[ At.wt.

- H=1, He=4, Li=7, Be=9, C= 12, N= 14, O= 16, Na= 23, Mg= 24, Al=27, Si=28, P=31,Ca= 40, S= 32, Cl= 35.5,
Fe= 56, Cu=63.5, Zn=64, Ag=108 ]
1. How many molecules of water and oxygen atoms are present in 0.9 g of water?
(A) 5x10-2 Na, 1.67x10-2 Na (B) 5x10-2 Na, 5x10-2 Na (C) 6x10-2 Na, 6x10-2 Na (D) None of these
2. Which of the following weighs equal to 32 g?
(A)1 mole of sulphur atoms (B) 1 mole of oxygen atoms (C) 1 mole of carbon dioxide (D) 11.2 L of O 2 at S.T.P
3. The largest no. of molecules is in
(A) 34 g of water (B) 28 g of water (C) 46 g of CH3OH (D) 54 g of N2O5
3
4. The mass of 112 cm of CH4 gas at STP is
(A) 0.16 g (B) 0.8 g (C) 0.08 g (D) 1.6 g
5. Calculate the number of atoms and volume of 1g He gas at NTP.
(A) NA/2, 22,400 ml (B) NA, 22,400 ml (C) NA/4, 5600 ml (D) NA/2, 11200 ml
6. How many g of NaOH will be needed to prepare 250 mL of 0.1 M solution ?
(A) 1 g (B) 10 g (C) 4 g (D) 6 g
7. For preparing M/10 solution of H2SO4 in one litre we need H2SO4
(A) 9.8 g (B) 49.0 g (C) 4.8 g (D) 0.09 g
8. Mole fraction of A in water is 0.2. The molality of A in water is
(A) 13.8 (B) 12.2 (C) 15.8 (D) 16.0
9. If 500 mL of a 5M solution is diluted to 1500 mL, what will be the molarity of the solution obtained?
(A) 1.5 M (B) 1.66 M (C) 0.017 M (D) 1.59 M
10. The number of atoms present in one mole of an element is equal to Avogadro number. Which of the following
element contains the greatest number of atoms?
(A) 4g He (B) 46g Na (C) 0.40g Ca (D) 12g He
11. If the concentration of glucose (C6H12O6) in blood is 0.9 g L–1, what will be the molarity of glucose in blood?
(A) 5 M (B) 50 M (C) 0.005 M (D) 0.5 M
12. What will be the molality of the solution containing 18.25 g of HCl gas in 500 g of water?
(A) 0.1 m (B) 1 M (C) 0.5 m (D) 1 m
13. What is the mass percent of carbon in carbon dioxide?
(A) 0.034% (B) 27.27% (C) 3.4% (D) 28.7%
14. The empirical formula and molecular mass of a compound are CH 2O and 180 g respectively. What will be the
molecular formula of the compound?
(A) C9H18O9 (B) CH2O (C) C6H12O6 (D) C2H4O2
15. Number of He atoms present in 52 amu. Sample is
(A) 2  6.02  1023 (B) 4  6.02  1023 (C) 400 (D) 13
16. Number of molecules of oxalic acid in 200 mL of 0.02 M oxalic acid solution are
(A) 10-3 x 6.023 x 1023 (B) 2 x 6.023 x 1023 (C) 3 x 6.023 x 1020 (D) 4 x 6.023 x 1020
17. Which of the following contains the greatest number of atoms?
(A) 1.0 g of butane (C4H10) (B) 1.0 g of (N2) (C) 1.0 g of silver (Ag) (D) 1.0 g of water
22
18. 6.022 x 10 molecules of N2 at NTP will occupy a volume of
(A) 22.4 litres (B) 2.24 litres (C) 6.02 litres (D) 6.02 mL
19. 1 mole of a diatomic element X 2 contains 34 and 40 moles of electrons and neutrons respectively. The isotopic
formula of the element is.
(A) 34X74 (B) 17X37 (C) 34 X 40 (D) 20X40
