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Kathon WT 1.5 Percent Biocide PDF

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The document describes a Safety Data Sheet (SDS) for a biocidal product called KATHONTM WT 1.5% BIOCIDE. It contains information about product identification, hazards, composition, first aid measures, fire fighting measures, accidental release measures, handling and storage, exposure controls/personal protection, physical and chemical properties, stability and reactivity, toxicological information, ecological information, disposal considerations, transport information, regulatory information, and other information.

The product being described is KATHONTM WT 1.5% BIOCIDE, which is a biocidal product.

The document lists several hazards of the product including causing severe skin burns and eye damage, and may cause an allergic skin reaction.

SAFETY DATA SHEET

THE DOW CHEMICAL COMPANY*

Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015


Print Date: 04/10/2015

THE DOW CHEMICAL COMPANY* encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. IDENTIFICATION
Product name: KATHON™ WT 1.5% BIOCIDE

Recommended use of the chemical and restrictions on use


Identified uses: Biocidal product

COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY*
Agent for Rohm and Haas Chemicals LLC
100 INDEPENDENCE MALL WEST
PHILADELPHIA PA 19106-2399
UNITED STATES

Customer Information Number: 215-592-3000


SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER


24-Hour Emergency Contact: 1 800 424 9300
Local Emergency Contact: 989-636-4400

2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Skin corrosion - Category 1B
Serious eye damage - Category 1
Skin sensitisation - Category 1

Label elements
Hazard pictograms

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 14


company of Dow
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Signal word: DANGER!

Hazards
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.

Precautionary statements
Prevention
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor/ physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/
physician.
If skin irritation or rash occurs: Get medical advice/ attention.
Wash contaminated clothing before reuse.

Storage
Store locked up.

Disposal
Dispose of contents/ container to an approved waste disposal plant.

Other hazards
no data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature: Aqueous solution of organic and inorganic compounds


This product is a mixture.
Component CASRN Concentration

5-Chloro-2-methyl-4-isothiazolin-3-one 26172-55-4 >= 1.15 - 1.25 %

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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

2-Methyl-4-isothiazolin-3-one 2682-20-4 >= 0.35 - 0.45 %

Magnesium Chloride 7786-30-3 >= 1.0 - 1.2 %

Magnesium nitrate 10377-60-3 >= 1.7 - 1.8 %

Copper nitrate 3251-23-8 >= 0.15 - 0.17 %

Water 7732-18-5 >= 95.5 - 96.2 %

4. FIRST AID MEASURES


Description of first aid measures
Inhalation: Move to fresh air. Give artificial respiration if breathing has stopped. If symptoms persist,
call a physician.

Skin contact: IMMEDIATELY get under a safety shower. Remove contaminated clothing. Wash off
with soap and water. Immediate medical attention is required. Wash contaminated clothing before re-
use. Do not take clothing home to be laundered. Discard contaminated shoes, belts, and other
articles made of leather.

Eye contact: Rinse immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.

Ingestion: Drink 1 or 2 glasses of water. IMMEDIATELY see a physician. Never give anything by
mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed


Notes to physician: MATERIAL IS CORROSIVE. It may not be advisable to induce vomiting.
Possible mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory
shock and convulsions maybe necessary.

5. FIREFIGHTING MEASURES
Suitable extinguishing media: Use extinguishing media appropriate for surrounding fire.

Unsuitable extinguishing media: no data available

Special hazards arising from the substance or mixture


Hazardous combustion products: no data available

Unusual Fire and Explosion Hazards: Combustion generates toxic fumes of the following: hydrogen
chloride Nitrogen oxides (NOx) sulfur oxides

Advice for firefighters

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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Fire Fighting Procedures: Cool containers/tanks with water spray. Minimize exposure. Do not
breathe fumes. Contain run-off.

Special protective equipment for firefighters: Wear self-contained breathing apparatus and
protective suit.

