Aits 1920 Ot Jeem TD 09 02 2020 PDF

FIITJEE
ALL INDIA TEST SERIES

OPEN TEST
JEE (Main)-2020
TEST DATE: 09-02-2020
Time Allotted: 3 Hours Maximum Marks: 300
General Instructions:
• The test consists of total 75 questions.
• Each subject (PCM) has 25 questions.
• This question paper contains Three Parts.
• Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
• Each part has only three sections: Section-A, Section-B and Section-C.
Section-A (01 – 20, 26 – 45, 51 – 70) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
Section-B (21 – 22, 46 – 47, 71 – 72) contains 6 Numerical based questions with answer as
numerical value from 0 to 9 and each question carries +4 marks for correct answer. There is no
negative marking.
Section-C (23 – 25, 48 – 50, 73 – 75) contains 9 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer. There is no negative marking.
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website: www.fiitjee.com
AITS-OT-PCM-JEE(Main)/20 2
Physics PART – I
SECTION – A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. A particle is projected with speed v at an angle  to the horizontal. If the magnitude of instantaneous
velocity at time ‘t’ is equal to the magnitude of average velocity from t = 0 to t = t. Find the time ‘t’.
2v sin 
(A)
3g
4v sin 
(B)
3g
3v sin 
(C)
4g
3v sin 
(D)
2g
Ans. B
Sol. v i = (v cos  )iˆ + (v sin  − gt)jˆ

gt
 v = (v cos  )iˆ + (v sin − )jˆ
2
vi =  v 
4v sin 
 t=
3g
2. In the given figure two straight infinite conductors carry a current I. They are 2a
parallel and separated by a distance 2a. A circular conducting ring of radius
‘a’ in the plane of the parallel wires lies between the two straight conductors
and is insulated from them. The mutual inductance between the circular ring
and the straight conductors is I I
(A) 0 a
(B) 20 a
0 a
(C)
2
(D) 40 a
Ans. B
AITS-OT-PCM-JEE(Main)/203
Sol. r = a(1− cos )  dr = a sin  d 2a

Flux through the element is
a
I  1 1  2 r
d = 0  +  2a sin d
2
2a  (1 − cos ) (1 + cos )  I I
 
0I 2a I
= 
 sin2 
0
sin2 d = 0 2a d

0

 = 20Ia
 mutual inductance
M = /I= 20a
3. A sphere of radius r is at a potential V and is immersed in a conducting medium of conductivity .

Find the current flowing from sphere to infinity.
(A) 2rV
(B) 4rV
rV
(C)
2
rV
(D)
4
Ans. B
Q
Sol. V=
k40r
Q
 = 4rv …(i)
k0
Q Q
I=  J  ds =   E  ds = k4 r
S S 0
2
4r 2 =
k0
= 4rv
4. A particle with charge q is travelling with a velocity v parallel to a wire with a uniform linear charge
distribution  per unit length. The wire also carries a current I. What should be the velocity of the
charged particle to travel in a straight line parallel to the wire at a distance r from the wire?
(c = speed of light)
2c 2
(A)
I
c 2
(B)
2I
c 2
(C)
I
4 c 2
(D)
I
Ans. C
q q I
Sol. − 0 v=0
20r 2r
 c 2
v= =
0 0I I
K
5. In an artificial medium, air pressure and volume are related as P = , where K is a constant.
V2
Considering air as an ideal gas of density , then the speed of sound in air is
2P
(A)

P
(B)

P
(C)
2
4P
(D)

Ans. A
B
Sol. Speed of sound, v =

PV2 = K
dP 2K
Bulk modulus, B = − V = = 2P
dV V 2
2P
v=

6. In the given circuit, the charge on 6 F capacitor in steady state 10 V 3F

is
3F 6F
20 V
(A) 7.5 C
(B) 15 C
(C) 30 C
(D) 45 C
Ans. D
Sol. In steady state, potential difference across 6 F capacitor = 7.5 V
 Charge on the 6F capacitor, q = 6  7.5 = 45 C
7. Water is completely filled in the spherical cavity of radius ‘a’ of a thick

spherical shell of inner and outer radii ‘a’ and ‘2a’ respectively as shown.
The initial temperature of water is 80C and the surrounding temperature a
is 0 = 30C. The thermal conductivity of the spherical shell varies as
 2a
k = 2 , where ‘r’ is the distance from the centre of shell and  is a
r
constant. The time required to decrease the temperature of water from
80C to 60C is ( = density of water, S = specific heat of water)
Sa4  5 
(A) n 
2 3
Sa4  5 
(B) n 
3 3
Sa4  5 
(C) n 
4 3
Sa4  5 
(D) n 
5 3
Ans. B
Sol. Thermal resistance of the spherical shell is

