Atomic Structure

Atomic structure
1. The nucleons are

I. Protons and electrons
II. Neutrons and electrons
III. Protons and neutrons
IV. None of these
2. The isotope deuterium of hydrogen has
I. No neutrons and one proton
II. One neutrons and two protons
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III. One electron and two neutron
IV. One proton and one neutron
3. The electrons present in the outermost shell are called
I. Valency electrons
II. Octate electrons
III. Duplet electrons
IV. Valence electrons
4. An alpha particle contains
I. 4 positive charge and 2 mass unit
II. 2 positive charge and 4 mass unit
III. 2 positive charge and 2 mass unit
IV. 4 positive charge and 4 mass unit
5. The atomic number of sodium is 11 and its mass number is 23. It has
I. 11 neutrons and 12 protons
II. 12 protons and 11 electrons
III. 11 electrons and 12 neutrons
IV. 12 electrons and 11 neutrons
6. The electronic configuration of chlorine is
I. 2,7
II. 2,8,8,7
III. 2,8,7
IV. 2,7,8
7. The isotope used to remove the brain tumours and treatment of cancer is
I. U-235
II. Na-24
III. Iodine
IV. C0-60
8. In an alpha scattering experiment, few alpha particles rebounded because
I. Most of the space in the atom is occupied
II. Positive charge of the atoms very little space
III. The mass of the atom is concentrated in the centre
IV. All the positive charge and mass of the atom is concentrated in small volume
ANSWERS
1. III
2. IV
3. IV
4. II
5. III
6. III
7. IV
8. II
1. If the electronic structure of oxygen atom is written as 1s2 2s2 2p4 it would violate
(A) Hund’s rule
(B) Paulis exclusion principle Techofworld.In

(C) Both Hund’s and Pauli’s principles
(D) None of these
2. Number of nodal planes for f-orbital are
(A) 3
(B) 2
(C) 1
(D) 0
3. One Bohr magneton equals
(A) ehc /4π n
(B) e c /4hπ m
(C) hc /m e4π
(D) eh /4π m c
4. Three isotopes of an element have mass numbers M, (M + 1) and (M + 2). If the mean
mass number is (M + 0.5) than which of the following ratio may be accepted for M , (M
+ 1) , (M + 2) in that order.
(A) 1 : 1 : 1
(B) 4 : 1 : 1
(C) 3 : 2 : 1
(D) 2 : 1 : 1
5. A possible set of quantum numbers for the last electron added to a gallium atom (Z =
31) in its ground state is
n l m ms
(A) 4 1 –1 +1/2
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(B) 4 0 0 –1/2
(C) 3 2 +2 +1/2
(D) 3 0 0 –1/2
6. The angle made by angular momentum vector of an electron with z axis is given by
(A) cosθ = l/m
(B) cosθ = √l/m
(C) cos θ = √[(l+1)/m ]
(D) cosθ = m/√l(l+1)
7. The distance between 3rd and 2nd orbit of hydrogen atom is
(A) 2.646 ×10–8 cm
(B) 2.116 ×10–8 cm
(C) 1.058 ×10–8 cm
(D) 0.529 × 10–8 cm
8. An atom has four unpaired electrons. The total spin of this atom will be
(A) 1
(B) 1.5
(C) 2
(D) 4
9. For a ‘ d ‘ electron , the orbital angular momentum is
(A) √6 h
(B) √2 h
(C) h
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(D) 2 h
10. Which of the following pairs can form correct set of isosters ?
(A) MgS , CaF2
(B) C6H6 , B3N3H6
(C) CO , N2O
(D) All the above
ANSWER:
1. (D) 2. (A) 3. (D) 4. (B) 5. (A) 6. (D) 7. (A) 8. (C) 9. (A) 10. (B)
11. Electromagnetic radiation (Photon) with least wavelength result when an electron in
the hydrogen atom falls from n = 5 to
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(A) n = 1
(B) n = 2
(C) n = 3
(D) n = 4
12. The first five ionization energies of an element are 801 , 2428 , 3660 , 25030 , 32835
in kJ/mol. Then the element could be
(A) a halogen
(B) a noble gas
(C) a third group element
(D) a second group element
13. The energy required to melt 1g ice is 33J. The number of quanta of radiation of
frequency 4.67 ×1013sec–1, that must be absorbed to melt 10 g ice is
(A) 1.065 × 1022