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures: Wear a NIOSH
approved (or equivalent) respirator (with organic vapor/acid gas cartridge and a dust/mist filter) during
spill clean-ups and deactivation of this material. MATERIAL IS CORROSIVE. Protective clothing,
including chemical splash goggles, nitrile or butyl rubber full length gloves, rubber apron, or clothing
made of nitrile or butyl rubber, and rubber overshoes must be worn during spill clean-ups and
deactivation of this material. If material comes in contact with the skin during clean-up operations,
IMMEDIATELY remove all contaminated clothing and wash exposed skin areas with soap and water.
See SECTION 4, First Aid Measures, for further information.

Environmental precautions: Do not allow material to contaminate ground water system. Prevent
product from entering drains.

Methods and materials for containment and cleaning up: WARNING: KEEP SPILLS AND
CLEAN-UP RESIDUALS OUTOF MUNICIPAL SEWERS AND OPEN BODIES OF WATER. Adsorb
the spill with spill pillows or inert solids such as clay or vermiculite, and transfer contaminated
materials to suitable containers for disposal. Deactivate spill area with freshly prepared solution of 5%
sodium bicarbonate and 5% sodium hypochlorite in water. Apply solution to the spill area at a ratio of
10 volumes deactivation solution per estimated volume of residual spill to deac tivate any residual
active ingredient. Let stand for 30 minutes. Flush the spill area with copious amounts of water to
chemical sewer (if in accordance with local procedures, permits and regulations). DO NOT add
deactivation solution to the waste pail to deactivate the adsorbed material. See Section 13, “Disposal
Considerations”, for information regarding the disposal of contained materials.

7. HANDLING AND STORAGE


Precautions for safe handling: This material is corrosive. For personal protection see section 8. Do
not handle material near food, feed or drinking water.

Conditions for safe storage: Keep in a well-ventilated place. The product as supplied may evolve
gas (largely carbon dioxide) slowly. To prevent the buildup of pressure the product is packaged in
specially vented containers, where necessary. Keep this product in the original container when not in
use. Container must be stored and transported in an upright position to prevent spilling the contents
through the vent, where fitted. Do not store this material in containers made of the following: steel Do
not store this material near food, feed or drinking water.
CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product
residue follow all MSDS and label warnings even after container is emptied. Expiration date based
only on retention of >95% actives during storage at 20ºC-25ºC (68ºF-77ºF).

Storage stability
Storage temperature: 1 - 55 °C (34 - 131 °F)

Page 4 of 14
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
5-Chloro-2-methyl-4- Rohm and Haas TWA 0.076 mg/m3
isothiazolin-3-one
Rohm and Haas STEL 0.23 mg/m3
2-Methyl-4-isothiazolin-3-one Rohm and Haas TWA 1.5 mg/m3
Rohm and Haas STEL 4.5 mg/m3

Exposure controls
Engineering controls: Use local exhaust ventilation with a minimum capture velocity of 150 ft/min.
(0.75 m/sec.) at the point of dust or mist evolution. Refer to the current edition of “Industrial
Ventilation: A Manual of Recommended Practice” published by the American Conference of
Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of
exhaust systems.

Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.

Individual protection measures


Eye/face protection: Use chemical splash goggles and face shield (ANSI Z87.1 or approved
equivalent). Eye protection worn must be compatible with respiratory protection system
employed.
Skin protection
Hand protection: Chemical-resistant gloves should be worn whenever this material is
handled. The glove(s) listed below may provide protection against permeation.
(Gloves of other chemically resistant materials may not provide adequate protection):
Butyl-rubber. Nitrile rubber. PVC gloves >1 mm thickness Gloves should be
removed and replaced immediately if there is any indication of degradation or
chemical breakthrough. Rinse and remove gloves immediately after use. Wash
hands with soap and water. NOTE: Material is a possible skin sensitizer.
Other protection: Wear as appropriate: Chemical resistant apron complete suit
protecting against chemicals
Respiratory protection: Typical use of this material does not result in workplace exposures
that exceed the exposure limits listed in the Exposure Limit Information Section. For those
special workplace conditions where the listed exposure limits are exceeded, a respiratory
protection program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed.
For concentrations up to 10 times the exposure limit, wear a properly fitted NIOSH approved
(or equivalent) half-mask or full facepiece air purifying respirator equipped with organic vapor
cartridges and N95 filters. If oil mist is present, use R95 or P95 filters. For those unlikely
situations where exposure may greatly exceed the listed exposure limits (i.e. greater than 10-
fold), or in any emergency situation, wear a properly fitted NIOSH approved (or equivalent)
self-contained breathing apparatus in the pressure demand mode or a full facepiece airline
respirator in the pressure demand mode with emergency escape provision. See SECTION 6,
Accidental Release Measures, for respirator and protective clothing requirements for spill
clean-up and decontamination of this material.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance

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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Physical state liquid


Color Light blue to light green
Odor Pungent odor
Odor Threshold no data available
pH 2.0 - 4.0
Melting point/range -3.00 °C ( 26.60 °F)
Freezing point no data available
Boiling point (760 mmHg) 100.00 °C ( 212.00 °F) estimated
Flash point Not applicable
Evaporation Rate (Butyl Acetate <1.00
= 1)
Flammability (solid, gas) Not Applicable
Lower explosion limit Not Applicable
Upper explosion limit Not Applicable
Vapor Pressure no data available
Relative Vapor Density (air = 1) 0.6200 estimated
Relative Density (water = 1) 1.0200
Water solubility completely soluble
Partition coefficient: n- log Pow: 0.401 Method Not Specified.
octanol/water
Auto-ignition temperature Not Applicable
Decomposition temperature no data available
Dynamic Viscosity 3.000 mPa.s at 25.00 °C (77.00 °F)
Kinematic Viscosity no data available
Explosive properties no data available
Oxidizing properties no data available
Molecular weight no data available
Percent volatility 95.00 - 96.00 % Water

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY


Reactivity: no data available

Chemical stability: no data available

Possibility of hazardous reactions: Stable under recommended storage conditions.


Product will not undergo polymerization.

Page 6 of 14
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Conditions to avoid: no data available

Incompatible materials: Avoid contact with the following: Oxidizing agents Amines. Reducing
agents. Mercaptans.

Hazardous decomposition products: Nitrogen oxides (NOx) Sulphur oxides hydrogen chloride

11. TOXICOLOGICAL INFORMATION

Toxicological information on this product or its components appear in this section when such data is
available.

Acute toxicity
Acute oral toxicity
LD50, Rat, female, 3,310 mg/kg
LD50, Rat, male, > 5,000 mg/kg

Acute dermal toxicity


LD50, Rabbit, > 5,000 mg/kg

Acute inhalation toxicity


LC50, Rat, 4 Hour, dust/mist, > 5 mg/l Estimated.

Skin corrosion/irritation
This material is corrosive.

Serious eye damage/eye irritation


Corrosive

Sensitization
Has caused allergic skin reactions when tested in guinea pigs.

Specific Target Organ Systemic Toxicity (Single Exposure)


Product test data not available.

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Product test data not available.

Carcinogenicity
Did not cause cancer in laboratory animals.

Teratogenicity
Did not show teratogenic effects in animal experiments.

Reproductive toxicity
In animal studies, did not interfere with reproduction.

Mutagenicity
Not mutagenic when tested in bacterial or mammalian systems.

Aspiration Hazard

Page 7 of 14
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Product test data not available.

COMPONENTS INFLUENCING TOXICOLOGY:

5-Chloro-2-methyl-4-isothiazolin-3-one
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.

Aspiration Hazard
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or
lung injury.

2-Methyl-4-isothiazolin-3-one
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: Inhalation
Target Organs: Respiratory Tract

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.

Aspiration Hazard
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or
lung injury.

Magnesium Chloride
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

Magnesium nitrate
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)


For similar material(s):
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.

Aspiration Hazard
Based on available information, aspiration hazard could not be determined.

Page 8 of 14
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Carcinogenicity
Component List Classification
Magnesium nitrate IARC Group 2A: Probably carcinogenic to
humans
Copper nitrate IARC Group 2A: Probably carcinogenic to
humans

12. ECOLOGICAL INFORMATION

Ecotoxicological information on this product or its components appear in this section when such data
is available.