2a 2a
dr dr a
R=  K4r
a
2
= 
a

4r 2
=
4
…(i) a
r2 C 2a
msd  − 0
− =
dt R
60 t
d
−mSR 
80
( − 0 )
= dt 
0
5
t = mSR n  
3
4 3  a  5
t= a S   n 
3  4   3 
Sa4  5 
t= n 
3 3
8. An ancient piece of wood shows an activity of 7.8 disintegration per second, per gram of 14 C . What
is the age of piece of the wood if fresh 14 C , shows an activity of 31.2 disintegration per second per
gram? Half life of 14 C is 5570 years.
(A) 16710 years
(B) 33420 years
(C) 11140 years
(D) 22280 years
Ans. C
Sol. A = A 0 e−t
n2
− t
7.8 = 31.2e 5570
n2
 −2 n2 = − t
5570
Solving, t = 11140 years
9. A fish in an aquarium approaching the left wall at 4 m/s

observes a fly is approaching it at 8 m/s. If the refractive
4
index of water is  = . Find the actual velocity of the fly.
3
(A) 3 m/s
(B) 6 m/s
(C) 9 m/s
(D) 12 m/s
Ans. A
Sol. Let v = actual velocity of fly towards right

vapproach = 4 + v
8 = 4 + v
 v = 3 m/s
10. A small ball of mass ‘m’ is suspended from inextensible massless string C
of length l. At certain instant of time the velocity of point C is v 0 (in v0
leftward direction) and of ball D is 2v0 (in rightward direction). The
tension in the string at this instant of time is
D 2v0
4mv 02
(A) mg +
9mv 02
(B) mg −
mv 02
(C) mg +
9mv 02
(D) mg +
Ans. D
( )
2
m 3v 0
Sol. T − mg =
9mv 02
T = mg +
11. A solid cylinder of mass m = 5 kg and radius R = 0.4 m is given an initial m

angular velocity 0 = 40 rad/s about a horizontal axis through its centre
and gently placed on a plank of mass m = 5 kg. The coefficient of friction 0
between the cylinder and plank is  = 0.2. The plank rests on a smooth
m
horizontal surface. The time after which pure rolling motion of cylinder
will start relative to the plank is (Take g = 10 m/s2)
(A) 2 sec
(B) 3 sec
(C) 4 sec
(D) 5 sec
Ans. A
Sol. CM = ICM m

mR2 v
mgR =  
2
v0
2g m
=
R
When pure rolling motion starts
R − v = v0
(0 − t)R − gt = gt
0R − 2gt − gt = gt mg
0R = 4gt
R 40  0.4
 t= 0 = = 2 sec mg
4g 4  0.2  10
12. An ideal diatomic gas is taken through a process AB as shown P

in the P-V diagram. The molar heat capacity of the gas in this
2P0 B
process will be :
P0
A
O V0 2V0 V
(A) 3R
(B) 4R
9R
(C)
2
R
(D)
2
Ans. A
Sol. The equation of process AB is

P  P
P =  0  V  PV −1 = 0 = constant
 V0  V0
 This is a polytropic process with a polytropic constant, x = −1
R 5R R
 Molar heat capacity, C = CV + = + = 3R
(1 − x) 2 2
13. The electric field strength produced by the radiations coming from 200 W bulb at a 5 m distance is
E. The electric field strength produced by the radiations coming from 100 W bulb at the same
distance 5m is
E
(A)
2
(B) 2E
E
(C)
2
(D) 2E
Ans. C
Sol. We know E  Pav

E2 P2 100 1
= = =
E1 P1 200 2
E
 E2 =
2
14. A particle ‘A’ of mass ‘m’ moving with an initial velocity ‘v’ collides elastically with a particle B of
 
mass 2m which is initially at rest. The ratio of the de-Broglie wavelengths  A  of the particles A
 B 
and B after collision is
(A) 2
(B) 3
(C) 8
(D) 4
Ans. D
Sol. From Conservation of momentum v v1 v2

mv + 0 = mv1 + 2mv2 m 2m m 2m
v = v1 + 2v2 …(i) A B A B
coefficient of restitution;
v − v1
e= 2
v
v2 − v1 = v …(ii)
from (i) and (ii);
2v v
v2 = , v1 = −
3 3
 A 2mv 2 2v 2
= = =4
B mv1 v1
15. In YDSE of equal width slits, if the intensity at the center of the screen is I 0, then the intensity at a

distance of from the central maxima is ( is fringe width, d is separation between the slits,  is
4
wavelength of light, D is separation between the plane of slits and the screen) (D>>d and d>>)
(A) I0
I0
(B)
2
I0
(C)
3
I0
(D)
4
Ans. B
 D
Sol. When y = =
4 4d
y    
Path difference, r = d sin = d   = d  = (for small ‘’)
D  4d  4
2 2  
 Phase difference,  =  r =  =
  4 2
  I
I = I0 cos2   = I0 cos2   = 0
2 4 2
16. A cylinder of length floats with its entire length immersed in

two liquids as shown in the figure. The upper liquid is water
/3
and lower liquid has density twice that of water. The two
liquids are immiscible. The cylinder is in equilibrium. Find the
specific gravity of the material of the cylinder.
2/3
(A) 2
(B) 5
(C) 4/3
(D) 5/3
Ans. D
2   
Sol. A   (2)g + A   g = A 0 g
 3  3
4 
+ = 0
3 3
5
 0 =
3
Specific gravity of the material of cylinder = 0/ = 5/3
17. A ring of circular cross section is made of a material of resistivity ‘’. The B = kt
inner and outer radii of ring are a and 2a respectively and its thickness
is ‘h’. The ring is placed in a time varying magnetic field B = kt (where k
is a constant) which is parallel to the axis of the ring as shown in the
figure. The induced current in the ring is a
h
2a
3kha2
(A)
4
3kha2
(B)
2
5kha2
(C)
4
5kha2
(D)
2
Ans. A
Sol. The emf induced in a thin circular ring of radius ‘r’ is

