Aggregates For Concrete
Aggregates For Concrete
Aggregates For Concrete
PAGE
CHAPTER 5
Aggregates for Concrete
The importance of using the right type and quality of bination of gravels or crushed stone with particles
aggregates cannot be overemphasized. The fine and predominantly larger than 5 mm (0.2 in.) and generally
coarse aggregates generally occupy 60% to 75% of the between 9.5 mm and 37.5 mm (3⁄8 in. and 11⁄2 in.). Some
concrete volume (70% to 85% by mass) and strongly influ- natural aggregate deposits, called pit-run gravel, consist
ence the concrete’s freshly mixed and hardened proper- of gravel and sand that can be readily used in concrete
ties, mixture proportions, and economy. Fine aggregates after minimal processing. Natural gravel and sand are
(Fig. 5-1) generally consist of natural sand or crushed usually dug or dredged from a pit, river, lake, or seabed.
stone with most particles smaller than 5 mm (0.2 in.). Crushed stone is produced by crushing quarry rock, boul-
Coarse aggregates (Fig. 5-2) consist of one or a com- ders, cobbles, or large-size gravel. Crushed air-cooled
blast-furnace slag is also used as fine or coarse aggregate.
The aggregates are usually washed and graded at the
pit or plant. Some variation in the type, quality, cleanli-
ness, grading, moisture content, and other properties is
expected. Close to half of the coarse aggregates used in
portland cement concrete in North America are gravels;
most of the remainder are crushed stones.
Naturally occurring concrete aggregates are a mixture
of rocks and minerals (see Table 5-1). A mineral is a natu-
rally occurring solid substance with an orderly internal
structure and a chemical composition that ranges within
narrow limits. Rocks, which are classified as igneous, sedi-
mentary, or metamorphic, depending on origin, are gener-
ally composed of several minerals. For example, granite
contains quartz, feldspar, mica, and a few other minerals;
Fig. 5-1. Closeup of fine aggregate (sand). (69792) most limestones consist of calcite, dolomite, and minor
amounts of quartz, feldspar, and clay. Weathering and
Video erosion of rocks produce particles of stone, gravel, sand,
silt, and clay.
Recycled concrete, or crushed waste concrete, is a
feasible source of aggregates and an economic reality,
especially where good aggregates are scarce. Conven-
tional stone crushing equipment can be used, and new
equipment has been developed to reduce noise and dust.
Aggregates must conform to certain standards for
optimum engineering use: they must be clean, hard,
strong, durable particles free of absorbed chemicals, coat-
ings of clay, and other fine materials in amounts that could
affect hydration and bond of the cement paste. Aggregate
particles that are friable or capable of being split are unde-
Fig. 5-2. Coarse aggregate. Rounded gravel (left) and sirable. Aggregates containing any appreciable amounts
crushed stone (right). (69791) of shale or other shaly rocks, soft and porous materials,
79
Design and Control of Concrete Mixtures ◆ EB001
Table 5-1. Rock and Mineral Constituents in should be avoided; certain types of chert should be espe-
Aggregates cially avoided since they have low resistance to weather-
Minerals Igneous rocks Metamorphic rocks
ing and can cause surface defects such as popouts.
Identification of the constituents of an aggregate
Silica Granite Marble
cannot alone provide a basis for predicting the behavior of
Quartz Syenite Metaquartzite
Opal Diorite Slate aggregates in service. Visual inspection will often disclose
Chalcedony Gabbro Phyllite weaknesses in coarse aggregates. Service records are
Tridymite Peridotite Schist invaluable in evaluating aggregates. In the absence of a
Cristobalite Pegmatite Amphibolite performance record, the aggregates should be tested
Silicates Volcanic glass Hornfels before they are used in concrete. The most commonly used
Feldspars Obsidian Gneiss aggregates—sand, gravel, crushed stone, and air-cooled
Ferromagnesian Pumice Serpentinite blast-furnace slag—produce freshly mixed normal-weight
Hornblende Tuff
concrete with a density (unit weight) of 2200 to 2400
Augite Scoria
Clay Perlite kg/m3 (140 to 150 lb/ft3). Aggregates of expanded shale,
Illites Pitchstone clay, slate, and slag (Fig. 5-3) are used to produce struc-
Kaolins Felsite tural lightweight concrete with a freshly mixed density
Chlorites Basalt ranging from about 1350 to 1850 kg/m3 (90 to 120 lb/ft3).
Montmorillonites Other lightweight materials such as pumice, scoria,
Mica Sedimentary rocks
perlite, vermiculite, and diatomite are used to produce
Zeolite Conglomerate insulating lightweight concretes ranging in density from
Carbonate Sandstone
about 250 to 1450 kg/m3 (15 to 90 lb/ft3). Heavyweight
Calcite Quartzite
Dolomite Graywacke
materials such as barite, limonite, magnetite, ilmenite,
Sulfate Subgraywacke hematite, iron, and steel punchings or shot are used to
Gypsum Arkose produce heavyweight concrete and radiation-shielding
Anhydrite Claystone, siltstone, concrete (ASTM C 637 and C 638). Only normal-weight
Iron sulfide argillite, and shale aggregates are discussed in this chapter. See Chapter 18
Pyrite Carbonates for special types of aggregates and concretes.
Marcasite Limestone Normal-weight aggregates should meet the require-
Pyrrhotite Dolomite ments of ASTM C 33 or AASHTO M 6/M 80. These speci-
Iron oxide Marl
fications limit the permissible amounts of deleterious
Magnetite Chalk
Hematite Chert substances and provide requirements for aggregate char-
Goethite acteristics. Compliance is determined by using one or
lmenite more of the several standard tests cited in the following
Limonite sections and tables. However, the fact that aggregates
satisfy ASTM C 33 or AASHTO M 6/M 80 requirements
For brief descriptions, see “Standard Descriptive Nomenclature of
Constituents of Natural Mineral Aggregates” (ASTM C 294). does not necessarily assure defect-free concrete.
For adequate consolidation of concrete, the desirable
amount of air, water, cement, and fine aggregate (that is,
the mortar fraction) should be about 50% to 65% by
absolute volume (45% to 60% by mass). Rounded aggre-
gate, such as gravel, requires slightly lower values, while
crushed aggregate requires slightly higher values. Fine
aggregate content is usually 35% to 45% by mass or
volume of the total aggregate content.
CHARACTERISTICS OF AGGREGATES
The important characteristics of aggregates for concrete are
listed in Table 5-2 and most are discussed in the following
section:
80
Chapter 5 ◆ Aggregates for Concrete
T 27). The range of particle sizes in aggregate is illustrated (0.046 in. to 4 in.). Tolerances for the dimensions of open-
in Fig. 5-4. The aggregate particle size is determined by ings in sieves are listed in ASTM E 11 (AASHTO M 92).
using wire-mesh sieves with square openings. The seven Size numbers (grading sizes) for coarse aggregates
standard ASTM C 33 (AASHTO M 6/M 80) sieves for fine apply to the amounts of aggregate (by mass) in percent-
aggregate have openings ranging from 150 µm to 9.5 mm ages that pass through an assortment of sieves (Fig. 5-5).
