design.
DYCOTE must be stored at ambient
Those able to achieve these results will see temperature (10-25 °C).
the benefits especially since the long life of Storage at a stable temperature will keep the
the coating is essential for dies to operate viscosity and density of the product constant.
consistently. Recently new compositions of Too high a temperature leads to changes in
DYCOTE have been formulated. A range of viscosity and accelerated biodegradation.
fine, medium and coarse DYCOTE coatings Too low a temperature will alter the viscosity
with extended life have been developed. In and may prevent the use of DYCOTE products
most cases further improvements in coating which, being generally water-based, will
life can also be achieved by curing DYCOTE freeze if the temperature falls below 0 °C,
coatings at 350 to 400 °C for over one hour causing it to lose its binding property.
immediately after coating.

Figure 10: Example of DYCOTE preparation room, seperated from production

12
Stocks are used on the basis of their „age“ Preparing the Mixtures
(priority is given to materials stored for the Proper mixing and preparation of DYCOTE is
longest period), so that the DYCOTE will be essential for obtaining the correct density, and
as fresh as possible. The quantity of stored also for obtaining optimum characteristics of
product must be such as to enable it to be use and reproducibility. Careful and controlled
used according to the date on the label. In preparation of the DYCOTE is an essential part
particular, purchasing the necessary material of the process and to ensure this the DYCOTE
one month in advance will provide an should be mixed and stored in a separate,
adequate level of stock. clean and controlled room remote from the
production area. Using an appropriate mixer
is the best way to prepare DYCOTE.
Foseco has developed a system called “Carry
& Mix“ which helps to dilute and store the
premixed coating. Carry & Mix is available in a
fixed and trolley mounted version.

Figure 11: Carry & Mix

13
The mixing procedure is as follows: Checking and Control
DYCOTE products are subjected to strict
+ 
Add approximately 1/3 to 1/2 of the total quality controls to ensure that they reach
water to the container the customer in optimum condition, however
further controls are required when the product
+ 
Start the mixer is used. Many of these controls fit easily into
the control programmes of the foundry.
+ 
Gradually add the correct quantity of pas-
te to form a thick mixture without lumps

+ Gradually add water until the mixture is


slightly thicker than the density of use

+ 
Once the mixture has a uniform appea-
rance, increase the quantity of water to
the required density for the application.

The mixed product must be kept covered.


Covering it reduces water evaporation and
reduces the risk of contaminants entering
the container. The container must be cleaned
regularly at least once a month. This is
required with water-based products to prevent
the formation of biological encrustation.

Figure 12: Density measured by weight and volume

14
Other checks:

+ 
The appearance of DYCOTE, as is or
mixed, should always be similar.

+ 
The presence of lumps or foreign matter
can be identified by examining the
product.

+ Checking the label / production date.

Figure 13: Baumé densimeter

Test Method Note


Baumé Density measurement using a gauge rod with a
bulb of calibrated weight at one end, which is
inserted into the mixture; the denser the mixture,
Density the less the rod sinks.
Weight/Vol. Measurement of the weight of a known volume of
material.
Solid Contents Dry residue A weighed quantity of the mixture is dried in an
oven and weighed again. The dry residue is the %
ratio between the final weight and initial weight.

15
Application Method Spray application
The coating can be applied using several Essentially there are two different types of
methods: spray devices:

+ 
Brush + 
Siphon pistol (air at high pressure), which
uses compressed air to create a partial
+ 
Spray
vacuum that forces the fluid through the
+ 
Immersion pistol, transforming the coating into tiny
droplets.
For dies the quickest and most suitable
+ 
Air-less systems, pumping the mixture at
method is spray application. Brush application
high pressure into the pistol where it is
is reserved for plain areas (runners and risers)
forced through a narrow portion and then
where the lining must be much thicker, or for
atomised by expansion.
small details that must be coated in a different
way from the rest of the die. Immersion
application is mainly used for copper alloys,
where the coating also has to cool the die.

Figure 14: DILUTION RATIO VS. ABRASION THICKNESS

Die Temperature - around 200 °C


Spray Distance - 20 cm
Coating thickness after abrasion test

Spraying Pressure - 0,5 MPa

Dilution Ratio (Water Parts)

16
The operations that must be performed
to obtain a correct coating are:

+ 
The pistol must be completely clean
throughout, particularly the nozzle.