d
=
dt a r dr
B = kt
=
d
dt
(
ktr 2 = kr 2 ) 2a
2a
kr hdr
2
 dI =  a
2r
2a
kh  r 2  3kha2
I=   =
2  2  4
a
18. A glass slab is placed between an object O and observer. The t

refractive index of glass slab varies with distance x from the A C
 x
face AB as  = 0  1 +  , where 0 = 1. How much closer
 t
(compared to original distance) the object appears to the
observer. (Consider normal incidence only) O
B D
(A) t(1 + n2)
(B) t(1 − n2)
(C) t(2 + n2)
(D) t(2 − n2)
Ans. B
 1
Sol. Shift, dS =  1 −  dx
  
t
 t 
 dS =  1 −  (t + x)  dx
0 0
t
 t − t  n(t + x) 0 = t − t n2 = t(1 − n2)
19. In the figure shown, the friction coefficient between the block of  = 0.4
mass 1 kg and the plank of mass 2 kg is 0.4 while that between 1 kg F
the plank and horizontal floor is 0.1. For what value of F will the  = 0.1
2 kg
block move with double the acceleration of that of the plank?
(Take g = 10 m/s2)
(A) 5N
(B) 6N
(C) 10 N
(D) 12.5 N
Ans. A
Sol. F − 4 = 2a …(i) 2a
4 − 3 = 2a …(ii)
 F = 5N 1 kg F
4N
a
4N
2 kg
3N
20. An n-p-n transistor is connected in common

emitter mode as shown in the figure. The terminal RL
of a 9 V battery is connected to the collector RB
C
through a load resistance RL = 1 k and to the
B
base through a resistance RB. If the base-emitter VCE VCC = 9V
voltage VBE E
VBE = 1.4 V, the collector-emitter voltage VCE = 5
V and  = 100. Then the value of resistance RB is
(A) 130 k
(B) 160 k
(C) 190 k
(D) 220 k
Ans. C
Sol. ICRL + VCE = VCC IB IC
ICRL = VCC − VCE = 9 − 5 = 4 V RL

4 4 RB
 IC = = 3
= 4  10−3 A C
RL 10 B
VCE VCC = 9 V
I E
IB = C = 4  10 −5 A
VBE

VCC = IBRB + VBE
V − VBE 9 − 1.4
RB = CC = = 1.9  105  = 190 k
IB 4  10−5
SECTION – B
(Single digit integer type)
This section contains 02 questions. The answer to each question is a single Digit integer ranging from 0
to 9, both inclusive.
21. A metallic rod of length 1 m is rigidly clamped at two points A A B

and B as shown in the figure. Longitudinal stationary waves are
setup in the rod. If the fundamental frequency of longitudinal
vibration of the rod is (10  n) kHz. Find the value of n. (Given 15 cm 70 cm 15 cm
Y = 1.6  1011 N/m2,  = 2500 kg/m3)
Ans. 4
Sol. Velocity of longitudinal wave in a solid rod is A B
Y 1.6 10 11
4
v= = =
 10 4 = 8000 m/s
 2500 5 15 cm 70 cm 15 cm
Now, n1 : n2 : n3 = 1 : 2 : 3
=15 : 70 : 15
= 1.5 : 7 : 1.5
No. of loops formed in the fundamental mode of vibration
= 1.5 + 7 + 1.5 = 10 loops
 10(/2) =
  = (2 )/10 = 0.2 m
v 8  103
 fundamental frequency, f = = = 40 kHz
 0.2
22. In an Atwood’s machine setup as shown. Data is given by m1 = (103.5  0.2)g

and m2 = (43.5  0.2)g and g = (9.80  0.01) m/s2 is acceleration due to gravity.
Find the percentage error in the acceleration of the blocks.
m1
m2
Ans. 1
 m − m2 
Sol. a= 1 g
 m1 + m2 
a g (m1 + m2 ) (m1 + m2 )
= + +
a g m1 − m2 m1 + m2
a 0.01 0.4 0.4
= + + = 1%
a 9.80 60 147
SECTION – C
(Numerical Answer Type)
This section contains 03 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
23. A small ball of mass 1 kg and charge 8 C is placed at the centre of a uniformly charged sphere of
1
radius 2m and charge mC . A narrow smooth groove is made in the sphere from centre to the
6
surface of sphere and the sphere is made to rotate about its vertical diameter at a constant rate of
1
revolution per second. Find the speed (in m/s) with respect to ground with which the ball slides
4
out from the groove. Ignore any magnetic force acting on the ball. (Take 2 = 1.41 )
Ans. 00002.82
1
Sol.  = 2n = 2  = 0.5 rad/s
4
R
1  3 KQq KQq 
mv r2 =  −  + m rdr 
2
2  2 R R  0
1 KQq m2R2 kQq
mv r2 = +  v r2 = + 2R2
2 2R 2 R
9  109  8 1
v r2 =   10−9 + 1 = 7  v r = 7 m/s
2 6
v t = R = 1 m/s
v = v r2 + v 2t = 7 + 1 = 8 = 2 2 = 2  1.41 = 2.82 m/s
24. The eyepiece of a compound microscope has a focal length of 2.5 cm and the objective has a focal
length of 1 cm. Two lenses are separated by 26 cm. Microscope is used by a person with normal
eye (near point at 25 cm). If the minimum magnification of the microscope is 100x. Find the value
of x.
Ans. 00002.25
Sol. v + fe = 26 cm
 v = 26 − 2.5 = 23.5 cm
1 1 1
− =
v u f0
v v v v 23.5
1− =  = 1− = 1− = −22.5 cm
u f0 u f0 1
vD 25
Angular magnification, m = = −22.5  = −225
u fe 2.5
|m| = 225
100x = 225  x = 2.25
25. A source of sound is moving with a constant speed