(No. 100 sieve to 3⁄8 in.). The 13 standard sieves for coarse For highway construction, ASTM D 448 (AASHTO M 43)
aggregate have openings ranging from 1.18 mm to 100 mm lists the same 13 size numbers as in ASTM C 33
81
Design and Control of Concrete Mixtures ◆ EB001
100
Video
80
at e
s an
60
reg
e
and
Fin
gg
ea
es
o. 5 te
F in
ars
e N ega
40
Co
7
Siz aggr
rse
Coa
20
Optional,
see text
Video
82
Chapter 5 ◆ Aggregates for Concrete
and shape; the middle beaker is filled with an equal Fine-Aggregate Grading
volume of small aggregate particles of uniform size and
shape; and the beaker on the right is filled with particles Requirements of ASTM C 33 or AASHTO M 6/M 43 per-
of both sizes. Below each beaker is a graduate with the mit a relatively wide range in fine-aggregate gradation,
amount of water required to fill the voids in that beaker. but specifications by other organizations are sometimes
Note that when the beakers are filled with one particle size more restrictive. The most desirable fine-aggregate grad-
of equal volume, the void content is constant, regardless of ing depends on the type of work, the richness of the
the particle size. When the two aggregate sizes are mixture, and the maximum size of coarse aggregate. In
combined, the void content is decreased. If this operation leaner mixtures, or when small-size coarse aggregates are
were repeated with several additional sizes, a further used, a grading that approaches the maximum recom-
reduction in voids would occur. The cement paste require- mended percentage passing each sieve is desirable for
ment for concrete is related to the void content of the workability. In general, if the water-cement ratio is kept
combined aggregates. constant and the ratio of fine-to-coarse aggregate is chosen
During the early years of concrete technology it was correctly, a wide range in grading can be used without
sometimes assumed that the smallest percentage of voids measurable effect on strength. However, the best economy
(greatest density of aggregates) was the most suitable for will sometimes be achieved by adjusting the concrete
concrete. At the same time, limits were placed on the mixture to suit the gradation of the local aggregates.
amount and size of the smallest particles. It is now known Fine-aggregate grading within the limits of ASTM C
that, even on this restricted basis, this is not the best target 33 (AASHTO M 6) is generally satisfactory for most
for the mix designer. However, production of satisfactory, concretes. The ASTM C 33 (AASHTO M 6) limits with
economical concrete requires aggregates of low void respect to sieve size are shown in Table 5-3.
content, but not the lowest. Voids in aggregates can be
tested according to ASTM C 29 or AASHTO T 19. Table 5-3. Fine-Aggregate Grading Limits
In reality, the amount of cement paste required in (ASTM C 33/AASHTO M 6)
concrete is greater than the volume of voids between the
Sieve size Percent passing by mass
aggregates. This is illustrated in Fig. 5-8. Sketch A repre-
sents large aggregates alone, with all particles in contact. 9.5 mm (3⁄8 in.) 100
Sketch B represents the dispersal of aggregates in a matrix 4.75 mm (No. 4) 95 to 100
2.36 mm (No. 8) 80 to 100
of paste. The amount of paste is necessarily greater than
1.18 mm (No. 16) 50 to 85
the void content of sketch A in order to provide workabil-
600 µm (No. 30) 25 to 60
ity to the concrete; the actual amount is influenced by the 300 µm (No. 50) 5 to 30 (AASHTO 10 to 30)
workability and cohesiveness of the paste. 150 µm (No. 100) 0 to 10 (AASHTO 2 to 10)
83
Design and Control of Concrete Mixtures ◆ EB001
ceeded, the fine aggregate should be rejected unless Table 5-4. Determination of Fineness Modulus of
suitable adjustments are made in proportions of fine Fine Aggregates
and coarse aggregate. Percentage
The amounts of fine aggregate passing the 300 µm of individual Cumulative
(No. 50) and 150, µm (No. 100) sieves affect workability, fraction Percentage percentage
retained, passing, retained,
surface texture, air content, and bleeding of concrete. Most
Sieve size by mass by mass by mass
specifications allow 5% to 30% to pass the 300 µm (No. 50)
9.5 mm (3⁄8 in.) 0 100 0
sieve. The lower limit may be sufficient for easy placing 4.75 mm (No. 4) 2 98 2
conditions or where concrete is mechanically finished, 2.36 mm (No. 8) 13 85 15
such as in pavements. However, for hand-finished 1.18 mm (No. 16) 20 65 35
concrete floors, or where a smooth surface texture is de- 600 µm (No. 30) 20 45 55
sired, fine aggregate with at least 15% passing the 300 µm 300 µm (No. 50) 24 21 79
(No. 50) sieve and 3% or more passing the 150 µm (No. 150 µm (No. 100) 18 3 97
Pan 3 0 —
100) sieve should be used.
Total 100 283
Video Fineness Modulus. The fineness modulus (FM) of either Fineness modulus
fine or coarse aggregate according to ASTM C 125 is calcu- = 283 ÷ 100 = 2.83
lated by adding the cumulative percentages by mass
retained on each of a specified series of sieves and divid-
ing the sum by 100. The specified sieves for determining given maximum-size coarse aggregate can be varied over
FM are: 150 µm (No. 100), 300 µm (No. 50), 600 µm (No. a moderate range without appreciable effect on cement
30), 1.18 mm (No. 16), 2.36 mm (No. 8), 4.75 mm (No. 4), and water requirement of a mixture if the proportion of
9.5 mm (3⁄8 in.), 19.0 mm (3⁄4 in.), 37.5 mm (11⁄2 in.), 75 mm fine aggregate to total aggregate produces concrete of
(3 in.) and, 150 mm (6 in.). good workability. Mixture proportions should be changed
FM is an index of the fineness of an aggregate—the to produce workable concrete if wide variations occur in
higher the FM, the coarser the aggregate. Different aggre- the coarse-aggregate grading. Since variations are difficult
gate grading may have the same FM. FM of fine aggregate
to anticipate, it is often more economical to maintain
is useful in estimating proportions of fine and coarse
uniformity in manufacturing and handling coarse aggre-
aggregates in concrete mixtures. An example of how the
gate than to reduce variations in gradation.
FM of a fine aggregate is determined (with an assumed
The maximum size of coarse aggregate used in con-
sieve analysis) is shown in Table 5-4.
Degradation of fine aggregate due to friction and crete has a bearing on the economy of concrete. Usually
abrasion will decrease the FM and increase the amount of more water and cement is required for small-size aggre-
materials finer than the 75 µm (No. 200) sieve. gates than for large sizes, due to an increase in total aggre-
gate surface area. The water and cement required for a
slump of approximately 75 mm (3 in.) is shown in Fig. 5-9
Coarse-Aggregate Grading for a wide range of coarse-aggregate sizes. Fig. 5-9 shows
The coarse aggregate grading requirements of ASTM C 33 that, for a given water-cement ratio, the amount of cement
(AASHTO M 80) permit a wide range in grading and a required decreases as the maximum size of coarse aggre-
variety of grading sizes (see Table 5-5). The grading for a gate increases. The increased cost of obtaining and/or
Table 5-5. Grading Requirements for Coarse Aggregates (ASTM C 33 and AASHTO M 80)
Amounts finer than each laboratory sieve, mass percent passing
Size Nominal size, sieves 100 mm 90 mm 75 mm 63 mm 50 mm
number with square openings (4 in.) (31⁄2 in.) (3 in.) (21⁄2 in.) (2 in.)