+ 
Fill the tank only with the quantity of
mixture necessary. Discard the excess
quantity or put it back in the mixer for
application.

+ Use the product in the pistol without


Figure 15: Krautzberger spraygun
lengthy stops (>10 minutes).

+ 
Set the line pressure to 0,4-0,5 MPa
(depending on the dilution of the + 
If the distance of application is too great,
mixture). Too much or too little pressure part of the water medium evaporates
causes the formation of drops instead of before contact with the die (dry spray),
a mist. producing coarse surfaces on the
resulting casting and poor coating
+ 
Start the coating runs from outside the adhesion.
die and avoid spraying intermittently.
Make short passes and keep the pistol + 
It is preferable to apply the coating in
moving all the time. several thin layers rather than in one or
two thick layers.
+ 
Maintain a distance of 20-30 cm between
pistol and die. + 
Between one layer and the next, the
coating must be allowed to dry.
+ 
Work quickly but carefully. Each pass
cools the die a little. + 
Depending on the type of casting a
typical coating thickness for insulation
+ 
If the distance of application is too close, should be 150 to 250 µm, whilst for
the coating tends to become thicker, smooth surface finish a coating thickness
slow to dry and can cause stains on the of 30 to 50 µm is applied.
casting; the layer tends to become too
thick.

17
+ 
For optimum performance the thickness + 
Do not allow the coating to run on the
of the coating should be measured at die.
various stages of application.
+ 
Always clean the equipment after use.
+ 
The operator should move around the
die to coat from several directions and
so reach the surfaces to be coated
from different angles, thus avoiding
the „shadow“ effect. This practice also
avoids accumulating too much coating
material on the operator‘s side and
getting „dry spray“ on the opposite side.

18
Controlling the Thickness of the Coating
The thickness of the coating is a difficult
parameter to control, because of the difficulty
of working on very hot surfaces, therefore
operators have always been left to work it out
from experience, the result being inconsistency
from one die to the next and between surfaces
of the same die. Thickness gauges are currently
available which can be used on hot dies, at all
points.
This allows the caster to relate the coating
thickness to the metallurgical structure of the
casting and, by adopting the correct spraying
system, to correct the thickness, adapt it to
requirements and avoid scrap. Controlling the
coating thickness also permits better control
of directional solidification, important for
Figure 16: Magnetic system „Pull off Gauge 157“
ensuring sound castings. Elcometer Instruments Ltd. Manchester

Figure 17: Ultrasonic system Sonacoat F


19
Controlling Die Temperature
Die temperature is a parameter that must
be controlled, in order to get the best bond
between the coating and the die. Although
an experienced operator may be able to
judge to temperature, best results are
obtained by using a suitable thermocouple.
Contact thermocouples and infrared or laser
thermometers are now available for controlling
die temperature. This enables the caster to
apply the coating at the correct temperatures.
Figure 18: Infrared thermometer

Figure 19: Contact thermocouple

20
Foseco DYCOTE Coatings

Grain Thinning
Type of coating Application, Description
size ratio
Base coating
DYCOTE DR87 25µm 1:1 - 1:3 Base coating for all applications, apply at 180°C
Insulating Coatings
DYCOTE 39 and 5µm 1:3 - 1:5 Low insulation, very good surface finish. ESS version
DYCOTE 39 ESS with extra binder.
DYCOTE D 39 and 15µm 1:3 - 1:5 Wheel castings. ESS version with extra binder.
DYCOTE D 39 ESS
DYCOTE D BN 120 35µm 1:10 - 1:20 Contains Boron Nitride for smooth
surface finish with long life.
DYCOTE D BN 130 50µm 1:10 - 1:20 Good surface finish with long life. Contains Boron
Nitride.
DYCOTE D 7039 78µm 1:3 - 1:5 Wheel casting for top die and top core;rib cylinder.
DYCOTE D BN7039 78µm 1:3 - 1:5 Coarse coating; Contains Boron Nitride.

DYCOTE F 140 35µm 1:3 - 1:5 High insulating.


