Kathon WT 1.5 Percent Biocide PDF
Kathon WT 1.5 Percent Biocide PDF
Kathon WT 1.5 Percent Biocide PDF
THE DOW CHEMICAL COMPANY* encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: KATHON™ WT 1.5% BIOCIDE
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY*
Agent for Rohm and Haas Chemicals LLC
100 INDEPENDENCE MALL WEST
PHILADELPHIA PA 19106-2399
UNITED STATES
2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Skin corrosion - Category 1B
Serious eye damage - Category 1
Skin sensitisation - Category 1
Label elements
Hazard pictograms
Hazards
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary statements
Prevention
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor/ physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/
physician.
If skin irritation or rash occurs: Get medical advice/ attention.
Wash contaminated clothing before reuse.
Storage
Store locked up.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
no data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Skin contact: IMMEDIATELY get under a safety shower. Remove contaminated clothing. Wash off
with soap and water. Immediate medical attention is required. Wash contaminated clothing before re-
use. Do not take clothing home to be laundered. Discard contaminated shoes, belts, and other
articles made of leather.
Eye contact: Rinse immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.
Ingestion: Drink 1 or 2 glasses of water. IMMEDIATELY see a physician. Never give anything by
mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Use extinguishing media appropriate for surrounding fire.
Unusual Fire and Explosion Hazards: Combustion generates toxic fumes of the following: hydrogen
chloride Nitrogen oxides (NOx) sulfur oxides
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Fire Fighting Procedures: Cool containers/tanks with water spray. Minimize exposure. Do not
breathe fumes. Contain run-off.
Special protective equipment for firefighters: Wear self-contained breathing apparatus and
protective suit.
Environmental precautions: Do not allow material to contaminate ground water system. Prevent
product from entering drains.
Methods and materials for containment and cleaning up: WARNING: KEEP SPILLS AND
CLEAN-UP RESIDUALS OUTOF MUNICIPAL SEWERS AND OPEN BODIES OF WATER. Adsorb
the spill with spill pillows or inert solids such as clay or vermiculite, and transfer contaminated
materials to suitable containers for disposal. Deactivate spill area with freshly prepared solution of 5%
sodium bicarbonate and 5% sodium hypochlorite in water. Apply solution to the spill area at a ratio of
10 volumes deactivation solution per estimated volume of residual spill to deac tivate any residual
active ingredient. Let stand for 30 minutes. Flush the spill area with copious amounts of water to
chemical sewer (if in accordance with local procedures, permits and regulations). DO NOT add
deactivation solution to the waste pail to deactivate the adsorbed material. See Section 13, “Disposal
Considerations”, for information regarding the disposal of contained materials.
Conditions for safe storage: Keep in a well-ventilated place. The product as supplied may evolve
gas (largely carbon dioxide) slowly. To prevent the buildup of pressure the product is packaged in
specially vented containers, where necessary. Keep this product in the original container when not in
use. Container must be stored and transported in an upright position to prevent spilling the contents
through the vent, where fitted. Do not store this material in containers made of the following: steel Do
not store this material near food, feed or drinking water.
CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product
residue follow all MSDS and label warnings even after container is emptied. Expiration date based
only on retention of >95% actives during storage at 20ºC-25ºC (68ºF-77ºF).
Storage stability
Storage temperature: 1 - 55 °C (34 - 131 °F)
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Exposure controls
Engineering controls: Use local exhaust ventilation with a minimum capture velocity of 150 ft/min.
(0.75 m/sec.) at the point of dust or mist evolution. Refer to the current edition of “Industrial
Ventilation: A Manual of Recommended Practice” published by the American Conference of
Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of
exhaust systems.
Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Incompatible materials: Avoid contact with the following: Oxidizing agents Amines. Reducing
agents. Mercaptans.
Hazardous decomposition products: Nitrogen oxides (NOx) Sulphur oxides hydrogen chloride
Toxicological information on this product or its components appear in this section when such data is
available.
Acute toxicity
Acute oral toxicity
LD50, Rat, female, 3,310 mg/kg
LD50, Rat, male, > 5,000 mg/kg
Skin corrosion/irritation
This material is corrosive.
Sensitization
Has caused allergic skin reactions when tested in guinea pigs.
Carcinogenicity
Did not cause cancer in laboratory animals.
Teratogenicity
Did not show teratogenic effects in animal experiments.
Reproductive toxicity
In animal studies, did not interfere with reproduction.
Mutagenicity
Not mutagenic when tested in bacterial or mammalian systems.
Aspiration Hazard
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
5-Chloro-2-methyl-4-isothiazolin-3-one
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Aspiration Hazard
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or
lung injury.