1 90 to 37.5 mm (31⁄2 to 11⁄2 in.) 100 90 to 100 — 25 to 60 —
2 63 to 37.5 mm (21⁄2 to 11⁄2 in.) — — 100 90 to 100 35 to 70
3 50 to 25.0 mm (2 to 1 in.) — — — 100 90 to 100
357 50 to 4.75 mm (2 in. to No. 4) — — — 100 95 to 100
4 37.5 to 19.0 mm (11⁄2 to 3⁄4 in.) — — — — 100
467 37.5 to 4.75 mm (11⁄2 in. to No. 4) — — — — 100
5 25.0 to 12.5 mm (1 to 1⁄2 in.) — — — — —
56 25.0 to 9.5 mm (1 to 3⁄8 in.) — — — — —
57 25.0 to 4.75 mm (1 in. to No. 4) — — — — —
6 19.0 to 9.5 mm (3⁄4 to 3⁄8 in.) — — — — —
67 19.0 to 4.75 mm (3⁄4 in. to No. 4) — — — — —
7 12.5 to 4.75 mm (1⁄2 in. to No. 4) — — — — —
8 9.5 to 2.36 mm (3⁄8 in. to No. 8) — — — — —
84
Chapter 5 ◆ Aggregates for Concrete
Maximum nominal size of aggregate, in. handling aggregates much larger than 50 mm (2 in.) may
3/16 3/8 1/2 3/4 1 11/2 2 3 43/8
300 offset the savings in using less cement. Furthermore,
500
aggregates of different maximum sizes may give slightly
different concrete strengths for the same water-cement
Non-air-entrained concrete 400 ratio. In some instances, at the same water-cement ratio,
concrete with a smaller maximum-size aggregate could
200 have higher compressive strength. This is especially true
for high-strength concrete. The optimum maximum size
Water, kg/m3
Water, lb/yd3
300
of coarse aggregate for higher strength depends on factors
Air-entrained concrete such as relative strength of the cement paste, cement-
200 aggregate bond, and strength of the aggregate particles.
100
The terminology used to specify size of coarse aggre-
gate must be chosen carefully. Particle size is determined
100
by size of sieve and applies to the aggregate passing that
Slump approximately 75 mm (3 in.)
w/c ratio: 0.54 by mass
sieve and not passing the next smaller sieve. When speak-
ing of an assortment of particle sizes, the size number (or
0 0
grading size) of the gradation is used. The size number
450
applies to the collective amount of aggregate that passes
700 through an assortment of sieves. As shown in Table 5-5,
400 the amount of aggregate passing the respective sieves is
given in percentages; it is called a sieve analysis.
Non-air-entrained concrete
Because of past usage, there is sometimes confusion
600
about what is meant by the maximum size of aggregate.
Cement, kg/m3
Cement, lb/yd3
350
ASTM C 125 and ACI 116 define this term and distinguish
it from nominal maximum size of aggregate. The maxi-
300 500 mum size of an aggregate is the smallest sieve that all of a
Air-entrained concrete
particular aggregate must pass through. The nominal
maximum size of an aggregate is the smallest sieve size
250
400
through which the major portion of the aggregate must
Slump approximately 75 mm (3 in.) pass. The nominal maximum-size sieve may retain 5% to
w/c ratio: 0.54 by mass
15% of the aggregate depending on the size number. For
200
example, aggregate size number 67 has a maximum size of
4.75 9.5 12.5 19.0 25.0 37.5 50.0 75.0 112.0
Maximum nominal size of aggregate, mm
25 mm (1 in.) and a nominal maximum size of 19 mm (3⁄4
in.). Ninety to one hundred percent of this aggregate must
Fig. 5-9. Cement and water contents in relation to maximum pass the 19-mm (3⁄4-in.) sieve and all of the particles must
size of aggregate for air-entrained and non-air-entrained con- pass the 25-mm (1-in.) sieve.
crete. Less cement and water are required in mixtures having
large coarse aggregate (Bureau of Reclamation 1981). The maximum size of aggregate that can be used
generally depends on the size and shape of the concrete
member and the amount and distribution of reinforcing
steel. The maximum size of aggregate particles generally
should not exceed:
85
Design and Control of Concrete Mixtures ◆ EB001
1. One-fifth the narrowest dimension of a concrete • The optimum mixture has the least particle interfer-
member ence and responds best to a high frequency, high
2. Three-quarters the clear spacing between reinforcing amplitude vibrator.
bars and between the reinforcing bars and forms However, this optimum mixture cannot be used for
3. One-third the depth of slabs all construction due to variations in placing and finishing
These requirements may be waived if, in the judg- needs and availability. Crouch (2000) found in his studies
ment of the engineer, the mixture possesses sufficient on air-entrained concrete that the water-cement ratio
workability that the concrete can be properly placed with- could be reduced by over 8% using combined aggregate
out honeycomb or voids. gradation. Shilstone (1990) also analyzes aggregate grada-
tion by coarseness and workability factors to improve
Combined Aggregate Grading aggregate gradation.
75
45
37.
25.
19.
12.
4.7
2.3
1.1
5
0.6
0.3
0.1
0.0
0.0
86
Chapter 5 ◆ Aggregates for Concrete
87
Design and Control of Concrete Mixtures ◆ EB001
30 Medium
The absorption and surface moisture of aggregates should grading
rodded fine aggregate
88
Chapter 5 ◆ Aggregates for Concrete
dated beforehand. Fig. 5-13 illustrates how the amount of with higher porosity values and medium-sized pores (0.1
bulking of fine aggregate varies with moisture content and to 5 µm) that are easily saturated and cause concrete dete-
grading; fine gradings bulk more than coarse gradings for rioration and popouts. Larger pores do not usually be-
a given amount of moisture. Fig. 5-14 shows similar infor- come saturated or cause concrete distress, and water in
mation in terms of weight for a particular fine aggregate. very fine pores may not freeze readily.
Since most fine aggregates are delivered in a damp condi- At any freezing rate, there may be a critical particle size
tion, wide variations can occur in batch quantities if batch- above which a particle will fail if frozen when critically
ing is done by volume. For this reason, good practice has saturated. This critical size is dependent upon the rate of
long favored weighing the aggregate and adjusting for freezing and the porosity, permeability, and tensile strength
moisture content when proportioning concrete. of the particle. For fine-grained aggregates with low perme-
ability (cherts for example), the critical particle size may be
Resistance to Freezing and Thawing within the range of normal aggregate sizes. It is higher for
coarse-grained materials or those with capillary systems
The frost resistance of an aggregate, an important charac- interrupted by numerous macropores (voids too large to
teristic for exterior concrete, is related to its porosity, hold moisture by capillary action). For these aggregates the
absorption, permeability, and pore structure. An aggre- critical particle size may be sufficiently large to be of no
gate particle may absorb so much water (to critical satura- consequence, even though the absorption may be high. If
tion) that it cannot accommodate the expansion and potentially vulnerable aggregates are used in concrete
hydraulic pressure that occurs during the freezing of subjected to periodic drying while in service, they may
water. If enough of the offending particles are present, the never become sufficiently saturated to cause failure.
result can be expansion of the aggregate and possible Cracking of concrete pavements caused by the freeze-
disintegration of the concrete. If a single problem particle thaw deterioration of the aggregate within concrete is
is near the surface of the concrete, it can cause a popout. called D-cracking. This type of cracking has been ob-
Popouts generally appear as conical fragments that break served in some pavements after three or more years of
out of the concrete surface. The offending aggregate parti- service. D-cracked concrete resembles frost-damaged
cle or a part of it is usually found at the bottom of the void. concrete caused by paste deterioration. D-cracks are
Generally it is coarse rather than fine aggregate particles closely spaced crack formations parallel to transverse and
longitudinal joints that later multiply outward from the
joints toward the center of the pavement panel (Fig. 5-15).