DYCOTE 140 and 30µm 1:3 - 1:5 General use. ESS version with extra binder.
DYCOTE 140 ESS
DYCOTE 32 ESS 30µm 1:3 - 1:5 Medium insulating coating,
effective for alloy wheels.
DYCOTE 34 and 80µm 1:3 - 1:5 Very highly insulating coating for thin section
DYCOTE 34 ESS castings typically automotive. ESS version with
extra binder.
DYCOTE D 34 and 80µm 1:3 - 1:5 Highly insulating coating for thin
DYCOTE D 34 ESS section castings typically automotive.
ESS version with extra binder.
DYCOTE 3480 75µm 1:3 - 1:5 As DYCOTE 34 ESS but with
modified, improved binder
DYCOTE F 34 50µm 1:3 - 1:5 General use.

DYCOTE D 5 45µm 1:3 - 1:5 General use.


DYCOTE D 6 ESS 85µm 1:3 - 1:5 Very highly insulating coating for thin
section castings. Textured casting finish.

21
DYCOTE D 6 ESSB 85µm 1:3 - 1:5 As DYCOTE D 6 ESS + extra binder.
DYCOTE 6 70µm 1:3 - 1:4 High insulation coating for general engineering
castings.
DYCOTE 2040 35µm 1:1 - 1:3 Insulating coating with medium particles.
DYCOTE 2050 35µm 1:2 - 1:3 For thicker section automotive castings offering
longer lifetime.
DYCOTE 3975 30µm 1:1 - 1:3 Very smooth coating.Contains Boron Nitride.
DYCOTE 3950 10µm 1:2 - 1:3 Used on front face of wheels offering longer
lifetime.
DYCOTE V 7 50µm 1:1 - 1:2 Highly insulating coating for actively cooled
moulds.

Type of coating Grain size Thinning ratio Application, Description


Heat conducting coatings
DYCOTE 40 1µm - Oil graphite blend for slides and moving parts.
DYCOTE D 38 5µm Fully colloidal graphite lubricating coating
1:10
without binder.
DYCOTE 11 15µm Water-based semi colloidal graphite for
1:5 - 1:15
release of castings from die. Without binder.
DYCOTE 36 35µm 1:3 - 1:5 As DYCOTE D 11, + binder
DYCOTE D 212F 70µm 1:5 - 1:15 Coarse graphite-based coating for release. Wit-
hout binder.
DYCOTE E 11 20µm 1:5 - 1:15 Semi-colloidal graphite. Without binder.
DYCOTE 11 I 70µm 1:5 - 1:15 Semi-colloidal graphite. For fast cooling
and good release. Without binder.
DYCOTE F 36 50µm 1:3 - 1:5 Medium insulating DYCOTE / good surface
finishing and good release for small pins with low
draft angles.
DYCOTE 38 25µm 1:10 Water-based graphite for release purposes.
Thinner than DYCOTE 11.
DYCOTE 61 30µm 1:10 - 1:30 Brass die-casting

22
Riser and ingate coating
DYCOTE 7029 Use undiluted or diluted only with water; application by brushing;
layer thickness up to 4 mm possible
Other
DYCOTE HARDENER Sodium silicate suitable for DYCOTE
DYCOTE 100 M Coating for automatic ladles
DYCOTE W Coating for automatic ladles
DYCOTE SAFEGUARD 12 1:1 Top coating to be applied on existing standart
DYCOTE product to extend lifetime

DURA DURA DURA DURA DURA DURA DURA


Types
500 510 520 400 410 420 310
Grain size 78 µm 78 µm 65 µm 50 µm 50 µm 35 µm 35 µm
1.38 1.45 1.58 1.63 1.29 1.47 1.54
Density
kg/ltr. kg/ltr. kg/ltr. kg/ltr. kg/ltr. kg/ltr. kg/ltr.
Part 1 5.5 kg 5.5 kg 6.3 kg 6.5 kg 5.2 kg 5.9 kg 6.2 kg
= = = = = = =
4 ltr. 3,8 ltr. 4 ltr. 4 ltr. 4 ltr. 4 ltr. 4 ltr.
Packaging
Part 2 2.8 kg 2.8 kg 2.8 kg 2.8 kg 2.8 kg 2.8 kg 2.8 kg
= = = = = = =
2 ltr. 2 ltr. 2 ltr. 2 ltr. 2 ltr. 2 ltr. 2 ltr.
Water addition to Part 1 8 ltr. 8 ltr. 8 ltr. 4 ltr. 8 ltr. 4 ltr. 8 ltr.
Mix ratio (Vol.): Part 1 : 1:2: 1:2: 1:2: 1:1: 1:2: 1:1: 1:2:
Water : Part 2 0,5 0,5 0,5 0,5 0,5 0,5 0,5
1 Part 0-1 Part 0-1 Part 0.8 1 Part 0.8 0.5
Typical extra water
= = = Parts = Parts Parts =
addition to get spraying
4 ltr. 0-4 ltr. 0-4 ltr. = 4 ltr. = 2 ltr.
consistency
3.2 ltr. 3.2 ltr.