of 20 m/s in a circle. There is a stationary observer D
at some distance greater than the radius of the
circle from the centre of circle as shown in the fiugre. observer
Find the difference between the maximum and vS
minimum frequency (in Hz) observed by the
observer. (Assume speed of sound to be 340 m/s
and frequency of the source is 360 Hz)
Ans. 00042.50
vS
 v 
Sol. fmax =  f
 v − vS 
D
340
fmax =  360 Hz = 382.5 Hz observer
320
vS
 v 
fmin =  f
 v + vS 
340
fmin =  360 Hz = 340.0 Hz
360
 fmax − fmin = 42.50 Hz
Chemistry PART – II
SECTION – A
26. Which of the following is correct?
(A) The value of steric factor P (regarding Arrheneous equation) decreases as the complexity
of reacting molecules decreases.
(B) During any individual reactive collision, the total energy of the colliding particles remain
constant.
(C) During a free radical chain reaction, if chain termination is faster than chain branching and
chain propagation, explosion occurs.
(D) In a termolecular elementary process : O + O2 + N2 ⎯⎯

→ O3 + N2 ; N2 serves as
catalyst, while the order of reaction is two (2).
Ans. B
Sol. (A) The value of steric factor decreases as the complexity of reacting molecules increases.
(C) If chain termination is slower than chain branching and chain propagation, explosion
occurs.
(D) N2 is used to remove the excess energy as O3 formed at lighter energy level can
redissociate.
27. Which of the following is most stable?
(A)
(B)
(C)
(D)
Ans. C
Sol. Stability order is

C>B>D>A
28. In which of the following M – F bond is strongest, among the given four compounds?
(M = central atom)
(A) CF4
(B) NF3
(C) BF3
(D) OF2
Ans. C
Sol. Due to highest electronegativity difference also due to bond order greater than 1 in BF3 (only).
29. Which of the following is aromatic?
(A)
(B)
(C)
(D) A & B both
Ans. A
Sol. B & C are non aromatic as both are non planar.
30. During extraction of sodium by Down’s cell process CaCl 2 is mixed with NaCl, which lowers the
fusion temperature, the main reason(s) for lowering the fusion temperature is:
(A) It is difficult to maintain 1081 K (fusion temperature of NaCl) during electrolysis and also at
lower temperature the consumption of electricity is reduced.
(B) Both Na and Cl2 exert corrosive nature/action on the vessel used for electrolysis at such
high temperature (1081 K).
(C) At lower/reduced fusion temperature (850 K), the sodium is obtained at iron cathode in
solid state.
(D) Both A and B are some of the reasons.
Ans. D
Sol. Melting point of sodium (Na) is 371 K (approx), hence it is obtained in liquid state even at 850 K,
the temperature of operation.
31. What is the pH of a saturated aqueous solution of AgOH? [Given K SP(AgOH) = 1.5 × 10-8, log
(1.225) = 0.088; log(1.5) = 0.176];
(A) 8.176
(B) 7.824
(C) 4.088
(D) 10.088
Ans. D
Sol. OH−  = 1.5  10−8 = 1.225 × 10-4; pOH = 3.912;

Hence, pH = 10.088
32. Which of the following is correct?
(A) Kjeldahal’s method of estimation of nitrogen is not applicable to the compounds containing
nitrogen in nitro groups, azo groups and nitrogen present in the ring.
(B) In Duma’s method of estimation of nitrogen, the organic compound containing nitrogen is
heated with Cu2O in an atmosphere of CO2, to yield H 2O, CO2 and free N2 gas along with
free copper.
(C) During Carius method of estimation of halogen, a known mass of organic compound is
heated with dil. HNO3, in presence of AgNO3.
(D) Phosphorous can not be detected by Lassaigne’s test.
Ans. A
Sol. (B) Duma’s method, the organic compound is heated with CuO, not with Cu 2O.
(C) Fuming HNO3 is used in Carius method.
(D) N, S, X (halogen) and phosphorus present in an organic compound are detected by
Lassaigne’s test.
33. Which of the following is not the constituent of ‘Acid Rain’?
(A) H2CO3
(B) H2SO4
(C) HNO3
(D) H3PO4
Ans. D
34. Analyse the following reaction sequence and select the correct statement, following the reaction?
Cl
MeOH/NaOH → A ⎯⎯⎯⎯⎯⎯ (i) O3 (ii) Zn/H2O dil.OH−
⎯⎯⎯⎯⎯⎯⎯
⎯→ B ⎯⎯⎯⎯  →C
( Major )
CH3
(A) ‘A’ has 1-degree of unsaturation.
(B) ‘B’ has 2-degree of unsaturation.
(C) ‘C’ is an a , -unsaturated ketone with 2-degree of unsaturation.
(D) All other three statements are incorrect.
Ans. B
Sol.
A= B= H
; ; ; C=
O O O
35. In which of the following maximum stereochemical inversion is expected to occur?
(A) H D
+ HCOOH ⎯⎯
→ SN − product
Ph OTs
(B) OTs
+ CH3 COO−NH4+ ⎯⎯
→ SN − product
(C) Cl
+ CH3 COOK ⎯⎯⎯⎯⎯
CH COOH → SN − product
3
Ph
(D) Br
+ dil. NaOH ⎯⎯
→ SN − product
Ph Ph
Ans. B
Sol. In A, C and D – SN1 runs in parallel.
36. In which of the following reaction, the given product is the major product of that reaction?
(A) Cl
(PhCO )
CCl4 + CH2 = CH − CH2 − CH2 − CH3 ⎯⎯⎯⎯