20. No. of electrons in 1.8 mL of H2O (A) is (density of water is 1 g/ml)
(A) 6.02 x 1023 (B) 3.011 x 1023 (C) 0.6022 X 1023 (D) 60.22 x 1023
21. Molecular weight of a gas, 11.2 litres of which at NTP weighs 14 g, is
(A) 14 (B) 28 (C)14 / 11.2 (D) 14 x 11.2
22. Number of HCl molecules present in 10 mL of 0.1 M HCl solution is
(A) 6.022 x 1023 (B) 6.022 X 1022 (C) 6.022 X 1021 (D) 6.022 x 1020
23. Number of atoms in 12 g of 6C12 is
(A) 6 (B) 12 (C) 6.022 X 1023 (D) 12 x 6.022 x 1023
24. Which of the following contains the greatest number of oxygen atoms?
(A) 1 g of O (B) 1 g of O2 (C) 1 g of O3 (D) all have the same number of atoms
25. How many moles of electrons weigh one kilogram?
(A) 6.022 x 1023 (B) 1 / 9.108 x 1031 (C) 6.022 / 9.108 x 1054 (D) (1/ 9.108 x 6.022) x 108
26. A gaseous mixture contains CO2(g) and N2O(g) in a 2 : 5 ratio by mass. The ratio of the number of molecules of
CO2(g) and N2O(g) is
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4
27. The number of molecules of water in 333 g of Al2(SO4)3. 18H2O is
(A) 18.0 x 6.02 x 1023 (B) 9.0 x 6.02 x 1023
(C) 18.0 (D) 36.0
28. For preparing M/10 solution of H2SO4 in one litre we need H2SO4 :
(A) 9.8 g (B) 49.0 g (C) 4.8 g (D) 0.09
29. The number of molecules present in 88 g of CO2 (Relative molecular mass of CO2 = 44)
(A) 1.24 × 1023 (B) 3.01 × 1023 (C) 6.023 × 1024 (D) 1.2046 ×1024
30. Which of the following has the least mass?
(A) 2 g atoms of nitrogen (B) 3 ×1023 atoms of carbon
(C) 1 mol of sulphur (D) 7.0 g of Ag
31. The atomic masses of two elements A and B are 20 and 40 respectively, if x gm of A contains y atoms, how
many atoms are present in 2x gm of B
y y
(A) y (B) 2y (C) 2 (D) 4
32. Haemoglobin contains 0.33% of iron by weight. The molecular weight of haemoglobin is approximately 67200.
The number of iron atoms (at wt. of Fe = 56) present in one molecule of haemoglobin are-
(A) 1 (B) 2 (C) 4 (D) 6
33. Total number of atoms in 4.4 mg of CO2 is -
(A) 1.806 ×1023 (B) 1.806 × 1020 (C) 6.02 × 1022 (D) 6.02 × 1019
34. Mass of 10 moles of sodium sulphite (Na2SO3) is –
(atomic masses Na = 23 , S = 32 , O = 16)
(A) 126 gram (B) 1260 gram (C) 126 amu (D) 1260 amu
35. Mole fraction of CH3OH in mixture containing CH 3OH and C2H5OH is 0.5. Hence mass percentage of CH 3OH in
the mixture is –
(A) 41% (B) 59% (C) 50% (D) 25%
36. Mass of 1 atom of Hydrogen is -
(A) 1.66 × 10–24 g (B) 10–22 g (C) 10–23 g (D) 10–25 g

37. One atom of an element ‘X’ weighs 6.664×10 –23 gm. The number of gram atoms in 40 kg of it
is -
(A) 10 (B) 100 (C) 10000 (D) 1000
38. The number of oxygen atoms present in 14.6 g of magnesium bicarbonate [Mg(HCO 3)2] is -
(A) 6NA (B) 0.6NA (C) NA (D) 0.5 NA

39. One mole of P4 molecules contains -

40. The total number of protons, electrons and neutrons in 12gm of 6C12 is -

(A) 1.084 × 1025 (B) 6.022 × 1023 (C) 6.022 × 1022 (D) 18