D-cracking is a function of the pore properties of certain
Bulking, percent by volume
30
types of aggregate particles and the environment in which
the pavement is placed. Due to the natural accumulation
20
of water under pavements in the base and subbase layers,
10 the aggregate may eventually become saturated. Then
2480
150
2280
140
2080 130
Bulk density, kg/m3
110
1680
100
1480
90
1280 80
0 2 4 6 8 10 12 14 16 18 20
Moisture in fine aggregate, percent by mass
Fig. 5-14. Bulk density is compared with the moisture con- Fig. 5-15. D-cracking along a transverse joint caused by
tent for a particular sand (PCA Major Series 172). failure of carbonate coarse aggregate (Stark 1976). (30639)
89
Design and Control of Concrete Mixtures ◆ EB001
with freezing and thawing cycles, cracking of the concrete ovendried and the percentage of weight loss calculated.
starts in the saturated aggregate (Fig. 5-16) at the bottom Unfortunately, this test is sometimes misleading.
of the slab and progresses upward until it reaches the Aggregates behaving satisfactorily in the test might
wearing surface. This problem can be reduced either by produce concrete with low freeze-thaw resistance;
selecting aggregates that perform better in freeze-thaw conversely, aggregates performing poorly might produce
cycles or, where marginal aggregates must be used, by concrete with adequate resistance. This is attributed, at
reducing the maximum particle size. Also, installation of least in part, to the fact that the aggregates in the test are
effective drainage systems for carrying free water out not confined by cement paste (as they would be in
from under the pavement may be helpful. concrete) and the mechanisms of attack are not the same as
The performance of aggregates under exposure to in freezing and thawing. The test is most reliable for strat-
freezing and thawing can be evaluated in two ways: (1) ified rocks with porous layers or weak bedding planes.
past performance in the field, and (2) laboratory freeze- An additional test that can be used to evaluate aggre-
thaw tests of concrete specimens. If aggregates from the gates for potential D-cracking is the rapid pressure release
same source have previously given satisfactory service method. An aggregate is placed in a pressurized chamber
when used in concrete, they might be considered suitable. and the pressure is rapidly released causing the aggregate
Aggregates not having a service record can be considered with a questionable pore system to fracture (Janssen and
acceptable if they perform satisfactorily in air-entrained Snyder 1994). The amount of fracturing relates to the
concretes subjected to freeze-thaw tests according to potential for D-cracking.
ASTM C 666 (AASHTO T 161). In these tests concrete spe-
cimens made with the aggregate in question are subjected Wetting and Drying Properties
to alternate cycles of freezing and thawing in water.
Deterioration is measured by (1) the reduction in the Weathering due to wetting and drying can also affect the
dynamic modulus of elasticity, (2) linear expansion, and durability of aggregates. The expansion and contraction
(3) weight loss of the specimens. An expansion failure coefficients of rocks vary with temperature and moisture
criterion of 0.035% in 350 freeze-thaw cycles or less is used content. If alternate wetting and drying occurs, severe
by a number of state highway departments to help indi- strain can develop in some aggregates, and with certain
cate whether or not an aggregate is susceptible to D-crack- types of rock this can cause a permanent increase in
ing. Different aggregate types may influence the criteria volume of the concrete and eventual breakdown. Clay
levels and empirical correlations between laboratory lumps and other friable particles can degrade rapidly with
freeze-thaw tests. Field service records should be made to repeated wetting and drying. Popouts can also develop
select the proper criterion (Vogler and Grove 1989). due to the moisture-swelling characteristics of certain
Specifications may require that resistance to weather- aggregates, especially clay balls and shales. While no
ing be demonstrated by a sodium sulfate or magnesium specific tests are available to determine this tendency, an
sulfate test (ASTM C 88 or AASHTO T 104). The test experienced petrographer can often be of assistance in
consists of a number of immersion cycles for a sample of determining this potential for distress.
the aggregate in a sulfate solution; this creates a pressure
through salt-crystal growth in the aggregate pores similar Abrasion and Skid Resistance
to that produced by freezing water. The sample is then
The abrasion resistance of an aggregate is often used as a
general index of its quality. Abrasion resistance is essential
when the aggregate is to be used in concrete subject to
abrasion, as in heavy-duty floors or pavements. Low abra-
sion resistance of an aggregate may increase the quantity
of fines in the concrete during mixing; consequently, this
may increase the water requirement and require an adjust-
ment in the water-cement ratio.
The most common test for abrasion resistance is the
Los Angeles abrasion test (rattler method) performed in
accordance with ASTM C 131 (AASHTO T 96) or ASTM C
535. In this test a specified quantity of aggregate is placed
in a steel drum containing steel balls, the drum is rotated,
and the percentage of material worn away is measured.
Specifications often set an upper limit on this mass loss.
However, a comparison of the results of aggregate abra-
Fig. 5-16. Fractured carbonate aggregate particle as a
source of distress in D-cracking (magnification 2.5X) (Stark sion tests with the abrasion resistance of concrete made
1976). (30639-A) with the same aggregate do not generally show a clear
90
Chapter 5 ◆ Aggregates for Concrete
0.02
Strength and Shrinkage
0.00
The strength of an aggregate is rarely tested and generally Sandstone Slate Granite Limestone Quartz
does not influence the strength of conventional concrete as
Fig. 5-17. Concretes containing sandstone or slate produce
much as the strength of the paste and the paste-aggregate
a high shrinkage concrete. Granite, limestone and quartz,
bond. However, aggregate strength does become important are low shrinkage-producing aggregates (ACI 221R).
in high-strength concrete. Aggregate stress levels in concrete
are often much higher than the average stress over the entire
cross section of the concrete. Aggregate tensile strengths
concrete. Siliceous aggregate should be avoided when
range from 2 to 15 MPa (300 to 2300 psi) and compressive
strong solutions of sodium hydroxide are present, as these
strengths from 65 to 270 MPa (10,000 to 40,000 psi).
solutions attack this type of aggregate.
Different aggregate types have different compressibil-
Acid rain (often with a pH of 4 to 4.5) can slightly etch
ity, modulus of elasticity, and moisture-related shrinkage
concrete surfaces, usually without affecting the perform-
characteristics that can influence the same properties in
ance of exposed concrete structures. Extreme acid rain or
concrete. Aggregates with high absorption may have high
strong acid water conditions may warrant special concrete
shrinkage on drying. Quartz and feldspar aggregates,
designs or precautions, especially in submerged areas.
along with limestone, dolomite, and granite, are consid- Continuous replenishment in acid with a pH of less than
ered low shrinkage aggregates; while aggregates with 4 is considered highly aggressive to buried concrete, such
sandstone, shale, slate, hornblende, and graywacke are as pipe (Scanlon 1987). Concrete continuously exposed to
often associated with high shrinkage in concrete (Fig. 5-17). liquid with a pH of less than 3 should be protected in a
manner similar to concrete exposed to dilute acid solu-
Resistance to Acid and tions (ACI 515.1R).