(B) 3.205 × 1023
(C) 9.076 × 1020
(D) none of these
14. If the wave length of first line of the Balmer series of hydrogen atom is 656.1 nm , the
wave length of second line of this series would be
(A) 218.7 nm
(B) 328.0 nm
(C) 486.0 nm
(D) 640.0 nm
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15. The energy of an electron in the first Bohr orbit for He+ ion is –54.4 eV. Which one
of the following is a possible excited state for electron in Bohr orbit of He+ ion ?
(A) –6.04 eV
(B) – 6.8eV
(C) – 1.7 eV
(D) +1.36 eV
16. The outermost electronic configuration of the most electronegative element is
(A) ns2 , np3
(B) ns2 , np4
(C) ns2 , np5
(D) ns2 , np6
17. The first four ionization energies of an element are 191 , 578 , 872 and 5962 kcal. The
number of valence electrons in the element is
(A) 1
(B) 2
(C) 3
(D) 4
18. The quantum numbers of +1/2 and –1/2 for the electron spin represent
(A) Rotation of the electron in clockwise and anticlockwise direction respectively
(B) Rotation of the electron in anticlockwise and clockwise direction respectively
(C) Magnetic moment of the electron pointing up and down respectively
(D) Two quantum mechanical spin states which have no classical analogue.
19. A atom forms an ion by the loss of three electrons. The ion has an electronic
configuration [Ar]3d6 . The symbol of the ion is
(A) Fe3+
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(B) Ni3+
(C) Co3+
(D) Mn+3
20. Given that in H–atom , the transition energy for n = 1 to n = 2 is 10.2 eV , the energy
for the same transition in Be3+ is
(A) 20.4 eV
(B) 30.6 eV
(C) 40.8 eV
(D) None of these

ANSWER:
11. (A) 12. (C) 13. (A) 14. (C) 15. (A) 16. (C) 17. (C) 18. (D) 9. (C) 20. (D)
1. Which of the following defines the Mass number of an atom?
a. number of protons + number of electrons

b. number of neutrons + number of electrons
c. number of protons + number of neutrons
d. number of electrons
Answer (c).
2. Who is credited with the discovery of electron?
a. JJ Thomson
b. James Chadwick
c. Ernest Rutherford
d. Niels Bohr
Answer (a).
3. An atom has a mass number of 37 and atomic number 17. How many protons does it have?
a. 20
b. 17
c. 54
d. 21
Answer (b).
4. Which of the following mostly accounts for the mass of an atom?
a. neutrons
b. neutron and proton
c. electron and proton
d. electron and neutron
Answer (b).
5. Within an atom, the nucleus when compared to the extra nuclear part is
a. bigger in volume and heavier in mass

b. smaller in volume but heavier in mass
c. smaller in volume and lighter in mass
d. same size
Answer (b).
6. What would be the atomic number of the element in whose atom the K and L shells are full?
a. 10
b. 12
c. 14
d. 16
Answer (a).
7. Which metal was used by Rutherford in his alpha-scattering experiment?
a. gold
b. platinum
c. silver
d. lead
Answer (a).
8. An element has an electronic configuration of 2, 8, 7. Its valency is
a. 2
b. 7
c. 3
d. 1
Answer (d).
9. During a chemical reaction, atomic number
a. changes
b. remains same
c. changes and then is restored
d. changes alternately
Answer (b).
10. Which isotope of hydrogen contains only one proton and no neutron in its nucleus?
a. protium
b. deuterium
c. tritium
d. None of the above
Answer (a).
11. Who of the following was awarded the Nobel Prize for his measurement of elementary electronic
charge?
a. Rutherford
b. Robert Millikan
c. James Chadwick
d. JJ Thomson
Answer (b).
12. How are the subshells in an atom labelled?
a. s, p, d, f, g
b. s, p, f, g, d
c. s, f, g, d, f
d. s, d, g, p, f
Answer (a).
13. The isotopes of neutral atoms of an element differ in
a. Atomic number
b. Mass number
c. Number of electrons
d. Chemical properties
Answer (b).
14. The electronic configuration of an atom having atomic number 20 is
a. 2, 8, 8, 2
b. 2, 8, 10
c. 2, 6, 8, 4
d. 2, 4, 8, 6
Answer (a).
15. Almost the entire mass of an atom is concentrated in the
a. proton
b. electrons
c. nucleus
d. neutrons
Answer (c).
16. An atom differs from its ion in
a. Nuclear charge
b. Mass number
c. Number of electrons
d. Number of neutrons
Answer (c).
17. The proton is heavier than an electron by
a. 187 times
b. 1837 times
c. 3837 times
d. 2827 times
Answer (b).
18. Which of the following is true about a charged atom?
a. anion is negatively charged