DYCOTE coatings are available in different pack sizes.


All DYCOTE coatings are frost sensitive, store between 5 and 25 °C.

23
Selection of DYCOTE coatings thick sections then a specific coating may be
A number of factors must be taken into required to help directional solidification.
consideration when selecting a DYCOTE. Where a casting has small draft angles, because
of design, then a coating with excellent release
The section thickness of the casting. One of may be required.
the main properties of a coating is its ability
to aid the filling of the die. When the casting The casting process may also influence DYCOTE
concerned has a thin section then a coarse selection. For example low-pressure castings
DYCOTE with high insulation properties should can be made with smoother coatings as the
be considered. process enables the die to be filled more easily.

The surface finish requirement of a casting is


Some causes of problems experienced with
very important but coatings which give very
permanent die coatings
good surface finish make it more difficult to fill
the die because of the smooth surface of the + Flaking Of Coating
coating and because the insulation is not as
good as with a coarser coating. The balance of + 
Coating Wears Away Quickly
surface finish and insulation will therefore be
a compromise. + 
Coating Won’t Stick To The Die

The geometry of casting can also be critical + Coating Is Too Rough


for good feeding. If a casting has certain
+ 
Misruns / Cold Shuts

24
Flaking of Coating wears Coating will not Coating surface is Misruns / Cold
Coating away quickly adhere to the Die too uneven Shuts
Layer too thick Spray distance too Coating has been Coating is under- Incorrect coating
great frozen diluted selection
Coating under- Die too hot Lack of die surface Spray distance too Insulating coating
diluted preparation short layer too thin
Lack of surface Coating under- Die temperature Plugged or worn Coating too
preparation - poor diluted too low / high spray nozzle smooth
cleaning
Die temperature Coating has been Low spray
too low frozen pressure
Coating layer too Contaminated
thick coating

25
Appendix 1 – Die cleaning with CO2
The technique known as „cryogenic“ blasting
is carried out by projecting pellets of solid
carbon dioxide (dry ice) onto the die, instead
of the usual sand or metal shot. Use of non-
abrasive dry ice removes the coating without
causing damage or wear to the die. In fact
the action performed is exclusively kinetic and
thermal. Carbon dioxide pellets, after striking
the surface of the die, sublimate (pass into the
vapour state) without producing deposits or
wetting the die. The temperature loss of the
die is very limited, and it is possible to proceed
with another coating in a short time.

Figure 20: Sanblasting system


With this system, which is becoming
increasingly popular in foundries, frequent
coatings can be applied, increasing the life of
the die and avoiding the problems met when
using sand or shot. A further advantage of this
process is that the die can be cleaned directly
on the casting machine, which reduces down
time. The disadvantage is, coatings with long
lifetimes may be difficult to remove with this
technique.

Figure 21: Parts of the sandblasting system

26
Appendix 2 - Coating Method Defects
Cause A
Build up of coating material restricts airflow in
hole „A“, with consequent increase of air flow
in the hole opposite and direction of spray to
the obstructed side.
Remedy
Remove the build up (with diluents) without
using metal instruments that could damage
the nozzle.

Cause
1) Build up of coating material around the
B
nozzle on side „B“ restricting the flow of
atomising air.
2) Air loss, or nozzle tilted or dented, or bent
needle.
Remedy
1) Remove the build up (with diluents) without
using metal instruments that could damage
the nozzle.
2) Change the nozzle and/or needle.

Cause
Air trapped in coating material, due to
absence or wear of the seals, defective collar
or punctured aspiration pipe.Remedy
Check all seals for tightness and check all
points where air might be sucked into the
coating material.

27
Cause
Spray split in two:
1) Air pressure too high.
2) Coating diffuser aperture too large in relation
to the dilution of the coating.
3) Shortage of product in the tank.
Remedy
1) Reduce air pressure.
2) Reduce aperture of diffuser (regulators „C“
and „D“).

Cause
“Salt and pepper“ spray effect caused by
insufficient pressure or coating too thick.
Remedy
Increase spray pressure.

28
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