2 2
→ ;
CCl3
(B)
CCl3
(PhCO2 )2
CCl4 + ⎯⎯⎯⎯

→ ;
Cl
(C) O O
+ h
⎯⎯⎯ →
H
(D) In all the reactions, the given products are major products.
Ans. D
Sol. All are free radical reactions.
37. During extraction process of Sn which of the following is the common method of reduction?
(A) Self reduction
(B) Aluminium reduction
(C) Electrolytic reduction
(D) Carbon reduction
Ans. D
Sol. Carbon reduction is employed for extraction of Fe, Pb, Zn and Sn etc. generally.
38. Which of the following show geometrical isomerism as well as ionization isomerism, and possesses
spin only magnetic moment of 3.87 BM?
(A) Co(NH3)4Br2Cl
(B) Cr(CN) (CO)4 (NO3)Cl
(C) Pd(NO2)2(NH3)2
(D) Co(CO)5Br(SO4)
Ans. B
Sol. Spin only magnetic moment of A, C and D are zero. ‘C’ cannot show ionization isomerism. While
‘D’ does not show geometrical isomerism.
39. Which of the following give Glycine?
() 2 3( )
CH3 CH2CH = CH − CH2 − CH3 ⎯⎯⎯⎯ → ⎯⎯⎯⎯⎯
( ii) H2 O → ⎯⎯⎯⎯⎯ → ⎯⎯⎯ →?
O3 /H2 O i Br /red P
H2 O NH excess
(A)
+ −
H3 O / 
(B) CH3 CH = CHCH3 ⎯⎯⎯→
O3 / Zn
⎯⎯⎯
NH4 Cl
NaCN
→ ⎯⎯⎯⎯ → ⎯⎯⎯⎯⎯
Very dil.OH
→?
3( )
CH3 CH = CHCH3 ⎯⎯⎯⎯ → ⎯⎯⎯⎯ → ⎯⎯⎯⎯⎯ → ⎯⎯⎯ →?
O3 /H2 O Br2 /red P NH excess
(C) H2 O
O
||
(D) CH3 C− COOH + NH3 ⎯⎯
→ ⎯⎯⎯→
H2 /Pd
?
Ans. C
H3C CH COO
Sol. By the processes defined in A, B and D, Alanine is formed.
NH3
40. Which one of the following statements is correct?

(Please ignore the balancing wherever is applicable)
(A) Al + dil. H2SO 4 ⎯⎯→ Al2 ( SO 4 )3 + SO2 + H2O .
(B) Al + AlCl3 ⎯⎯⎯⎯⎯⎯⎯

High temperature
→ Al2Cl3 .
(C) FeSO4.(NH4)2 SO4.6H2O is called Mohr’s salt.
(D) AlCl is stable up to 800oC.
Ans. C
Sol. (A) Al + dil. H2SO 4 ⎯⎯→ Al2 ( SO 4 )3 + H2 
(B) Al + AlCl3 ⎯⎯⎯⎯⎯⎯⎯

High temperature
→ AlCl
(D) AlCl disproportionates below 800oC to give AlCl3 and Al.
41. Which of the following molecules is non linear?
(A) HCN
(B) CO2
 AgCl2 
−
(C)
(D) BaCl2
Ans. D
Sol. Shapes of MX2 (M = alkali earth metals) change from linear to bent from top to bottom.
42. Which of the following is expected to be most acidic solution?
(A) Dilute aq. H3BO3 solution.
(B) Dilute aq. CH3COOH solution.
(C) Dilute aq. HCOOH solution.
(D) Aq. Be(OH)2 soluiton.
Ans. C
Sol. Be(OH)2 solution is amphoteric.

• pKa of CH3COOH is 4.76.
• pKa of CH3COOH is 3.76.
43. Which of the following process is expected to have the largest value of equilibrium constant, at
room temperature?
(A) H3PO2 H+ + HPO2− ; K1
(B) H3PO3 H+ + H2PO3− ; K2
(C) H3PO4 H+ + H2PO4− ; K3
(D) H2PO4− H+ + HPO24− ; K4
Ans. A
Sol. The order of corresponding equilibrium constants is : K4 < K3 < K2 < K1.
44. Which of the following colloid combination is correctly classified?
(A) Rain cloud – Sol
(B) Soapsuds – Aerosol
(C) Silt in water – Sol
(D) Milk of magnesia – Foam
Ans. C
Sol. (A) Rain cloud – Aerosol
(B) Soapsuds – Foam
(D) Milk of magnesia – Sol
45. Cl2 gas is passed into an aqueous solution of NaBr and NaI, followed by the addition of CHCl 3.
What colour of CHCl3 layer will be observed, ultimately?
(A) Blue
(B) Greenish yellow
(C) Reddish brown
(D) Violet
Ans. D
Sol. Chlorine water oxidizes Br − to Br2 and I− to I2.