b. cation is negatively charged
c. cation has gained an electron
d. anion has lost an electron
Answer (a).
19. Which of the following is not a fundamental particle?
a. Proton
b. Neutron
c. Alpha particle
d. Electron
Answer (c).
20. Which one among the following most correctly determines the atomic number of an element?
a. Number of protons
b. Number of protons and electrons
c. Number of ions
d. Number of nucleons
Answer (a).
21. Which of the following is the correct electronic configuration of Nickel with an atomic number 28?
a. 1s2 2s2 2p4 3s2 3p8 3d10

b. 1s2 2s2 2p6 3s2 3p6 3d10
c. 1s2 2s2 2p4 3s2 3p6 3d10 4s2
d. 1s2 2s2 2p6 3s2 3p6 3d8 4s2
Answer (d).
22. How many electrons does the outermost shell of neon have?
a. 4
b. 8
c. 2
d. 16
Answer (b).
23. Which of the following determines the chemical properties of an element?
a. Number of electrons
b. Number of neutrons
c. Number of protons
d. All of the above
Answer (a).
24. The number of protons in a negatively charged atom (anion) is
a. more than the atomic number of the element

b. less than the atomic number of the element
c. more than the number of electrons in the atom
d. less than the number of electrons in the atom
Answer (d).
25. Atoms which have same mass number but different atomic number are called
a. isotopes
b. isomers
c. isotones
d. isobars
Answer (d).
26. The atomic theory of matter was first proposed by
a. John Dalton
b. Rutherford
c. J. J. Thomson
d. Niels Bohr
Answer (a).
1. All of the following were theorized by Bohr in his description of the atom except
Angular momentum of electrons in Electrons revolve in discrete circular

A. B.
multiples of h/2? orbits
Energy of each electron is directly Electrons radiate energy continuously

C. D.
proportional to n2 in a given orbit.
Answer & Explanation
Answer: Option D
Explanation:
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2. The letters s p d and f are used to represent which quantum numbers
A. Principal B. Azimuthal
C. Magnetic D. Spin
Answer: Option B
Explanation:
3. The magnetic quantum number (QN) has its values determined directly by the value of
A. Principal (QN) B. Azimuthal (QN)
C. Spin (QN) D. Both a & b
Answer: Option B
Explanation:
4. The atomic number of an element having maximum number of unpaired electrons in p-subshell is
A. 7 B. 10
C. 12 D. 16
Answer: Option A
Explanation:
5. The maximum number of electron in a sub shell with ? = 3fs
A. 6 B. 10
C. 14 D. 18
Answer: Option C
Explanation:
6. Radius of the third shell of H-atom is
A. 5.761 A? B. 4.761 A?
C. 6.671 A? D. 3.716 A?
Answer: Option B
Explanation:
7. When an atom absorbs energy the lines in the spectrum will appear which are
A. Brighter B. Darker
C. Colourless D. Hard to locate
Answer: Option B
Explanation:

8. Colour of fluorescene produced by cathode rays depends upon
A. Temperature B. Pressure
C. Volume D. Composition of glass
Answer: Option D
Explanation:
9. Which one is not true about cathode rays?
A. 9.11x10-31 Kg B. Cast shadow
C. Heat up the platinum foil D. Cannot ionize
Answer: Option D
Explanation:
10. Positive rays are produced
A. By burning of gas B. By cooling of the gas
By the bombardment of cathode rays From anode like cathode rays

C. D.
on gas molecules produced from cathode
Answer: Option C
Explanation:
11. A fast moving neutron can eject from nitrogen
A. ? = rays B. ? = rays
C. ? = rays D. electrons
Answer: Option B
Explanation:
12. Rutherfords planet like structure was defective and unsatisfactory because
Moving e- accelerate towards the

A. B. Continuous spectrum
nucleus
behavior of electron remain

C. D. all
unexplained
Answer: Option D
Explanation:
13. The relationship between energy of a photon of light and its frequency is given by
A. de-Broglie duel nature of matter B. Bohrs model
C. Plancks Quantum theory D. Rutherfords atomic model
Answer: Option C
Explanation:
14. Splitting of spectral lines when atom is subjected to magnetic field is called
A. Zeemans effect B. Starks effect
C. Photo electric effect D. Compton effect
Answer: Option A
Explanation:
15. The velocity of the photon
A. Is independent of wavelength B. Depends upon source
C. Depends upon its frequency D. Equals to the square of amplitude

