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    Thermo Simple

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    Daniel Andres Canro Calderón
    This document outlines the key concepts of thermodynamics, including: 1) It defines the zeroth law of thermodynamics which introduces the concept of temperature as a state function. 2) The first law of thermodynamics defines internal energy and establishes that heat is equal to change in internal energy plus work. 3) The second law of thermodynamics introduces entropy as a state function and establishes the relationship between heat and entropy. 4) It shows the Carnot cycle on a temperature-entropy diagram and defines the efficiency of heat engines in terms of temperature.

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    Thermo Simple

    Uploaded by

    Daniel Andres Canro Calderón
    37 views1 page
    This document outlines the key concepts of thermodynamics, including: 1) It defines the zeroth law of thermodynamics which introduces the concept of temperature as a state function. 2) The first law of thermodynamics defines internal energy and establishes that heat is equal to change in internal energy plus work. 3) The second law of thermodynamics introduces entropy as a state function and establishes the relationship between heat and entropy. 4) It shows the Carnot cycle on a temperature-entropy diagram and defines the efficiency of heat engines in terms of temperature.

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    thermo_simple.doc

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    This document outlines the key concepts of thermodynamics, including: 1) It defines the zeroth law of thermodynamics which introduces the concept of temperature as a state function. 2) The first law of thermodynamics defines internal energy and establishes that heat is equal to change in internal energy plus work. 3) The second law of thermodynamics introduces entropy as a state function and establishes the relationship between heat and entropy. 4) It shows the Carnot cycle on a temperature-entropy diagram and defines the efficiency of heat engines in terms of temperature.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    37 views1 page

    Thermo Simple

    Uploaded by

    Daniel Andres Canro Calderón
    This document outlines the key concepts of thermodynamics, including: 1) It defines the zeroth law of thermodynamics which introduces the concept of temperature as a state function. 2) The first law of thermodynamics defines internal energy and establishes that heat is equal to change in internal energy plus work. 3) The second law of thermodynamics introduces entropy as a state function and establishes the relationship between heat and entropy. 4) It shows the Carnot cycle on a temperature-entropy diagram and defines the efficiency of heat engines in terms of temperature.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    of 1

    Everything there is to know about thermodynamics

    (Assuming an understanding of the Carnot Cycle on a TS diagram)

    KNOWN QUANTITIES FROM PHYSICS:


    Mass, moles, pressure, volume, work; W=PV

    ZEROTH LAW OF THERMODYNAMICS:


    Postulate the state function temperature, T, with no mention of heat
    PV
    T 
    R

    FIRST LAW OF THERMODYNAMICS:


    Postulate the state function Internal Energy, U, for an adiabatic process as
    U  W only then is heat defined as Q  U  W

    The first law is not enough; consider the facts about the efficiency of a heat engine
    W (out )
    Q (in)  Q (out )  W (out ) ; W (out )  Q (in) ; EFF  ; EFF  1
    Q(in)

    SECOND LAW OF THERMODYNAMICS:


    Postulate the state function Entropy, S, as
    q
    S  or Q  TS
    T

    W (out ) TH (S )  TC (S ) TH  TC


    CARNOT CYCLE ON TS DIAGRAM : EFF   
    Q(in) TH (S ) TH
    A
    B A
    S B
    O S
    L
    U Q(in) O
    L
    T
    S S
    U
    E TH T
    E
    T
    E T

    W(out) Q(out)
    M E
    P M
    E
    TC
    P
    R E
    A R
    T A
    U T
    R U
    E R
    E

    ENTROPY ENTROPY

    WE NOW HAVE ALL BASIC THERMODYNAMIC STATE FUNCTIONS


    dGi ˆ Gi E
    H  U  PV ; G  H  TS , A  U  TS ;  d ln f i ,  ln  i
    RT RT

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