Midrex Process
Midrex Process
Midrex Process
contents
2 commentary:
It’s Not Easy Being Green
3 The Production Of Steels
Applying 100% DRI for
Nitrogen Removal
www.midrex.com
2 table of contents < >
Introduction
In 1994, the electric steelmaking shop of ArcelorMittal Lázaro table I Nitrogen Requirements for Steel Applications
Cardenas Flat Carbon began using 100% DRI for some heats. Since NItrogen
then, it has become the normal practice. The main variables of Application Requirement (ppm)
DRI steelmaking, degree of metallization, carbon content, gangue Reinforcing Bar 120
content (especially acid gangue; SiO2 + Al2O3) have been studied Forging Grades 80
and evaluated extensively at AMLC-FC through the years. This Cold Heading Quality 80
analysis has allowed AMLC-FC to determine the most cost effec- Low Carbon Wire 60
tive methods throughout the value chain of steel production. Each SBQ Wire 50
variable has a special impact in the final cost of the steel produced. Hot Band (Commercial) 60
Usage of 100% DRI has been a very important tool for Hot Band (High Quality) 40
the production of clean steels, with very low tramp elements
Deep Drawing for Automotive Parts 20
(Cu+Ni+Cr+Sn = 0.05%), as well as the production of steel with
API X Steel Grades for Sour Gas Application 45
low nitrogen content (< 25 ppm at meltdown and 40 ppm in final
product) for the API X steel grades. Table I shows the nitrogen
requirements for some steel grades. EAF and Secondary Metallurgy Process Engineer, Ruben.Lule@arcelormittal.com,
1),3)
2)
EAF-LF-CC Process Engineering Manager, Francisco.Lopez@mittalsteel.com,
4)
Steelmaking and CC Director, Raul.Torres@arcelormittal.com, 5) Professor Department
of Metallurgy, IPN-ESIQIE and K&E Technologies President, rmorales@ipn.mx.
Figure 1 Effect of High %C on the Nitrogen content at meltdown and at the Ladle Furnace.
was to increase the %C in the DRI in order to decrease the energy via dilution. The observations indicate that the CO from DRI is
consumption in the EAF. The results obtained were in excellent evolved rapidly while the pellet remains buoyant in the slag phase.
agreement with the calculated expectations. Besides the benefit of The rate of CO evolution from DRI at steelmaking temperatures
decreasing the energy consumption, another important improvement is fast, controlled by heat transfer, and occurs at relatively low
was observed, namely the fact that the nitrogen content at meltdown temperatures ranging between 800°C to 1200°C.
was lower as the %C increased in the DRI. At that time, the main idea In the electric steelmaking shop at ArcelorMittal Lázaro Cardenas
was to prove that the high %C in the DRI can be important to decrease Flat Carbon, the normal practice is to feed 100% DRI for the production
the energy consumption of the EAF by means of increasing oxygen of steels that require low residual elements and low nitrogen
injection (the oxidation of carbon representing an important energy content. A hot heel practice is always used. Prior to Power On, 5000 kg
contribution). However, during these trials, the final nitrogen was of DRI together with 1,000 kg of coke are fed onto the 50-60 ton of the
very low when DRI with 2.90 %C was applied. The results showed hot heel that remains from the previous heat. Immediately a vigorous
the final nitrogen content at meltdown with this carbon content in foaming slag formation takes place and allows the pre-deoxidation of
the DRI was 7-12 ppm. The next charts show these results. the metal bath and decreases the %FeO in the slag. This practice is
In previous research, Goldstein and Fruehan established the mandatory because 30 seconds after the Power On, the EAF reaches
mechanism for nitrogen removal by applying large proportions its highest active power (135 MW). The CO formation continues
of DRI. They established that nitrogen removal was possible due to through all the heat because the DRI is fed to the EAF by continuous
the CO evolution by the carbon oxidation, and additionally that by charging at a rate of 4500-5000 kg/minute. The %C in the DRI is 2.70%,
applying big proportions of DRI, low nitrogen levels are possible therefore the carbon contribution by the DRI per minute is 135 kg.