Answer: Option A
Explanation:
16. Which one of the following explain the shape of orbitals
A. Principal of quantum number B. Azimuthal quantum number
C. Magnetic quantum number D. Spin quantum number
Answer: Option B
Explanation:
17. Atom cannot be divided into simple unitstheorized by
A. Rutherford B. Dalton
C. Bohr D. Schrodinger
Answer: Option B
Explanation:
18. Pressure in gas discharge tube was kept
A. 10 torr B. 1 torr
C. 0.1 torr D. 0.01 torr
Answer: Option D
Explanation:
19. The number of fundamental particles in an atom of the lightest isotope carbon are
A. 6 B. 12
C. 18 D. 20
Answer: Option C
Explanation:
20. Angle of deflection was studied by
A. Hitorff B. Stoney
C. William Crookes D. J.Perrin
Answer: Option D
Explanation:
21. Increase in atomic number is observed during
A. Alpha emission B. Beta emission
C. Both a & b D. Radioactivity
Answer: Option B
Explanation:
22. Positive rays give flash on
A. AgNO3 plate B. AgCl plate
C. ZnO D. ZnS
Answer: Option D
Explanation:
23. Free neutron changes into proton with the emission of

A. Neutrino B. Electron
C. Both a & b D. Meson
Answer: Option C
Explanation:
24. The value of e/m ratio of electron is
A. 6.02 x 1023 C/kg B. 1.7588 x 1020 C/kg
C. 9.1095 x 10-31 C/kg D. 1.7588 x 1011 C/kg
Answer: Option D
Explanation:
25. Charge of electron was measured by
A. J.J Thomson B. Millikan
C. Rutherford D. Perrin
Answer: Option B
Explanation:
26. Rutherford bombarded ______________ particles in discovery of nucleus
A. Gamma-rays B. Alpha-rays
C. Beta-rays D. X-rays
Answer: Option B
Explanation:
27. Planks theory says energy is emitted
A. In continuous manner B. Discontinuous manner
C. Simultaneously D. In the form of heat
Answer: Option B
Explanation:
28. Angular momentum of an electron
A. n2h/2? B. nk2/2?
C. nh/4? D. nh/2?
Answer: Option D
Explanation:
29. 2nd orbit is _______ away from nucleus of H-atom as compared to 1st orbit is
A. 2-times B. 3-times
C. 4-times D. 6 times
Answer: Option C
Explanation:
30. The maximum number of orbitals present in a subshell that is represented by Azimuthal
quantum number = 3 will be
A. 1 B. 3
C. 5 D. 7

Answer: Option D
Explanation:
31. The correct electronic configuration of Cu is
A. [Ar]4s1 B. [Ar]4s2
C. [Ar]3d104s1 D. [Ar]3d94s2
Answer: Option C
Explanation:
32. Pfund series are produced in the spectrum of hydrogen atom
when electrons jump down to 2nd- when electrons jump down to 3rd-
A. B.
orbit orbit
when electrons jump down to 4th- when electrons jump down to 5th-
C. D.
orbit orbit
Answer: Option D
Explanation:
33. Atomic orbits having same evergy are called
A. Degenerate orbitals B. Bonding molecular orbitals
C. Anti bonding molecular orbitals D. Half filled orbitals
Answer: Option A
Explanation:
34. Sommerfelds modification in Bohrs model is
A. Orbit is cylindrical B. Orbit is elliptical

C. Orbit is longitudinal D. Orbit is asymmetrical
Answer: Option B
Explanation:
35. When electrons collide with heavy metals than ______ are produced.
A. Beta-rays B. Alpha-rays
C. X-rays D. Gamma-rays
Answer: Option C
Explanation:
36. Plancks equation is
A. E = mc2 B. mvr = nh/2?
C. E = h? D. ? = h/mv
Answer: Option C
Explanation:
37. Atom with higher atomic number produces X-rays of
A. Shorter wavelength B. Larger wavelength
C. X-ray not produced D. All are possible
Answer: Option A
Explanation:

38. Wavelength of electron was verified by
A. Moseley B. Davisson and Germer
C. Einstein D. Roentgen
Answer: Option B
Explanation:
39. Space around nucleus where finding probability of electrons is maximum is called
A. Orbital B. Orbit is elliptical
C. subshell D. Electron cloud
Answer: Option A
Explanation:
40. Quantum number which tells the energy of electron is
A. n B. 1
C. m D. s
Answer: Option A
Explanation:
41. Electronic configuration of K is
A. [Ar]4s2 B. [Ar]4s1
C. [Kr]5s1 D. [He]2s1
Answer: Option B
Explanation:
42. ____________ can expel proteons from paraffins
A. Electron B. Positron
C. Neutron D. None of above has such capability
Answer: Option C
Explanation:
43. Milikan used __________ in his atomizer
A. Milk B. Honey
C. Oil D. Water
Answer: Option C
Explanation:
44. Centrifugal forces are balanced in atom by
A. Attractive forces B. Repulsive force
C. Electrons D. Neutrons
Answer: Option A
Explanation:
45. Spectrum is produced due to
A. Different wavelength B. Different colours
C. Different intensities D. all have little contribution

Answer: Option A
Explanation:
46. When 6d orbital is complete the entering electron goes into
A. 7f B. 7s
C. 7p D. 7d
Answer: Option C
Explanation:
47. When electron jump into orbit 1 then series obtained is
A. Lyman B. Paschen
C. Pfund D. Brackett
Answer: Option A
Explanation:
48. Neutrons moving with an energy of 1.2 MeV are called
A. Fast neutrons B. Slow neutrons
C. Moderate neutrons D. All are possible
Answer: Option A
Explanation:
49. Splitting of spectral lines when atoms are subjected to strong electric filed is called
A. Zeeman effect B. Stark effect

C. Photoelectric effect D. Compton effect
Answer: Option B
Explanation:
50. Three quantum number have been derived from equation of
A. de-Broglie B. Plancks
C. Schrodinger D. Heisenberg
Answer: Option C
Explanation:

Atomic Structure

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Atomic structure

1. The nucleons are

(A) Hund’s rule

(B) Paulis exclusion principle Techofworld.In

(D) None of these

2. Number of nodal planes for f-orbital are

3. One Bohr magneton equals

(A) ehc /4π n

(A) cosθ = l/m

(B) cosθ = √l/m

(C) cos θ = √[(l+1)/m ]

(D) cosθ = m/√l(l+1)

7. The distance between 3rd and 2nd orbit of hydrogen atom is

(A) 2.646 ×10–8 cm

(B) 2.116 ×10–8 cm

(C) 1.058 ×10–8 cm

(D) 0.529 × 10–8 cm

9. For a ‘ d ‘ electron , the orbital angular momentum is

(A) MgS , CaF2

(B) C6H6 , B3N3H6

(D) All the above

(B) a noble gas

(C) a third group element

(D) a second group element

(A) 1.065 × 1022

(C) 9.076 × 1020

(D) none of these

16. The outermost electronic configuration of the most electronegative element is

(A) ns2 , np3

(B) ns2 , np4

(C) ns2 , np5

(D) ns2 , np6

(A) Rotation of the electron in clockwise and anticlockwise direction respectively

(B) Rotation of the electron in anticlockwise and clockwise direction respectively

(C) Magnetic moment of the electron pointing up and down respectively

(D) None of these

1. Which of the following defines the Mass number of an atom?

a. number of protons + number of electrons

2. Who is credited with the discovery of electron?

4. Which of the following mostly accounts for the mass of an atom?

a. bigger in volume and heavier in mass

7. Which metal was used by Rutherford in his alpha-scattering experiment?

8. An element has an electronic configuration of 2, 8, 7. Its valency is

9. During a chemical reaction, atomic number

12. How are the subshells in an atom labelled?

13. The isotopes of neutral atoms of an element differ in

14. The electronic configuration of an atom having atomic number 20 is

15. Almost the entire mass of an atom is concentrated in the

16. An atom differs from its ion in

18. Which of the following is true about a charged atom?

a. anion is negatively charged

19. Which of the following is not a fundamental particle?

a. 1s2 2s2 2p4 3s2 3p8 3d10

24. The number of protons in a negatively charged atom (anion) is

a. more than the atomic number of the element

26. The atomic theory of matter was first proposed by

Angular momentum of electrons in Electrons revolve in discrete circular

Energy of each electron is directly Electrons radiate energy continuously