Toxicity

5-Chloro-2-methyl-4-isothiazolin-3-one
Acute toxicity to fish
Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1
mg/L in the most sensitive species tested).
LC50, Rainbow trout (Oncorhynchus mykiss), 96 Hour, 0.19 mg/l, OECD Test Guideline 203
or Equivalent
LC50, Bluegill sunfish (Lepomis macrochirus), 96 Hour, 0.28 mg/l

Acute toxicity to aquatic invertebrates


EC50, Daphnia magna, 48 Hour, 0.16 mg/l

Acute toxicity to algae/aquatic plants


NOEC, Selenastrum capricornutum (green algae), Growth rate, 0.0099 mg/l
EC50, Algae (Selenastrum capricornutum), 72 Hour, Growth rate, 0.018 mg/l

Toxicity to bacteria
EC50, Bacteria, 16 Hour, 5.7 mg/l

Chronic toxicity to aquatic invertebrates


NOEC, Daphnia magna (Water flea), 21 d, number of offspring, 0.172000 mg/l
LOEC, Daphnia magna (Water flea), 21 d, number of offspring, 0.572000 mg/l

2-Methyl-4-isothiazolin-3-one
Acute toxicity to fish
Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1
mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 4.77 mg/l, OECD Test Guideline 203 or
Equivalent

Acute toxicity to aquatic invertebrates


LC50, Daphnia magna (Water flea), 48 Hour, 0.93 - 1.9 mg/l

Acute toxicity to algae/aquatic plants


EC50, Algae (Selenastrum capricornutum), 72 Hour, Growth rate, 0.158 mg/l, OECD Test
Guideline 201

Chronic toxicity to aquatic invertebrates

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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

NOEC, Daphnia magna, 21 d, 0.04 mg/l

Magnesium Chloride
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Gambusia affinis (Mosquito fish), static test, 96 Hour, 16,500 mg/l, Method Not
Specified.

Acute toxicity to aquatic invertebrates


EC50, Daphnia magna (Water flea), 24 Hour, 3,190 mg/l, Directive 84/449/EEC, C.2

Acute toxicity to algae/aquatic plants


EC50, alga Scenedesmus sp., 72 Hour, Biomass, 2,200 mg/l, OECD Test Guideline 201 or
Equivalent

Magnesium nitrate
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.
For similar material(s):
LC50, Poecilia reticulata (guppy), 96 Hour, > 100 mg/l

Acute toxicity to aquatic invertebrates


For similar material(s):
EC50, Daphnia magna, 48 Hour, > 100 mg/l

Acute toxicity to algae/aquatic plants


For similar material(s):
ErC50, Algae, 72 Hour, Growth rate, > 100 mg/l

Copper nitrate
Acute toxicity to fish
Material is very highly toxic to aquatic organisms on an acute basis (LC50/EC50 <0.1 mg/L in
the most sensitive species).
LC50, Coho salmon, silver salmon (Oncorhynchus kisutch), 96 Hour, 0.286 mg/l, Method Not
Specified.
LC50, Cyprinodon variegatus (sheepshead minnow), 96 Hour, 0.22 mg/l, Method Not
Specified.
LC50, Zebra fish (Danio/Brachydanio rerio), 96 Hour, 0.21 mg/l, Method Not Specified.
LC50, Mosquito fish (Gambusia affinis), 72 Hour, 0.12 mg/l, Method Not Specified.
LC50, Bluegill sunfish (Lepomis macrochirus), 96 Hour, 0.62 mg/l, Method Not Specified.
EC10, Rainbow trout (Salmo gairdneri), 672 Hour, 0.0165 mg/l, Method Not Specified.

Acute toxicity to aquatic invertebrates


LC50, ceriodaphnia dubia (water flea), 48 Hour, 0.066 mg/l, Method Not Specified.

Acute toxicity to algae/aquatic plants


EC50, Marine diatom (Thalassiosira pseudonana), 72 Hour, Growth rate, 0.005 mg/l
EC50, Algae, 96 Hour, Growth rate, 0.033 mg/l
EC50, Algae (Selenastrum capricornutum), 336 Hour, 0.085 mg/l
EC50, Algae, 504 Hour, 0.07 mg/l

Persistence and degradability

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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

5-Chloro-2-methyl-4-isothiazolin-3-one
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Not applicable
Biodegradation: 98 %
Exposure time: 2 d
Method: OECD Test Guideline 302B or Equivalent

2-Methyl-4-isothiazolin-3-one
Biodegradability: Material is expected to be readily biodegradable.