Other Corrosive Substances Natural waters usually have a pH of more than 7 and
seldom less than 6. Waters with a pH greater than 6.5 may
Portland cement concrete is durable in most natural envi- be aggressive if they contain bicarbonates. Carbonic acid
ronments; however, concrete in service is occasionally solutions with concentrations between 0.9 and 3 parts per
exposed to substances that will attack it. million are considered to be destructive to concrete (ACI
Most acidic solutions will slowly or rapidly disinte- 515.1R and Kerkhoff 2001).
grate portland cement concrete depending on the type and A low water-cement ratio, low permeability, and low-
concentration of acid. Certain acids, such as oxalic acid, are to-moderate cement content can increase the acid or corro-
harmless. Weak solutions of some acids have insignificant sion resistance of concrete. A low permeability resulting
effects. Although acids generally attack and leach away the from a low water-cement ratio or the use of silica fume or
calcium compounds of the cement paste, they may not other pozzolans, helps keep the corrosive agent from
readily attack certain aggregates, such as siliceous aggre- penetrating into the concrete. Low-to-moderate cement
gates. Calcareous aggregates often react readily with acids. contents result in less available paste to attack. The use of
However, the sacrificial effect of calcareous aggregates is sacrificial calcareous aggregates should be considered
often a benefit over siliceous aggregate in mild acid expo- where indicated.
sures or in areas where water is not flowing. With calcare- Certain acids, gases, salts, and other substances that
ous aggregate, the acid attacks the entire exposed concrete are not mentioned here also can disintegrate concrete.
surface uniformly, reducing the rate of attack on the paste Acids and other chemicals that severely attack portland
and preventing loss of aggregate particles at the surface. cement concrete should be prevented from coming in
Calcareous aggregates also tend to neutralize the acid, contact with the concrete by using protective coatings
especially in stagnant locations. Acids can also discolor (Kerkhoff 2001).
91
Design and Control of Concrete Mixtures ◆ EB001
Fire Resistance and Thermal Properties Table 5-6. Harmful Materials in Aggregates
Effect on Test
The fire resistance and thermal properties of concrete— Substances concrete designation
conductivity, diffusivity, and coefficient of thermal expan- Organic Affects setting ASTM C 40 (AASHTO T 21)
sion—depend to some extent on the mineral constituents impurities and hardening, ASTM C 87 (AASHTO T 71)
of the aggregates used. Manufactured and some naturally may cause
occurring lightweight aggregates are more fire resistant deterioration
than normal-weight aggregates due to their insulating Materials finer Affects bond, ASTM C 117 (AASHTO T 11)
than the 75-µm increases water
properties and high-temperature stability. Concrete
(No. 200) sieve requirement
containing a calcareous coarse aggregate performs better
Coal, lignite, Affects durability, ASTM C 123 (AASHTO T 113)
under fire exposure than a concrete containing quartz or or other may cause
siliceous aggregate such as granite or quartzite. At about lightweight stains and
590°C (1060°F), quartz expands 0.85% causing disruptive materials popouts
expansion (ACI 216 and ACI 221). The coefficient of ther- Soft particles Affects durability ASTM C 235
mal expansion of aggregates ranges from 0.55 x 10-6 per °C Clay lumps Affects work- ASTM C 142 (AASHTO T 112)
to 5 x 10-6 per °C (1 x 10-6 per °F to 9 x 10-6 per °F). For and friable ability and
more information refer to Chapter 15 for temperature- particles durability, may
cause popouts
induced volume changes and to Chapter 18 for thermal
conductivity and mass concrete considerations. Chert of less Affects ASTM C 123 (AASHTO T 113)
than 2.40 durability, may ASTM C 295
relative density cause popouts
Alkali-reactive Causes ASTM C 227
POTENTIALLY HARMFUL MATERIALS aggregates abnormal ASTM C 289
expansion, ASTM C 295
Harmful substances that may be present in aggregates map cracking, ASTM C 342
include organic impurities, silt, clay, shale, iron oxide, coal, and popouts ASTM C 586
lignite, and certain lightweight and soft particles (Table ASTM C 1260 (AASHTO T 303)
5-6). In addition, rocks and minerals such as some cherts, ASTM C 1293
strained quartz (Buck and Mather 1984), and certain dolo-
mitic limestones are alkali reactive (see Table 5-7). Gypsum
and anhydrite may cause sulfate attack. Certain aggre-
gates, such as some shales, will cause popouts by swelling Table 5-7. Some Potentially Harmful Reactive
(simply by absorbing water) or by freezing of absorbed Minerals, Rock, and Synthetic Materials
water (Fig. 5-18). Most specifications limit the permissible
amounts of these substances. The performance history of Alkali-carbonate
Alkali-silica reactive substances* reactive substances**
an aggregate should be a determining factor in setting the
limits for harmful substances. Test methods for detecting Andesites Opal Calcitic dolomites
Argillites Opaline shales Dolomitic limestones
harmful substances qualitatively or quantitatively are
Certain siliceous Phylites Fine-grained dolomites
listed in Table 5-6.
limestones Quartzites
Aggregates are potentially harmful if they contain and dolomites Quartzoses
compounds known to react chemically with portland Chalcedonic cherts Cherts
cement concrete and produce any of the following: (1) Chalcedony Rhyolites
significant volume changes of the paste, aggregates, or Cristobalite Schists
both; (2) interference with the normal hydration of Dacites Siliceous shales
cement; and (3) otherwise harmful byproducts. Glassy or Strained quartz
Organic impurities may delay setting and hardening cryptocrystalline and certain
Video volcanics other forms
of concrete, may reduce strength gain, and in unusual
Granite gneiss of quartz
cases may cause deterioration. Organic impurities such as
Graywackes Synthetic and
peat, humus, and organic loam may not be as detrimental
Metagraywackes natural silicious
but should be avoided. glass
Video Materials finer than the 75-µm (No. 200) sieve, espe- Tridymite
cially silt and clay, may be present as loose dust and may
form a coating on the aggregate particles. Even thin coat- * Several of the rocks listed (granite gneiss and certain quartz for-
mations for example) react very slowly and may not show evi-
ings of silt or clay on gravel particles can be harmful dence of any harmful degree of reactivity until the concrete is over
because they may weaken the bond between the cement 20 years old.
** Only certain sources of these materials have shown reactivity.
paste and aggregate. If certain types of silt or clay are pres-
ent in excessive amounts, water requirements may
increase significantly.
92
Chapter 5 ◆ Aggregates for Concrete
ALKALI-AGGREGATE
REACTIVITY
Fig. 5-19. Iron oxide stain
Aggregates containing certain caused by impurities in the
constituents can react with coarse aggregate. (70024)
Fig. 5-18. A popout is the breaking away of a small frag- alkali hydroxides in concrete.
ment of concrete surface due to internal pressure that
The reactivity is potentially
leaves a shallow, typically conical depression. (113)
harmful only when it produces significant expansion
(Mather 1975). This alkali-aggregate reactivity (AAR) has
There is a tendency for some fine aggregates to two forms—alkali-silica reaction (ASR) and alkali-carbonate
degrade from the grinding action in a concrete mixer; this reaction (ACR). ASR is of more concern than ACR because
effect, which is measured using ASTM C 1137, may alter the occurrence of aggregates containing reactive silica
mixing water, entrained air and slump requirements. minerals is more common. Alkali-reactive carbonate aggre-
Coal or lignite, or other low-density materials such as gates have a specific composition that is not very common.