high carbon, raw material selection is very important to assure low To avoid nitrogen pick up in the ladle furnace, it is important to
nitrogen content. control the argon flow rate as well as to avoid fluxes (lime and CaF2 )
Figure 4 shows the results obtained regarding Nitrogen and carbonaceous material additions. Power On time must also be
versus the carbon content of the DRI. controlled in order to avoid nitrogen dissociation. Figure 6 shows
histograms of nitrogen content at EAF meltdown and at the end of
the LF process. Figure 7 indicates the %S in the steel relative to the
nitrogen obtained.
CONCLUSIONS
1. The usage of 100% DRI with high carbon (> 2.50%) is extreme-
ly important for the production of the steel grades that specify
low nitrogen contents (< 45 ppm). Our experience allows us to
produce 1.4 MT per year.
By Robert Hunter,
Product Application Manager
Midrex Technologies, Inc.
The remainder of processing steps in steelmaking generate an injected into the blast furnace at the tuyeres). This carbon monox-
additional one to two percent. Note that each one percent repre- ide diffuses into the highly porous ore and collects an additional
sents 310 million tons per year. oxygen atom from the iron oxide, creating metallic iron (Fe) and
forming carbon dioxide. On the other hand, when methane is used,
Using Natural Gas Direct Reduction each molecule of CH4 is first reformed into one carbon monoxide
So, let’s return to the question of how iron is reduced from the oxide molecule) and two hydrogen molecules (each is H2). Each of these
into metal. In 1957 in Monterrey, Mexico, Juan Celada of Hylsamex three molecules will take one oxygen atom fromeach molecule of
started up the first commercial ironmaking plant using methane CH4 is first reformed into one carbon monoxide molecule) and two
as the reductant. In 1969, Don Beggs of Midland-Ross commis- hydrogen molecules (each is H2). Each of these three molecules will
sioned the first MIDREX Direct Reduction Plant for Gilmore Steel
®
take one oxygen atom from the iron oxide. So the products of the
in Portland, Oregon. Today the heirs of these technologies make reduction reaction are two water molecules (H2O) and one carbon
over 50 million tons per year of direct reduced iron using natural dioxide molecule (CO2). Only one-third as much CO2 is generated.
gas. In 2008, 40 million tons were made by the MIDREX Pro- ®
Were it possible to produce the entire world’s iron with natural
cess, almost 10 million tons by the HYL/Energiron Process and an gas direct reduction plants, over one billion tons of CO2 could be
additional one million tons by a plant in Venezuela which avoided per year. While that is not likely, the CO2 savings through
operates using the Finmet Process. use of DRI are significant. An example is the use of DRI in the blast
What is different about using methane instead of charcoal furnace, as is done by AK Steel of Middletown, Ohio.
or coke? Answer: the environmental effects. Methane is a far
cleaner fuel, especially when CO2 generation is considered. Results: Experience at AK Steel
To reduce iron with coke or charcoal each atom of oxygen in the For nearly two decades, AK Steel has been adding hot briquetted
iron oxide (iron ore) requires one atom of carbon. In a blast furnace iron (HBI) to the charge mix of their blast furnace. This is quite
the carbon from the coke or charcoal is first partially oxidized to car- similar to the practice of adding prepared scrap or other metallic
bon monoxide (CO) using gaseous oxygen. This oxygen is provided sources of iron (used grinding balls, for instance) to a blast
by the blast air (heated air enriched with additional oxygen, then furnace. It greatly enhances the productivity of the furnace while
With much of Midrex’s present and future direct reduction business in the Middle East and Eastern Europe/CIS, this office
provides an exceptional location for holding meetings with potential clients, suppliers, and others. In addition, it will prove useful
in the future for coordinating and managing projects.
A further benefit is that given London’s preeminence in global financing, there is ready access to a wealth of commercial and
investment banks, financial consultants, and other financial expertise.