Also, Br2 water oxidize I− to I2.
SECTION – B
46. If value of equilibrium constant for the following equilibria is 10+x, then find the value of ‘x’.
2Fe3 + + 2I− 2Fe2 + + I2
o
Given: EFe3+
/Fe2+
= 0.77 V
EIo /I− = 0.53 V
2
2.303 RT
= 0.06
F
Ans. 8
Sol. For the given reaction : n = 2.

Eocell = 0.24
0.06
Hence, Eo = logK eq
2
0.24  2
= logK eq
0.06
K eq = 108
Hence, x = 8.
47. 18 gm of glucose (C6H12O6) is treated with sufficient amount of HIO4, under requisite conditions.
How much formaldehyde (in gm) is formed?
Ans. 3
C6H12O6 ⎯⎯⎯
HIO
Sol. 4
→ 5HCOOH + HCHO;
(Glucose)
1 mole  180 gm glucose give 30 gm HCHO
Hence, 18 gm glucose give 3 gm of HCHO.
SECTION – C
48. Excess of NH4HS(s) is heated at 300 K, in a closed container and at equilibrium the partial pressure
of NH3 is found to be 1.5 atm. Some amount of NH3 is added to the reaction mixture so that at new
equilibrium, under same conditions, the partial pressure of NH3 becomes 2 atm, what is the ratio of
total pressures before adding NH3 and after addition of NH3.
Ans. 00000.96
Sol. K P = 1.5  1.5 = 2.25 atm2

At new equilibrium:
2.25 = PH2S  2
PH2S = 1.125
Ptotal = 3.125
3
Hence, the desired ratio is = 0.96
3.125
49. Calculate the heat of formation of H2O(g) by the following data and give its numerical value only (in
kJ/mole).
H−H = 436 kJ / mole; O =O = 497 kJ / mole;
Average H−O = 492 kJ / mole
Ans. 00299.50
1
Sol. H2 ( g) + O2 ( g) ⎯⎯→ H2O ( g ) ;
2
1
Hf (H2O, g) =H−H + O =O −2 O −H
2
= - 299.50 (kJ/mole)
50. A metal (At. Mass = 65) has a fcc lattice with all the atoms at the lattice points. The edge length of
the unit cell is 300 pm. What is its density. (in gm/cm 3) (Given: NA = 6.022 × 1023)
Ans. 00015.99
ZM
Sol. Density = ;Z = 4 ( fcc )
N.a3
M = 65 gm/mole
a = 300 pm = 3 × 10-8 cm.
Hence, density = 15.99 gm/cm3.
Mathematics PART – III
SECTION – A
51. (p  q)  (q  r) is
(A) a tautology
(B) a contradiction
(C) equivalent to (~q  p)  (~r  q)
(D) equivalent to (p  q)  r
Ans. A
Sol. (~p  q)  (~q  r)
52. Let S = {(x, y) : x2 + y2 – 4x – 2y + 4 = 0 & x2 + y2 – 2y = 0},  = set of circles which pass through
all point(s) in S. Then the number of elements in  with unit radius that pass through all the point(s)
in S and the origin is
(A) 0
(B) 1
(C) 2
(D) 3
Ans. C
Sol. The circles touch each other at (1, 1)
 2 4  2
53. The number of solution(s) of the equation tan−1  x +  − tan−1 − tan−1  x −  = 0 is
 x x  x
(A) 0
(B) 1
(C) 2
(D) more than 2
Ans. C
Sol. x= 2
a b c
54. For ABC, = = , where m, n  R+. Given three statement(s):
1+ m n 2 2
m +n
2 2 (1 − m )(1 + n2 )
2
m mnbc
(I) BAC = 2 tan−1 , (II) ABC = 2 tan−1 mn and (III) area of ABC = 2 .
n m + n2
Which of the following options lists all the correct statements about ABC?
(A) I only
(B) II and III only
(C) I and II only
(D) I, II and III
Ans. D
Sol. Use half angle formulae and Heron’s formula
55. A statue built on a 50m high pedestal subtends 45 at two points, A1 and A2, 50m apart on the
ground. If the straight line joining A1 and A2 passes through the base of the pedestal, then what is
the height of the statue (without the pedestal) (assume that the statue and pedestal are vertical)
(A) 25 2
(B) 50
(C) 150
(D) 250
Ans. D
Sol. A1, A2, S1 and S2 are concyclic. S2