Biodegradation: 98 %
Exposure time: 48 d
Method: Simulation study

Magnesium Chloride
Biodegradability: Biodegradation is not applicable.

Magnesium nitrate
Biodegradability: No relevant data found.

Bioaccumulative potential
Partition coefficient: n-octanol/water(log Pow): 0.401 Method Not Specified.

Mobility in soil

5-Chloro-2-methyl-4-isothiazolin-3-one
No relevant data found.

2-Methyl-4-isothiazolin-3-one
No relevant data found.

Magnesium Chloride
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient(Koc): 23.7

Magnesium nitrate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry’s constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient(Koc): 24

Copper nitrate
No data available.

13. DISPOSAL CONSIDERATIONS


Disposal methods: Incinerate liquid and contaminated solids in accordance with local, state, and
federal regulations. (See 40 CFR 268)

Page 11 of 14
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

14. TRANSPORT INFORMATION


DOT
Proper shipping name Corrosive liquid, acidic, organic, n.o.s.(5-Chloro-2-methyl-4-
isothiazolin-3-one)
UN number UN 3265
Class 8
Packing group II

Classification for SEA transport (IMO-IMDG):


Proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(5-Chloro-
2-methyl-4-isothiazolin-3-one)
UN number UN 3265
Class 8
Packing group II
Marine pollutant 5-Chloro-2-methyl-4-isothiazolin-3-one
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):


Proper shipping name Corrosive liquid, acidic, organic, n.o.s.(5-Chloro-2-methyl-4-
isothiazolin-3-one)
UN number UN 3265
Class 8
Packing group II

This information is not intended to convey all specific regulatory or operational


requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION


OSHA Hazard Communication Standard
This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR
1910.1200).

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Acute Health Hazard

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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains a chemical which is listed in Section 313 at or above de minimis concentrations.
The following listed chemicals are present: (Quantity present is found elsewhere on this MSDS.)
Components CASRN
Magnesium nitrate (10377-60-3) as nitrate compound 10377-60-3

Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)


Section 103
This material is regulated under the Comprehensive Environmental Response, Compensation and
Liability Act (CERCLA)and the Superfund Amendments and Reauthorization Act (SARA) Title III
Section 304. This material is or contains chemical(s) listed in 40 CFR Table 302.4 or nondesignated
RCRA ICR substance(s). (Nondesignated ICR substances apply to materials that will not be reused.)
The Reportable Quantity(s) (RQ) are listed below. Releases in excess of its reportable quantity must
be reported to the National Response Center (1-800-424-8802) and to the appropriate state and local
emergency response organizations.
D002, 100lbs.

Pennsylvania
Any material listed as “Not Hazardous” in the CAS REG NO. column of SECTION 2,
Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the
Pennsylvania Worker and Community Right-to-Know Act.

United States TSCA Inventory (TSCA)


This product contains chemical substance(s) exempt from U.S. EPA TSCA Inventory requirements. It
is regulated as a pesticide subject to Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA)
requirements.

Federal Insecticide, Fungicide and Rodenticide Act


EPA Registration Number: 707-133
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels
of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:

DANGER

Corrosive
Causes irreversible eye damage and skin burns
May cause allergic skin reaction
Harmful if inhaled
Harmful if swallowed or absorbed through the skin
This chemical is toxic to aquatic plants, fish and aquatic invertebrates.

16. OTHER INFORMATION

Hazard Rating System


HMIS

Page 13 of 14
Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015

Physical
Health Flammability
Hazard
3 0 0

Revision
Identification Number: 101080112 / 1001 / Issue Date: 04/01/2015 / Version: 2.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
Rohm and Haas Rohm and Haas OEL’s
STEL Short Term Exposure Limit (STEL):
TWA Time Weighted Average (TWA):

Information Source and References


This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

THE DOW CHEMICAL COMPANY* urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.

Page 14 of 14

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