Video Alkali-silica reactivity has been recognized as a poten-
wood or fibrous materials, in excessive amounts will affect
tial source of distress in concrete since the late 1930s
the durability of concrete. If these impurities occur at or
(Stanton 1940 and PCA 1940). Even though potentially
near the surface, they might disintegrate, pop out, or
reactive aggregates exist throughout North America, ASR
cause stains. Potentially harmful chert in coarse aggregate
distress in structural concrete is not common. There are a
can be identified by using ASTM C 123 (AASHTO T 113).
number of reasons for this:
Video Soft particles in coarse aggregate are especially objec-
tionable because they cause popouts and can affect dura- • Most aggregates are chemically stable in hydraulic-
bility and wear resistance of concrete. If friable, they could cement concrete.
break up during mixing and thereby increase the amount • Aggregates with good service records are abundant in
of water required. Where abrasion resistance is critical, many areas.
such as in heavy-duty industrial floors, testing may indi- • Most concrete in service is dry enough to inhibit ASR.
cate that further investigation or another aggregate source • Use of certain pozzolans or slags can control ASR.
is warranted. • In many concrete mixtures, the alkali content of the
Clay lumps present in concrete may absorb some of concrete is low enough to control harmful ASR.
• Some forms of ASR do not produce significant delete-
the mixing water, cause popouts in hardened concrete,
rious expansion.
and affect durability and wear resistance. They can also
break up during mixing and thereby increase the mixing- To reduce ASR potential requires understanding the
water demand. ASR mechanism; properly using tests to identify poten-
Aggregates can occasionally contain particles of iron tially reactive aggregates; and, if needed, taking steps to
oxide and iron sulfide that result in unsightly stains on minimize the potential for expansion and related cracking.
exposed concrete surfaces (Fig. 5-19). The aggregate
should meet the staining requirements of ASTM C 330
(AASHTO M 195) when tested according to ASTM C 641;
Alkali-Silica Reaction
the quarry face and aggregate stockpiles should not show Visual Symptoms of Expansive ASR. Typical indicators
evidence of staining. of ASR might be any of the following: a network of cracks
As an additional aid in identifying staining particles, (Fig. 5-20); closed or spalled joints; relative displacements
the aggregate can be immersed in a lime slurry. If staining of different parts of a structure; or fragments breaking out
particles are present, a blue-green gelatinous precipitate of the surface of the concrete (popouts) (Fig. 5-21). Because
will form within 5 to 10 minutes; this will rapidly change ASR deterioration is slow, the risk of catastrophic failure is
to a brown color on exposure to air and light. The reaction low. However, ASR can cause serviceability problems and
should be complete within 30 minutes. If no brown gelat- can exacerbate other deterioration mechanisms such as
inous precipitate is formed when a suspect aggregate is those that occur in frost, deicer, or sulfate exposures.
93
Design and Control of Concrete Mixtures ◆ EB001
94
Chapter 5 ◆ Aggregates for Concrete
0.3
Identification of Potentially Reactive Aggregates. Field Sudbury aggregate
performance history is the best method of evaluating the
susceptibility of an aggregate to ASR. For the most defini- 0.25
tive evaluation, the existing concrete should have been in
service for at least 15 years. Comparisons should be made 0.10% expansion limit for evaluating
14-Day expansion, %
0.2
effectiveness of supplementary
between the existing and proposed concrete’s mix propor- cementitious materials against AAR
tions, ingredients, and service environments. This process
0.15
should tell whether special requirements are needed, are
not needed, or whether testing of the aggregate or job
concrete is required. The use of newer, faster test methods 0.1
can be utilized for initial screening. Where uncertainties
arise, lengthier tests can be used to confirm results. Table 0.05
5-8 describes different test methods used to evaluate
potential alkali-silica reactivity. These tests should not be
0
used to disqualify use of potentially reactive aggregates,
20 30 56 35 50 65 7.5 10 12.5
as reactive aggregates can be safely used with the careful Control % Fly ash % Slag % Silica fume
selection of cementitious materials as discussed below.
Fig. 5-23. Influence of different amounts of fly ash, slag,
Materials and Methods to Control ASR. The most effec- and silica fume by mass of cementing material on mortar
tive way of controlling expansion due to ASR is to design bar expansion (ASTM C 1260) after 14 days when using
mixtures specifically to control ASR, preferably using reactive aggregate (Fournier 1997).
locally available materials. The following options are not
listed in priority order and, although usually not neces-
sary, they can be used in combination with one another.
In North America, current practices include the use of ness must be determined by tests such as ASTM C 1260
a supplementary cementitious material or blended cement (modified) or C 1293. Where applicable, different amounts
proven by testing to control ASR or limiting the alkali of pozzolan or slag should be tested to determine the opti-
content of the concrete. Supplementary cementitious mate- mum dosage. Expansion usually decreases as the dosage
rials include fly ash, ground granulated blast-furnace slag, of the pozzolan or slag increases (see Fig. 5-23). Lithium-
silica fume, and natural pozzolans. Blended cements use based admixtures are also available to control ASR. Lime-
slag, fly ash, silica fume, and natural pozzolans to control stone sweetening (the popular term for replacing
ASR. Low-alkali portland cement (ASTM C 150) with an approximately 30% of the reactive sand-gravel aggregate
alkali content of not more than 0.60% (equivalent sodium with crushed limestone) is effective in controlling deterio-
oxide) can be used to control ASR. Its use has been success- ration in some sand-gravel aggregate concretes. See
ful with slightly reactive to moderately reactive aggre- AASHTO (2001), Farny and Kosmatka (1997), and PCA
gates. However, low-alkali cements are not available in all (1998) for more information on tests to demonstrate the
areas. Thus, the use of locally available cements in combi- effectiveness of the above control measures.
nation with pozzolans, slags, or blended cements is prefer-
able for controlling ASR. When pozzolans, slags, or
Alkali-Carbonate Reaction
blended cements are used to control ASR, their effective-
Mechanism of ACR. Reactions observed with certain
dolomitic rocks are associated with alkali-carbonate reac-
tion (ACR). Reactive rocks usually contain large crystals of
dolomite scattered in and surrounded by a fine-grained
matrix of calcite and clay. Calcite is one of the mineral
forms of calcium carbonate; dolomite is the common
name for calcium-magnesium carbonate. ACR is relatively
rare because aggregates susceptible to this reaction are
usually unsuitable for use in concrete for other reasons,
such as strength potential. Argillaceous dolomitic lime-
stone contains calcite and dolomite with appreciable
amounts of clay and can contain small amounts of reactive
silica. Alkali reactivity of carbonate rocks is not usually
dependent upon its clay mineral composition (Hadley
1961). Aggregates have potential for expansive ACR if the
Fig. 5-22. Polished section view of an alkali reactive aggregate
in concrete. Observe the alkali-silica reaction rim around the following lithological characteristics exist (Ozol 1994 and
reactive aggregate and the crack formation. (43090) Swenson 1967):
95
Design and Control of Concrete Mixtures ◆ EB001
Table 5-8. Test Methods for Alkali-Silica Reactivity (Farny and Kosmatka 1997)
Test name Purpose Type of test Type of sample
ASTM C 227, To test the susceptibility of Mortar bars stored over At least 4 mortar bars of
Potential alkali-reactivity cement-aggregate com- water at 37.8°C (100°F) standard dimensions:
of cement-aggregate binations to expansive and high relative 25 x 25 x 285 mm
combinations reactions involving humidity (1 x 1 x 111⁄4 in.)