2-Methyl-4-isothiazolin-3-one
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: Inhalation
Target Organs: Respiratory Tract
Aspiration Hazard
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or
lung injury.
Magnesium Chloride
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Magnesium nitrate
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Carcinogenicity
Component List Classification
Magnesium nitrate IARC Group 2A: Probably carcinogenic to
humans
Copper nitrate IARC Group 2A: Probably carcinogenic to
humans
Ecotoxicological information on this product or its components appear in this section when such data
is available.
Toxicity
5-Chloro-2-methyl-4-isothiazolin-3-one
Acute toxicity to fish
Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1
mg/L in the most sensitive species tested).
LC50, Rainbow trout (Oncorhynchus mykiss), 96 Hour, 0.19 mg/l, OECD Test Guideline 203
or Equivalent
LC50, Bluegill sunfish (Lepomis macrochirus), 96 Hour, 0.28 mg/l
Toxicity to bacteria
EC50, Bacteria, 16 Hour, 5.7 mg/l
2-Methyl-4-isothiazolin-3-one
Acute toxicity to fish
Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1
mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 4.77 mg/l, OECD Test Guideline 203 or
Equivalent
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Magnesium Chloride
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Gambusia affinis (Mosquito fish), static test, 96 Hour, 16,500 mg/l, Method Not
Specified.
Magnesium nitrate
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.
For similar material(s):
LC50, Poecilia reticulata (guppy), 96 Hour, > 100 mg/l
Copper nitrate
Acute toxicity to fish
Material is very highly toxic to aquatic organisms on an acute basis (LC50/EC50 <0.1 mg/L in
the most sensitive species).
LC50, Coho salmon, silver salmon (Oncorhynchus kisutch), 96 Hour, 0.286 mg/l, Method Not
Specified.
LC50, Cyprinodon variegatus (sheepshead minnow), 96 Hour, 0.22 mg/l, Method Not
Specified.
LC50, Zebra fish (Danio/Brachydanio rerio), 96 Hour, 0.21 mg/l, Method Not Specified.
LC50, Mosquito fish (Gambusia affinis), 72 Hour, 0.12 mg/l, Method Not Specified.
LC50, Bluegill sunfish (Lepomis macrochirus), 96 Hour, 0.62 mg/l, Method Not Specified.
EC10, Rainbow trout (Salmo gairdneri), 672 Hour, 0.0165 mg/l, Method Not Specified.
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
5-Chloro-2-methyl-4-isothiazolin-3-one
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Not applicable
Biodegradation: 98 %
Exposure time: 2 d
Method: OECD Test Guideline 302B or Equivalent
2-Methyl-4-isothiazolin-3-one
Biodegradability: Material is expected to be readily biodegradable.
Biodegradation: 98 %
Exposure time: 48 d
Method: Simulation study
Magnesium Chloride
Biodegradability: Biodegradation is not applicable.
Magnesium nitrate
Biodegradability: No relevant data found.
Bioaccumulative potential
Partition coefficient: n-octanol/water(log Pow): 0.401 Method Not Specified.
Mobility in soil
5-Chloro-2-methyl-4-isothiazolin-3-one
No relevant data found.
2-Methyl-4-isothiazolin-3-one
No relevant data found.
Magnesium Chloride
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient(Koc): 23.7
Magnesium nitrate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry’s constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient(Koc): 24
Copper nitrate
No data available.
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Acute Health Hazard
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains a chemical which is listed in Section 313 at or above de minimis concentrations.
The following listed chemicals are present: (Quantity present is found elsewhere on this MSDS.)
Components CASRN
Magnesium nitrate (10377-60-3) as nitrate compound 10377-60-3
Pennsylvania
Any material listed as “Not Hazardous” in the CAS REG NO. column of SECTION 2,
Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the
Pennsylvania Worker and Community Right-to-Know Act.
DANGER
Corrosive
Causes irreversible eye damage and skin burns
May cause allergic skin reaction
Harmful if inhaled
Harmful if swallowed or absorbed through the skin
This chemical is toxic to aquatic plants, fish and aquatic invertebrates.
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Product name: KATHON™ WT 1.5% BIOCIDE Issue Date: 04/01/2015
Physical
Health Flammability
Hazard
3 0 0
Revision
Identification Number: 101080112 / 1001 / Issue Date: 04/01/2015 / Version: 2.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
Rohm and Haas Rohm and Haas OEL’s
STEL Short Term Exposure Limit (STEL):
TWA Time Weighted Average (TWA):
THE DOW CHEMICAL COMPANY* urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
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