S2A1S1 = S2A2S1 = 45 and S1A1A2 = S1S2A2 = 
 A1S1A2 = A1S2A2 = 45 – 2 S1
50 A1S1
= , but A1S1 = 50 cosec  50
   3  45º 45º
sin  − 2  sin  + 
4   4 
P
1 A1S1  A1 A2
 tan  =  S1S2 =  sin = 250 50
3   4
sin  −  
4 
56. If tangents are drawn from a point P to the parabola y 2 = 4x with focus (S) such that the lengths of
the tangents are 5 and 10 , then SP is equal to
(A)
5
(1 + 2 )
2
(B) 5 2
2 10
(C)
1+ 2
(D) none of these
Ans. B
Sol. Property, SP = Geometric mean of length of tangents
x2 y2
57. Let the tangents drawn to the ellipse + = 1 from the endpoints (AL and BL) of a chord (L)
4 9
passing through the point (1, 1) intersect at point CL. As L varies CL traces which of the following
curves
(A) an ellipse
(B) a parabola
(C) a circle
(D) a straight line
Ans. D
x y
Sol. + =1
4 9
58. Consider a chord to the hyperbola xy = 9 which has x-intercept 3 and y-intercept 15. The mid-point
of this chord is
 15 3 
(A)  , 
 2 2
 3 15 
(B)  , 
2 2 
(C) (9, 12)
(D) (12, 9)
Ans. B
Sol. Midpoint of segment between asymptotes is same as midpoint of chord
y2
59. A chord of x 2 − = 1 subtending 90 at the centre of the hyperbola can have the equation
66
(A) 5x + 7y = 5 3
(B) 3x + 7y = 59
(C) 7x + 2y = 3 6
(D) 7x + 4y = 66
Ans. D
y2 1 65
= ( x + my )  1 −
2
Sol. x2 − 2
− − m2 = 0  2
+ m2 =
66 66 66
60. If (3a + c)(2a + 3b + 6c) < 0, then the number of roots of ax2 + bx + c = 0 in interval (–5, 5) is
(A) exactly zero
(B) at least one
(C) exactly two
(D) can not be determined
Ans. B
3 1
Sol. 
−3

f ( x ) dx  f ( x ) dx  0 , where f(x) = ax2 + bx + c
0
61. Let S be the set of points in the Argand plane satisfying |z – 3 – 4i|  5. If z1  S such that |z1 – 4 +
10 − ( z1 + z1 )
3i|  |z1 – z0|  z0  S, then is equal to
20 − i ( z1 − z1 )
(A) 1
1
(B)
2
1
(C)
5
1
(D)
7
Ans. D
Sol. z1 lies on line joining 3 + 4i and 4 – 3i, which also contains the point 5 – 10i. So, expression is
slope of perpendicular to this line
62. If c is directed along the internal bisector of the angle between the vectors a = 7iˆ − 4ˆj − 4kˆ and
b = −2iˆ − ˆj + 2kˆ , with c = 5 6 , then c is
(A) ( i − 7ˆj + 2kˆ )

5 ˆ
3
(B) ( 5i + 5ˆj + 2kˆ )

5 ˆ
3
(C) ( i + 7ˆj + 2kˆ )

5 ˆ
3
(D)
5
( −5iˆ + 5ˆj + 2kˆ )
3
Ans. A
a b
Sol. c =  − + 
a b
63. If the area of the region bounded by the curves xy + x = 1, y2 = 12x and the x-axis is A, then
(A) A>1
(B) A < ln 2
1
(C) A2 <
2
1
(D) A>
2
Ans. D
1
3 1
1 
Sol. A= 
0
12x dx +  − 1 dx
1
x  
3
n −1
n2 i
64. lim
n→
i
i=1
4
+ n4
is equal to
(A) ln 2
1
(B) ln2
2

(C)
4

(D)
8
Ans. D
i
n −1 1 1


1 n2 = x 1

−1 2
Sol. lim = tan x =
n→ n
i=1 1 + i
4
0
1+ x 4 2 0 8
2
n
65. If (z + 1)2n + (z – 1)2n = 0, where z is a complex number and n  N, then which of the following is
always true?
(A) z=z
(B) z = z2
(C) z+z =0
(D) z2 + z 2 = 1
Ans. C
2n
 z + 1
Sol.   = −1
 z − 1
66. Given a triangular plot of land as per the figure, the owner wants to build a fence ST such that the
plot is divided into 2 equal parts. The minimum length of fencing required is (where s is the semi-
perimeter of ABC)
C
b
a
T
S
B A
c
where a  b  c
(A) 2 ( s − b )( s − c )
(B) s (s − a)
(C) a (b + c )
s
(D)
2
Ans. A
1
Sol. ST2 = AS2 + AT2 – 2AS·AT·cos  and AS·AT = bc
2
1 1 1
67. If Sn = + + ..... + , then lim Sn is equal to
1 3  4 2  4  5 n n + 2 ) (n + 3 )
( n→
1
(A)
2
5
(B)
36
5
(C)
12
5
(D)
6
Ans. B
1 1
Sol. tn = +
( n + 1)( n + 2 ) ( n + 3 ) n (n + 1)(n + 2 ) (n + 3 )
 
 ; if x  0, 4 
2

 2
68. If A, B  R such that the function f ( x ) =  B tan−1 ; if x  ( 4, 6 ) , is continuous in
 x−4
 −1 ( 
sin 7 − x ) + A 4 ; if x   6, 8 

