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(In Vacuum With Medium Dielectric Constant 1

This document provides instructions for a chemistry homework assignment involving tutorial problem set 2. Students are asked to solve 10 problems related to topics covered in lectures 8 through 14, including drawing resonance structures, writing electronic configurations, explaining differences in bond energies and dissociation constants, determining atomic term symbols, drawing Lewis structures, writing molecular electronic configurations, and calculating interaction energies and bond characteristics. The problems cover concepts in inorganic chemistry, including molecular geometry and bonding. Students are instructed to show their work, write legibly, and bring their completed assignment to the next tutorial hour.

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Karthik Sharma
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Download as PDF, TXT or read online on Scribd
27 views

(In Vacuum With Medium Dielectric Constant 1

This document provides instructions for a chemistry homework assignment involving tutorial problem set 2. Students are asked to solve 10 problems related to topics covered in lectures 8 through 14, including drawing resonance structures, writing electronic configurations, explaining differences in bond energies and dissociation constants, determining atomic term symbols, drawing Lewis structures, writing molecular electronic configurations, and calculating interaction energies and bond characteristics. The problems cover concepts in inorganic chemistry, including molecular geometry and bonding. Students are instructed to show their work, write legibly, and bring their completed assignment to the next tutorial hour.

Uploaded by

Karthik Sharma
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Birla Institute of Technology & Science, Pilani, Rajasthan 333031

I Semester, 2006-2007

Course Number: CHEM C141 Course Title: Chemistry I Marks: 6


Tutorial Problem Set 2 (based on Lecture No.’s: 8-14 in the course handout)
Instructions to the student: The following problems should be solved as home assignment
within a week of distribution. The respective tutorial hour instructor will assign any one problem
as a closed book class test in the following tutorial hour. Do not misplace this sheet. Bring it with
you for the next tutorial hour. Solve and submit the assigned problem to the instructor. Carefully
write your name and ID no. on your answer sheet. Write legibly and do not overwrite. Strike out
clearly the rough work if any. Do not write anything in this sheet other than your name and ID.

Useful data: ε0 = 8.85419 × 10-12 J-1C2m-1, Atomic No. for B = 5, N = 7, F =9, S = 16, Cl = 17
1D = 3.33564 × 10-30 C m.
1. Draw all the resonating forms for ozone (O3), boron trifluoride (BF3), nitrate anion (NO3-),
nitrite anion (NO2-), sulfate anion (SO4-2) and carbonate anion (CO3-).
2. Write electronic configuration of the followings
(a) Fe(26) (b) Fe3+(23) (c) Sc(21) (d) Cr(24) (e) S (32) (f) Cu(29)
3. Why does N2 has greater dissociation energy than N2+2 whereas O2 has lower dissociation
energy than O2+ ?
4. (a) Determine the atomic term symbols for electrons for which L = 2 and S = 1. (b) Predict
whether the molecules SF6, NH3, CO2, H2O, CHCl3 and CCl4 will have dipole moments.
5. Determine the atomic term symbol for (a) hydrogen atom (b) Helium atom in ground state
and excited state.
6. Write Lewis structures (structures in which each electron pair bond is designated by
a line joining the nuclei and dots are used to designate unshared electrons in the
valency shell) for SCN-, N3-, CO2, HF, NH4+, SO2
7. Give the molecular electronic configuration for each species: O2+, O2, O2-, O2-2 and
predict (a) which species are paramagnetic (b) the order of increasing bond
dissociation energy among the species.
8. (a) Two HCl molecules (µ = 1.08 D) are separated by 4.0 Å (400 pm) in air. Calculate (in
-1
vacuum with medium dielectric constant = 1) the dipole-dipole interaction energy in kJmol
if they oriented end-to-end, that is H-Cl H-Cl, considering HCl as point dipole.
(b) Explain why ammonia is soluble in water but nitrogen trichloride is not.
9. The bond angle in H2S is 97º and its dipole moment is 1.47 D. Find the S-H bond moment.
Estimate the percentage of ionic character of the S-H bond in H2S. The S-H bond distance
is 0.1334 nm.
10. Write electronic configuration for C2, B2 and N2. Explain why C2 and B2 are paramagnetic
whereas N2 is diamagnetic.

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