(mortar-bar method) alkalies
ASTM C 289, To determine potential Sample reacted with Three 25-gram samples
Potential alkali-silica reactivity of siliceous alkaline solution at 80°C (176°F) of crushed and sieved
reactivity of aggregates aggregates aggregate
(chemical method)
ASTM C 342, To determine the poten- Mortar bars stored in Three mortar bars per
Potential volume tial ASR expansion of water at 23°C (73.4°F) cement-aggregate
change of cement- cement-aggregate combination of standard
aggregate combinations dimensions: 25 x 25 x 285 mm
combinations (1 x 1 x 111⁄4 in.)
ASTM C 441, To determine effectiveness Mortar bars—using Pyrex At least 3 mortar bars
Effectiveness of mineral of supplementary cementing glass as aggregate— and also 3 mortar bars
admixtures or GBFS in materials in controlling stored over water at of control mixture
preventing excessive expansion from ASR 37.8°C (100°F) and
expansion of concrete high relative humidity
due to alkali-silica reaction
ASTM C 856, To outline petrographic Visual (unmagnified) At least one 150-mm
Petrographic examination procedures and microscopic exam- diameter by 300-mm long
examination of for hardened concrete— ination of prepared core (6-in. diameter by
hardened concrete useful in determining samples 12-in. long)
condition or performance
ASTM C 856 To identify products of Staining of a freshly- Varies: core with lapped
(AASHTO T 299), ASR in hardened exposed concrete surface, core with
Annex uranyl-acetate concrete surface and viewing broken surface
treatment procedure under UV light
Los Alamos staining To identify products of Staining of a freshly-exposed Varies: core with lapped
method ASR in hardened concrete surface with two surface, core with
(Powers 1999) concrete different reagents broken surface
ASTM C 1260 To test the potential for Immersion of mortar At least 3 mortar bars
(AASHTO T 303), deleterious alkali-silica bars in alkaline
Potential alkali-reactivity reaction of aggregate solution at 80°C (176°F)
of aggregates (mortar- in mortar bars
bar method)
ASTM C 1293, To determine the Concrete prisms stored Three prisms per cement-
Determination of length potential ASR expansion over water at 38°C (100.4°F) aggregate combination of
change of concrete of cement-aggregate standard dimensions:
due to alkali-silica combinations 75 x 75 x 285 mm
reaction (concrete (3 x 3 x 111⁄4 in.)
prism test)
Accelerated concrete To determine the Concrete prisms stored Three prisms per cement-
prism test (modified potential ASR expansion stored over water aggregate combination of
ASTM C 1293) of cement-aggregate at 60°C (140°F) standard dimensions:
combinations 75 x 75 x 285 mm
(3 x 3 x 111⁄4 in.)
96
Chapter 5 ◆ Aggregates for Concrete
Varies: first measure- Length change Per ASTM C 989, minimum Highly reactive artificial
ment at 14 days, then 1,2, 75% reduction in expansion aggregate may not represent
3,4,5,9, and 12 months; or 0.020% maximum expan- real aggregate conditions.
every 6 months after sion or per ASTM C 618, com- Pyrex contains alkalies.
that as necessary parison against low-alkali
control
Short duration—includes Is the aggregate known See measurement—this Specimens can be examined
preparation of samples to be reactive? examination determines with stereomicroscopes,
and visual and micro- Orientation and if ASR reactions have polarizing microscopes,
scope examination geometry of cracks. taken place and their metallographic microscopes,
Is there any gel effects upon the concrete. and scanning electron
present? Used in conjunction with microscope.
other tests.
Immediate results Intensity of Lack of fluorescence Identifies small amounts of
fluorescence ASR gel whether they cause
expansion or not.
Opal, a natural aggregate,
and carbonated paste can
Immediate results Color of stain Dark pink stain corresponds glow—interpret results
to ASR gel and indicates an accordingly.
advanced state of Tests must be supplemented
degradation by petrographic examination
and physical tests for deter-
mining concrete expansion.
16 days Length change If greater than 0.10%, Very fast alternative to C 227.
go to supplementary test Useful for slowly reacting
procedures; if greater than aggregates or those that
0.20%, indicative of poten- produce expansion late in
tial deleterious expansion the reaction.
Varies: first measure- Length change Per Appendix X1, potentially Requires long test duration
ment at 7 days, then 28 deleteriously reactive if ex- for meaningful results.
and 56 days, then 3,6,9, pansion equals or exceeds Use as a supplement to C 227,
and 12 months; every 0.04% at one year C 295, C 289, and C 1260.
6 months as after that as Similar to CSA A23.2-14A.
necessary
3 month (91 days) Length change Potentially deleteriously Fast alternative to C 227.
reactive if expansion Good correlation to ASTM
equals or exceeds 0.04% C 227 for carbonate and
at 91 days sedimentary rocks.
97
Design and Control of Concrete Mixtures ◆ EB001
• clay content, or insoluble residue content, in the range minerals and water proportioned to have a relative density
of 5% to 25%; (specific gravity) less than that of the desirable aggregate
• calcite-to-dolomite ratio of approximately 1:1; particles but greater than that of the deleterious particles.
• increase in the dolomite volume up to a point at The heavier particles sink to the bottom while the lighter
which interlocking texture becomes a restraining particles float to the surface. This process can be used when
factor; and acceptable and harmful particles have distinguishable rela-
• small size of the discrete dolomite crystals (rhombs) tive densities.
suspended in a clay matrix. Jigging separates particles with small differences in
density by pulsating water current. Upward pulsations of
Dedolomitization. Dedolomitization, or the breaking water through a jig (a box with a perforated bottom) move
down of dolomite, is normally associated with expansive the lighter material into a layer on top of the heavier mate-
ACR (Hadley 1961). Concrete that contains dolomite and rial; the top layer is then removed.
has expanded also contains brucite (magnesium hydrox- Rising-current classification separates particles with
ide, Mg(OH)2), which is formed by dedolomitization. De- large differences in density. Light materials, such as wood
dolomitization proceeds according to the following and lignite, are floated away in a rapidly upward moving
equation (Ozol 1994): stream of water.
CaMgCO3 (dolomite) + alkali hydroxide solution → Crushing is also used to remove soft and friable parti-
MgOH2 (brucite) + CaCO3 (calcium carbonate) + cles from coarse aggregates. This process is sometimes the
K2CO3 (potassium carbonate) + alkali hydroxide only means of making material suitable for use. Unfortun-
The dedolomitization reaction and subsequent crystalliza- ately, with any process some acceptable material is always
tion of brucite may cause considerable expansion. lost and removal of all harmful particles may be difficult
Whether dedolomitization causes expansion directly or or expensive.
indirectly, it’s usually a prerequisite to other expansive
processes (Tang, Deng, Lon, and Han 1994).
HANDLING AND STORING AGGREGATES
Test Methods for Identifying ACR Distress. The three
test methods commonly used to identify potentially alkali- Aggregates should be handled and stored in a way that
carbonate reactive aggregate are: minimizes segregation and degradation and prevents
• petrographic examination (ASTM C 295); contamination by deleterious substances (Fig. 5-24). Stock-
• rock cylinder method (ASTM C 586); and piles should be built up in thin layers of uniform thickness
• concrete prism test (ASTM C 1105). to minimize segregation. The most economical and
acceptable method of forming aggregate stockpiles is the
See Farny and Kosmatka (1997) for detailed information. truck-dump method, which discharges the loads in a way
Materials and Methods to Control ACR. ACR-suscepti- that keeps them tightly joined. The aggregate is then re-
ble aggregate has a specific composition that is readily claimed with a front-end loader. The loader should re-
identified by petrographic testing. If a rock indicates ACR- move slices from the edges of the pile from bottom to top
susceptibility, one of the following preventive measures so that every slice will contain a portion of each horizon-
should be taken: tal layer.