[0, 8], then A2 + B2 is equal to
(A) 1
(B) 2
(C) 3
(D) 4
Ans. B
Sol. A = –1, B = 1
cos x x 1
f(x)
69. If f ( x ) = 2sin x x 2
2x , then lim is equal to
x →0 x
tan x x 1
(A) –2
(B) 0
(C) 1
(D) 2
Ans. A
Sol. f(x) = x2 (tan x – cos x)
dy
70. If y = f(x) satisfies the differential equation x + y ( 2x + 1) = xex and f(0) = 0, then the number of
dx
2
solution(s) of f(x) = is equal to
x
(A) 0
(B) 1
(C) 2
(D) more than 2
Ans. C
xe3x e3x 1
Sol. xye2x = − +
3 9 9
SECTION – B
71. 5 boys (B1, B2, B3, B4 and B5) and 5 girls (G1, G2, G3, G4 and G5) are to be seated around a round
table such that boy and girl sit alternately and Bi does not sit beside Gi  i  {1, 2, 3, 4, 5}. If the
number of such arrangements is N, then the sum of digits of N is equal to
Ans. 6
Sol. 4!·(2!·3 + 2  2 + 3) = 312
72. A sample of 20 observations has mean of 50 and variance of 1, while a sample of 40 observations
has mean of 50 and standard deviation 2. The 2 samples are combined to give complete set of 60
observations with variance 2, then 32 is equal to
Ans. 9
20  1 + 40  22
Sol. 2 = = 3 (Because mean of both samples is the same)
60
SECTION – C
1
x 3
73. Let f(x) = 27x3 + 8x2 + x + 1, then lim is equal to
x → f −1 ( 27x ) − f −1 ( x )
Ans. 00001.50
( )1
( 1
f x 3  27x  f x 3 − 1  )


Sol.  1  1   for large enough x, now use Sandwich Theorem.
 x3   x3 
f   x  f − 1 
 3   3 
x −1 y − 2 z − 3
74. A plane (P) is parallel to the line L  = = . If the image of origin in P lies on the line
1 1 1
L, then the square of distance of (3, 2, 1) from P is equal to
Ans. 00004.50
3
Sol. Plane is –x + z = 1  d =
2
75. An aeroplane has 100 seats (numbered 1 to 100) and 100 passengers waiting to board each having
a ticket with a number from 1 to 100. No number is on 2 tickets or on 2 seats. The rules of boarding
are as below:
(i) Passengers board in the order of the number on their respective ticket,
(ii) The first passenger to board can sit on any seat, and
(iii) A passenger with ticket number i (i  1) boards the plane and sits on seat numbered ‘i’ if it
is empty, however if that seat is occupied he can sit on any empty seat.
If p is the probability that the 100th passenger sits in his assigned seat, then p2 + (1 – p)2 is equal
to
Ans. 00000.50
Sol. p = 0.5 as there is a bijection between the sequences where 100th passenger sits in his assigned
seat and the sequences where he doesn’t.

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FIITJEE

ALL INDIA TEST SERIES

• The test consists of total 75 questions.

• Each subject (PCM) has 25 questions.

• This question paper contains Three Parts.

• Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

Sol. v i = (v cos  )iˆ + (v sin  − gt)jˆ

Sol. r = a(1− cos )  dr = a sin  d 2a

3. A sphere of radius r is at a potential V and is immersed in a conducting medium of conductivity .

6. In the given circuit, the charge on 6 F capacitor in steady state 10 V 3F

 Charge on the 6F capacitor, q = 6  7.5 = 45 C

7. Water is completely filled in the spherical cavity of radius ‘a’ of a thick

Sol. Thermal resistance of the spherical shell is

(A) 16710 years

(B) 33420 years

(C) 11140 years

(D) 22280 years

9. A fish in an aquarium approaching the left wall at 4 m/s

Sol. Let v = actual velocity of fly towards right

11. A solid cylinder of mass m = 5 kg and radius R = 0.4 m is given an initial m

Sol. CM = ICM m

12. An ideal diatomic gas is taken through a process AB as shown P

Sol. The equation of process AB is

Sol. We know E  Pav

Sol. From Conservation of momentum v v1 v2

16. A cylinder of length floats with its entire length immersed in

Sol. The emf induced in a thin circular ring of radius ‘r’ is

18. A glass slab is placed between an object O and observer. The t

(A) t(1 + n2)

(B) t(1 − n2)

(C) t(2 + n2)

(D) t(2 − n2)

20. An n-p-n transistor is connected in common

Sol. ICRL + VCE = VCC IB IC

ICRL = VCC − VCE = 9 − 5 = 4 V RL

21. A metallic rod of length 1 m is rigidly clamped at two points A A B

Y = 1.6  1011 N/m2,  = 2500 kg/m3)

Sol. Velocity of longitudinal wave in a solid rod is A B

22. In an Atwood’s machine setup as shown. Data is given by m1 = (103.5  0.2)g

v = v r2 + v 2t = 7 + 1 = 8 = 2 2 = 2  1.41 = 2.82 m/s

25. A source of sound is moving with a constant speed

26. Which of the following is correct?

(D) In a termolecular elementary process : O + O2 + N2 ⎯⎯

27. Which of the following is most stable?

Sol. Stability order is

29. Which of the following is aromatic?

(D) A & B both

Sol. B & C are non aromatic as both are non planar.

(D) Both A and B are some of the reasons.

Sol. OH−  = 1.5  10−8 = 1.225 × 10-4; pOH = 3.912;

32. Which of the following is correct?

(D) Phosphorous can not be detected by Lassaigne’s test.

33. Which of the following is not the constituent of ‘Acid Rain’?

(A) ‘A’ has 1-degree of unsaturation.

(B) ‘B’ has 2-degree of unsaturation.

(C) ‘C’ is an a , -unsaturated ketone with 2-degree of unsaturation.

(D) All other three statements are incorrect.

35. In which of the following maximum stereochemical inversion is expected to occur?

Sol. In A, C and D – SN1 runs in parallel.

Sol. All are free radical reactions.

(A) Self reduction

(B) Aluminium reduction