• selective quarrying to completely avoid reactive ag-
gregate;
• blend aggregate according to Appendix in ASTM C
1105; or Video
• limit aggregate size to smallest practical.
Low-alkali cement and pozzolans are generally not very
effective in controlling expansive ACR.
98
Chapter 5 ◆ Aggregates for Concrete
When aggregates are not delivered by truck, accept- Seashells may be present in the aggregate source.
able and inexpensive results can be obtained by forming These shells are a hard material that can produce good
the stockpile in layers with a clamshell bucket (cast-and- quality concrete, however, a higher cement content may
spread method); in the case of aggregates not subject to be required. Also, due to the angularity of the shells, addi-
degradation, spreading the aggregates with a rubber-tire tional cement paste is required to obtain the desired work-
dozer and reclaiming with a front-end loader can be used. ability. Aggregate containing complete shells (uncrushed)
By spreading the material in thin layers, segregation is should be avoided as their presence may result in voids in
minimized. Whether aggregates are handled by truck, the concrete and lower the compressive strength.
bucket loader, clamshell, or conveyor belt, stockpiles Marine-dredged aggregates often contain salt from the
should not be built up in high, cone-shaped piles since this seawater. The primary salts are sodium chloride and
results in segregation. However, if circumstances necessi- magnesium sulfate and the amount of salt on the aggregate
tate construction of a conical pile, or if a stockpile has is often not more than about 1% of the mass of the mixing
segregated, gradation variations can be minimized when water. The highest salt content occurs in sands located just
the pile is reclaimed; in such cases aggregates should be above the high-tide level. Use of these aggregates with
loaded by continually moving around the circumference drinkable mix water often contributes less salt to the
of the pile to blend sizes rather than by starting on one mixture than the use of seawater (as mix water) with salt-
side and working straight through the pile. free aggregates.
Crushed aggregates segregate less than rounded Marine aggregates can be an appreciable source of
(gravel) aggregates and larger-size aggregates segregate chlorides. The presence of these chlorides may affect the
more than smaller sizes. To avoid segregation of coarse concrete by (1) altering the time of set, (2) increasing drying
shrinkage, (3) significantly increasing the risk of corrosion
aggregates, size fractions can be stockpiled and batched
of steel reinforcement, and (4) causing efflorescence.
separately. Proper stockpiling procedures, however,
Generally, marine aggregates containing large amounts of
should eliminate the need for this. Specifications provide
chloride should not be used in reinforced concrete.
a range in the amount of material permitted in any size
Marine-dredged aggregates can be washed with fresh
fraction partly because of segregation in stockpiling and
water to reduce the salt content. There is no maximum
batching operations.
limit on the salt content of coarse or fine aggregate;
Washed aggregates should be stockpiled in sufficient
however, the chloride limits presented in Chapter 9
time before use so that they can drain to a uniform mois-
should be followed.
ture content. Damp fine material has less tendency to
segregate than dry material. When dry fine aggregate is
dropped from buckets or conveyors, wind can blow away RECYCLED-CONCRETE AGGREGATE
the fines; this should be avoided if possible.
Bulkheads or dividers should be used to avoid In recent years, the concept of using old concrete pave-
contamination of aggregate stockpiles. Partitions between ments, buildings, and other structures as a source of aggre-
stockpiles should be high enough to prevent intermingling gate has been demonstrated on several projects, resulting
of materials. Storage bins should be circular or nearly in both material and energy savings (ECCO 1999). The
square. Their bottoms should slope not less than 50 procedure involves (1) breaking up and removing the old
degrees from the horizontal on all sides to a center outlet. concrete, (2) crushing in primary and secondary crushers
When loading the bin, the material should fall vertically (Fig. 5-25), (3) removing reinforcing steel and other embed-
over the outlet into the bin. Chuting the material into a bin
at an angle and against the bin sides will cause segregation.
Baffle plates or dividers will help minimize segregation.
Bins should be kept as full as possible since this reduces
breakage of aggregate particles and the tendency to segre-
gate. Recommended methods of handling and storing
aggregates are discussed at length in Matthews (1965 to
1967), NCHRP (1967), and Bureau of Reclamation (1981).
MARINE-DREDGED AGGREGATE
Marine-dredged aggregate from tidal estuaries and sand
and gravel from the seashore can be used with caution in
some concrete applications when other aggregate sources
are not available. Aggregates obtained from seabeds have Fig. 5-25. Heavily reinforced concrete is crushed with a
two problems: (1) seashells and (2) salt. beamcrusher. (69779)
99
Design and Control of Concrete Mixtures ◆ EB001
ded items, (4) grading and washing, and (5) finally stock- 12
piling the resulting coarse and fine aggregate (Fig. 5-26).
Dirt, gypsum board, wood, and other foreign materials 10
from 3% to 10%, depending on the concrete being recy- Recycled Natural Lightweight
cled; this absorption lies between those values for natural Aggregate size
and lightweight aggregate. The values increase as coarse Fig. 5-27. Comparison of water absorption of three different
particle size decreases (Fig. 5-27). The high absorption of recycled aggregate particle sizes and one size of natural and
the recycled aggregate makes it necessary to add more lightweight coarse aggregate. (Kerkhoff and Siebel 2001)
water to achieve the same workability and slump than for
concrete with conventional aggregates. Dry recycled
aggregate absorbs water during and after mixing. To
avoid this, recycled aggregate should be prewetted or adequate compressive strength. The use of recycled fine
stockpiles should be kept moist. aggregate can result in minor compressive strength reduc-
The particle shape of recycled-concrete aggregate is tions. However, drying shrinkage and creep of concrete
similar to crushed rock as shown in Fig. 5-28. The relative made with recycled aggregates is up to 100% higher than
density decreases progressively as particle size decreases. concrete with a corresponding conventional aggregate.
The sulfate content of recycled-concrete aggregate should This is due to the large amount of old cement paste and
be determined to assess the possibility of deleterious mortar especially in the fine aggregate. Therefore, consid-
sulfate reactivity. The chloride content should also be erably lower values of drying shrinkage can be achieved
determined where applicable. using recycled coarse aggregate with natural sand
New concrete made from recycled-concrete aggregate (Kerkhoff and Siebel 2001). As with any new aggregate
generally has good durability. Carbonation, permeability, source, recycled-concrete aggregate should be tested for
and resistance to freeze-thaw action have been found to be durability, gradation, and other properties.
the same or even better than concrete with conventional Recycled concrete used as coarse aggregate in new
aggregates. Concrete made with recycled coarse aggre- concrete possesses some potential for alkali-silica-reaction
gates and conventional fine aggregate can obtain an if the old concrete contained alkali-reactive aggregate. The
Fig. 5-26. Stockpile of recycled-concrete aggregate. (69813) Fig. 5-28. Recycled-concrete aggregate. (69812)
100
Chapter 5 ◆ Aggregates for Concrete
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